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At least 91 records · Page 5

A Dual Source Ion Trap Mass Spectrometer for the Mars Organic Molecule Analyzer of ExoMars 2018

We present details on the objectives, requirements, design and operational approach of the core mass spectrometer of the Mars Organic Molecule Analyzer (MOMA) investigation on the 2018 ExoMars mission. The MOMA mass spectrometer enables the investigation to fulfill its objective of analyzing the chemical composition of organic compounds in solid samples obtained from the near surface of Mars. Two methods of ionization are realized, associated with different modes of MOMA operation, in a single compact ion trap mass spectrometer. The stringent mass and power constraints of the mission have led to features such as low voltage and low frequency RF operation [1] and pulse counting detection.

Brickerhoff, William B.↗

Miniaturized GC/MS instrumentation for in situ measurements: micro gas chromatography coupled with miniature quadrupole array and paul ion trap mass spectrometers

Miniaturized chemical instrumentation is needed for in situ measurements in planetary exploration and other spaceflight applications where factors such as reduction in payload requirements and enhanced robustness are important. In response to this need, we are 'continuing to develop miniaturized GC/MS instrumentation which combines chemical separations by gas chromatography (GC) with mass spectrometry (MS) to provide positive identification of chemical compounds in complex mixtures of gases, such as those found in the International Space Station's cabin atmosphere. Our design approach utilizes micro gas chromatography components coupled with either a miniature quadrupole mass spectrometer array (QMSA) or compact, high-resolution Paul ion trap.

GC/MC miniature mass spectrometry MEMS↗

A Quadrupole Ion Trap Mass Spectrometer for Quantitative Analysis of Nitrogen-Purged Compartments within the Space Shuttle

To enter orbit, the Space Shuttle burns 1.8 million liters of liquid hydrogen combined with 0.8 million liters of liquid oxygen through three rocket engines mounted in the aft. NASA monitors the nitrogen-purged aft compartment for increased levels of hydrogen or oxygen in order to detect and determine the severity of a cryogenic fuel leak. Current monitoring is accomplished with a group of mass spectrometer systems located as much as 400 feet away from the Shuttle. It can take up to 45 seconds for gas to reach the mass spectrometer, which precludes monitoring for leaks in the final moments before liftoff (the orbiter engines are started at T-00:06 seconds). To remedy the situation, NASA is developing a small rugged mass spectrometer to be used as point-sensors around the Space Shuttle. As part of this project, numerous mass analyzer technologies are being investigated. Presented here are the preliminary results for one such technology, quadrupole ion trap mass spectrometry (QITMS). A compact QITMS system has been developed in-house at the University of Florida for monitoring trace levels of four primary gases, hydrogen, helium, oxygen, and argon, all in a nitrogen background. Since commercially available QITMS systems are incapable of mass analysis at m/z(exp 2), the home-built system is preferred for the evaluation of QITMS technology.

Ottens, Andrew K.↗

Improved Linear Ion Trap

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Linear Ion Trap (LIT) ions microwave resonance reg↗

A (201)Hg+ Comagnetometer for (199)Hg+ Trapped Ion Space Atomic Clocks

A method has been developed for unambiguously measuring the exact magnetic field experienced by trapped mercury ions contained within an atomic clock intended for space applications. In general, atomic clocks are insensitive to external perturbations that would change the frequency at which the clocks operate. On a space platform, these perturbative effects can be much larger than they would be on the ground, especially in dealing with the magnetic field environment. The solution is to use a different isotope of mercury held within the same trap as the clock isotope. The magnetic field can be very accurately measured with a magnetic-field-sensitive atomic transition in the added isotope. Further, this measurement can be made simultaneously with normal clock operation, thereby not degrading clock performance. Instead of using a conventional magnetometer to measure ambient fields, which would necessarily be placed some distance away from the clock atoms, first order field-sensitive atomic transition frequency changes in the atoms themselves determine the variations in the magnetic field. As a result, all ambiguity over the exact field value experienced by the atoms is removed. Atoms used in atomic clocks always have an atomic transition (often referred to as the clock transition) that is sensitive to magnetic fields only in second order, and usually have one or more transitions that are first-order field sensitive. For operating parameters used in the (199)Hg(+) clock, the latter can be five orders of magnitude or more sensitive to field fluctuations than the clock transition, thereby providing an unambiguous probe of the magnetic field strength.

Burt, Eric A.↗

Magnetospherically trapped ions as a source of magnetosheath energetic ions

It has been suggested that energetic ions observed in the magnetosheath may be due to the direct leakage of trapped magnetospheric ions. To test this hypothesis, three-dimensional ion spectra from the energetic particle experiment on ISEE 1 for a magnetopause crossing on Nov. 10, 1977 are utilized to construct three-dimensional distribution functions in the magnetosphere and in the sheath. Using the observed magnetic field, a simple one-dimensional model of the magnetopause is developed. Ions are then followed in the model, starting in the magnetosphere, through the magnetopause and ending up in the sheath. Using Liouville's Theorem a model sheath distribution function is then built up by following the magnetospheric distribution function through the model fields. The model distribution is then compared with the observed sheath distribution. For this case it is found that the main features of the observed ions in the sheath are consistent with direct leakage and with no energization or de-energization processes, and an inward-pointing normal component is required. The energetic particles mapped in this case apparently follow a flux tube which does not penetrate the magnetopause where local tangential electric fields have been reported.

Speiser, T. W.↗

Effects of equatorially trapped ions on refilling of the plasmasphere

The kinetic aspects of shock formation in response to the equatorial heating of ions are reported by means of small-scale kinetic simulations of countersteaming plasma flows along a spatially varying magnetic field having the features of the dipolar magnetic field lines. Attention is given to the trapping of the field-aligned flowing ions in response to the simulated equatorial heating of ions and the associated self-consistent structures in the electric potentials and the f-plasma flow pattern. Trapping is found to lead to the formation of electrostatic shocks, which propagate away from the 'equator' as seen in the hydrodynamic model of Singh and Torr (1990). The shocks form near the mirror points of the 'equatorially' heated ions. The second stage of the refilling with equatorially trapped ions is reported. A variety of structures in density and temperature distributions as the refilling proceeds slowly is found.

Singh, Nagendra↗

Comparison between Liouville's theorem and observed latitudinal distributions of trapped ions in the plasmapause region

The presence of anisotropic plasma distributions, trapped at the Earth's magnetic equator, has consequences for the electric field structure which must exist in equilibrium along the magnetic field line. Data from SCATHA and Dynamics Explorer 1 indicate that the core ion distributions at the magnetic equator can be well described as bi-Maxwellian distributions, with a perpendicular temperature an order of magnitude larger than the parallel temperature. A collisionless model is developed for the variation in plasma parameters, following the forms developed by Whipple (1977). If the core electron anisotropy is low, the resulting electric field of approximately 0.1 microV/m is pointed away from the equator. Under these conditions the self-consistent electric field will not overcome the effects of magnetic trapping. The resulting potential distribution results in a local maximum in total plasma density at the equator. Only when the electron distribution is primarily field-aligned can there be a density minimum at the equator. Comparisons are made between this model and the observed variations in DE 1 plasma parameters with latitude.

Olsen, R. C.↗

Planar ion trap (retarding potential analyzer) experiment for atmosphere explorer

The retarding potential analyzer and drift meter were carried aboard all three Atmosphere Explorer spacecraft. These instruments measure the total thermal ion concentration and temperature, the bulk thermal ion velocity vector and some limited properties of the relative abundance of H(+), He(+), O(+) and molecular ions. These instruments functioned with no internal failures on all the spacecraft. On AE-E there existed some evidence for external surface contamination that damaged the integrity of the RPA sweep grids. This led to some difficulties in data reduction and interpretation that did not prove to be a disastrous problem. The AE-D spacecraft functioned for only a few months before it re-entered. During this time the satellite suffered from a nutation about the spin axis of about + or - 2 deg. This 2 deg modulation was superimposed upon the ion drift meter horizontal ion arrival angle output requiring the employment of filtering techniques to retrieve the real data.

Hanson, W. B.↗

Trapped-ion frequency standards

Frequency standards based on stored atomic ions are briefly reviewed. Specific examples are chosen to illustrate what is currently possible. Both rf/microwave and optical devices are discussed. The present limitations to existing experiments and possibilities for future improvement are outlined.

Wineland, David J.↗

A Quadrupole Ion Trap Mass Spectrometer for Quantitative Analysis of Nitrogen-Purged Compartments within the Space Shuttle

To enter orbit the Space Shuttle burns 1.8 million liters of liquid hydrogen combined with 0.8 million liters of liquid oxygen through three rocket engines mounted in the aft. NASA monitors the nitrogen-purged aft compartment for increased levels of hydrogen or oxygen in order to detect and determine the severity of a cryogenic fuel leak. Current monitoring is accomplished with a group of mass spectrometer systems located as much as 400 feet away from the shuttle. It can take up to 45 seconds for gas to reach the mass spectrometer, which precludes monitoring for leaks in the final moments before liftoff (the orbiter engines are started at T-00:06 seconds). To remedy the situation, NASA is developing a small rugged mass spectrometer to be used as point-sources around the Space Shuttle.

Ottens, Andrew K.↗