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NASA NTRS1994

Near-IR diode laser absorption for measurement of tropospheric HO2

The possibility of using tunable lead salt diode lasers in the infrared for measurement of tropospheric HO2 has been frequently considered. Although the sensitivity of diode laser absorption has been improved through the use of high frequency detection techniques, nature has been unkind in that the HO2 absorption cross sections are weak. Even using the most optimistic assumptions about attainable path length and detectable absorbance, measurement of tropospheric HO2 by diode laser absorption in the mid-IR appears marginal. A possible alternative method for measuring HO2 is by absorption at near-infrared wavelengths. Several absorption bands of HO2 occur in the wavelength region between 1.2 and 1.6 micron due to electronic transitions and overtones of the fundamental vibrational modes. InGaAsP diode lasers operate in this wavelength region and can be used for high resolution spectroscopy in a manner analogous to the lead salt lasers. A diode laser system in the near-IR offers some advantages.

Stanton, Alan C.↗
NASA NTRS1994

Wavelength calibration techniques and subtle surface and atmospheric absorption features in the Mariner 6, 7 IRS reflectance data

1994 marks the 25th anniversary of the Mariner 6 and 7 flyby missions to Mars. Despite its age, the Mariner 6,7 Infrared Spectrometer (IRS) data are a unique set of measurements that can provide important information about the Martian surface, atmospheric, and atmospheric aerosol composition. For certain mid-IR wavelengths, the IRS spectra are the only such spacecraft data obtained for Mars. At other wavelengths, IRS measured surface regions different from those measured by Mariner 9 or Phobos 2 and under different dust opacity conditions. We are interested in examining the IRS reflectance data in the 1.8 to 3.0 micron region because there are numerous diagnostic absorption features at these wavelengths that could be indicative of hydrated silicate minerals or of carbonate- or sulfate-bearing minerals. Groundbased telescopic data and recent Phobos ISM measurements have provided controversial and somewhat contradictory evidence for the existence of mineralogic absorption features at these wavelengths. Our goal is to determine whether any such features can be seen in the IRS data and to use their presence or absence to re-assess the quality and interpretations of previous telescopic and spacecraft measurements.

Bell, James F., III↗
NASA NTRS1994

Evolution of macromolecular dust: Far-ultraviolet spectral dust extinction and gas absorption of stellar light as measured with the Hopkins Ultraviolet Telescope

From far-ultraviolet (FUV) spectra of B stars taken with the Hopkins Ultraviolet Telescope (HUT) and Voyager space observations, we determine the far-ultraviolet extinction by Galactic dust and hydrogen absorption in the local spiral-arm clouds towards HD 25443 (B0.5 III), HD 37903 (B1.5 V), and HD 200775 (B3 Ve). We find that the (n (H)) = 1.3 cu cm and number fraction (f = 0.31) of H atoms in molecular hydrogen relative to the total hydrogen indicates a mostly diffuse medium toward HD 25443. We also determine f = 0.56 for the gas in the photodissociation region (PDR) in front of HD 37903 and f approximately equals 0.36 for the HD 200775 PDR. The inferred ratios of N(H2)/I(CO) = 2.4 to 2.8 x 10(exp 20)/K(km/s)/sq cm for cool gas in dark clouds agree with previous canonical estimates of N(H2)/I(CO) = 2 to 3 x 10(exp 20)/K(km/s)/sq cm and support the use of the ratio for determining masses of molecular clouds. We find that the shape and strength of the HD 25443 FUV extinction is the same as a diffuse-medium mean extinction (R(sub nu) = 2.95) extrapolated from mid-UV wavelengths (normal). The HD 37903 FUV extinction through a bright H2 photodissociation region is higher than a mean FUV extinction(R(sub nu) = 4.11), as is the HD 200775 extinction. Another star from the literature rho Oph, probes the dense medium and exhibits an FUV extinction of normal mean strength (R(sub nu) = 4.55) but steeper shape. The normal FUV -extinction of HD 25443 implies that the small FUV-extinction dust in the diffuse medium forms in p art from larger grains as the grains shatter under shocks. The normal strength of the rho Oph FUV-extinction indicates that the minute dust condenses onto or coagulates into larger grains in the dense medium. The high extinction deviation of the HD 37903 PDR (and HD 200775 PDR) shows that FUV radiation from hot stars with T(sub eff) approximately equals 20,000 to 23,000 K in PDRs can evaporate some of the FUV-extinction dust from grain surfaces. In contrast, previously measured extinctions in Galactic H(+) (H II) regions shows that FUV radiation at T(sub eff) greater than 25,000 K can destroy some of the dust in H(+) regions. Thus, some of the FUV-extinction dust is highly volatile. We find that the dust carrier of the variable FUV-extinction is correlated (r = 0.99) with the mid-IR (12 micrometers) radiation from hydrocarbon dust. The volatile FUV-extinction component could thus be due to minute hydrocarbon dust particles or macromolecules, probably PAHs, which are known to condense onto larger grains in the dense medium. Larger grains compsed of PAHs clustered into a solid could thus produce the steep FUV extinction of the rho Oph dense medium. After exposure to FUV photons wihtin approximately 1 pc of HD 37903, PAHs with about 30 carbon atoms would evaporate off the larger grains, increasing gaseous PAH abundance by approximately 14%. Also, after receiving shocks in the diffuse medium toward HD 25443, the larger hydrocarbon grains would shatter into PAH molecules. In summary, as the Galactic medium cycles betwee n the diffuse and dense medium, hydrocarbon dust cycles into and out of larger grains under the influence of shocks, radiation, and condensation.

Buss, Richard H., Jr.↗
NASA NTRS1994

Obscuration, orientation, and the infrared properties of radio-loud active galaxies

We report on a study of the mid- and far-infrared (MFIR) properties of several different classes of radio-loud active galactic nuclei (AGNs) using the IRAS database. Our goal is to try to improve the understanding of the possible relationships between the diverse classes of AGNs. The MFIR and radio properties of radio-loud AGNs are especially useful in this regard, since (excluding the blazar class, which we do not study here) the radio emission is thought to be emitted isotropically, and the radio and MFIR radiation should be much less affected by dust obscuration than radiation at shorter wavelengths. We have first compared samples of 3CR broad-line radio galaxies (BLRGs) and narrow-line radio galaxies (NLRGs) matched in radio flux and mean redshift. We find that the BLRGs are stronger than the NLRGs by a factor of 4-5 in their mid-IR emission but are similar to the NLRGs in the far-IR. This is qualitatively consistent with recent 'unification' models for NLRGs and BLRGs which invoke thermal MFIR emission from dusty 'obscuring tori,' but there may be an additional source of far-IR emission present in the more luminous broad-line objects (the radio-loud quasars) studied previously by Heckman, Chambers & Postman (1992). We have also compared samples of Fanaroff-Riley class I (FRI) and Fanaroff-Riley class II (FRII) radio galaxies matched in radio flux and redshift. The FRII galaxies are stronger MFIR emitters than the FRI galaxies by a factor of about 4. This is consistent with suggestions that the central engine in FRI galaxies produces relatively little radiant energy per unit jet power (expecially since we find that the weak MFIR emission from the FRI galaxies may not be powered by the AGN). Comparing samples of gigahertz-peaked spectrum (GPS) and compact steep spectrum (CSS) sources versus non-GPS-CSS sources, we find that the GPS-CSS and non-GPS-CSS sources have similar MFIR strengths. This suggests that the efficiency of the conversion of jet kinetic energy into radio emission is not much higher in the GPS-CSS sources, contrary to some theoretical predictions. Overall, we find that the MFIR and radio powers of all the classes of radio-loud AGNs we have studied correlate well with one another over a range of about 10(exp 3) in power. This is most naturally understood if the MFIR is primarily powered by the AGN in most highly luminous radio-loud AGNs. However, other processes (starbursts or the intracluster medium) may contribute significantly in the less radio-luminous radio galaxies.

Heckman, Timothy M.↗
NASA NTRS1993

Edison and radiatively-cooled IR space observatories

Radiative cooling of IR space telescopes is an alternative to embedding within massive cryostats and should offer advantages for future missions, including longer life, larger aperture for a fixed spacecraft size, lower cost due to less complex engineering, and easier ground handling. Relatively simple analyses of conventional designs show that it is possible to achieve telescope temperatures in the range of 25 to 40 K at distances from the sun of about 1 AU. Lower temperatures may be possible with 'open' designs or distant orbits. At approximately 25 K, an observatory will be limited by the celestial thermal background in the near- and mid-IR and by the confusion limit in the far-IR. We outline here our concept for a moderate aperture (approximately 1.75 m; Ariane 4 or Atlas launch) international space observatory for the next decade.

Thronson, H. A.↗
NASA NTRS1994

Near-surface thermal gradients and their effects on mid-infrared emission spectra of planetary surfaces

We model the heat transfer by radiation and conduction in the top few millimeters of a planetary surface to determine the magnitude of near-surface (approximately 100 micrometers) thermal gradients and their effects on mid-infrared emission spectra for a number of planetary environments. The model is one-dimensional and uses a finite difference scheme for approximately 10 micrometers layers. Calculations are peformed for samples heated at the base and from above by sunlight. Our results indicate that near-surface radiative cooling creates significant thermal gradients in the top few hundred microns of surfaces in which radiation is an importamnt heat transfer mechanism. The effect is maximized in evacuated, underdense particulate media with sufficiently high temperatures. Near-surface thermal gradients will be significant in fine-grained particulate surfaces on the Moon (40-60 K/100 micrometers) and Mercury (approximately 80 K/100 micrometers), increasing spectral contrast and creating emission maxima in the transparent regions of the spectra. They will be of lesser importance on the surface of Mars, with a maximum value of around 5 k/100 micrometers in areas of low thermal inertia, and will be negligible on planets with more substantial atmospheres (less than 1 K/100 micrometers). We conclude that the effects that thermal gradients have on mid-IR emission spectra are predictable and do not negate the utility of emission spectroscopy for remote determination of planetary surface composition.

Henderson, B. G.↗
NASA NTRS1993

Evaluation of infrared emission spectroscopy for mapping the Moon's surface composition from lunar orbit

Infrared thermal emission spectroscopy is evaluated for its possible application to compositional mapping of the Moon's surface from lunar orbit. Principles of the mid-IR (approximately 4-25 microns) technique, previous lunar ground-based observations, and laboratory studies of Moon samples are reviewed and summarized. A lunar thermal emission spectrometer experiment is described, patterned after a similar instrument on the Mars Observer spacecraft. Thermal emission spectrometry from a polar-orbiting lunar spacecraft could provide a valuable mapping tool to aid in exploration for lunar resources and help provide understanding of the origin of the Moon and history of lunar surface processes.

Nash, Douglas B.↗
NASA NTRS1994

The Titan haze revisted: Magnetospheric energy sorces quantitative tholin yields

We present laboratory measurements of the radiation yields of complex organic solids produced from N2/CH4 gas mixtures containing 10 or 0.1% CH4. These tholins are thought to resemble organic aerosols produced in the atmospheres of Titan, Pluto, and Triton. The tholin yields are large compared to the total yield of gaseous products: nominally, 13 (C + N)/100 eV for Titan tholin and 2.1 (C + N)/100 eV for Triton tholin. High-energy magnetospheric electrons responsible for tholin production represents a class distinct from the plasma electrons considered in models of Titan's aiglow. Electrons with E greater than 20 keV provide an energy flux approximately 1 x 10(exp -2) erg/cm/sec, implying from our measured tholin yields a mass flux of 0.5 to 4.0 x 10(exp -14) g/sq cm/sec of tholin. (The corresponding thickness of the tholin sedimentary column accumulated over 4 Gyr on Titan's surface is 4 to 30 m). This figure is in agreement with required mass fluxes computed from recent radiative transfer and sedimentation models. If, however, theses results, derived from experiments at approximately 2 mb, are applied to lower pressure levels toward peak auroral electron energy deposition and scaled with pressure as the gas-phase organic yields, the derived tholin mass flux is at least an order of magnitude less. We attrribute this difference to the fact that tholin synthesis occurs well below the level of maximum electron energy depositon and to possible contributions to tholis from UV-derived C2-hydrocarbons. We conclude that Tita tholin, produced by magnetospheric electrons, is alone sufficient to supply at least a significant fraction of Titan's haze-a result consistent with the fact that the optical properties of Titan tholin, among all proposed material, are best at reproducing Titan's geometric albedo spectrum from near UV to mid-IR in light-scattering models.

Thompson, W. Reid↗
NASA NTRS1995

Models of far-IR sources at W3-IRS4 and W3-IRS5

Far-IR continuum maps made with the KAO of W3 at 47 and 95 micrometers show peaks identified with the mid-IR sources IRS4 and IRS5 and extended emission identified with the radio source W3A. We have taken the steepest radial scan profiles from the peaks at IRS4 and IRS5 to represent the objects as spherical clouds. Spherically symmetric models were created in an attempt to match the observed profiles. Radiative transfer dust cloud models heated by central protostars or stars do not match extended emission in the 47 micrometers scan profile for any assumed density distribution for either source. However, both sources can be approximately fit by power law density profiles and ad hoc temperature profiles which are much less steep than those by the single source radiative transfer models. One possible physical explanation for the shallow temperature gradients suggested by the data is heating by a distribution of luminosity sources.

Campbell, M. F.↗
NASA NTRS1995

Mid-infrared (5.0-7.0 microns) imaging spectroscopy of the moon from the KAO

A series of 71 mid-infrared images of a small region of the Moon were obtained from the KAO in October, 1993. These images have been assembled into a 5.0 to 7.0 micron image cube that has been calibrated relative to the average spectrum of this region of the Moon at these wavelengths. The data show that clear, detectable spectral differences exist on the Moon in the mid-IR. Some of the spectral differences are correlated with morphologic features such as craters. Specific spectral features near 5.6 and 6.7 microns may be related to the presence of plagioclase or pyroxene.

Bell, James F., III↗
NASA NTRS1995

KAO observations of SN1987A

Explosion calculations of SN1987A generate pictures of Rayleigh-Taylor fingers of radioactive Ni-56 (Ni-56 yields Co-56 yields Fe-56) which are boosted to velocities of several thousand km/s. From the KAO observations of the mid-IR iron lines, a picture of the iron in the ejecta emerges which is consistent with the 'frothy iron fingers' having expanded to fill about 50% of the metal-rich volume of the ejecta (nu(sub m) less than or equal to 2500 km/s). The ratio of the nickel line intensities I(sub (Ni I)7.5 micron)/I(sub (Ni II)6.6 microns) yields a high ionization fraction of x(sub Ni) greater than or equal to 0.9 in the volume associated with the iron-group elements at day 415, before dust condenses in the ejecta. From the KAO observations of the dust's thermal emission (2 microns to 100 microns), it is deduced that when the grains condense, their infrared radiation is trapped, their apparent opacity is gray, and they have a surface area filling factor of about 50%. The dust emission from SN1987A is featureless: no 9.7 micron silicate feature, nor PAH features, nor dust emission features of any kind are seen at any time. The total dust opacity increases with time even though the surface area filling factor and the dust/gas ratio remain constant. This suggests that the dust forms along coherent structures which can maintain their radial line-of-sight opacities, i.e., along fat fingers. The coincidence of the filling factor of the dust and the filling factor of the iron strongly suggests that the dust condenses within the iron, and therefore the dust is iron-rich. It only takes approximately 10(exp -4) solar mass of dust for the ejecta to be optically thick out to approximately 100 microns; a lower limit of 4 x 10(exp -4) solar mass of condensed grains exists in the metal-rich volume, but much more dust could be present. The episode of dust formation started at about 539 days and proceeded rapidly, so that by 600 days 45% of the bolometric luminosity was being emitted in the IR; by 775 days, 86% of the bolometric luminosity was being reradiated by the dust. Measurements of the bolometric luminosity of SN1987A from 1000 to 2300 days are based on 10 micron and 20 micron photometry and rely on the suppositions that the IR emission is a graybody (proven to be true by the KAO observations at 615 and 775 days) and that the dust temperature drops to and remainsat 150 K. The late-time bolometric luminosity is stronger than that expected from the radioactive decay of Co-56, Co-57, Ti-44, and Na-22 and the late-time dust temperatures are consistent with the presence of a compact object.

Wooden, Diane H.↗
NASA NTRS1997

The Origin, Composition and History of Comets from Spectroscopic Studies

A wealth of information essential to understanding the composition and physical structure of cometary ice and hence gain deep insight into the comet's origin and history, can be gleaned by carrying out a full range of spectroscopic studies on the returned sample. These studies ought to be among the first performed as they are generally non-destructive and will provide a broad data bank which will be crucial in planning subsequent analysis. Examples of the spectroscopic techniques along with relative sensitivities and transitions probed, are discussed. Different kind of "spectroscopy" is summarized, with emphasis placed on the kind of information each provides. Infrared spectroscopy should be the premier method of analysis as the mid-IR absorption spectrum of a substance contains more global information about the identity and structure of that material than any other property. In fact, the greatest strides in our understanding of the composition of interstellar ices (thought by many to be the primordial material from which comets have formed) have been taken during the past ten years or so because this was when high quality infrared spectra of the interstellar medium (ISM) first became available. The interpretation of the infrared spectra of mixtures, such as expected in comets, is often (not always) ambiguous. Consequently, a full range of other non-destructive, complementary spectroscopic measurements are required to fully characterize the material, to probe for substances for which the IR is not well suited and to lay the groundwork for future analysis. Given the likelihood that the icy component (including some of the organic and mineral phases) of the returned sample will be exceedingly complex, these techniques must be intensely developed over the next decade and then made ready to apply flawlessly to what will certainly be one of the most precious, and most challenging, samples ever analyzed.

Allamandola, L. J.↗
NASA NTRS1998

"CHON" particles: The interstellar component of cometary dust

Interstellar dust is characterized by strong absorption in the ultraviolet and the mid-IR. Current models of interstellar dust are based on three chemically distinct components: a form of carbon (usually graphite), a silicate, and a blend of polycyclic aromatic hydrocarbons or other carbonaceous material. Previous work using effective medium theories to understand the optical properties of cometary dust suggested that an amalgam of materials could reproduce the observed interstellar and cometary dust features. Recently, Lawler and Brownlee (1992) re-analyzed the PIA and PUMA-1 data sets from the Giotto flyby of P/Halley and discovered that the so-called "CHON" particles were actually composed of a blend of carbon-bearing and silicon-bearing materials. Based on effective medium theories, the absorption spectrum of such a material would display the spectral features of each of the components - strong UV absorption from the carbonaceous component and strong absorption in the IR from the silicate component. To test this idea, vapor-deposited samples were created using two different deposition techniques: sputtering with an argon RF magnetron and deposition from an argon plasma torch. Two different compositions were tested: a blend of graphite and silica in a 7:1 ratio and an amalgam of materials whose approximate composition matches the "CHON"-silicate abundances for the uncompressed PIA data set of Lawler and Brownlee: graphite, iron oxide, magnesium oxide, ammonium sulfate, calcium carbonate, and silica in mass ratios of 6:4.3:4:2.2:1:9. The samples were finely ground and pressed into 2" diameter disks using a 40 ton press. In all, four different experiments were performed: one with each of the compositions (C:SiO and "CHON") in both the RF magnetron and the plasma torch chambers. The RF magnetron created a uniform dark thin film on the substrate surface, and the plasma torch created a coating of small (<100 micron) diameter grey particles. The spectra of all four samples show a strong, broad absorption feature at around 220 nm as well as a strong but narrower absorption peak near 10 microns. The RF magnetron sputtered samples showed some sub-structure in the UV, and the peak of the absorption was shifted toward longer wavelengths. The UV absorption in the plasma torch deposited samples have no sub-structure, and the peak absorption is very near 220 nm. Strong absorption near 9 microns is seen in the spectra from both sample preparation techniques, and is consistent with the IR spectra of some terrestrial silicates. Other features, particularly at 6.2 and 8.6 microns, are seen in the interstellar medium. A strong feature near 2 microns is due to absorbed water in the sample. Based on the results of these experiments, there is evidence that a material with a composition similar to that detected in "CHON" particles in the coma of P/Halley have a spectral signature which reproduces the main absorption features of interstellar dust. This suggests that the "CHON" particles could be the interstellar component of cometary dust.

Lien, David J.↗
NASA NTRS1998

The Mid-Infrared Spectrum of the Galactic Center: A Starburst Nucleus

Using the Michelson interferometer on the Midcourse Space Experiment (MSX), we have taken spectra of many positions in the central 25 min of the Galactic Center (GC) with a 6 min x 9 min FOV. The spectral coverage was 380 to 1700/ cm (6 to 26 microns) and the resolution was approx. 21/cm. The spectra exhibit strong UIR/PAH features at 6.2, 7.7, 8.6 and 11.3 microns, in addition to the ionic lines of (Ne II), at 12.8 microns, (S III) 18.7 microns, and (Ar II) 6.98 microns. There are deep silicate absorption features at 10 and 18 microns and a cold continuum increasing at the longest wavelengths. Additional weak features are present in the spectra. We discuss the variation in the extinction at 10 microns as a function of location in the GC. Compared to the MSX spectrum of the Orion nebula, smoothed to the same resolution and multiplied by the estimated GC extinction, the GC spectra have similar PAH features, but the Orion Nebula also has strong lines of (He III) 15.6 microns, (S IV) 10.5 microns, and (Ar III) 8.99 microns and its 25 microns continuum is stronger (colder). Thus, the GC exhibits the mid-IR spectrum of a low excitation H II region and a nearby molecular cloud with a surface photodissociation region (PDR). This is in excellent agreement with the canonical model of a starburst nucleus in which the hot stars and molecular clouds are randomly distributed. The outer surfaces of the clouds are photodissociated and ionized by the photons from the stars located outside the clouds. The PAH molecules are transiently heated by the stellar photons. Since the exciting stars are located well outside the clouds, the radiation field is dilute compared to a newly-formed blister H II region like Orion; this dilute radiation field causes the relatively low excitation of the ionic lines.

Simpson, J. P.↗
NASA NTRS1998

The Spectral Energy Distribution of z = 4.7 Quasar: BR1202-0727

BR 1202-0721 is a z = 4.1 quasar which is a 4" double source in the mm, possibly lensed, and has a Lyman alpha emission companion 2" away. The mm spectrum shows a large mass of cool dust ( l0Ell Msun). We report on ground based optical and near-infrared (IR) and space-based, Infrared Space Observatory (ISO) mid-IR observations of this source, combined with data from the literature. The resulting spectral energy distribution show the source to be about two orders-of-magnitude over luminous in the rest-frame near-IR in comparison with typical low-redshift quasars.

Wilkes, Belinda↗
NASA NTRS1999

Path Radiance Technique for Retrieving Aerosol Optical Thickness Over Land

The key issue in retrieving aerosol optical thickness over land from shortwave satellite radiances is to identify and separate the signal due to scattering by a largely transparent aerosol layer from the noise due to reflection by the background surface, where the signal is relatively uniform compared to the highly inhomogeneous surface contribution. Sensitivity studies in aerosol optical thickness retrievals reveal that the apparent reflectance at the top of the atmosphere is very susceptible to the surface reflectance, especially when aerosol optical thickness is small. Uncertainties associated with surface reflectance estimation can greatly amplify the error of the aerosol optical thickness retrieval. To reduce these uncertainties, we have developed a "path radiance" method to retrieve aerosol optical thickness over land by extending the traditional technique that uses the "dark object" approach to extract the aerosol signal. This method uses the signature of the correlation of visible and mid-IR reflectance at the surface, and couples the correlation with the atmospheric effect. We have applied this method to a Landsat TM (Thematic Mapper) image acquired over the Oklahoma Southern Great Plains (SGP) site of DoE's ARM (Department of Energy's Atmospheric Radiation Measurement) program on September 27,1997, a very clear day (aerosol optical thickness of 0.07 at 0.5 microns) during the first Landsat Intensive Observation Period (IOP). The retrieved mean aerosol optical thickness for TM band 1 at 0.49 micron and band 3 at 0.66 micron agree very well with the ground-based sun-photometer measurements at the ARM site. The ability to retrieve small aerosol optical thickness makes this path radiance technique promising. More importantly, the path radiance is relatively insensitive to surface inhomogeneity. The retrieved mean path radiances in reflectance units have very small standard deviations for both TM blue and red bands. This small variability of path radiance further supports the current aerosol retrieval method.

Tsay, S.-C.↗
NASA NTRS1994

Explosion Calculations of SN1087

Explosion calculations of SNT1987A generate pictures of Rayleigh-Taylor fingers of radioactive Ni-56 which are boosted to velocities of several thousand km/s. From the KAO observations of the mid-IR iron lines, a picture of the iron in the ejecta emerges which is consistent with the "frothy iron fingers" having expanded to fill about 50% of the metal-rich volume of the ejecta. The ratio of the nickel line intensities yields a high ionization fraction of greater than or equal to 0.9 in the volume associated with the iron-group elements at day 415, before dust condenses in the ejecta. From the KAO observations of the dust's thermal emission, it is deduced that when the grains condense their infrared radiation is trapped, their apparent opacity is gray, and they have a surface area filling factor of about 50%. The dust emission from SN1987A is featureless: no 9.7 micrometer silicate feature, nor PAH features, nor dust emission features of any kind are seen at any time. The total dust opacity increases with time even though the surface area filling factor and the dust/gas ratio remain constant. This suggests that the dust forms along coherent structures which can maintain their radial line-of-sight opacities, i.e., along fat fingers. The coincidence of the filling factor of the dust and the filling factor of the iron strongly suggests that the dust condenses within the iron, and therefore the dust is iron-rich. It only takes approximately 4 x 10(exp -4) solar mass of dust for the ejecta to be optically thick out to approximately 100 micrometers; a lower limit of 4 x 10(exp -4) solar mass of condensed grains exists in the metal-rich volume, but much more dust could be present. The episode of dust formation started at about 530 days and proceeded rapidly, so that by 600 days 45% of the bolometric luminosity was being emitted in the IR; by 775 days, 86% of the bolometric luminosity was being reradiated by the dust. Measurements of the bolometric luminosity of SN1987A from 1000 - 1800 days are based on 10 micrometers and 20 micrometers photometry and rely on the suppositions that the IR emission is a greybody (proven to be true by the KAO observations at 615 and 775 days) and that the dust temperature drops to and remains at 150 K. The late time bolometric luminosity is stronger than that expected from the radioactive decay of Co-56, Co-57, Ti-44, and Na-22 and the possibility of an embedded compact object will be discussed.

Wooden, Diane H.↗
NASA NTRS1994

Application of Tunable Diode Laser Spectrometry for Isotopic Analysis

Lead-salt tunable diode lasers are now commercially available with operating temperatures above 77 K and excellent single-mode characteristics which make them very useful for spectroscopy in the mid-IR spectral range. Using these lasers for absorption measurements in the 4.3 micrometer spectral region we have made accurate measurements of isotopic abundances in CO2. The method involves assembly language controlled data acquisition of spectra of selected adjacent isotopic rotational lines, an etalon spectral frequency calibration technique, the fitting of multiple Voigt profiles to the data, and the ratioing of absorbances from simultaneously acquired sample and reference data scans. The accuracy achieved is better than 0.4% for the C-13/C-12 ratio and 1% for the O-18/O-16 ratio. Higher accuracy is expected from improvements now being implemented.

Sauke, T. B.↗