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Lunar and Planetary Science XXXV: Moon and Mercury

The session" Moon and Mercury" included the following reports:Helium Production of Prompt Neutrinos on the Moon; Vapor Deposition and Solar Wind Implantation on Lunar Soil-Grain Surfaces as Comparable Processes; A New Lunar Geologic Mapping Program; Physical Backgrounds to Measure Instantaneous Spin Components of Terrestrial Planets from Earth with Arcsecond Accuracy; Preliminary Findings of a Study of the Lunar Global Megaregolith; Maps Characterizing the Lunar Regolith Maturity; Probable Model of Anomalies in the Polar Regions of Mercury; Parameters of the Maximum of Positive Polarization of the Moon; Database Structure Development for Space Surveying Results by Moon -Zond Program; CM2-type Micrometeoritic Lunar Winds During the Late Heavy Bombardment; A Comparison of Textural and Chemical Features of Spinel Within Lunar Mare Basalts; The Reiner Gamma Formation as Characterized by Earth-based Photometry at Large Phase Angles; The Significance of the Geometries of Linear Graben for the Widths of Shallow Dike Intrusions on the Moon; Lunar Prospector Data, Surface Roughness and IR Thermal Emission of the Moon; The Influence of a Magma Ocean on the Lunar Global Stress Field Due to Tidal Interaction Between the Earth and Moon; Variations of the Mercurian Photometric Relief; A Model of Positive Polarization of Regolith; Ground Truth and Lunar Global Thorium Map Calibration: Are We There Yet?;and Space Weathering of Apollo 16 Sample 62255: Lunar Rocks as Witness Plates for Deciphering Regolith Formation Processes.

Source record

Ion microprobe, electron microprobe and cathodoluminescence data for Allende inclusions with emphasis on plagioclase chemistry

Three Type B inclusions from the Allende meteorite have been analyzed. A grain-to-grain characterization of mineral chemistry and isotopic content was made possible by the use of a range of techniques, including luminescence and scanning electron microscopy and electron and ion microprobe analysis. Cathodoluminescence was used in fine-grained, optically opaque regions to distinguish between sub-micrometer phases, such as garnet and Si-rich material, subsequently identified by electron probe and scanning electron microscope analyses. Four types of luminescence patterns, due to twinning, primary sector zoning, alteration of boundaries and fractures, and shock effects, were identified in Allende plagioclase. Luminescence color exhibited a strong correlation with Mg content and provided a guide for an electron probe quantitative map of Mg and Na distributions. Ion microprobe studies of individual grains revealed large excesses of Mg-26.

Hutcheon, I. D.

Influence of rolling reduction and annealing on recrystallization and grain structure in Ta-2.5W alloys

The microstructural evolution of wrought Tantalum - 2.5 wt% Tungsten (Ta-2.5W) alloys during thermomechanical processing is critical for optimizing their mechanical reliability in demanding applications such as aerospace, chemical processing, and nuclear technology. Despite the widespread use of Ta-W alloys, a comprehensive understanding of how rolling reduction, annealing temperature, and elemental inhomogeneity interact to determine recrystallization behavior and grain refinement remains incomplete. Here, in this study, we systematically investigate the effects of cold rolling and subsequent annealing on the microstructure of Ta-2.5W, with particular attention to grain orientation, stored energy, and elemental banding. Our results demonstrate that higher rolling reduction rates lower the onset and completion temperatures for recrystallization, resulting in finer and more homogeneous grain structures. Electron backscatter diffraction (EBSD) analysis reveals that grains with a 〈111〉 parallel to the plate normal possess higher stored energy and nucleate recrystallization more readily than grains with a 〈001〉 parallel to the plate normal. Elemental mapping shows that tungsten inhomogeneity leads to localized bands of accelerated recrystallization and hardness variation. These findings provide new insights into the mechanisms of microstructure refinement in Ta-2.5W alloys, offering guidance for tailoring processing routes to achieve superior performance in demanding engineering environments.

Annealing

Thermal-infrared and visual imaging of comet Giacobini-Zinner

Thermal-infrared and visual images obtained simultaneously of comet Giacobini-Zinner on UT 1985 August 4.4 are presented. The 10.8-micron map, which spans several arc minutes with 8-arcsec resolution, is the first ground-based infrared image of a comet. Considerable spatial structure is evident in the map, including a curved dust tail consisting primarily of dust grains larger than 100 microns. The width of this large-grain tail implies that these grains depart the nucleus with velocities less than 3 m/s. The distribution of grain albedo is determined for the central 1 arcmin. It is speculated that an observed increase in the albedo by a factor of 2 with distance from the nucleus and prolonged radius vector results from the confinement to the orbital plane of large fluffy grains previously considered for GZ by others; the lower albedo of this dust could result from multiple internal scattering increasing the probability of absorption of incident light. It is estimated that dust was departing the nucleus at the rate of about 8 x 10 to the 5th g/s, comparable to that derived for many other comets.

Telesco, C. M.

Principles for problem aggregation and assignment in medium scale multiprocessors

One of the most important issues in parallel processing is the mapping of workload to processors. This paper considers a large class of problems having a high degree of potential fine grained parallelism, and execution requirements that are either not predictable, or are too costly to predict. The main issues in mapping such a problem onto medium scale multiprocessors are those of aggregation and assignment. We study a method of parameterized aggregation that makes few assumptions about the workload. The mapping of aggregate units of work onto processors is uniform, and exploits locality of workload intensity to balance the unknown workload. In general, a finer aggregate granularity leads to a better balance at the price of increased communication/synchronization costs; the aggregation parameters can be adjusted to find a reasonable granularity. The effectiveness of this scheme is demonstrated on three model problems: an adaptive one-dimensional fluid dynamics problem with message passing, a sparse triangular linear system solver on both a shared memory and a message-passing machine, and a two-dimensional time-driven battlefield simulation employing message passing. Using the model problems, the tradeoffs are studied between balanced workload and the communication/synchronization costs. Finally, an analytical model is used to explain why the method balances workload and minimizes the variance in system behavior.

Nicol, David M.

Using Satellite Remote Sensing Data in a Spatially Explicit Price Model

Famine early warning organizations use data from multiple disciplines to assess food insecurity of communities and regions in less-developed parts of the World. In this paper we integrate several indicators that are available to enhance the information for preparation for and responses to food security emergencies. The assessment uses a price model based on the relationship between the suitability of the growing season and market prices for coarse grain. The model is then used to create spatially continuous maps of millet prices. The model is applied to the dry central and northern areas of West Africa, using satellite-derived vegetation indices for the entire region. By coupling the model with vegetation data estimated for one to four months into the future, maps are created of a leading indicator of potential price movements. It is anticipated that these maps can be used to enable early warning of famine and for planning appropriate responses.

Brown, Molly E.

Simulation of Creep Deformation and Failure in Graded AM Microstructures

This report describes modeling tools and techniques developed to simulate the long-term material performance of 316H stainless steel manufactured using Laser Powder Bed Fusion (LPBF). A physics-based Crystal Plasticity Finite Element model is used to simulate creep in microstructures and to study the roles of grain morphology, porosity, and texture. We describe our modeling methodology, including an orientation-mapping technique to capture the spatially varying crystallographic orientation that results from the build conditions. Our study of microstructural features shows that AM microstructures produced by LPBF tend to creep faster in the build direction, while texture and grain boundaries strengthen the transverse directions. However, when grain-boundary porosity and the consequent cavity growth are included in the model, the transverse directions begin to creep faster. In examining texture, the results indicate that spatially varying orientation arising from the build conditions increases anisotropy in the material, making it critical to account for orientation gradients in the material to accurately model its mechanical behavior. We also describe a material-model calibration campaign in which we calibrated the constitutive model specifically for LPBF 316H stainless steel at 725℃ for both solution-annealed and as-built conditions. Finally, these tools and techniques are used to model creep in microstructures representing different regions of an LPBF material with graded microstructure, owing to intentional variation in processing conditions. The creep simulation results show good agreement with experimental data across all three microstructures, with future work planned to study rupture in the material.

36 MATERIALS SCIENCE

Mentat/A: Medium grain parallel processing

The objective of this project is to support the Algorithm to Architecture Mapping Model (ATAMM) firing rules using the Mentat run-time system and the Mentat Programming Language (MPL). Specifically, this required changes to (1) modify the run-time system to control queue length and inhibit actor firing until required data tokens are available and space is available in the input queues of all of the direct descendent actors, (2) disallow the specification of persistent object classes in the MPL, and (3) permit only decision free graphs in the MPL. We have been successful in implementing the spirit of the plan, although some goals changed as we came to better understand the problem. Here, we report on what we accomplished and the lessons we learned. The Mentat/A runtime system, the compiler, results for three applications, and a summary and some observations are given. Appendix A contains a list of technical reports and published papers partially supported by the grant. Appendix B contains listings for the three applications.

Grimshaw, Andrew S.

Mentat/A: Medium grain parallel processing

The objective of this project is to test the Algorithm to Architecture Mapping Model (ATAMM) firing rules using the Mentat run-time system and the Mentat Programming Language (MPL). A special version of Mentat, Mentat/A (Mentat/ATAMM) was constructed. This required changes to: (1) modify the run-time system to control queue length and inhibit actor firing until required data tokens are available and space is available in the input queues of all of the direct descendent actors; (2) disallow the specification of persistent object classes in the MPL; and (3) permit only decision free graphs in the MPL. We were successful in implementing the spirit of the plan, although some goals changed as we came to better understand the problem. We report on what we accomplished and the lessons we learned. The Mentat/A run-time system is discussed, and we briefly present the compiler. We present results for three applications and conclude with a summary and some observations. Appendix A contains a list of technical reports and published papers partially supported by the grant. Appendix B contains listings for the three applications.

Grimshaw, Andrew S.

Infrared emission from hydrogenated amorphous carbon and amorphous carbon grains in the interstellar medium

The correlations deduced by Boulanger et al. (1990) from IRAS maps of the Chamaeleon, Taurus and Ursa Major molecular cloud complexes are interpreted in terms of the evolutionary hydrogenated amorphous carbon model of interstellar dust. In particular, regions of relatively strong 12-micron emission may be regions where recently accreted carbon is being converted by ambient UV to small PAHs in situ. Regions of weak 12-micron emission are probably quiescent regions where carbon has been annealed to amorphous carbon. Observational consequences of these inferences are briefly described.

Duley, W. W.

Electron Backscatter Diffraction (EBSD) Analysis and U-Pb Geochronology of the Oldest Lunar Zircon: Constraining Early Lunar Differentiation and Dating Impact-Related Deformation

The evolution of the early moon was dominated by two processes (i) crystallization of the Lunar Magma Ocean (LMO) and differentiation of potassium-rare earth element-phosphorous-rich residual magma reservoir referred to as KREEP, and (ii) an intense meteorite bombardment referred to as lunar cataclysm . The exact timing of these processes is disputed, and resolution relies on collection and interpretation of precise age data. This study examines the microstructure and geochronology of zircon from lunar impact breccias collected during the Apollo 17 mission. A large zircon clast within lunar breccia 72215,195 shows sector zoning in optical microscopy, cathodoluminescence (CL) imaging and Raman mapping, and indicates that it was a relict fragment of a much larger magmatic grain. Sensitive high resolution ion microprobe (SHRIMP) U-Pb analysis of the zircon shows that U and Th concentration correlate with sector zoning, with darkest CL domains corresponding with high-U and Th (approx.150 and approx.100 ppm respectively), and the brightest-CL sectors containing approx.30-50 ppm U and approx.10-20 ppm Th. This indicates that variations in optical CL and Raman properties correspond to differential accumulation of alpha-radiation damage in each sector. Electron backscatter diffraction (EBSD) mapping shows that the quality of electron backscatter patterns (band contrast) varies with sector zoning, with the poorest quality patterns obtained from high-U and Th, dark-CL zones. EBSD mapping also reveals a deformation microstructure that is cryptic in optical, CL and Raman imaging. Two orthogonal sets of straight discrete and gradational low-angle boundaries accommodate approx.12 misorientation across the grain. The deformation bands are parallel to the crystallographic {a}-planes of the zircon, have misorientation axes parallel to the c-axis, and are geometrically consistent with formation by dislocation creep associated with <100>{010} slip. The deformation bands are unlike curved morphology of crystal-plastic microstructures in tectonically deformed terrestrial zircon, and geometrically similar to dislocation microstructures reported in experimentally shocked zircon. We interpret these crystal-plastic deformation microstructures to have resulted from a significant impact, either directly from impact shock, or during ductile flow directly following the impact. The deformation bands appear to continue undeflected through the non-indexed, radiation-damaged areas of the grain, which suggests that the orientation variation predates any significant mechanical weakening from radiation damage in the grain, and therefore occurred early in its history.

Timms, Nick

Pristine Presolar Silicon Carbide

In this talk we discuss a simple physical disaggregation technique coupled with an X-ray mapping procedure used to locate 81 micrometer-sized presolar SiC grains from the Murchison carbonaceous chondrite, that preserves them in their pristine state. We then describe pristine SiC surface characteristics and overall morphologies determined by high resolution field emission scanning electron microscopy (FESEM), and compare these features to those of presolar SiC grains that have been prepared using chemical dissolution techniques.

Bernatowicz, T. J.

Multiscale Modeling of Structurally-Graded Materials Using Discrete Dislocation Plasticity Models and Continuum Crystal Plasticity Models

A multiscale modeling methodology that combines the predictive capability of discrete dislocation plasticity and the computational efficiency of continuum crystal plasticity is developed. Single crystal configurations of different grain sizes modeled with periodic boundary conditions are analyzed using discrete dislocation plasticity (DD) to obtain grain size-dependent stress-strain predictions. These relationships are mapped into crystal plasticity parameters to develop a multiscale DD/CP model for continuum level simulations. A polycrystal model of a structurally-graded microstructure is developed, analyzed and used as a benchmark for comparison between the multiscale DD/CP model and the DD predictions. The multiscale DD/CP model follows the DD predictions closely up to an initial peak stress and then follows a strain hardening path that is parallel but somewhat offset from the DD predictions. The difference is believed to be from a combination of the strain rate in the DD simulation and the inability of the DD/CP model to represent non-monotonic material response.

Saether, Erik

Evolution and folding of repeat proteins

Repeat proteins are made with tandem copies of similar amino acid stretches that fold into elongated architectures. These proteins constitute excellent model systems to investigate how evolution relates to structure, folding, and function. Here, we propose a scheme to map evolutionary information at the sequence level to a coarse-grained model for repeat-protein folding and use it to investigate the folding of thousands of repeat proteins. We model the energetics by a combination of an inverse Potts-model scheme with an explicit mechanistic model of duplications and deletions of repeats to calculate the evolutionary parameters of the system at the single-residue level. These parameters are used to inform an Ising-like model that allows for the generation of folding curves, apparent domain emergence, and occupation of intermediate states that are highly compatible with experimental data in specific case studies. We analyzed the folding of thousands of natural Ankyrin repeat proteins and found that a multiplicity of folding mechanisms are possible. Fully cooperative all-or-none transitions are obtained for arrays with enough sequence-similar elements and strong interactions between them, while noncooperative element-by-element intermittent folding arose if the elements are dissimilar and the interactions between them are energetically weak. Additionally, we characterized nucleation-propagation and multidomain folding mechanisms. We show that the global stability and cooperativity of the repeating arrays can be predicted from simple sequence scores.

Ezequiel A. Galpern

Diurnally Migrating Lunar Water: Evidence from Ultraviolet Data

Data from the Lunar Reconnaissance Orbiter Lyman Alpha Mapping Project and Diviner are consistent with surface water on the Moon varying in abundance with both terrain type and local time/temperature. A thermal desorption model including latitudinally varying desorption activation energy reproduces the observations. We interpret the observed variability in spectral slopes as water molecules in the uppermost lunar regolith (<1% of a monolayer) thermally adsorbing and desorbing from grains depending upon the local temperature and availability of chemisorption sites. The Lyman Alpha Mapping Project data also demonstrate that in the Earth's magnetotail, where the solar wind source of protons is absent, a decrease in H2O on the surface is not observed. This rules out a steady state process involving aprompt solar wind source and favors a migration mechanism for the distribution of adsorbed water onthe Moon.

Diurnally

The X-ray halo of Cygnus X-1

Four Einstein HRI images of Cygnus X-1 were examined for the presence of a halo due to scattering of X-rays by interstellar grains. The analysis technique exploits the intrinsic aperiodic variability of the source to map the point response function of the optics. A residual, nonvariable component to the surface brightness distribution (comprising approximately more than 12 percent of the source flux) is interpreted as a scattered halo. The halo flux does not reflect the short term time variability of the central source as it is smoothed by differential time delays of order days. The Cygnus X-1 halo is consistent with those of other sources derived in previous studies using different techniques. Comparison is made with a scattering model, and the sensitivity of the halo flux to maximal grain size is demonstrated.

Bode, M. F.

The wavelength dependence of polarization in NGC 2023

NGC 2023 is a bright reflection nebula illuminated by the central star HD37903. At 2 microns the nebula is seen solely by reflected light from the central star but in the NIR there is excess radiation that is supposed to arise from thermal emission from a population of small grains (Sellgren, 1984). The unexpectedly high surface brightness at R and I wavelengths has led to the suggestion that even at these wavelengths there is a significant contribution from this thermal emission process (Witt, Schild, and Kraiman, 1984). If the nebula is seen by reflected starlight then this radiation will be linearly polarized. The level of polarization depends on the scattering geometry, grain size distribution, etc., and is typically 20 to 40 percent for nebulae such as NGC 1999 which is morphologically similar to NGC 2023. If, in any waveband, there is a contribution of radiation from emission processes this radiation will be unpolarized and will serve to dilute the scattered radiation to give a lower level of observed polarization. A study of the wavelength dependence of polarization in nebulae in which there may be thermal emission from grains will indicate the contribution from this process to the total luminosity. Polarization maps were produced in BVRI wavebands for the NGC 2023 nebulosity which confirm that at all wavelengths it is a reflection nebula illuminated by a central star. The wavelength dependence of polarization at representative points in the nebula and in a scatter plot of polarization in V and I wavebands at all points at which measurements are given. Results indicate that throughout the nebula there is a general trend for the level of polarization to increase with wavelength and that maximum levels of polarization occur at the longest wavelengths. No evidence is seen in the data for any significant contribution from the thermal emission from grains in the BVRI luminosity of NGC 2023.

Rolph, C. D.

Cometary grains

CCD observations of cometary comas in the spectral continuum are reported. Radial brightness profiles of 14 comets and isophotal maps of three are presented. For 10 of the 14, the azimuthally averaged brightness in the vicinity of the nucleus falls off faster than rho exp -1, where rho is the projected radial distance from the nucleus in the plane of the sky. Simple modeling is used to show that radiation pressure alone cannot account for the observed departures from rho exp -1; it is postulated that the grains fade, i.e., decrease in albedo or size, while they glow outward. For only three of the comets no evidence was found of any grain fading at all. Cases with the most rapid grain fading occurred at small heliocentric distances, but so did some of the cases with no fading, from which large intrinsic differences from comet to comet in the nature of the grain population are inferred.

Baum, William A.