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Laboratory and observational study of the interrelation of the carbonaceous component of interstellar dust and solar system materials

By studying the chemical and isotopic composition of interstellar ice and dust, one gains insight into the composition and chemical evolution of the solid bodies in the solar nebula and the nature of the material subsequently brought into the inner part of the solar system by comets and meteorites. It is now possible to spectroscopically probe the composition of interstellar ice and dust in the mid-infrared, the spectral range which is most diagnostic of fundamental molecular vibrations. We can compare these spectra of various astronomical objects (including the diffuse and dense interstellar medium, comets, and the icy outer planets and their satellites) with the spectra of analogs we produce in the laboratory under conditions which mimic those in these different objects. In this way one can determine the composition and abundances of the major constituents of the various ices and place general constraints on the types of organics coating the grains in the diffuse interstellar medium. In particular we have shown the ices in the dense clouds contain H2O, CH3OH, CO, perhaps some NH3 and H2CO, we well as nitriles and ketones or esters. Furthermore, by studying the photochemistry of these ice analogs in the laboratory, one gains insight into the chemistry which takes place in interstellar/precometary ices. Chemical and spectroscopic studies of photolyzed analogs (including deuterated species) are now underway. The results of some of these studies will be presented and implications for the evolution of the biogenic elements in interstellar dust and comets will be discussed.

Allamandola, L. J.↗

Evidence for X-ray scattering by interstellar dust

X ray images of distant point sources obtained with the Einstein Observatory have been examined for the presence of halos produced by X-ray scattering from interstellar dust. Evidence for detection of dust halos has been obtained by comparing the apparent surface brightness in images of four low-latitude galactic center sources with the surface brightness predicted from the telescope point response function and the simultaneously measured source spectra. This evidence is considerably strengthened by the same comparison using images of two sources at higher galactic latitude, where the column density of dust is expected to be far lower. Simple assumptions indicate the observed scattering halos are consistent with production by the population of dust grains inferred from optical extinction measurements.

Catura, R. C.↗

Interstellar Dust - A Review

The study of the formation and the destruction processes of cosmic dust is essential to understand and to quantify the budget of extraterrestrial organic materials. Although dust with all its components plays an important role in the evolution of interstellar physics and chemistry and in the formation of organic materials, little is known on the formation and destruction processes of carbonaceous dust. Laboratory experiments that are performed under conditions that simulate interstellar and circumstellar environments to provide information on the nature, the size and the structure of interstellar dust particles, the growth and the destruction processes of interstellar dust and the resulting budget of extraterrestrial organic molecules. A review of the properties of dust and of the laboratory experiments that are conducted to study the formation processes of dust grains from molecular precursors will be given.

Salama, Farid↗

The capability of the ultraviolet imaging telescope for observing interstellar dust

The Ultraviolet Imaging Telescope (UIT) was designed to be able to obtain deep images of nearby galaxies with a single frame. This ability makes it ideal for many imaging problems of the interstellar dust. The instrument has a forty arc-minute field of view with two arc-second resolution. It has 11 ultraviolet filters and a grating which is used as a grism for full field spectroscopy. In a thirty minute exposure (one orbital night) the limiting magnitude for hot objects is V = 25, or a UV mag of 22 for point sources and a UV mag of 26 for extended sources. Programs are planned for the observation of dust in reflection nebulae H II regions, planetaries, dark nebulae, the diffuse galactic light, and dust in other galaxies are planned. The UIT was integrated into the Astro Spacelab Payload and is scheduled to be launched on the Columbia in Nov. 1989.

Stecher, Theodore P.↗

Erosion of circumstellar particle disks by interstellar dust

Circumstellar particle disks appear to be a common phenomenon; however, their properties vary greatly. Models of the evolution of such systems focus on internal mechanisms such as interparticle collisions and Poynting-Robertson drag. Herein it is shown that 'sandblasting' by interstellar dust can be an important and even dominant contributor to the evolution of circumstellar particle disks. Stars spend up to about 3 percent of their main-sequence lifetimes within atomic clouds. Among an IRAS sample of 21 nearby main-sequence A stars, beta Pictoris has the brightest disk; it also possesses the smallest random velocity and therefore the slowest predicted erosion rate.

Lissauer, Jack J.↗

Interstellar dust spectra between 2.5 and 3.3 microns - A search for hydrated silicates

Spectra in the 2.5-3.3 micron wavelength region of VI Cyg 12, AFGL 2205, and AFGL 2885 were obtained in a search for bound water, hydroxyl groups, and hydrated minerals in interstellar dust. No new absorption bands were found. Comparison of expected strengths of bands of serpentine and chlorite-like minerals with the data suggests that less than 25 percent and 50 percent, respectively, of the silicate in the grains is composed of these materials.

Knacke, R. F.↗

Revised Depletions and New Constraints on Interstellar Dust Composition

We have reviewed the literature on composition of young stars, both hot and cool, as well as older solar-type stars. We find that all these classes of stars have lower abundances of the heavy elements (specifically C, N, O, Mg, Si, and Fe) than the sun. Therefore studies of interstellar depletions in which the solar composition is used as the reference standard are probably in error, tending to overestimate the total quantities of these elements, hence the depletions. We have revised the depletion estimates, using stellar abundances as the reference standard and making use of recent IS gas-phase abundance measurements. As a result of our revised depletions, we can place new and stringent constraints on several published models for the interstellar dust.

Snow, Theodore P.↗

A rocket-borne measurement of interstellar dust emission at high galactic latitude

The diffuse brightness of the sky was measured in six submillimeter passbands, using a rocket-borne, liquid helium-cooled, absolute radiometer. The average brightness was reported which was observed in each of the passbands, and the dominant source of emission was tentatively identified in the three shortest wavelength bands as interstellar dust (ISD). Spacial structure was observed in these bands, as would be expected for emission from the ISD. The average column density of H I was calculated in each field of view along the scan path. All three bands show a significant correlation with H I. The obtained values are in excellent agreement with those computed for a mixture of graphite and silicate grains. A significant residual emission, not correlated with the H I column density, is evident in all three channels.

Lange, Andrew E.↗

The albedo and scattering phase function of interstellar dust and the diffuse background at far-ultraviolet wavelengths

The diffuse FUV background in a variety of targets has been observed with a nebular spectrometer designed specifically to eliminate potential sources of contamination. The intensity of the background near the Galactic plane is found to be much lower than previously published. The data are analyzed using a radiative transfer model with a limited set of free parameters, including those which describe the scattering properties of the interstellar dust. Strong evidence is presented that scattering of starlight by Galactic dust associated with neutral hydrogen produces the major part of the FUV diffuse background. Few assumptions are necessary to conclude that the albedo of the grains is low in the FUV. The grains, at least at high latitude, scatter fairly isotropically in the FUV. The low FUV albedo and the usual phase factor g are not consistent with predictions of standard models for the size distribution and composition of interstellar grains.

Hurwitz, Mark↗

Dirbe evidence for a wrap in the interstellar dust layer and stellar disk of the galaxy

The Diffuse Infrared Background Experiment (DIRBE) of the Cosmic Background Explorer (COBE) has mapped the surface brightness distributions of the Galactic plane at wavelengths from 1.25 to 240 micrometers. In these maps the latitude of peak brightness, as a function of longitude, traces a roughly sinusoidal curve of period approximately 360 deg. In the far-infrared, where emission by interstellar dust dominates the surface brightness, this curve agrees well with that derived from maps of the velocity-integrated H 1, suggesting that the layers of dust and neutral atomic hydrogen are similarly displaced from the Galactic plane. In the near-infrared (lambda less than 5 micrometers), where old disk stars dominate the emission, the brightness crest exhibits the same phase but roughly half the amplitude. The reduced amplitude of the warp in stellar light could result from a lesser warping of the stellar disk, or from a more rapid falloff of the density of stars relative to the density of gas, possibly due to a radial truncation of the disk.

Freudenreich, H. T.↗

Interstellar dust as generator of x ray radiation

The x ray generation due to arising of hot dense plasma balls at high-velocity (greater than or equal to 70 km/s) collisions of dust grains in the interstellar medium is considered. Analytical expressions for efficiency of conversions of colliding dust particle kinetic energy into x ray radiation are presented. The observed intensity distribution of the diffuse component of soft cosmic x rays (0.1 to 1 keV) may be partly caused by collisions between the dusty components of high velocity clouds and of the disk of the Galaxy.

Ibadov, Subhon↗

Chemical Evolution of Interstellar Dust into Planetary Materials

Comets are believed to retain some interstellar materials, stored in fairly pristine conditions since-their formation. The composition and properties of cometary dust grains should reflect those of grains in the outer part of the protosolar nebula which, at least in part, were inherited from the presolar molecular cloud. However, infrared emission features in comets differ from their interstellar counterparts. These differences imply processing of interstellar material on its way to incorporation in comets, but C and N appear to be retained. Overall dust evolution from the interstellar medium (ISM) to planetary materials is accompanied by an increase in proportion of complex organics and a decrease in pure carbon phases. The composition of cometary dust grains was measured in situ during fly-by missions to comet Halley in 1986. The mass spectra of about 5000 cometary dust grains with masses of 5 x 10(exp -17) - 5 x 10(exp -12) g provide data about the presence and relative abundances of the major elements H, C, N, O,Na, Mg, Al, Si, S, Cl, K, Ca, Ti, Cr, Fe, Ni. The bulk abundances of major rock-forming elements integrated over all spectra were found to be solar within a factor of 2, while the volatile elements H, C, N, O in dust are depleted in respect to their total cosmic abundances. The abundances of C and N in comet dust are much closer to interstellar than to meteoritic and are higher than those of dust in the diffuse ISM. In dense molecular clouds dust grains are covered by icy mantles, the average composition of which is estimated to be H:C:N:O = 96:14:1:34. Up to 40% of elemental C and O may be sequestered in mantles. If we use this upper limit to add H, C, N and O as icy mantle material to the abundances residing in dust in the diffuse ISM, then the resulting values for H. C, and N match cometary abundances. Thus, ice mantles undergoing chemical evolution on grains in the dense ISM appear to have been transformed into less volatile and more complex organic residues wherein the H, C and N are largely retained and ultimately accreted in cometary dust. The abundance of O is about the same for cometary dust, meteorites and interstellar dust. In all these samples, most of O in a solid phase is bonded to silicates. In dense molecular clouds, the abundance of O in dust+mantles is significantly higher then in cometary dust. This difference may reflect the greater lability of oxygenated species toward astrophysical processing. Laboratory studies show that O-bearing functional groups in organic compounds tend to be relatively easily removed by heating and/or UV and particle irradiation . In Halley's coma, O-containing organic grains, being unstable, were located closest to the nucleus. The decomposition of the organic grain component in the coma provided a significant extended source contribution to O-containing gaseous species such as CO and H2CO.

Fomenkova, M. N.↗

New measurements of the far ultraviolet scattering properties of interstellar dust

An analysis is presented for the spectra of the diffuse ultraviolet background taken during shuttle flight STS-61C (January 1986). Eight regions of the sky were observed for approximately 20 minutes each, using a spectrograph designed specifically to perform measurements of the UV background. The field of view was 3.8 deg x 8 min, with imaging along the slit to confine stellar contamination. The instrument featured a shutter mechanism to measure internal background during flight, a low-scatter holographically ruled diffraction grating, photon counting microchannel plate detectors, through baffling, and a crystal window to further attenuate stray light. The spectra covered the range 1400 to 1850 A and was binned in 50 A bands. The procedure for substracting the contribution of stars too faint to be detected as discrete sources during the observations (in general this represents a small fraction of the total intensity detected except at the longest wavelengths). A radiative transfer model used to interpret the data and set confidence intervals on the relevant parameters is described. It was found that the continuum component of the diffuse ultraviolet background arises primarily from two sources. One source is scattering of starlight by interstellar dust with an albedo of about 12 percent and a relatively isotropic phase function. A second source consists of about 150 photons/cm/sec/ster/A of extragalactic light which is attenuated by the dust in the galaxy. Although emission features possibly associated with molecular H2 are detected in one look direction, fluorescence of H2 is not a major contributor to the diffuse UV background, at least at galactic latitudes greater than -10 degrees.

Hurwitz, Mark↗

The Organic Component of Interstellar Dust

The distribution, chemical structure, and formation of organic matter in the interstellar medium are important to our understanding of the overall evolution of dust. The exchange of dust between the dense and diffuse interstellar medium, and the effects of processing on dust within dense clouds will affect the inventory of material available for incorporation into newly forming star and planetary systems. Observational ground-based studies have confirmed the widespread distribution of the 3.4 pm absorption band attributed to aliphatic hydrocarbons in the diffuse interstellar medium of our own galaxy, and in the dusty spectra of a few nearby galaxies, while space based observations from IS0 probed the signatures of corresponding mid-infrared features. Laboratory experiments which utilize both thermal processes and energetic processing by high energy photons and cosmic rays, produce candidate materials which offer close matches to the observed diffuse interstellar medium and extragalactic hydrocarbon absorption features. Through an analysis of the 4000 to 1000 cm (2.5 to 10 micrometers) region of the spectrum of diffuse interstellar medium (DISM) dust compared with the spectra of thirteen chemical entities produced in the laboratory which serve as analogs to the interstellar material, significant constraints have been placed on the applicability of proposed candidate materials to explain the interstellar features. The results indicate that the organic refractory material in the diffuse interstellar medium is predominantly hydrocarbon in nature, possessing little nitrogen or oxygen, with the carbon distributed between the aromatic and aliphatic forms. Long alkane chains H3C-(CH2),- with n much greater than 4 or 5 are not major constituents of this material. Comparisons to laboratory analogs indicate the DISM organic material resembles plasma processed pure hydrocarbon residues much more so than energetically processed ice residues. This result is consistent with a birthsite for the carrier of the 3.4 micrometers band in the outflow region of evolved carbon stars. Comparisons of dust from our own galaxy with that of distant galaxies suggests that the organic component of interstellar dust is widespread and may be an important universal reservoir of prebiotic organic carbon.

Pendleton, Yvonne↗

Unusual relative strengths of the diffuse interstellar bands in some interstellar dust clouds

Some of the diffuse interstellar features (DIBs) in the spectra of certain stars at high galactic latitudes (1 is greater than 15 degrees) are unusually weak or absent while others have the strength expected for their color excess. In some cases the stars are probably reddened by single interstellar clouds. There appear to be three families of DIBs. The effects of these families are examined. The existance of the three families implies that at least three agents cause the DIBs and that the proportions of the agents or the physical conditions giving rise to the DIBs can vary from cloud to cloud.

Krelowski, J.↗

Interplanetary and Interstellar Dust Observed by the Wind/WAVES Electric Field Instrument

Observations of hypervelocity dust particles impacting the Wind spacecraft are reported here for the first time using data from the WindWAVES electric field instrument. A unique combination of rotating spacecraft, amplitude-triggered high-cadence waveform collection, and electric field antenna configuration allow the first direct determination of dust impact direction by any spacecraft using electric field data. Dust flux and impact direction data indicate that the observed dust is approximately micron-sized with both interplanetary and interstellar populations. Nanometer radius dust is not detected by Wind during times when nanometer dust is observed on the STEREO spacecraft and both spacecraft are in close proximity. Determined impact directions suggest that interplanetary dust detected by electric field instruments at 1 AU is dominated by particles on bound trajectories crossing Earths orbit, rather than dust with hyperbolic orbits.

Wind spacecraft↗

Comet Halley as an aggregate of interstellar dust and further evidence for the photochemical formation of organics in the interstellar medium

Photolysis of mixtures of CO:NH3:H2O at 12 K results in the formation of an organic residue which is not volatile in high vacuum at room temperature. Analysis of this fraction by GC-MS resulted in the detection of C2-C3 hydroxy acids and hydroxy amides, glycerol, urea, glycine, hexamethylene tetramine, formamidine and ethanolamine. Use of isotopically labeled gases made it possible to establish that the observed products were not contaminants. The reaction pathways for the formation of these products were determined from the position of the isotopic labels in the mass spectral fragments. The significance of these findings to the composition of comets and the origins of life is discussed.

Briggs, R.↗

Hydrocarbons on Saturns Satellites: Relationship to Interstellar Dust and the Solar Nebula

To understand the origin and evolution of our Solar System, and the basic components that led to life on Earth, we study interstellar and planetary spectroscopic signatures. The possible relationship of organic material detected in carbonaceous meteorites, interplanetary dust particles (IDPs), comets and the interstellar medium have been the source of speculation over the years as the composition and processes that governed the early solar nebula have been explored to understand the extent to which primitive material survived or became processed. The Cassini VIMS has provided new data relevant to this problem. Three of Saturn's satellites, Phoebe, Iapetus, and Hyperion, are found to have aromatic and aliphatic hydrocarbons on their surfaces. The aromatic hydrocarbon signature (C-H stretching mode at 3.28 micrometers) is proportionally significantly stronger (relative to the aliphatic bands) than that seen in other Solar System bodies (e.g., comets) and materials (Stardust samples, IDPs, meteorites) and the distinctive sub-features of the 3.4 micrometer aliphatic band (CH2 and CH3 groups) are reminiscent of those widely detected throughout the diffuse ISM. Phoebe may be a captured object that originated in the region beyond the present orbit of Neptune, where the solar nebula contained a large fraction of original interstellar ice and dust that was less processed than material closer to the Sun. Debris from Phoebe now resident on Iapetus and Hyperion, as well as o Phoebe itself, thus presents a unique blend of hydrocarbons, amenable to comparisons with interstellar hydrocarbons and other Solar System materials. The dust ring surrounding Saturn, in which Phoebe is embedded, probably originated from a collision with Phoebe. Dust ring particles are the likely source of the organic-bearing materials, and perhaps the recently identified small particles of Fe detected on Saturn's satellites. Lab measurements of the absolute band strengths of representative aliphatic and aromatic molecules, together with measurements from the VIMS data, allow us to calculate the number of C atoms to find the relative abundances of C atoms in the two kinds of organic molecules. The strength of the prominent aromatic C-H stretch band relative to the aliphatic band complex in Phoebe and Iapetus indicates that the relative abundance of aromatic to aliphatic carbon is very large (greater than 200). In contract, the aromatic band is nearly imperceptible in spectra of interplanetary dust particles (IDP), returned samples from comet 91P/Wild 2, insoluable carbonaceous material in most meteorites, and the diffuse interstellar dust (DISM) (although aromatics are known in all these materials-here we consider only the spectroscopic signature)

Cruikshank, D. P.↗