SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Electric ion source in orbit around earth to generate probes for magnetosphere studies of electric fields, ion diffusion, and distant magnetic field configuration
The permeability of Halobacterium halobium vesicle membranes to potassium ions was investigated, and possible mechanisms for the regulation of the gradient of protons by the transmembrane movement of these ions were studied. The lack of a potassium ion diffusion potential in the absence of valinomycin, light-induced electrical potentials in excess of the chemical potential difference for potassium ions, and direct measurements of potassium ion influx during illumination show that the membranes are relatively impermeable to these ions. As a result of sodium ion extrusion during illumination, chlorine ions and water must be lost and the vesicles collapse. The light-induced collapse of vesicles is diminished only if the influx of potassium ions is increased.
Commercialization of lithium-air batteries faces many challenges, such as electrolyte decomposition, short cycle life, low energy and power density, etc. However, commercialization of Li-O2 batteries for aeronautics is much more challenging due to additional safety constraints on cyclability and performance (high specific power and specific energy). For this presentation, we will discuss inter-related aspects of physics-based modeling of a pack: cell and battery model calibration. In addition, we will evaluate and present optimal battery designs for high discharge current density, high discharge time, and low battery mass using simulation-based optimization.The Finite Element Model (FEM) used to simulate a Li-O2 cell is based on the work of Bevara [1]. The different aspects of the model are based on: porous electrode theory and concentrated electrolyte theory; quantum tunneling model for the resistance of conformal layer of discharge product (Li2O2) [1]; Butler-Volmer kinetics for electrochemical reaction; Fick's diffusion for oxygen transport; and an oxygen dissolution model is applied at the air/electrolyte interface [2]. The electrolyte properties such as ion conductivity, ion diffusion, oxygen diffusion, and mass density of the electrolyte were taken from Molecular Dynamics (MD) simulations [3]; while the other model parameters, which includes mass of cell components, were calibrated to match experiments at high discharge current densities. The cell mass includes the anode, cathode, separator, electrolyte, and other components (such as current collector). This calibrated model is used to perform parametric studies on cathode thickness, porosity, tortuosity, carbon particle size, electrolyte transport and material properties, partial pressure of oxygen, discharge time, and discharge current density to study optimal designs for high specific power and energy. References:1. Bevara, V. & Andrei, P. (2014), J. Electrochem. Soc. 161 (14), A2068-A2079.2.Mehta, M. & Andrei, P. (2015), J. Power Sources. 286, 299-308.3.Liyana-Arachchi, T.; Haskins, J.; Burke, C.; Diederichsen, K.; McCloskey, B.; & Lawson, J. (2018), J. Phys. Chem. B. 122 (36), 8548 - 8559.4.Choi, W.; Kikumoto, H.; Choudhary, R. & Ooka, R. (2018), Applied Energy, 209, 306-321.
Model calculations of the neutral O cloud of Io, based on atom-electron-impact excitation and ionization processes in the plasma torus, are presented. The model is quantitatively anchored to the 6300-A O I emission intensity observations of Brown (1981), and uses a plasma temperature and density structure based on Voyager 1 and 2 and EUV data. Parameters predicted by the model include satellite emission flux = 1.5 x 10 to the 9th/sq cm sec, ion-loading rate = 6.2 x 10 to the 26th ions/sec, O mass-loading rate = 16.6 kg/sec, and O ion-energy input rate = 2.7 x 10 to the 10th W. The spatial morphologies of the parameters are shown. Rough estimates obtained by accounting for a neutral S cloud and plasma-torus charge-exchange reactions include O source flux = 1.2 x 10 to the 10th/sq cm sec, ion-loading rate = 4.0 x 10 to the 27th ions/sec, ion-diffusive-loss time = 200 days, plasma mass-loading rate = 150 kg/sec, satellite mass-loss rate = 270 kg/sec, and maximum ion-energy input = 4 x 10 to the 11th W.
The diffusion in velocity space of cometary ions was studied using the distributions of ions measured by the implanted ion spectrometer in Giotto during the inbound pass. The measurements were transformed into a frame comoving with the solar wind and oriented with the magnetic field. The observations show the evolution of the pitch angle distribution in the solar wind turbulence to form a shell from the initial ring. Diffusion in energy takes place simultaneously but on a longer time scale. Comparison with theory is inhibited by the lack of a suitable spatial model, but the simple arguments that can be made indicate that pitch angle diffusion and the process of parallel pickup take place more slowly than theory suggests.
A finite one-dimensional kinetic model was developed to estimate the cooling rates of lunar rocks. The model takes into consideration the compositional zonation of olivine and applies Buening and Buseck (1973) data on ion diffusion in olivine. Since the 'as-solidified' profile of a given olivine is not known, a step-function, with infinite gradient, is assumed; the position of this step is based on mass balance considerations of the measured compositional profile. A minimum cooling rate would be associated with the preservation of a given gradient. The linear cooling rates of lunar rocks 12002 and 15555 were estimated by use of the olivine cooling-rate indicator to be 10 C/day and 5 C/day, respectively. These values are lower than those obtained by dynamic crystallization studies (10-20 C/day).
The source of energetic particles in two upstream events which occurred during the great magnetospheric compression of November 1, 1984 were investigated. Ten tests, which could distinguish between the Fermi and the leakage sources for upstream diffuse ion events, were applied to simultaneous magnetospheric, magnetosheath, and upstream energetic particle observations obtained during the November-1 upstream events by several spacecraft. Results showed that magnetospheric leakage satisfactorily explains these observations, while in situ Fermi acceleration does not. It is concluded that, during these two events, magnetospheric leakage was a sufficient source for upstream particles.
A theoretical model of the Jovian magnetosphere is used to describe the mechanism by which energy is transported from Jupiter's rotation into heavy ions precipitating into the atmosphere, and resulting in intense ultraviolet aurora. The flow and magnetic field configurations used in the model are drawn from data collected by the Voyager orbiter. It is shown that the observed Jovian auroral radiation power is supplied by the precipitation of heavy ions of Iogenic origin. The ions are created by a charge exchange between the Io torus and fly as neutrals to the outer magnetosphere. A small fraction of the ions are photoionized in the outer magnetosphere where they acquire a magnetic moment determined by the local corotation electric field and planetary magnetic field. As the ions diffuse inward they are energized adiabatically. A schematic drawing illustrating the evolution of this process is provided. It is also shown that Jupiter may be a significant source of heavy ions for the solar wind by means of photoionization of a neutral wind. Secondary charge exchange in the outer magnetosphere could supply a flux of minimum energy neutral atoms that may have been measured by the Voyager Low Energy Charged Particle detector (LECP).
The objective of the research is to use the low-frequency wave spectrum measured by the Plasma Wave Instrument on the DE-1 spacecraft to include the wave-particle interaction (WPI) in the different polar wind models that are available at Utah State University. A Monte Carlo technique was used to simulate the ion diffusion in the velocity space due to scattering by the waves. This enabled us to study the effect of WPI on the magnitude as well as the composition of the outflow of the ionospheric ions. In particular, in the first year the 1-D semi-kinetic code developed by Barakat and Schunk (1983) was modified in order to include the effect of the WPI.
Calculating free energy in computer simulations is of central importance in statistical mechanics of condensed media and its applications to chemistry and biology not only because it is the most comprehensive and informative quantity that characterizes the eqUilibrium state, but also because it often provides an efficient route to access dynamic and kinetic properties of a system. Most of applications of equilibrium free energy calculations to non-equilibrium processes rely on a description in which a molecule or an ion diffuses in the potential of mean force. In general case this description is a simplification, but it might be satisfactorily accurate in many instances of practical interest. This hypothesis has been tested in the example of the electrodiffusion equation . Conductance of model ion channels has been calculated directly through counting the number of ion crossing events observed during long molecular dynamics simulations and has been compared with the conductance obtained from solving the generalized Nernst-Plank equation. It has been shown that under relatively modest conditions the agreement between these two approaches is excellent, thus demonstrating the assumptions underlying the diffusion equation are fulfilled. Under these conditions the electrodiffusion equation provides an efficient approach to calculating the full voltage-current dependence routinely measured in electrophysiological experiments.
A comparison is made between recent AMPTE/IRM observations of diffuse ions detected upstream of the earth's bow shock when the interplanetary magnetic field was nearly parallel to the solar wind direction and a known collisionless quasi-parallel shock model. These observations, which provide the proton spectrum for all of velocity space, give a direct measure of the shock acceleration efficiency and show how thermal solar winds are injected into the diffusive shock acceleration mechanism. The model accurately describes the proton spectrum; moreover, it predicts the shock structure, the complete particle spectrum, the relative velocity distributions of different ion species in the down stream region, and the enhancement of heavy ions over protons relative to the unshocked solar wind.
It has recently been suggested that Io is an important source of ions for the plasma detected by Pioneer 10 in the inner magnetosphere of Jupiter. Assuming this to be true, we show that near the orbit of Io the central collector of the Pioneer-10 plasma instrument could detect only inwardly diffusing ions created at a radial distance greater than that of the spacecraft. The rapid decrease in ion density observed beyond Io's orbit is attributed, at least partially, to this effect and thus may not represent a real plasma boundary such as a 'plasmapause'. Instead, the drop in observed ion density could correspond to a decrease in the density of Io-associated neutral particles orbiting Jupiter.
Examples of an interplanetary and the bow shock illustrate the small relative size of the electrostatic layer relative to the scale of the magnetic fluctuations in quasi-parallel shocks. While both examples are supercritical, the interplanetary example is marginally so, showing a thickness in absolute and convected ion larmor radii units that is thicker (approximately 13 U/omega sub ci) than at the bow shock (approximately omega sub ci). The fluid speed changes abruptly in the quasi-parallel shock on this shorter scale. The increase in electron and ion random energies also is clearly seen on this shorter scale. In the interplanetary example the scale of the electric layer is certainly less than 1/60th that of the up or downstreams magnetic fluctuations. The thickness of the earth's bow shock deceleration layer is dramatically narrower than any domain of upstream waves as controlled by reflected, intermediate, or diffuse ions.
Additive manufacturing, also called 3D printing, represents a unique approach to develop three dimensional shape-conformable batteries with enhanced electrodes, specific surface area, improved ion diffusion, and power. For the first time, the formulation of a composite photocurable resin loaded with battery electrochemically active components was designed to feed a vat photopolymerization (VPP) 3D printer. In direct alignment with NASA’s Artemis mission goals to develop sustainable lunar energy storage infrastructure necessary to support long-term human operations, TiO 2 was here selected as an active material for the negative electrode for sodium-ion and lithium-ion batteries due to its abundance on the lunar surface. The TiO 2 loading in the composite photocurable resin and in the resulting VPP-printed negative electrode was increased as high as possible to enhance the electrochemical performance, while simultaneously ensuring the printability and acceptable mechanical strength for sample handling. The effect of thermal post-processing on the electrical, electrochemical and mechanical performance is reported. Finally, a configurational study is implemented to identify the impact of two different electrode designs (cubic and gyroid lattice unit cells) on the electrochemical performance. This work addresses the difficulties related to the introduction of solid particles within a VPP photocurable resin and the need for a compromise between the electrochemical performances and printability to obtain fully functional VPP-printed electrodes.
The quasi-linear diffusion of particles from resonant interactions with a spectrum of electrostatic waves is investigated theoretically, extending results obtained for no magnetic field and for strong magnetic fields to cases where the ambient magnetic field which organizes azimuthally symmetric wave and particle distributions does not have to be taken into consideration in evaluating the local interaction. The derivation of the governing equations is explained, and numerical results are presented in extensive graphs and characterized in detail. Slow-mode ion-acoustic waves are shown to be unstable under the plasma conditions studied, and the dependence of resonant-ion diffusion rates with pitch angle, speed, and the distribution of wave energy in wavenumber space is explored. The implications of the present findings for theoretical models of the earth bow shock and plasma-sheet boundary layer are indicated.
The linear theory of the electromagnetic ion beam instability for arbitrary angles of propagation has been studied. The parameters considered in the theory are typical of the solar wind upstream of the earth's bow shock when a 'reflected' proton beam is present. Maximum growth occurs for propagation parallel to the ambient magnetic field B, but this instability also displays significant growth at wave-vectors oblique to B. Oblique, unstable modes seem to be the likely source of the compressive magnetic fluctuations recently observed in conjunction with the 'diffuse' ion population. An energetic ion beam does not directly give rise to linear growth of either ion acoustic or whistler mode instabilities.
The electron diffusion region forms the inner core of the magnetic reconnection machine. In this region, physical processes act to sustain a reconnection electric field, they accelerate to provide current density, and the heat to provide particle pressure in the current layer. The relative roles of these processes depend on whether the overall geometry is anti-parallel or asymmetric, and whether a guide field is present of not, but the overall concept applies in each case. The EDR is embedded in successively larger regions, starting with the ion diffusion region to even larger scales, where the plasma increasingly behaves like an anisotropic MHD plasma. With our new understanding of how the EDR works, it is of great interest to study how EDR processes couple to the larger scale environment. The ultimate efficacy of the magnetic reconnection is shaped by this interesting example of micro-macro coupling. In this presentation, we present some thoughts pertaining to this topic. In particular, we will discuss how information transport between scales is mediated, and how the very small scales can reach balance with the larger, overall system. We will review any pertinent research and present a set of questions inviting future research.
The structure of the drift instability was examined in several density regimes. Let sub e be the total electron mean free path, k sub z the wave-vector component along the magnetic field, and the ratio of perpendicular ion diffusion to parallel electron streaming rates. At low densities (k sub z lambda 1) the drift mode is isothermal and should be treated kineticly. In the finite heat conduction regime square root of m/M k sub z Lambda sub 1) the drift instability threshold is reduced at low densities and increased at high densities as compared to the isothermal threshold. Finally, in the energy transfer limit (k sub z kambda sub e square root of m/M) the drift instability behaves adiabatically in a fully ionized plasma and isothermally in a partially ionized plasma for an ion-neutral to Coulomb collision frequency ratio.