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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Neutron Identification Capabilities in MicroBooNE Through the Application of Machine Learning with Blips

Neutrinos (ν) are subatomic particles first observed in 1956 by LANL physicists Clyde Cowan and Frederick Reines but first theorized by Wolfgang Pauli in 1930. Neutrinos are the least massive known particle and are classified as leptons with 3 flavors corresponding to their leptonic counterparts (electron, muon, and tau). We know that they are abundant, 65 billion neutrinos travel through your fingertip every second, and elusive, a single neutrino could fly through a lightyear of lead without interacting at all. Though, there is much still unknown and a better characterization of these “ghostly” particles can give us clues as to the matter/anti-matter asymmetry in the early universe and possible glimpses into new physics. To measure a particle that is extremely light and rarely interacting, physicists have developed an extremely sensitive detector known as a Liquid Argon Time Projection Chamber (LArTPC). The fiducial volume (or TPC) is bombarded with neutrinos, some of which interact with argon (Ar) atoms to produce particles that in turn excite and ionize the Ar. The products of these are free electrons which then drift through the TPC’s applied magnetic field towards a multi-plane wire readout system. The electrons’ charge is collected at this anode and the light from the initial interactions is collected by photomultiplier tubes (PMTs). In conjunction, these mechanisms allow LArTPCs to achieve millimeter spatial resolution and sub-MeV energy thresholds. The detector of interest in this study is the MicroBooNE Experiment at Fermilab. MicroBooNE is an above ground LArTPC with dimensions of approximately 10m × 2.5m × 2.3m, about the size of a school bus. Its purpose is to study neutrinos, so to improve rates of measured ν interactions, the detector is squarely in the path of the Booster Neutrino Beam (BNB) at Fermilab. A major challenge in neutrino studies is energy reconstruction, much of the neutrino’s original energy is lost in interactions that the detector is not sensitive to, often due to low-energy products. The initial goal of this analysis was to better identify neutrons, the main source of poor energy reconstruction in neutrino events. Because neutrons are neutral particles, like neutrinos, we can only directly measure the products of their interactions in LArTPCs. Most of these products are low-energy signals and while each one contributes a negligible amount of energy, collectively these signals make up most of the lost energy in each neutrino event. We define these signals as blips; point-like, isolated depositions of charge in the detector. Blips have MeV-scale energies and are the size of a single hit (charge deposition) or a cluster of a few hits on at least two wire planes. Blips are the principal detector features used to study low-energy physics; thus, they are the key to unlocking information not only about neutrons but gamma photons, supernova and solar neutrinos as well as helping us better identify certain particles. Therefore, this analysis strives to use blips for improved neutron identification (ID) and characterization.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Benchmarking Cu/BEA and HBEA catalysts for high-octane gasoline synthesis

We distinguish rates at which carbon deposition occurs during initiation, rates at which catalytic centers are lost during deactivation, and paraffin-to-olefin ratio during propagation as benchmarks that distinguish 5 wt% Cu/H-BEA and H-BEA (Si/Al = 13.5) catalysts during dimethyl ether (DME) homologation in the presence of hydrogen. Studies that systematically vary initial DME contact time (210, 94, and 45 mol H+, initial s (mol C ) -1 ), DME pressure (4 and 22 kPa), and H 2 pressure (1, 24, and 48 kPa) reveal that Cu enables lower carbon deposition rates (on a per proton basis) in the induction period, increases the effluent paraffin-to-olefin ratio during propagation, and decreases the instantaneous site-loss yields by a factor of ~ 1.5-2x (moles of active sites lost per mole of DME) during termination sequences thus affecting the degree of product saturation and catalyst stability during DME homologation. Furthermore, these results provide mechanistic insights revealing the critical role of Cu in facilitating DME homologation to high value, high-octane gasoline-range hydrocarbons with higher cumulative turnovers than proton form H-BEA.

09 BIOMASS FUELS↗

Industrial Energy Management During a Pandemic: Lessons Learned from DOE Better Plants Program Partners

The COVID-19 pandemic is causing many challenges for manufacturers, especially those that depend on workers whose jobs cannot be performed remotely. This has detrimentally impacted the energy management workforce, energy support system performance, as well as operations and supply chains.This article discusses four primary challenges for industrial energy management caused by the pandemic, strained budget for energy projects, increased energy intensity caused by low production rates and other safety practices, limited access to energy systems, and the lost knowledge and experience of senior staff. This article also proposes some potential solutions for these challenges that include implementing no- and low-cost energy conservation measures, adopting alternative financing options, improving shutdown procedures, reducing baseloads, creating an effective online energy-monitoring system, performing virtual energy assessments, building a robust EnMS, and attending online and in-person training events.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Thermal volatilization studies on lunar samples.

The results of thermal volatilization studies on lunar basalts, breccias, and soils, carried out to measure the depletion of selected elemental abundances during heating under vacuum, are evaluated. The kinetics of K, Rb, and Pb loss are found to be sufficiently fast to permit vaporization and loss of these elements during the production of impact glasses. There is little probability that lunar basalt flows have lost a significant percentage of K, Rb, and Na by volatilization, unless the flow is extensively stirred. The uniformly low Na concentrations of mare basalts cannot be attributed to post eruption vaporization and loss on Na.

Gibson, E. K., Jr.↗

Utilizing remote sensing of Thematic Mapper data to improve our understanding of estuarine processes and their influence on the productivity of estuarine-dependent fisheries

The purpose of the project is to refine and validate a probabilistic spatial computer model through the analyses of thematic mapper imagery. The model is designed to determine how the interface between marshland and water changes as marshland is converted to water in a disintegrating marsh. Coastal marshland in Louisiana is disintegrating at the rate of approximately 40 sq mi a year, and an evaluation of the potential impact of this loss on the landings of estuarine-dependent fisheries is needed by fisheries managers. Understanding how marshland-water interface changes as coastal marshland is lost is essential to the process of evaluating fisheries effects, because several studies suggest that the production of estuarine-dependent fish and shellfish may be more closely related to the interface between marshland and water than to acreage of marshland. The need to address this practical problem has provided an opportunity to apply some scientifically interesting new techniques to the analyses of satellite imagery. Progress with the development of these techniques is the subject of this report.

Browder, Joan A.↗

Decontamination Strategies to Increase Fuel and Product Conversion Yields of Municipal Solid Waste

Since the implementation of China’s Green Fence and National Sword policies, many areas lost a market for heavily contaminated municipal solid waste (MSW). Approximately 17.2 million tons of paper and 26.9 million tons of plastic were landfilled in the United States in 2018. This non-recyclable waste that would normally be landfilled can be converted into fuels and chemicals, but common contaminants that are present in non-recyclable waste can negatively affect low and high-temperature conversion yields. In addition, MSW is a heterogeneous feedstock whose composition can vary widely across geographical areas and socio-economic statuses. This presents a unique challenge for providing a consistent feedstock to biorefineries around the world. Techniques that are commonly used in other industries, in addition to pre-processing methods used for traditional biomass, can be used to increase conversion yields. Drawing on established techniques, as well as experimental decontamination strategies, non-recyclable MSW could represent a viable alternative to agricultural residues for biofuel production. Although many of the techniques explored in this chapter have been used extensively in other industries, the feedstock composition needs to be carefully considered when choosing prospective decontamination methods. It is likely that there is not a “one-size-fits-all” decontamination method for MSW. In conclusion, a pre-processing and decontamination plan will rely heavily on the composition of the individual waste stream.

09 BIOMASS FUELS↗

Self-Assembling Cell-Free Systems for Scalable Bioconversion

This project focused on developing cell-free systems to directly express multi-enzyme catalysts and perform CO2 bioconversions for industrial chemical production. The use of cell-free expression (CFE) systems derived from bacterial lysates is emerging as a promising approach for biomanufacturing. CFEs are genetically programmable, permit the expression of toxic enzymes, and allow for rapid prototyping of metabolic pathways. Research Contributions: 1. Understanding the Area Investigated: This research advances the understanding of cell-free systems by demonstrating their capability to perform complex multi-enzyme reactions. By directly expressing multi-gene systems, CFEs avoid the high costs and inefficiencies associated with producing and purifying enzymes for multi-step pathways. 2. Technical Effectiveness and Economic Feasibility: The project successfully engineered a CFE-based multienzyme biocatalyst for the de novo synthesis of serine and glycine from CO2 equivalents (formate and bicarbonate) and ammonia. This method achieved a 30% conversion rate of formate into these industrially important amino acids. Additionally, an 8-gene CFE biocatalyst was developed to produce malate, conserving 43% of carbon that would otherwise be lost as CO2. This approach has the potential to reach higher carbon efficiency than microbial production. 3. Public Benefit: The cell-free production of chemicals like serine, glycine, and malate using electrochemically generated formate could significantly reduce CO2 emissions. For example, satisfying the global malate market with this method could avoid approximately 400,000 tons of CO2 emissions annually. This work demonstrates the potential of CFE systems to produce platform chemicals, contributing to environmental sustainability and reducing reliance on petrochemicals. Future Prospects: The CFE-based biocatalyst process could be extended to produce a variety of chemicals, including other industrial di-acids, aromatics, terpenes, alcohols, and polymers. This project showcases the capabilities of cell-free expression systems for prototyping carbon-conserving pathways and sustainably bioproducing platform chemicals, marking a significant step towards economically-viable industrial processes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Loss circulation prevention in geothermal drilling by shape memory polymer

Geothermal formations are naturally fractured with large fracture openings and networks. This can often lead to frequent drilling fluid loss events which is a major contributor to the cost and non-productive time in geothermal drilling. Development of smarter technologies and methods to tackle problem lost circulation is vital for geothermal drilling cost reduction required for geothermal energy to be recognized as a competitive alternative energy source. Mitigation of this problem and other drilling problems such as stuck pipe can minimize overall project cost. In this report, a thermoset shape memory polymer that can be activated by formation natural heat was assessed to seal near wellbore fractures in geothermal wells. The performance of the shape memory polymer (SMP) was evaluated using artificial fractures created in aluminum discs and cylindrical granite cores. Rheology and particle size distribution were considered. A novel testing setup was built for this work, which allows testing of sealing efficiency under dynamic conditions at high temperature. Analysis showed that the SMP has efficiently succeeded in forming a strong plug inside the fractures and stopped fluid loss at high sealing pressure. This smart loss circulation material can expand within the fractures to reduces non-drilling time and strengthen the wellbore in high-temperature drilling operations.

58 GEOSCIENCES↗

Separating Oil-Water Mixtures Using Bump Arrays

Particle separation is an important process step across many fields. One technique being applied for separating solids such as blood components or sand particles from carrier fluids is the use of arrays of aligned posts called deterministic lateral arrays to bump particles to one side in the flow stream to enhance separation. This technique may be useful for separation of deformable particles. The ability to efficiently separate two-phase industrial (oil/water) mixtures is key for future use of valuable resources. Over 1 trillion gallons of petroleum production water could be reclaimed annually for reuse in the drought-ridden western US states. The ability to reclaim this petroleum production water may be critical for the Central High Plains (Colorado, Kansas, Oklahoma, Texas, and New Mexico). Trends in just the High Plains area already lost 20 to 25% of the irrigated farming area due to insufficient ground water storage to irrigate, and farmland losses are expected to grow to 40%. Proving this technology is key to reuse of petroleum production water for crop irrigation or to replace water from currently failing aquifers in rich agricultural lands of the Central High Plains. We conducted experiments applying mesofluidic separation for flowing two-phase (oil/water) mixtures. Experiments were conducted using oils of differing viscosities with water as the carrier fluid; separation was achieved over a range of oil-water concentrations. We describe the results of these experiments in this paper.

oil-water separation, micelle, droplet separation,↗

Irradiation of NH3-CH4 mixtures as a model of photochemical processes in the Jovian planets and Titan

The reactions occurring upon the ultraviolet irradiation of ammonia-methane mixtures are investigated in a simulation of the atmospheric chemistry of the Jovian planets and Titan. Gas mixtures were irradiated at 185 nm at temperatures from 156-298 K, and product and reactant concentrations were determined by means of gas chromatography. The ratio of the moles of CH4 lost per mole of NH3 decomposed is found to be 0.25, with the extent of CH4 decomposition independent of temperature. The absence of a temperature effect suggests that nonthermal atoms, probably hydrogen, initiate CH4 decomposition by the extraction of a hydrogen atom. A decrease in CH4 loss with increasing pressure or the addition of other gases to the photolysis mixture, and the lack of an increase in NH3 photolysis with CH4 pressure support this mechanism. Major reaction products obtained include C2H2, C3H8 or CH3NH2, and C4H10. Considerations of atmospheric concentrations of H2 and He indicate that NH3 photolysis does not contribute to CH4 decomposition on Jupiter, Saturn, Uranus, and Neptune, although it may have had a role in the formation of the Titan atmosphere.

Ferris, J. P.↗

Development of Cast Valve Bodies For High Temperature Service

Gen 3 Concentrating Solar-Thermal Power (CSP) system components are required to operate at 750°C - 800°C to achieve the Sunshot target of 6 cents/kWh. Haynes ® 282 and IN ® 740H are preferred alloys for the construction of these components due to their high tensile and creep strengths for service at temperatures greater than 750°C. There is significant motivation to lower the cost of materials and components so that the capital costs can be minimized. One approach to reduce costs is to fabricate castings at the lowest possible cost. To obtain the lowest cost in castings, there is a significant need to maximize yields in castings by decreasing rejects due to casting defects and to minimize wastage in material lost in the gating systems. However, very little work has been performed to develop cast products using Haynes ® 282. Although preliminary work has established the feasibility of casting Haynes ® 282 using investment and sand casting, there are no commercial cast components available. In particular, there is significant interest in the development of casting design and process technology for the fabrication of components such as valve bodies using Haynes ® 282.

14 SOLAR ENERGY↗

Effect of simulated weightlessness on energy metabolism in the rat

Results of measurements of food uptake and body weight changes occurring in rats suspended from a harness so that the antigravity muscles were not used for locomotion are presented. The rats were tested in pairs, with both in a harness but only one suspended off its hind legs; this section lasted 7 days. A second phase of the experiment involved feeding the nonsuspended rat the same amount of food the experimental rat had consumed the previous day. All rats experienced decreased in body weight and food intake in the first stage, while in the second stage the suspended rat lost more weight. The total oxygen uptake, CO2 output, and rate of C-14O2 production were depressed in the suspended rats, then returned to normal levels once the rats were back on the ground. It is concluded that the gross metabolic processes are unaffected by simulated weightlessness.

Jordan, J. P.↗

A Robust Biomarker

Polymers of bacterial origin, either through cell secretion or the degraded product of cell lysis, form isolated mucoidal strands as well as well-developed biofilms on interfaces. Biofilms are structurally and compositionally complex and are readily distinguishable from abiogenic films. These structures range in size from micrometers to decimeters, the latter occurring as the well-known, mineralised biofilms called stromatolites. Compositionally bacterial polymers are greater than 90 % water, with while the majority of the macromolecules forming the framework of the polymers consisting of polysaccharides (with and some nucteic acids and proteins). These macromolecules contain a vaste amount of functional groups, such as carboxyls, hydroxyls, and phosphoryls which are implicated in cation-binding. It is the elevated metal- binding capacity which provides the bacterial polymer with structural support and also helps to preserves it for up to 3.5 b.y. in the terrestrial rock record. The macromolecules, thus, can become rapidly mineralised and trapped in a mineral matrix. Through early and late diagenesis (bacterial degradation, burial, heat, pressure and time) they break down, losing the functional groups and, gradually, their hydrogen atoms. The degraded product is known as "kerogen". With further diagenesis and metamorphism, all the hydrogen atoms are lost and the carbonaceous matter becomes graphite. until the remnant carbonaceous material become graphitised. This last sentence reads a bit as if ALL these macromolecules break down and end up as graphite., but since we find 441 this is not true for all of the macromolecules. We have traced fossilised polymer and biofilms in rocks from throughout Earth's history, to rocks as old as the oldest being 3.5 b.y.-old. Furthermore, Time of Flight Secondary Ion Mass Spectrometry has been able to identify individual macromolecules of bacterial origin, the identities of which are still being investigated, in all the samples containing fossil biofilm, including the 3.5 b.y..-old carbonaceous cherts from South Africa and Australia. As a result of the unique compositional, structural and "mineralisable" properties of bacterial polymer and biofilms, we conclude that bacterial polymers and biofilms constitute a robust and reliable biomarker for life on Earth and could be a potential biomarker for extraterrestrial life.

Westall, F.↗

Television Transmission Technology

The VKP-7990 Multistage Depressed Collector (MDC) Klystron is a result of cooperative development by Varian Associates, Inc., the National Association of Broadcasters, Lewis Research Center, the Public Broadcasting System and TV transmitter manufacturers. The effort was initiated to make power amplifying devices with efficiencies comparable to VHF available to UHF operators. The klystron is a vacuum tube used to generate and amplify ultrahigh frequencies but at low efficiencies because most of the energy is dissipated as waste heat. Lewis had earlier developed the MDC to enhance the efficiency of communications satellite transmissions. Varian Microwave Power Tube Products, which has since become Communications and Power Industries, and Lewis combined the MDC and the klystron, resulting in a product which increases efficiency by recovering some of the residual energy that normally would be lost as heat. The MDC klystron cuts the electric power consumption of UHF-TV transmitters in half; there are 90 units in operation in 36 UHF-TV stations.

Source record↗

Sustainable Resource Recovery from Trash, Waste, and Overboard Venting

Space travel and planetary missions for long-endurance human presence require Environmental Control and Life Support (ECLS) loop-closure. The air and water resource loops are generally closed with their processes having been established through extensive development, testing, and long-term use on International Space Station. Closure of the air and water loops have enabled oxygen and hydrogen sustainability. Carbon sustainability has yet to be addressed. Waste and trash, which also contains hydrogen and oxygen and abundant carbon have not been developed to the extent air and water have. Waste and trash have generally been dealt with in terms of simple safening, storage, and disposal. In externally disposing of waste, which includes C1 and C2 hydrocarbon gases, lost resources not only increase mission cost they can result in space and planetary pollution that can lead to unfavorable public opinion. With all this in mind, we explore the idea of carbon sustainability within closed-cycle waste, trash, and C1/C2 reprocessing. Starting from the current ECLS System roadmap, we identify resources that are not yet captured in closed-cycle processes but are lost when crossing the thermodynamic boundaries of an open system. Such pseudo-resources are trash, waste, and the gaseous carbon products of carbon dioxide reduction. We then consider different means and processes for minimizing pseudo-resource loss so as to “close the carbon loop.” There are cases in which pseudo-resources need to be externally discarded, such as reducing spacecraft acceleration mass. In this case we examine various processes that can be beneficial to missions even when these pseudo-resources are lost. An example would be the conversion of waste into propellant, which can produce thrust while at the same time reducing mass for transit acceleration (and ultimately propellant mass at launch), in which case we propose a means for evaluating the value of converting waste into propellant for different propulsion systems.

waste↗

Catching up with the trees: empirical advancements to improve herbaceous representation in models

Ecosystems dominated by herbaceous vegetation (i.e. nonwoody species) represent c. 40% of the terrestrial land surface on Earth (White et al., 2000), facilitate large quantities of carbon sequestration (reviewed by Bai & Cotrufo, 2022), and provide much of the food production for humans (O'Mara, 2012). Many of these ecosystems are currently in danger of being lost due to global change drivers, shrub encroachment, and calls for afforestation (Bond et al., 2019). Furthermore, our predictive understanding of these systems is limited, which can be seen from high levels of uncertainty in modeled future carbon (C) storage of these systems (e.g. fig. 3 in McGuire et al., 2018).

59 BASIC BIOLOGICAL SCIENCES↗

Effects of a CFD-improved dimple stepped-lip piston on thermal efficiency and emissions in a medium-duty diesel engine

Diesel piston-bowl shape is a key design parameter that affects spray-wall interactions and turbulent flow development, and in turn affects the engine’s thermal efficiency and emissions. It is hypothesized that thermal efficiency can be improved by enhancing squish-region vortices as they are hypothesized to promote fuel-air mixing, leading to faster heat-release rates. However, the strength and longevity of these vortices decrease with advanced injection timings for typical stepped-lip (SL) piston geometries. Dimple stepped-lip (DSL) pistons enhance vortex formation at early injection timings. Previous engine experiments with such a bowl show 1.4% thermal efficiency gains over an SL piston. However, soot was increased dramatically [SAE 2022-01-0400]. In a previous study, a new DSL bowl was designed using non-combusting computational fluid dynamic simulations. This improved DSL bowl is predicted to promote stronger, more rotationally energetic vortices than the baseline DSL piston: it employs shallower, narrower, and steeper-curved dimples that are placed further out into the squish region. In the current experimental study, this improved bowl is tested in a medium-duty diesel engine and compared against the SL piston over an injection timing sweep at low-load and part-load operating conditions. No substantial thermal efficiency gains are achieved at the early injection timing with the improved DSL design, but soot emissions are lowered by 45% relative to the production SL piston, likely due to improved air utilization and soot oxidation. However, these benefits are lost at late injection timings, where the DSL piston renders a lower thermal efficiency than that of the SL piston. Energy balance analyses show higher wall heat transfer with the DSL piston than with the SL piston despite a 1.3% reduction in the piston surface area. Vortex enhancement may not necessarily lead to improved efficiency as more energetic squish-region vortices can lead to higher convective heat transfer losses.

42 ENGINEERING↗

Integrated Advanced Microwave Sounding Unit-A (AMSU-A). Performance Verification Report: METSAT Phase Locked Oscillator Assembly, P/N 1334360-1, S/N's F03 and F04

Two Flight Model AMSU-A Phase Locked Oscillators (P/N 1348360-1, S/Ns F03 and F04) have been tested per AES Test Procedure AE-26758. The tests included vibration testing, thermal cycle testing, AM/FM Noise testing, and full functional testing. EMI/REO 2 Testing was not performed. (See test data for S/N F01). Both AMSU-A Phase Locked Oscillators satisfactorily passed all performance requirements of the AE-26633 Product specification. During thermal cycling of PLO serial number F03, the oven and data logger momentarily lost power, including a loss of data. The unit did not experience any thermal stress. TAR 003134 describes the corrective action. Prior to testing PLO serial number FO4, power was applied to the unit. (+15v,-15v) the unit did not display the proper phase lock. Upon test equipment check out a connector was found to be defective. TAR 003133 describes the corrective action. After completion of testing of PLO serial number F04 was installed into Receiver Assembly F02. Upon testing F02 Receiver Assembly the unit was found not to phase lock at ambient temperature. Removal of PLO Assembly F04 was required. R2 was the real issue. Solithane was secondary. Troubleshooting revealed excessive solithane on inner PLL Assembly cover inhibiting optimum grounding. Also, R2 was reselected which increased the lock range from -30 C to +60 C. TAR 002737 describes the corrective action.

Pines, D.↗