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At least 91 records · Page 5

Electron-temperature dependence of the recombination of HCO(+) ions with electrons

A microwave-afterglow mass-spectrometer apparatus employing microwave heating of the electrons has been used to determine the dependence on Te of the recombination coefficient of electrons with HCO(+) ions. By comparison of the observed electron-density decays to the computed behavior of a recombination- and ambipolar-diffusion-controlled afterglow, it is found that the Te dependence of the recombination coefficients follows a power law with an index of -0.69 + or - 0.07 over the range Te = 293-5500 K. The magnitude of the recombination coefficient is similar to that observed and calculated for simple diatomic ions, while the temperature dependence is somewhat stronger than the Te exp -0.5 dependence predicted by a simplified theory for diatomic ions.

Ganguli, B.↗

The Hyperspectral Microwave Photonic Instrument (HyMPI) and its NEDT Performance

This work presents an overview of a hyperspectral microwave-photonic spectrometer and demonstrates the system end-to-end noise equivalent delta temperature (NEDT) performance. The system aims at augmenting the remote sensing capability from space, with a focus on the Earth’s planetary boundary layer (PBL) thermal microwave (MW) spectral region (0-200 GHz). Combining a Photonic Integrated Circuit (PIC) channelizer and an application-specific integrated circuit (ASIC) spectrometer, the PIC & ASIC (PICASIC) module is capable of processing 40 GHz spectra at hyperspectral (4 MHz) resolution. The photonic technology is agnostic to the spectral region and multiple photonic modules can cover the entire 200 GHz spectrum. Measured results of the end-to-end system NEDT agree with predicted values confirming that the NEDT is primarily dominated by the noise figure of the MW front-end, with the optical link adding no significant noise. The data also demonstrate that a single module enables simultaneous super- and hyper-spectral resolution channel analysis across a 40 GHz range.

spectrometer↗

Measurements of recombination of electrons with H3(plus) and H5(plus) ions

The electron-ion recombination coefficients for H3(+) and H5(+) ions were determined by means of a microwave afterglow/mass spectrometer apparatus. Measurements of electron density decays in helium-hydrogen mixtures are correlated with the decay of mass-identified ion currents to the wall of the microwave cavity. At low partial pressures of hydrogen in the mixture, the ion H3(+) dominates the ion composition and the ion wall current tracks the electron density decay curves. From recombination controlled electron density decay curves, the values alpha (H3(+)) = (2.9 + or - 0.3), (2.3 + or - 0.3), and (2.0 + or - 0.2) x 0.0000001 cu cm per sec, are obtained at 205, 300 and 450 K, respectively. At higher partial pressures of hydrogen and low temperatures, where (H5(+)) is the dominant ion, the value alpha (H5(+)) = (3.6 + or - 1.0) x 0.0000001 cu cm per sec is obtained at 205 K. The implications of these results concerning ionization levels in the atmospheres of the outer planets and in the interstellar medium are discussed.

Leu, M. T.↗

Measurements of recombination of electrons with H3O(plus)-(H2O)n series ions

Recombination coefficients of electrons with ions of the hydrated hydronium ion series (H3O(+))(H2O)n, where n = 0, 1, 2, 3, 4, 5, 6, were determined with a microwave afterglow/mass spectrometer apparatus. Afterglow measurements of electron density decays in helium-water vapor mixtures are correlated with the decay of mass-identified ion currents to the wall of the microwave cavity. By varying the temperature of the gas and the partial pressure of the water vapor in the mixture, different groups of hydronium series ions are made to dominate the afterglow.

Leu, M. T.↗

Measurements of recombination of electrons with HCO(plus) ions

Recombination coefficients of electrons with HCO(+) ions were determined with a microwave afterglow/mass spectrometer apparatus. Afterglow measurements of electron density decays in neon-hydrogen-carbon monoxide mixtures are correlated with the decay of mass-identified ion currents to the wall of the microwave cavity. At the appropriate partial pressures of hydrogen and carbon monoxide in the mixture, the ion HCO(+) dominates the ion composition and its wall current approximately tracks the electron density decay curve. From recombination controlled electron density decay curves, the values alpha (HCO(+)) = (3.3 + or - 0.5) and (2.0 + or - 0.3) 0.0000001 cu cm/sec are obtained at 205 and 300 K, respectively. The implications of these results for models of polyatomic molecule formation in dense interstellar clouds are briefly discussed.

Leu, M. T.↗

A Study of the Conformational Isomerism of n-Propyl Nitrate by Microwave Spectroscopy

The rotational spectrum of n-propyl nitrate was measured in the frequency range between 6 to 18 GHz using a Balle-Flygare Fourier transform microwave jet/cavity spectrometer. Parent, 13C and 15N isotopologue transitions for the lower-energy anti-gauche (AG) conformer were found using this instrument. The search for spectra from other conformers was performed using a broadband chirped-pulse jet spectrometer. Transitions from the anti-anti (AA) conformer were observed in this manner. Parent, 13C and 15N isotopologue transitions for the AA conformer were rescanned using the cavity instrument to improve resolution and the signal-to-noise ratio. Rotational, centrifugal distortion, and nuclear electric quadrupole coupling constants for all conformers/isotopologues were fit using Pickett’s SPFIT program. The structure of n-propyl nitrate is discussed considering these results.

Orellana, Will D.↗

MAS2-8 radar and digital control unit

The design of the MAS 2-8 (2 to 8 GHz microwave-active spectrometer), a ground-based sensor system, is presented. A major modification in 1974 to the MAS 2-8, that of a control subsystem to automate the data-taking operation, is the prime focus. The digital control unit automatically changes all system parameters except FM rate and records the return signal on paper tape. The overall system operation and a detailed discussion of the design and operation of the digital control unit are presented.

Oberg, J. M.↗

Microwave spectra of some volatile organic compounds

A computer-controlled microwave (MRR) spectrometer was used to catalog reference spectra for chemical analysis. Tables of absorption frequency, peak absorption intensity, and integrated intensity are included for 26 volatile organic compounds, all but one of which contain oxygen.

White, W. F.↗

Agricultural and hydrological applications of radar

Program objectives, covering a wide range of disciplines and activities in radar remote sensing, include radar systems development and analysis, data processing and display, and data interpretation in geology, geography and oceanography. Research was focused on the evaluation of radar remote sensing applications in hydrology and agriculture based on data acquired with the Microwave Active Spectrometer (MAS) system. The title, author(s) and abstract of each of the 62 technical reports generated under this contract are appended.

Ulaby, F. T.↗

Snow backscatter in the 1-8 GHz region

The 1-8 GHz microwave active spectrometer system was used to measure the backscatter response of snow covered ground. The scattering coefficient was measured for all linear polarization combinations at angles of incidence between nadir and 70 deg. Ground truth data consisted of soil moisture, soil temperature profile, snow depth, snow temperature profile, and snow water equivalent. The radar sensitivity to snow water equivalent increased in magnitude with increasing frequency and was almost angle independent for angles of incidence higher than 30 deg, particularly at the higher frequencies. In the 50 deg to 70 deg angular range and in the 6 to 8 GHz frequency range, the sensitivity was typically between -0.4 dB/.1 g/sq cm and -0.5 dB/,1 g/sq cm, and the associated linear correlation coefficient had a magnitude of about 0.8.

Ulaby, F. T.↗

Variations of temporal, spectral and angular radar backscattering coefficient of vegetation

Results of an experimental program is reviewed which over the past five years has succeeded in documenting the variations of the radar backscattering coefficient of a variety of crop types as a function of time, signal frequency (1-18 GHz), angular range (nadir to 80 deg) and polarization (HH, VV and HV). The systems were the microwave active spectrometers (MAS); one MAS system covers the 1-8 GHz band and the other system covers the 8-18 GHz band. Each MAS system was mounted on a mobile truck-mounted boom and was operated by a computer controller. To date, these two systems have acquired over 3 million data points from agricultural crops, bare ground and trees.

Ulaby, F. T.↗

Vegetation clutter model

The statistical behavior of the radar backscattering coefficient of agricultural crops is examined. The data used were obtained by the microwave active spectrometer (MAS) systems in 1975 and 1976. Based on an evaluation of the angular and spectral variation of the mean, median, and 90-percent dynamic range of the coefficient (dB) histograms, empirical expressions describing the joint angular and frequency dependence of the mean and median were generated for each linear polarization configuration. The clutter model thus generated covers the angular range between 0 deg (nadir) and 80 deg and the frequency range between 1 GHz and 18 GHz. Decorrelation of the coefficient with frequency spacing was also evaluated and modeled.

Ulaby, F. T.↗

Potential application of satellite radar to monitor soil moisture

The microwave backscattering characteristics of soils as a function of moisture content are reviewed as a basis for the evaluation of the applicability of satellite radar to soil moisture determinations. Results of experiments showing the dependence of the complex dielectric constant, power reflection coefficient and backscattering coefficient of soil on its volumetric moisture content are presented. Results of a research program using the truck-mounted University of Kansas microwave active spectrometer to determine if, by the proper choice of sensor frequency, polarization and incidence, the sensor dynamic range in response to moisture variations may be greater than its response to other variations are considered in detail, and the optimum conditions of frequency (between 4 and 5 GHz), angular incidence (between 7 and 20 deg from nadir) and polarization (HH) obtained are indicated. An empirical model for the backscattering coefficient as a function of gravimetric moisture content derived on the basis of the experimental data is presented, and it is noted that available airborne and spaceborne data confirm the results of the ground-based sensors.

Ulaby, F. T.↗

Crop classification with a Landsat/radar sensor combination

A combined Landsat/radar approach to classification of remotely sensed data, with emphasis on crops, was undertaken. Radar data were obtained by microwave radar spectrometers over fields near Eudora, Kansas and Landsat image data were obtained for the same test site. After Landsat digital images were registered and test-cells extracted, a comparable set of radar image pixels were simulated to match the Landsat pixels. The combined data set is then used for classification, and the results are examined with the best combination of sensor variables identified. Finally, the usefulness of radar in a simulated cloud-cover situation is demonstrated. The major conclusion derived from this study is that the combination of radar/optical sensors is superior to either one alone.

Li, R. Y.↗

Active microwave investigation of snowpacks: Experimental documentation, Colorado 1979-1980

During the winter of 1979-1980, the University of Kansas Microwave Active Spectrometer systems measured the backscattering properties of snowpacks under varying conditions at four test sites in Colorado. In addition to the radar data over 1-35 GHz, ground-truth measurements of the atmospheric, snow, and soil characteristics were obtained for each radar data set. The test sites, data acquisition procedures, and data that were acquired in this experiment are presented and described.

Stiles, W. H.↗

Selection of representative instruments for a global change technology architecture trade study

The objectives of Task 2 of the Global Change Technology Initiative (GCTI) Architectural Trade Study were to select representative sets of instruments for making the science measurements specified in Task 1 and to identify instruments that, when flown together, form special complementary packages for measurement purposes. The list of representative instruments and their complementary relationships provide a payload manifest defined in terms of mass, power, size, viewing angles, data rates, etc. which can be used to focus spacecraft trade studies and the definition of a candidate GCTI fleet. Science requirements from Task 1 are given in tabular form. Numerous instruments are described, including visible-infrared radiometers, visible-infrared spectrometers, gas correction radiometers, active systems for Earth observation, Limb viewing instruments, visible-infrared and grating spectrometers, and microwave radiometers.

Hypes, Warren D.↗

The use of multispectral thermal infrared image data to estimate the sulfur dioxide flux from volcanoes: A case study from Mount Etna, Sicily, July 29, 1986

We have found that image data acquired with NASA's airborne Thermal Infrared Multispectral Scanner (TIMS) can be used to make estimates of the SO2 content of volcanic plumes. TIMS image data are most applicable to the study of partially transparent SO2 plumes, such as those released during quiescent periods or nonexplosive eruptions. The estimation procedure is based on the LOWTRAN 7 radiative transfer code, which we use to model the radiance perceived by TIMS as it views the ground through an SO2 plume. The input to the procedure includes the altitudes of the aircraft and ground, the altitude and thickness of the SO2 plume, the emissivity of the ground, and altitude profiles of the atmospheric pressure, temperature, and relative humidity. We use the TIMS data to estimate both ground temperatures beneath a plume and SO2 concentrations within a plume. Applying our procedure to TIMS data acquired over Mount Etna, Sicily, on July 29, 1986, we estimate that the SO2 flux from the volcano was approximately 6700 t d(exp -1). The use of TIMS to study SO2 plumes represents a bridge between highly localized methods, such as correlation spectroscopy or direct sampling, and small-scale mapping techniques involving satellite instruments such as the Total Ozone Mapping Spectrometer or Microwave Limb Sounder. We require further airborne experiments to refine our estimation procedure. This refinement is a necessary preparation for the schedueled 1998 launch of the Advanced Spaceborne Thermal Emission and Reflectance Radiometer, which will allow large-scale multispectral thermal infrared image data to be collected over virtually any volcano on Earth at least once every 16 days.

Realmuto, Vincent J.↗