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More Surprises from the Moon

Even with the naked eye, the dark, extensive plains of the lunar maria can be clearly seen on the surface of the Moon. The maria formed after meteorite impacts created large craters that later filled with lava flows. Mare volcanism is the dominant type of volcanic activity on the Moon and the lavas are made up of basaltic rocks. However, non-mare volcanic deposits, though rare, have been observed on the lunar nearside. The deposits are distinguished from the maria because they are compositionally more evolved rich in silica, potassium and thorium. The deposits are limited in surface extent and it was unknown whether similar non-mare volcanism occurred at all on the Moon s farside. Writing in Nature Geoscience, Jolliff et al. report using Lunar Reconnaissance Orbiter images and compositional data to identify the rare occurrence of more compositionally evolved volcanic deposits in an isolated area on the Moon s farside. In the 1960s and 1970s, rock and soil samples were collected by the Apollo and Luna missions, by the USA and USSR respectively. This material represents a geologic treasure trove that continues to provide a wealth of information about the Moon and its evolution, and it was a very small fraction of these samples that gave the first hint that non-mare volcanic activity might have occurred. The samples contained fragments of complex volcanic rocks that were unrelated to the maria basalts. Violent bombardment of the Moon by meteorite impacts has caused significant mixing of the rocks at its surface, so the fragments could have had a source hundreds or thousands of kilometres away. The origin of the fragments was unknown. Several decades later, the Lunar Prospector mission used a gamma-ray spectrometer to map the distribution and abundance of various elements, including thorium, on the Moon s surface. The maps identified a distinct and large area of high thorium concentration, as well as several smaller, but equally peculiar areas of high thorium concentration on the nearside of the Moon (Fig. 1). The rocks that contained high thorium contents also exhibited geomorphological and spectral features that were typical of volcanic deposits, and so the thorium hotspots were thought to represent non-mare volcanism on the nearside of the Moon. A relatively large region with extremely high thorium concentrations - the Compton-Belkovich thorium anomaly - was also identified on the Moon s farside. This thorium hotspot was particularly unusual because it was completely isolated, alone on the farside of the Moon, far from the nearest maria. No high-resolution image data were available for this region, so a definitive interpretation of the source of this isolated anomaly has been impossible.

Petro, Noah↗

Cometary and meteorite swarm impact on planetary surfaces

The impact-induced deformation from hypothetical cometary objects having initial densities in the 0.01 to 1 g/cu cm range and heats of vaporization in the approximately 2 kJ/g (corresponding to water) to approximately 10 to the 7th J/g range is examined for impacts in the 5 to 45 km/s range. Even though the direct effect of an atmosphere is neglected, the atmosphere may in fact cause a cometary object to break up into a shower or equivalent very porous impactor. Besides examining the partitioning of impact energy into internal energy of the impacted planet and impacting cometary material, calculations are made of the relative efficiency of shock-induced melting and vaporization by comets on planetary surface materials and the mass loss from a given planet for various escape velocities.

Okeefe, J. D.↗

Nitrogen geochemistry of a Cretaceous-Tertiary boundary site in New Zealand

Nitrogen in the basal layer of the K-T boundary clay at Woodside Creek, New Zealand, has an abundance of 1100 ppm, a 20-fold enrichment over Cretaceous and Tertiary values. The enrichment parallels that for Ir and elemental carbon (soot); all decrease over the next 6 mm of the boundary clay. The C/N ratio, assuming the nitrogen to be associated with organic rather than elemental carbon, is approximately 5 for the basal layer compared to 20 to 30 for the remainder of the boundary clay. The correlation between N and Ir abundances appears to persist above the boundary, implying that the N is intimately associated with the primary fallout and remained with it during the secondary redeposition processes that kept the Ir abundance relatively high into the lowermost Tertiary. Apparently the basal layer of the boundary clay represents the accumulation of a substantial quantity of N with an isotopic composition approximately 10 percent heavier than background delta value of N-15 values. If the boundary clay represents an altered impact glass from a meteorite impact than it probably denotes a time period of less than 1 year. Therefore, the changes in nitrogen geochemistry apparently occurred over a very short period of time. The high abundance of N and the correspondingly low C/N ratio may reflect enhanced preservation of organic material as a result of the rapid sweepout and burial of plankton by impact ejecta, with little or no bacterial degradation. It is conceivable that the shift in delta value of N-15 may represent an influx of nitrogen from a different source deposited contemporaneously with the impact ejecta. An interesting possibility is that it may be derived from nitrate, produced from the combustion of atmospheric nitrogen.

Gilmour, Iain↗

Astronaut's guide to terrestrial impact craters

Impact cratering of the earth's surface is discussed and compared with lunar craters. The basic types found on earth are either simple craters or complex impact structures and basins. Meteorite fragments and shock metamorphism provide evidence of a crater's formation by meteorite impact. Known craters on earth are ordered by location and a few principal facts are given for each crater and the general terrain in which it is located. A satellite picture of each crater and maps identifying crater locations are provided.

Grieve, R. A. F.↗

Isotopic Tracers for CO 2 Produced During A Planetary Impact Into Limestone Target Rocks

Terrestrial meteorite impacts have been directly linked with multiple mass extinction events throughout Earth’s history. Among these impacts, those that land in sedimentary target rocks are thought to generate large quantities of CO 2 via decarbonation. This injection of CO 2 into the atmosphere has the potential to alter the climate and threaten terrestrial habitability. The magnitude of this change depends upon the net amount of CO 2 released, which is controlled by how much CO 2 is produced by the impact, how much CO 2 is removed by back-reactions after the impact, and other post-impact CO 2 sinks. To interrogate the behavior of CO 2 release into the impact atmosphere, we present carbon (δ 13 C), oxygen (δ 18 O), and clumped (Δ 47 ) isotope results from carbonate clasts preserved within the impact breccia of the Steen River Impact Structure (SRIS) in Alberta, Canada. These clasts exhibit a ~65‰ range in δ 13 C and a ~5‰ variation in δ 18 O. However, while δ 13 C and δ 18 O are positively correlated, Δ 47 unexpectedly has a negative relationship with δ 13 C and δ 18 O. Based on prior assumptions, there would either be (1) no relationship with carbonate Δ 47 and the bulk ratios because Δ 47 would be reset at extreme impact temperatures, or (2) Δ 47 would have a positive correlation with the bulk ratios, reflecting gradual Δ 47 ‘resetting.’ To reconcile the SRIS result with these expectations, we conducted a series of in vacuo heating experiments at temperatures above calcite decomposition. As predicted by Rayleigh fractionation, these heating experiments generated depletions in δ 13 C and δ 18 O that increased with reaction time. Mimicking the SRIS results, these experiments also produced concomitant increases in Δ 47 . Using an adaptation of a mechanistic model for decomposition fractionation (Hayles & Killingsworth, 2022) we hypothesize that these exotic isotope trends are caused by Rayleigh fractionation and a Δ 47 kinetic isotope effect that results from the disproportionation of O to CaO and CO 2 during thermal decomposition. This high Δ 47 CO 2 subsequently exchanges with the residual CaCO 3 . This work highlights a potential pathway for identifying and quantifying CO 2 generation by impacts and builds on the relatively limited literature characterizing the behavior of carbonate clumped isotopes at very high geologic temperatures.

Multi-isotope systems↗

Analysis of Siderite Thermal Decomposition by Differential Scanning Calorimetry

Characterization of carbonate devolitilization has important implications for atmospheric interactions and climatic effects related to large meteorite impacts in platform sediments. On a smaller scale, meteorites contain carbonates which have witnessed shock metamorphic events and may record pressure/temperature histories of impact(s). ALH84001 meteorite contains zoned Ca-Mg-Fe-carbonates which formed on Mars. Magnetite crystals are found in the rims and cores of these carbonates and some are associated with void spaces leading to the suggestion by Brearley et al. that the crystals were produced by thermal decomposition of the carbonate at high temperature, possibly by incipient shock melting or devolitilization. Golden et al. recently synthesized spherical Mg-Fe-Ca-carbonates from solution under mild hydrothermal conditions that have similar carbonate compositional zoning to those of ALH84001. They have shown experimental evidence that the carbonate-sulfide-magnetite assemblage in ALH84001 can result from a multistep inorganic process involving heating possibly due to shock events. Experimental shock studies on calcium carbonate prove its stability to approx. 60 GPa, well in excess of the approx. 45 GPa peak pressures indicated by other shock features in ALH84001. In addition, Raman spectroscopy of carbonate globules in ALH84001 indicates no presence of CaO and MgO. Such oxide phases should be found associated with the magnetites in voids if these magnetites are high temperature shock products, the voids resulting from devolitilization of CO2 from calcium or magnesium carbonate. However, if the starting material was siderite (FeCO3), thermal breakdown of the ALH84001 carbonate at 470 C would produce iron oxide + CO2. As no documentation of shock effects in siderite exists, we have begun shock experiments to determine whether or not magnetite is produced by the decomposition of siderite within the < 45GPa pressure window and by the resultant thermal pulse to approx. 600 C experienced by ALH84001. Here, we report thermal and compositional characterization of unshocked siderite and its transition to magnetite. Additional information is contained in the original extended abstract.

Bell, M. S.↗

Mineralogical diversity (spectral reflectance and Moessbauer data) in compositionally similar impact melt rocks from Manicouagan Crater, Canada

Meteoritic impacts under oxidizing surface conditions occur on both earth and Mars. Oxidative alteration of impact melt sheets is reported at several terrestrial impact structures including Manicouagan, West Clearwater Lake, and the Ries Basin. A number of studies have advocated that a significant fraction of Martian soil may consist of erosional products of oxidatively altered impact melt sheets. If so, the signature of the Fe-bearing mineralogies formed by the process may be present in visible and near infrared reflectivity data for the Martian surface. Of concern is what mineral assemblages form in impact melt sheets produced under oxidizing conditions and what their spectral signatures are. Spectral and Moessbauer data for 19 powder samples of impact melt rock from Manicouagan Crater are reported. Results show for naturally occurring materials that composite hematite-pyroxene bands have minima in the 910-nm region. Thus many of the anomalous Phobos-2 spectra, characterized by a shallow band minimum in the near-IR whose position varies between approximately 850 and 1000 nm, can be explained by assemblages whose endmembers (hematite and pyroxene) are accepted to be present on Mars. Furthermore, results show that a mineralogically diverse suite of rocks can be generated at essentially constant composition, which implies that variations in Martian surface mineralogy do not necessarily imply variations in chemical composition.

Morris, R. V.↗

Impact metamorphism

Diagnostic petrographic criteria for establishing progressive stages of hypervelocity meteorite impact

METEORITIC CRATER↗

Lunar impact craters

Topography and evolution of lunar craters - meteoritic impact - selenography

TOPOGRAPHY↗

Modification of premare impact craters by volcanism and tectonism

Many lunar craters greater than 10 km in diameter exhibit a variety of morphological characteristics which are not produced by meteorite impact or meteorite erosion. Most such craters are located in or near the margins of the maria. Although some could have resulted from processes such as cauldron resurgence, caldera formation, or ring dike emplacement, most have formed by modification of impact craters by endogenic processes including erosion by flowing lava, fissure volcanism, plutonism, and uplift of crater floors along ring fractures of impact origin.

Brennan, W. J.↗

Shock effects from a large impact on the moon

The paper calculates the shock and shear deformation-induced internal energy distribution associated with a major basin-forming hypervelocity meteorite impact on the moon. The Hageman and Walsh formulation of the axisymmetric two-dimensional conservation equations in finite difference form is used, and the flow field induced upon impact of an iron meteorite traveling at 15 km/sec with a gabbroic anorthosite lunar crust is calculated for sequential time steps over a grid of hoop-shaped zones fixed in space. If an energy of 5 times 10 to the 32nd power ergs for the projectile energy is required to excavate a basin of Imbrium size, than a flow field of approximately 210 km in radius approximately 19 seconds after impact is indicated. The meteorite residue, the melt, and the ejecta are discussed, and the results are compared with the Gault and Heitowit (1963) formulation.

Okeefe, J. D.↗

FOSSIL METEORITE CRATERS

Impact pressure of meteorites from coesite and stishouite deposits in fossil meteorite craters

IMPACT↗

Mobilization of the platinum group elements by low-temperature fluids: Implications for mineralization and the iridium controversy

Geochemical investigations on the widely dispersed Late Proterozoic Acraman impact ejecta horizon and its host marine shales in the Adelaide Geosyncline provide strong evidence for low-temperature mobilization of the platinum group elements (PGE), including Ir. The ejecta horizon was formed when the middle Proterozoic dacitic volcanics in the Gawler Ranges, central South Australia, were impacted by a very large (ca. 4 km) meteorite. The resulting structure, now represented by Lake Acraman, is Australia's largest meteorite impact structure. Debris from the impact was blasted for many hundreds of kilometers, some falling into the shallow sea of the Adelaide Geosyncline, some 300 km to the east of the impact site.

Dowling, Kim↗