Partition of Sr, Ba, Ca, Y, Eu/2+/, EU/3+/, and other REE between plagioclase feldspar and magmatic liquid - An experimental study
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Fluorine surface deposits on Apollo 15 green glass, Apollo 17 orange glass, and on vesicle linings from Apollo 15 basalts were studied by a resonant nuclear reaction technique. Surface layers of about 10 to the 15th F atoms/sq cm were observed on unbroken spheroidal glass surfaces, whereas thinner (about 10 to the 14th atoms/sq cm) deposits were found on the vesicle linings.
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A model is proposed to account for the observed properties of Io. The crust is probably siliceous, but the outermost visible surface is composed primarily of several allotropes of elemental sulfur, plus frosts of SO2, H2S, and S2O. The 4-micron feature in Io's IR reflectance is identified as the (nu 1 + nu 3) band of SO2 frost. A possible source of the S is dissociation of iron sulfide brought up from the core by mantle convection. The SO2 is produced in the volcanoes, and the H2S by interaction of magnetospheric protons with the surface S. Delayed luminescence from S2O could cause the posteclipse brightening. The orbital torus is sustained by evaporation from molten ejecta from the volcanoes. Several additional diagnostic absorption bands and two additional minor torus species are predicted by this model.
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Sparse, granular inclusions of early-formed minerals found within the Little Glass Mountain rhyolite flows in northern California are shown to provide a means of characterizing the physical conditions, at depth, beneath the Medicine Lake Highland during the latest phase of volcanic activity. Mineral compositions, in combination with thermodynamic calculations and experiments, suggest crystalization at a pressure of 5,200 bars within a 966-836 C temperature range; implying that mineral segregation and equilibration occurred at a depth of 15-18 km beneath the surface. In addition, mass balance calculations indicate that the Medicine Lake flow is a close approximation to the parental magma for the latest silicic lavas.
The significance of the lunar highland pristine cumulate samples were reevaluated with the aid of the additional insights provided by geologically constrained terrestrial investigations. This exercise involved a review of the state of knowledge about terrestrial and lunar cumulate rocks as well as an enumeration and reevaluation of the processes hypothesized to have been responsible for their formation, both classically and at present.
Three achondrites were examined for chronology, petrogenesis, and relationships among the shergotites. Isotopic and trace elements analyses were carried out through neutron activation and mass spectrometry on Shergotty, Zagami, and ALHA77005 samples. Attention was given the Rb-Sr, Sm-Nd, and the Ar-39/Ar-40 ages in the samples. Evidence was detected for a shock metamorphism and a younger age of the meteorites than with most other achondrites. Depletions of the rare-earth elements were observed in Shergotty and Zagami, and to a more pronounced degree in ALHA77005. The Rb-Sr internal isochrons for all three meteorites were about 180 Myr, while the Ar-39/Ar-40 plateau ages of Shergotty and Zagami maskelynite were determined at 250-260 Myr. No precise identification of the crystallization ages was found. It is suggested that the achondrites originated in a parent body which experienced at least two epochs of sustained melting.
The partitioning behavior of Pb in the three-phase system metal-troilite-sulfide liquid was investigated. Microscopic examination and electron microprobe analysis of a polished section showed three phases--Fe metal, troilite and an Fe-S-Pb-O metallic liquid. The Pb concentration of the metallic liquid was 1.4 wt.%; the Pb contents of both the troilite and the Fe metal were below the detection limit of the electron probe. To better define the Pb concentrations of the solid phases, the same sample was analyzed for Pb and Fe using the M.I.T., Harvard and Brown ion microprobe. Even at this level of precision, some conclusions and speculations are possible: (1) The D(Pb) (troilite/metallic liquid) is low (.01 to .001) and, contrary to expectation, troilite, like metal, excludes Pb very effectively during the crystallization of metallic liquids; (2) Pb in iron meteorites is conceivably concentrated in trace phases which are less susceptible to contamination than metal and troilite; and (3) taken at face value D(Pb)(metal/troilite) is 0.1, but given the Pb and Fe ion yields from simple endmember phases (Fe, FeS, Pb, PbS), this D is more likely to be 0.05 to 0.03.
Experimental problems associated with metallic solid/metallic liquid partitioning investigations are evaluated. Of particular concern is the discrepancy of partition coefficient results obtained from experiments which were static (constant temperature for the duration of the experiment) and those which were dynamic (where an experimental charge is slowly drawn from the furnace).
Variations in the geometry, distribution and thickness of Cambrian igneous and sedimentary units within southwest Oklahoma are related to a late Proterozoic - early Paleozoic rifting event which formed the Southern Oklahoma aulacogen. These rock units are exposed in the Wichita Mountains, southwest Olkahoma, located on the northern margin of a Proterozoic basin, identified in the subsurface by COCORP reflection data. Overprinting of the Cambrian extensional event by Pennyslvanian tectonism obsured the influence of pre-existing basement structures and contrasting basement lithologies upon the initial development of the aulacogen.
Leveling measurements conducted in 1980-1981 by the National Geodetic Survey in the Socorro area of the Rio Grande rift are analyzed. Crustal uplift related to magma inflation in the midcrustal magma body is detected; an uplift of 0.18 cm/yr is measured for the time between 1951-1980. The survey data of 1911 and 1959 are compared to the present data and good correlation is observed. The systematic leveling errors including height-dependence and refraction errors are studied. The 30-km-wide subsidence in the area is examined. The spatial correlation between seismic activity, the Socorro magma body, and crustal deformation in Socorro is investigated. The crustal movement from magma reservior activities is modeled using the formulations of Dieterich and Decker (1975). The modeling of the deformation reveals that the movement in the Socorro area is associated with the 19-km deep Socorro magma body.
The compositions and mineralogy of metal-sulfide spherules trapped in ureilites are studied. Electron microprobe analyses of metallic phases and sulfides in spherules were conducted and backscattered electron images of metallic spherules in olivine and in ureilites are presented. It is observed that the spherules are composed of cohenite, Fe-Ni metal, troilite, and rare phosphorus-bearing minerals. The intergranular metal and graphite in the ureilites are analyzed. The phase relations of cohenite-bearing spherules are considered. Spherules represent Fe-Ni-C-S alloys that exist as immiscible metallic liquid droplets in the silicate magma from which ureilite olivine and pigeonite crystallized. The data reveal that graphite crystals occur as inclusions in olivine and ureilites and therefore graphite in ureilites is a primary magnetic component. It is hypothesized that graphite is a residue from the solid source materials that melted to produce the ureilite parent magma or crystallized from the magma.
Sediments from three sites in the Santa Barbara Basin were examined with a 160X power light microscope and TEM equipment to characterize the magnetostatic bacteria (MB) in the samples. Both the free magnetite and the crystals in the MB in the samples had lengths from 40-60 nm in length and increased in size from one end to the next. An intact magnetosome was also observed. Scanning the sediments with saturation isothermal remanent magnetization (SIRM) and altering field demagnetization techniques using a SQUID magnetometer yielded coercivity spectra which showed that the primary remanence carrier in the sediments was single domain magnetite. Although it is expected that the predominance of the bacterial magnetite component will decrease with depth in the open ocean basin, single-domain bacteria as old as 50 Myr have been observed in oceanic sediments.
The SNC meteorites record relatively recent (less than b.y.) basaltic volcanism on a hydrous planet with a core. This much was known about Mars even before the Viking mission. The SNCs tell that the basalts were unusually low in Al2O3 and, despite overall similarities in major elements, apparently sampled two isotopically distinct regions of Mars: one is relatively depleted in incompatible elements (Nahklite source) with a U-Pb model age of 4.3 b.y. and is probably a portion of the upper Martian mantle, whereas the other is relatively enriched in incompatible elements (Shergottite source) with a 4.5 b.y. U-Pb age and is probably Martian crust assimulated into the mantle-derived Shergottite magma. The SNCs tell that the overall abundances of moderately volatile elements, such as alkalies, are higher on Mars than on earth. Given extensive volcanism and a depleted mantle, the present day absence of a thick atmosphere is more likely due to catastrophic removal of a primordial atmosphere than lack of degassing.
The design and calibration of concentric cylinder viscometer for rhyolitic magma applications are described together with the methods of data reduction and error analysis. Experimental data are presented on two rhyolitic magmas (melt plus a small fraction of vapor) under conditions of varying temperature (1100-1350 C) and shear rate (0.05-13.0/sec) at 100 kPa total pressure. Data obtained include a first reported measurement of a normal stress coefficient for magma.
By estimating the total amount of water released by volcanic processes on Mars, the abundance of H2O at 10 m was estimated. This value was based on mapping volcanic units, estimating thicknesses and volumes, and using a 10 wt. percent value H2O from terrestrial analogs. By combining such estimates with crater count ages, it is also possible to estimate the timing of water release through Martian history.