Remote sensing of lunar surface mineralogy - Implications from visible and near-infrared reflectivity of Apollo 11 samples
Lunar rocks mineralogy and visible and near IR reflectivity, discussing depression in telescopic curve
Adams, J. B.↗
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Analysis of thin films of DC-704 on aluminum, germanium, and KRS-5 surfaces by infrared reflection spectroscopy
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Honeycutt, R. H., III↗
Properties of the clouds of Venus, as inferred from airborne observations of its near-infrared reflectivity spectrum
The shape and absolute value of Venus' reflectivity spectrum is measured in the 1.2- to 4.0 micrometer spectral region with a circular variable filter wheel spectrometer having a spectral resolution of 1.5%. Comparing these spectra with synthetic spectra generated with a multiple-scattering computer code, a number of properties of the Venus clouds are inferred. Evidence is obtained indicating that the clouds are made of a water solution of sulfuric acid in their top unit optical depth, and that the clouds are made of this material down to an optical depth of at least 25. In addition, the acid concentration is 84 plus or minus 2% H2SO4 by weight in the top unit optical depth, the total optical depth of the clouds is 37.5 plus or minus 12.5, and the cross-sectional weighted mean particle radius lies between 0.5 and 1.4 micrometers in the top unit optical depth of the clouds. It is found that the average volume mixing ratio of H2SO4 and H2O contained in the cloud material both equal approximately 2 x 10 to the -6. Employing vapor pressure arguments, the acid concentration is shown to equal 84 plus or minus 6% at the cloud bottom and the water vapor mixing ratio beneath the clouds lies between 6 x 10 to the -4 and 10 to the -2.
Pollack, J. B.↗
The near-infrared reflectivity of the dark and light faces of Iapetus
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Soifer, B. T.↗
The rings of Saturn - New near-infrared reflectance measurements and a 0.326-4.08 micron summary
A new high-photometric-precision reflectance spectrum of Saturn's rings covering the spectral region 0.65 to 2.5 microns is presented and three previously unreported absorption features at 1.25, 0.85, and probably 1.04 microns are identified. The 1.25- and 1.04 micron absorptions are due to water ice. The 0.85 microns feature may be due to a combination of 0.81- and 0.90 micron ice absorptions but this feature appears too strong relative to the 1.04 micron band to be completely explained by water ice. Another possibility is that the 0.85 micron band is due to Fe(3+)-bearing minerals in an ice-mineral mixture. This explanation could also account for the drop in the visible and ultraviolet reflectance and the rise in reflectance around 3.6 microns. Finally, a composite spectrum from 0.325 to 4.08 is presented which will be useful for future analysis and laboratory studies.
Clark, R. N.↗
Effect of leaf variables on visible, near-infrared and mid-infrared reflectance of excised leaves
Effects of an imposed (excised) leaf orientation, differing species and differing venation patterns on reflectance measurements in the LANDSAT-4 thematic mapper (TM) channels TM3 (0.63 to 0.69 microns), TM4 (0.76 to 0.90 microns), and TM5 (1.55 to 1.75 microns) were investigated. Orientation of leaves (random vs. systematic placement) was found to affect measurements in the TM4 channel, but not the TM3 and TM5 measurements. Venation caused no significant changes for any band. Azimuth of incident radiation was not a significant main effect, but in conjunction with changes in orientation, angle did have a significant effect on reflectance values in TM3, TM4 and TM5. Specific differences were highly significant (P f or = 0.006) in all but one borderline (P F or = 0.0222) case for TM5. For spectral examination of excised leaves, the sampling arrangement of the leaves should as closely approximate in situ positioning as possible (with respect to remote sensing instrumentation). This dictates a random rather than aligned arrangement.
Bell, R.↗
Correlation of infrared reflectance ratios at 2.3 microns/1.6 micron and 1.1 micron/1.6 micron with delta O-18 values delineating fossil hydrothermal systems in the Idaho batholith
Reflectance ratios from laboratory spectra and airborne multispectral images are found to be strongly correlated with delta O-18 values of granite rocks in the Idaho batholith. The correlation is largely a result of interactions between hot water and rock, which lowered the delta O-18 values of the rocks and produced secondary hydrous material. Maps of the ratio of reflectivities at 2.3 and 1.6 microns should delineate fossil hydrothermal systems and provide estimates of alteration intensity. However, hydrous minerals produced during deuteric alteration or weathering cannot be unambiguously distinguished in remotely sensed images from the products of propylitic alteration without the use of narrow-band scanners. The reflectivity at 1.6 micron is strongly correlated with rock density and may be useful in distinguishing rock types in granitic terranes.
Gillespie, A. R.↗
Measurement of leaf relative water content by infrared reflectance
From basic considerations and Beer's law, a leaf water content index incorporating reflectances of wavelengths from 0.76 to 0.90 microns and from 1.55 to 1.75 microns was developed that relates leaf reflectance to leaf relative water content. For the leaf succulent, Agave deserti, the leaf water content index was not significantly different from the relative water content for either individual leaves or an entire plant. Also, the relative water contents of intact plants of Encelia farinosa and Hilaria rigida in the field were estimated by the leaf water content index; variations in the proportion of living to dead leaf area could cause large errors in the estimate of relative water content. Thus, the leaf water content index may be able to estimate average relative water content of canopies when TM4 and TM5 are measured at a known relative water content and fraction of dead leaf material.
Hunt, E. Raymond, Jr.↗
Infrared reflectance spectra of Na2S with contaminant Na2CO3 - Effects of adsorbed H2O and CO2 and relation to studies of Io
A previously reported laboratory determination of the IR spectrum of Na2S is presently noted to have been incorrectly interpreted, due to the inadvertent contamination of the sample with Na2CO3. New Na2S spectra are presented, and the Na2CO3 spectrum is examined in order to demonstrate that this phase is the primary sample contaminant. Na2S is a candidate surface component on the Jupiter satellite, Io, in view of its apparent high IR brightness and spectral neutrality in the 1-5 micron range.
Nash, Douglas B.↗
Prediction of leaf chemistry by the use of visible and near infrared reflectance spectroscopy
The chemical content of dry, ground leaf material sampled from deciduous and conifer tree species from sites in Alaska, Wisconsin, and California was estimated using visible and shortwave IR spectroscopy. Seven chemical components - sugar, starch, protein, cellulose, total chlorophyll, lignin, and total nitrogen - were analyzed by wet chemical methods and their concentrations regressed against log 1/rho and first and second differences of log 1/rho (where rho is measured reflectance) at wavelengths selected by stepwise regression. Predictions of chemical concentrations based on cross validation suggest that this technique may be useful for extracting vegetation canopy biochemical information by remote sensing.
Card, Don H.↗
Studies of dust grain properties in infrared reflection nebulae
A model has been developed for reflection nebulae around luminous IR sources embedded in dense dust clouds. The shape of the IR spectrum is shown to be the result of a combination of the scattering properties of the dust, the spectrum of the illuminating source, and foreground extinction, while geometry plays a minor role. Comparison of the model results with IR observations of the reflection nebula surrounding OMC-2/IRS 1 shows that either a grain size distribution like that found in the diffuse ISM, or consisting of larger grains, can explain the observed shape of the spectrum. However, the absolute intensity level of the scattered light, as well as the observed polarization, requires large grains. By adding water-ice mantles to the silicate and graphite cores, the 3.08 micron ice-band feature observed in the spectra of several IR reflection nebulae has been modeled. It is shown that this ice band arises naturally in optically thick reflection nebulae containing ice-coated grains.
Pendleton, Y. J.↗
Detection of changes in leaf water content using near- and middle-infrared reflectances
A method to detect plant water stress by remote sensing is proposed using indices of near-IR and mid-IR wavelengths. The ability of the Leaf Water Content Index (LWCI) to determine leaf relative water content (RWC) is tested on species with different leaf morphologies. The way in which the Misture Stress Index (MSI) varies with RWC is studied. On test with several species, it is found that LWCI is equal to RWC, although the reflectances at 1.6 microns for two different RWC must be known to accurately predict unknown RWC. A linear correlation is found between MSI and RWC with each species having a different regression equation. Also, MSI is correlated with log sub 10 Equivalent Water Thickness (EWT) with data for all species falling on the same regression line. It is found that the minimum significant change of RWC that could be detected by appying the linear regression equation of MSI to EWT is 52 percent. Because the natural RWC variation from water stress is about 20 percent for most species, it is concluded that the near-IR and mid-IR reflectances cannot be used to remotely sense water stress.
Hunt, E. Raymond, Jr.↗
Infrared studies of dust grains in infrared reflection nebulae
IR reflection nebulae, regions of dust which are illuminated by nearby embedded sources, were observed in several regions of ongoing star formation. Near IR observation and theoretical modelling of the scattered light form IR reflection nebulae can provide information about the dust grain properties in star forming regions. IR reflection nebulae were modelled as plane parallel slabs assuming isotropically scattering grains. For the grain scattering properties, graphite and silicate grains were used with a power law grain size distribution. Among the free parameters of the model are the stellar luminosity and effective temperature, the optical depth of the nebula, and the extinction by foreground material. The typical results from this model are presented and discussed.
Pendleton, Yvonne J.↗
An infrared reflectance study of low albedo surface constituents
Observational testing of the idea that the distribution of water is the key to understanding the volatile content of the asteroid belt relies on the exploration of the 3 micron absorption feature in hydrated silicates - the only diagnostic spectral band evident in the dark, volatile rich CI and CM meteorites. The existence of the band has demonstrated the presence of hydrated silicates on asteroids. An example of this feature is shown in the spectrum of the CI meteorite Orgueil. The feature is characterized by a sharp reflectance drop at 2.7 microns, due to structural OH, and by an absorption due to H2O that decreases slowly out to about 3.5 microns. In their present observational program, researchers are expanding their observational program to include other low-albedo classes of asteroids - asteroids that range primarily from the middle and outer asteroid belt (greater than 2.5 AU) to the Trojan region at 5.2 AU. Preliminary results indicate that the outer belt and Trojan asteroids do not show feature diagnostic of hydrated silicates. Researchers conclude that these asteroids have not undergone the alteration processes that we see in C-class asteroids.
Lebofsky, Larry A.↗
Near infrared reflectance spectra: Applications to problems in asteroid-meteorite relationships
An observing program designed to search for evidence of ordinary chondrite parent bodies near the 3:1 Kirkwood Gap was carried out in 1985 and 1986. Studies by Wisdom (1985), Wetherill (1985), and subsequent work by Milani et al. (1989) indicate that the 3:1 Kirkwood gap is the most probable source region for the majority of ordinary chondrite meteorites. The diversity of the reflectance spectra among this small data set is surprising. Early work by Gaffey and McCord (1978) showed that the inner region of the main asteroid belt is dominated by high albedo objects with mafic silicate surfaces. One would expect to see mostly spectra with 1- and 2-micron absorption bands based on this earlier work. Only 5 (of 12) spectra have these expected features. The distribution of taxonomic types presented by Gradie and Tedesco (1982) is in most cases a useful simplification of the compositional structure of the asteroid belt. The range of spectral characteristics seen with higher resolution in the near-IR has not been previously reported and is not represented in the standard asteroid taxonomy. Near-IR spectra contain valuable mineralogical information which enhances knowledge of the composition and structure of asteroids.
Mcfadden, Lucy A.↗
Correcting for diffraction in the far-infrared reflectance measurement of rough surfaces
The manner in which diffraction can increase the reflectance measured from very rough surfaces is shown by observations of diffracted light within the instrument profile of a far-IR reflectometer system. A correction to the calibration signal based on numerical integration of the diffracted part of the instrument profile is described. Diffraction correction factors as large as 2.94 have been found with small optics at long wavelength (630 microns). The effect of diffraction on diffuse reflectance measurements of a very rough perfect reflector is shown at wavelengths from 56 to 200 microns.
Smith, Sheldon M.↗
An almost 'perfectly' diffuse, 'perfect' reflector for far-infrared reflectance calibration
Specular and diffuse reflectance measurements made near normal incidence of two very rough, solid aluminum surfaces are presented for the wavelength range from 2.2 to 512 microns. The diffuse measurements made at nonspecular angles by two different detectors indicate that between 33 and 201 microns the reflectance of one surface is nearly Lambertian (isotropic) with a bidirectional reflectance distribution function (BRDF) value within 32 percent of the theoretical value of (1/pi)/sr for a perfectly diffuse, perfect reflector. Photometric reflectance spectra at the specular angle show that between 6.9 and 100 microns the specular BRDF of these surfaces is within 5 percent of the theoretical value of (1/pi)/sr. At longer wavelengths of 235, 320, and 512 microns the specular reflectance rapidly departs from that of a perfectly diffuse, perfect reflector. The two samples studied have rms surface roughnesses of 44 and 60 microns. A durable metal surface with these near perfect reflectance characteristics can be advantageously used in the FIR as a black-body source, the interior surface of an integrating sphere, and most especially as an absolute calibration standard. BRDF measurements at 40 deg incidence, though still highly diffuse, show a significant departure from Lambertian reflectance.
Smith, Sheldon M.↗
The effects of atmospheric pressure on infrared reflectance spectra of Martian analogs
The use of terrestrial samples as analogs of Mars soils are complicated by the Martian atmosphere. Spectral features due to the Martian atmosphere can be removed from telescopic spectra of Mars and ISM spectra of Mars, but this does not account for any spectral differences resulting from atmospheric pressure or any interactions between the atmosphere and the surface. We are examining the effects of atmospheric pressure on reflectance spectra of powdered samples in the laboratory. Contrary to a previous experiment with granite, no significant changes in albedo or the Christiansen feature were observed from 1 bar pressure down to a pressure of 8 micrometers Hg. However, reducing the atmospheric pressure does have a pronounced affect on the hydration features, even for samples retained in a dry environment for years.
Bishop, Janice L.↗