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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

The Aquarius Ocean Salinity Mission High Stability L-band Radiometer

The NASA Earth Science System Pathfinder (ESSP) mission Aquarius, will measure global ocean surface salinity with approx.120 km spatial resolution every 7-days with an average monthly salinity accuracy of 0.2 psu (parts per thousand). This requires an L-band low-noise radiometer with the long-term calibration stability of less than or equal to 0.15 K over 7 days. The instrument utilizes a push-broom configuration which makes it impractical to use a traditional warm load and cold plate in front of the feedhorns. Therefore, to achieve the necessary performance Aquarius utilizes a Dicke radiometer with noise injection to perform a warm - hot calibration. The radiometer sequence between antenna, Dicke load, and noise diode has been optimized to maximize antenna observations and therefore minimize NEDT. This is possible due the ability to thermally control the radiometer electronics and front-end components to 0.1 Crms over 7 days.

Pellerano, Fernando A.↗

The Aquarius ocean salinity mission high stability L-band radiometer

The NASA Earth Science System Pathfinder (ESSP) mission Aquarius, will measure global ocean surface salinity with ~120 km spatial resolution every 7-days with an average monthly salinity accuracy of 0.2 psu (parts per thousand) [1]. This requires an L-band low-noise radiometer with the long-term calibration stability of ≤0.15 K over 7 days. The instrument utilizes a push-broom configuration which makes it impractical to use a traditional warm load and cold plate in front of the feedhorns. Therefore, to achieve the necessary performance Aquarius utilizes a Dicke radiometer with noise injection to perform a warm – hot calibration. The radiometer sequence between antenna, Dicke load, and noise diode has been optimized to maximize antenna observations and therefore minimize NEDT. This is possible due the ability to thermally control the radiometer electronics and front-end components to 0.1 °Crms over 7 days.

Freedman, Adam↗

Development of a high stability microstrip-based L-band radiometer for ocean salinity measurements.

The development of a microstrip-based L-band Dicke radiometer with the long-term stability required for future ocean salinity measurements to an accuracy of 0.1 psu is presented. This will require the L-band radiometer requirements and configuration to achieve this objective. System configuration and component performance have been evaluated with radiometer test beds at both JPL and GSFC. The GSFC testbed uses a cryogenic chamber that al-lows long-term characterization at radiometric temperatures in the range of 70 - 120 K. The research has addressed several areas including component characterization as a function of temperature and bias, system linearity, optimum noise diode injection calibration and precision temperature control of components. A breadboard radiometer, utilizing microstrip-based technologies, has been built to demonstrate this long-term stability. This system is partially polarimetric providing V, H, -45 and +45 signals. Test results are compared to current and future ocean salinity radiometer requirements to show that the desire performance is possible.

Tanner, Alan B.↗

Early transition metal stabilized high capacity cobalt free cathodes for lithium-ion batteries

A cathode for a lithium battery includes LiNi 0.5 -x/2Mn 0.5 -x/2M x O 2 where M is at least one selected from the group consisting of Mo, Ti, Cr, Zr and V, and x is between 0.005-0.02. The LiNi 0.5 -x/2Mn 0.5 -x/2M x O 2 can be coated with Mn 2 P 2 O 7 . The Mn 2 P 2 O 7 can be 1-3 wt. %, based on the total weight of the LiNi 0.5 -x/2Mn 0.5 -x/2M x O 2 and Mn 2 P 2 O 7 . A cathode composition, a lithium battery, and a method of making a lithium battery are also disclosed.

25 ENERGY STORAGE↗

A New Class of Proton Conductors with Dramatically Enhanced Stability and High Conductivity for Reversible Solid Oxide Cells

Reversible solid oxide cells based on proton conductors (P-ReSOCs) have potential to be the most efficient and low-cost option for large-scale energy storage and power generation, holding promise as an enabler for the implementation of intermittent renewable energy technologies and the widespread utilization of hydrogen. Here, the rational design of a new class of hexavalent Mo/W-doped proton-conducting electrolytes with excellent durability while maintaining high conductivity is reported. Specifically, BaMo(W) 0.03 Ce 0.71 Yb 0.26 O 3-δ exhibits dramatically enhanced chemical stability against high concentrations of steam and carbon dioxide than the state-of-the-art electrolyte materials while retaining similar ionic conductivity. In addition, P-ReSOCs based on BaW 0.03 Ce 0.71 Yb 0.26 O 3-δ demonstrate high peak power densities of 1.54, 1.03, 0.72, and 0.48 W cm –2 at 650, 600, 550, and 500 °C, respectively, in the fuel cell mode. During steam electrolysis, a high current density of 2.28 A cm –2 is achieved at a cell voltage of 1.3 V at 600 °C, and the electrolysis cell can operate stably with no noticeable degradation when exposed to high humidity of 30% H 2 O at –0.5 A cm –2 and 600 °C for over 300 h. Altogether, this work demonstrates the promise of donor doping for obtaining proton conductors with both high conductivity and chemical stability for P-ReSOCs.

25 ENERGY STORAGE↗

Unravelling high-temperature stability of lithium-ion battery with lithium-rich oxide cathode in localized high-concentration electrolyte

Lithium (Li)-rich manganese (Mn)-rich oxide (LMR) cathode materials, despite of the high specific capacity up to 250 mAh g-1 suffer from instability of cathode/electrolyte interfacial layer at high working voltages, causing continuous voltage decay and capacity fading, especially at elevated temperatures. In various battery systems, localized high-concentration electrolytes (LHCEs) have been widely reported as a promising candidate to form effective electrode/electrolyte interphases. Here, an optimized LHCE is studied in graphite (Gr)-based full cells being cycled at 25, 45 and 60 °C with the reference of a conventional LiPF6-based electrolyte. It is revealed that the LHCE can effectively suppress continuous electrolyte decompositions and mitigate the dissolution of Mn ions due to the formation of more protective electrode/electrolyte interphases on both anode and cathode, which, in turn, lead to significantly improved cycling stability and enhanced rate capability under the selected temperatures. The mechanistic understanding on the failure of the conventional LiPF6-containing electrolyte and the function of the LHCE in Gr||LMR cells under high temperatures provides valuable perspectives of electrolyte development for practical application of LMR cathodes in high energy density batteries over a wide temperature range.

Localized high-concentration electrolyte, Lithium-↗

A Comparison of Novel Woodstove Catalytic Combustors to Improve Low Temperature Light off and Catalyst Stability at High Temperatures and Corrosive Environments, Including Stability of Catalytic Combustors used in Coastal Environments

Wood heaters with catalytic combustors often emit higher levels of particulate matter (PM) and volatile organic compounds (VOCs) at startup before the catalytic combustor is at operational temperature. This project aims to advance wood heater catalytic combustor technology by studying degradation mechanisms in failed field catalysts and using those insights to develop an improved catalytic combustor. Findings will provide critical insights into the degradation mechanisms of wood heater catalytic combustors and inform the design of catalysts that deliver improved efficiency, durability, and performance compared to current commercial products. The outcomes of this project will not only improve catalytic combustor technology but also contribute to operational guidelines to extend catalyst lifetimes.

99 GENERAL AND MISCELLANEOUS↗

Electronic circuit delivers pulse of high interval stability

Circuit generates a pulse of high interval stability with a complexity level considerably below systems of comparable stability. This circuit is being used as a linear frequency discriminator in the signal conditioner of the Apollo command module.

Fisher, B.↗