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NASA NTRS2016

Mineralogical and Geochemical Trends in a Fluviolacustrine Sequence in Gale Crater, Mars

The Mars Science Laboratory rover, Curiosity, landed at Gale crater in August 2012 and has been investigating a sequence of dominantly fluviolacustrine sediments deposited 3.6-3.2 billion years ago. Curiosity collects quantitative mineralogical data with the CheMin XRD/XRF instrument and quantitative chemical data with the APXS and ChemCam instruments. These datasets show stratigraphic mineralogical and geochemical variability that suggest a complex aqueous history. The Murray Formation, primarily composed of fine-laminated mudstone, has been studied in detail since the arrival at the Pahrump Hills in September 2014. CheMin data from four samples show variable amounts of iron oxides, phyllosilicates, sulfates, amorphous and crystalline silica, and mafic silicate minerals. Geochemical data throughout the section show that there is significant variability in Zn, Ni, and Mn concentrations. Mineralogical and geochemical trends with stratigraphy suggest one of possibly several aqueous episodes involved alteration in an open system under acidic pH, though other working hypotheses may explain these and other trends. Data from the Murray Formation contrast with those collected from the Sheepbed mudstone located approximately 60 meters below the base of the Murray Formation, which showed evidence for diagenesis in a closed system at circumneutral pH. Ca-sulfates filled late-stage veins in both mudstones.

Rampe, E.↗
NASA NTRS2016

Martian Surface Mineralogy from Rovers with Spirit, Opportunity, and Curiosity

Beginning in 2004, NASA has landed three well-instrumented rovers on the equatorial martian surface. The Spirit rover landed in Gusev crater in early January, 2004, and the Opportunity rover landed on the opposite side of Mars at Meridian Planum 21 days later. The Curiosity rover landed in Gale crater to the west of Gusev crater in August, 2012. Both Opportunity and Curiosity are currently operational. The twin rovers Spirit and Opportunity carried Mossbauer spectrometers to determine the oxidation state of iron and its mineralogical composition. The Curiosity rover has an X-ray diffraction instrument for identification and quantification of crystalline materials including clay minerals. Instrument suites on all three rovers are capable of distinguishing primary rock-forming minerals like olivine, pyroxene and magnetite and products of aqueous alteration in including amorphous iron oxides, hematite, goethite, sulfates, and clay minerals. The oxidation state of iron ranges from that typical for unweathered rocks and soils to nearly completely oxidized (weathered) rocks and soils as products of aqueous and acid-sulfate alteration. The in situ rover mineralogy also serves as ground-truth for orbital observations, and orbital mineralogical inferences are used for evaluating and planning rover exploration.

Morris, Richard V.↗
NASA NTRS2020

Mineralogy of Vera Rubin Ridge from the Mars Science Laboratory CheMin Instrument

Vera Rubin ridge (VRR) is an erosion-resistant feature on the northwestern slope of Mount Sharp in Gale crater, Mars, and orbital visible/short-wave infrared measurements indicate it contains red-colored hematite. The Mars Science Laboratory Curiosity rover performed an extensive campaign on VRR to study its mineralogy, geochemistry, and sedimentology to determine the depositional and diagenetic history of the ridge and constrain the processes by which the hematite could have formed. X-ray diffraction (XRD) data from the CheMin instrument of four samples drilled on and below VRR demonstrate differences in iron, phyllosilicate, and sulfate mineralogy and hematite grain size. Hematite is common across the ridge, and its detection in a gray-colored outcrop suggested localized regions with coarse-grained hematite, which commonly forms from warm fluids. Broad XRD peaks for hematite in one sample below VRR and the abundance of FeOT in the amorphous component suggest the presence of nano-crystalline hematite and amorphous Fe oxides/oxyhydroxides. Well-crystalline akaganeite and jarosite are present in two samples drilled from VRR, indicating at least limited alteration by acid-saline fluids. Collapsed nontronite is present below VRR, but samples from VRR contain phyllosilicate with d(001) = 9.6 Å, possibly from ferripyrophyllite or an acid-altered smectite. The most likely cementing agents creating the ridge are hematite and opaline silica. We hypothesize late diagenesis can explain much of the mineralogical variation on the ridge, where multiple fluid episodes with variable pH, salinity, and temperature altered the rocks, causing the precipitation and crystallization of phases that are not otherwise in equilibrium.

E. B. Rampe↗
NASA NTRSDate not supplied

Mineralogy of the Greenheugh Pediment and Underlying Murray Formation from the Mars Science Laboratory CheMin Instrument

The Mars Science Laboratory Curiosity rover has been investigating a sequence of ancient fluvio-lacustrine and eolian units in Gale crater. For much of the mission, Curiosity has studied the fluvio-lacustrine deposits of the Murray formation. Curiosity has also studied the ancient eolian Stimson formation in a few locations, which unconformably overlies the Murray fm. The Stimson formation was previously studied at the Naukluft and Emerson Plateaus and recently studied at the Greenheugh pediment capping unit. The Curiosity science team also investigated the Murray formation directly underlying the pediment. Curiosity drilled the “Edinburgh” target within the pediment capping unit and the “Hutton” target in the Murray formation near the contact with the pediment and delivered these materials to the CheMin X-ray diffractometer to characterize bulk mineralogy. Edinburgh contains abundant plagioclase, pyroxene, magnetite, olivine, and X-ray amorphous materials, with 10 wt.% smectite and minor sanidine. The mineralogy of the Stimson at Greenheugh is distinct from the mineralogy of the Stimson at Naukluft and Emerson because previous Stimson targets did not contain olivine or clay minerals. This suggests sediments in the pediment may have a different source and/or different aqueous alteration history than those from Naukluft and Emerson. Hutton contains abundant plagioclase, pyroxene, magnetite, and X-ray amorphous materials, 6 wt.% smectite, and minor cristobalite, opal-CT, sanidine, hematite, fluorapatite, and anhydrite. Other Murray targets in the surrounding Glen Torridon region that are farther from the pediment contact contain ~30 wt.% smectite and lack cristobalite and opal-CT. Cristobalite and/or opal-CT are present in a few other targets elsewhere along the traverse, including the top of the nearby Vera Rubin ridge and the top of the Pahrump Hills outcrop. Stimson overlies the Pahrump Hills, and, based on projections of the pediment slope, the Stimson may have overlain Vera Rubin ridge. The proximity of the low-smectite and cristobalite- and/or opal-CT-bearing outcrops to the contact between the Murray and Stimson suggests the contact provided a conduit for diagenetic fluids that altered clay minerals and formed crystalline and paracrystalline silica.

E. B. Rampe↗
NASA NTRSDate not supplied

Elemental Partitioning Constraints on the Mineralogy of the Martian Mantle

Incompatible elements weakly partition into mantle mineral phases so precise measurements of incompatible element abundances in mantle melts have been used to infer mineralogy of mantle sources [1, 2]. In a recent study [3], we showed that several incompatible chalcophile elements (As, Tl, Pb) relative to REE were more compatible in martian igneous rocks than in terrestrial basalts. This observation can be accounted for by (1) the bulk partition coefficients of chalcophile elements being higher due to the presence of more residual sulfide in the martian mantle [3] and/or (2) different relative compatibilities in the martian mantle due to differences in mineralogy. In this study, the compatibility sequences of lithophile elements in martian and MORB mantles are revised to better represent relative partitioning behavior during mantle differentiation and the influence of mantle mineralogy is examined.

mantle geochemistry↗
NASA NTRSDate not supplied

Eruption Characterisitics of Lunar Localized Pyroclastic Deposits Based on Water Content, Mineralogy, Regolith Properties

Lunar pyroclastic deposits are low albedo deposits present throughout the lunar surface including both maria and highlands, nearside and farside, and high latitudes and equatorial regions [e.g., 1]. There are two main types of pyroclastic deposits based upon size: localized (<2500 km2) and regional pyroclastic deposits (>2500 km2) [1]. In this study, we focus on the smaller localized pyroclastic deposits. The first and most detailed study of localized pyroclastic deposits are the deposits in Alphonsus crater [2]. This study included examining the radar and volumetric properties of these deposits. They found that vulcanian-like eruptions are most consistent with their observations. They imagined that a dike intrudes into the crust and creates a cooled basaltic cap. With increasing pressure under the basaltic cap, the pressure eventually overwhelms the surrounding rocks and results in explosive decompression. Later studies examined several pyroclastic deposits across the lunar surface using radar [2–4], digital terrain models (DTMs) [2,4], visible and near-infrared spectrometers [1,4–7], and a radiometer [4] to determine the mineralogy (e.g., olivine, glass, clinopyroxene, orthopyroxene, and plagioclase), deposit thickness and volume, proportion of juvenile material, radar backscatter, surface rock abundance, and regolith density. These various properties were examined against one another to better group localized pyroclastic deposits and understand how they relate to one another [4]. One of the studies divided pyroclastic deposits into three groups based upon the shape of the 1-μm absorption feature. The three Groups could be interpretated as having highlands and pyroclastic material (Group I), mare and pyroclastic material (Group II), and glass and orthopyroxene material (Group III) [5]. Building on that foundation, another study divided the pyroclastic deposits into four groups based upon their surface rock abundance and glass abundance [4], where deposits are classified based upon low surface rock abundance and high glass abundance (Glassy deposits); high rock abundance, high glass abundance (Blocky deposits); moderate rock abundance and low glass abundance (Crystalline deposits); and high rock abundance and low glass abundance (Indistinct Group). In addition to these studies, we can now look at their water contents using the new Effective Single Particle Absorption Thickness (ESPAT) parameter map [8]. The ESPAT map measures the strength of the 3-μm absorption feature in single scattering albedo space. The strength of this feature and its relationship to water content has been calibrated to returned samples, which allows for water content to be derived from remote spectral data (i.e., Moon Mineralogy Mapper). The goal of this study is to examine how water content in the pyroclastic deposits varies with respect to the geometric, mineralogic, and physical properties of the localized pyroclastic deposits as measured by a previous study [i.e., 4]. A more complete version of this work is found in [9].

D Trang↗
NASA NTRS2022

GRO 95577 (CR1) as a mineralogical analogue for asteroid (101955) Bennu

Orbital spectra of asteroid (101955) Bennu collected by NASA's Origins, Spectral Interpretation, Resource Identification, Security–Regolith Explorer (OSIRIS–REx) spacecraft have identified ungrouped C, CI, and CM meteorites having petrologic types 1, 1/2, and 2 as the best mineralogical analogues to Bennu to date. Here we present spectral evidence that Grosvenor Mountains (GRO) 95577, a CR1, is a better analogue for Bennu's bulk surface mineralogy. CR-like parent bodies are targets of interest because they contain some of the most pristine materials from the solar nebula and can contain substantial amounts of H2O and OH− in addition to exotic organics. Unfortunately, terrestrial weathering makes constraining their indigenous mineralogy and organics challenging. Analysis of samples retrieved directly from an asteroid would help us disentangle the effects of terrestrial weathering and asteroidal aqueous alteration and hence whether some of the exotic organics and large populations of presolar grains were affected by terrestrial processes in meteorites. If Bennu is comprised of CR1(−like) material, in whole or in part, the OSIRIS–REx returned sample represents a tremendous opportunity to explore in depth what is currently a unique material among carbonaceous chondrites.

Asteroids↗
NASA NTRSDate not supplied

Mineralogical Evidence for Environmental Change in the Clay-Sulfate Transition at Gale Crater, Mars

A primary reason for selecting Gale crater as the Mars Science Laboratory (MSL) Curiosity rover landing site was a clear mineralogical transition from Fe/Mg smectite in older strata to hydrated Mg sulfate salts in younger strata observed in orbital visible/shortwave-infrared reflectance data. This transition has been observed in other early-Hesperian terrains on Mars and has been hypothesized to signal a planet-wide change in climate from relatively warm and wet to cold and dry. Curiosity studied the sedimentology and geochemical and mineralogical composition of rocks in this “clay-sulfate transition” region from sols 3052 to 3572 (i.e., March 2021 to August 2022), with arrival at the sulfate unit on sol 3574. Here, we report on the mineralogical measurements made by the CheMin X-ray diffractometer of the six drill targets in the clay-sulfate transition and the first drill target in the sulfate unit. We use compositional data and sedimentological observations to interpret depositional and diagenetic environments and present hypotheses to explain the transition from clay minerals to hydrated Mg sulfates.

E. B. Rampe↗
NASA NTRS2019

Bayesian Estimation of Earth’s Undiscovered Mineralogical Diversity Using Noninformative Priors

Recently, statistical distributions have been explored to provide estimates of the mineralogical diversity of Earth, and Earth-like planets. In this paper, a Bayesian approach is introduced to estimate Earth’s undiscovered mineralogical diversity. Samples are generated from a posterior distribution of the model parameters using Markov chain Monte Carlo simulations such that estimates and inference are directly obtained. It was previously shown that the mineral species frequency distribution conforms to a generalized inverse Gauss–Poisson (GIGP) large number of rare events model. Even though the model fit was good, the population size estimate obtained by using this model was found to be unreasonably low by mineralogists. In this paper, several zero-truncated, mixed Poisson distributions are fitted and compared, where the Poisson-lognormal distribution is found to provide the best fit. Subsequently, the population size estimates obtained by Bayesian methods are compared to the empirical Bayes estimates. Species accumulation curves are constructed and employed to estimate the population size as a function of sampling size. Finally, the relative abundances, and hence the occurrence probabilities of species in a random sample, are calculated numerically for all mineral species in Earth’s crust using the Poisson-lognormal distribution. These calculations are connected and compared to the calculations obtained in a previous paper using the GIGP model for which mineralogical criteria of an Earth-like planet were given.

Bayesian statistics↗
NASA NTRSDate not supplied

The Chemistry and Mineralogy of Mars Soils: A Tour of Landed Mission Results from the Last 45 years

Eight landed missions demonstrated that martian soils (defined as loose, unconsolidated surface material) consist of basaltic mineralogy, iron (hydr)oxides, amorphous material, sulfate, chloride, (per)chlorate, nitrate, carbonate, and possible organic C. The Viking Lander 1 and 2 (1976), Mars Pathfinder (1997), and Mars Exploration Rover (MER-A,B) (2004) missions determined that martian soil was similar at all landing sites by having mafic chemistry, high S (~ 7 wt.% SO3) and Cl (0.7 wt.%), and spectral detections of poorly crystalline and crystalline Fe-(hydr)oxide phases. The MER Mössbauer spectrometers detected Fe-bearing olivine and pyroxene along with magnetite, nano-phase Fe-oxides (npOx), hematite, and ferric sulfate. The 2008 Phoenix Lander instrumentation measured a soil pH of 7.7 and detected ~0.6 wt.% perchlorate, 3-5 wt.% Ca-rich carbonate and carbon (500 gC/g) consistent with oxidized organics and Fe-rich carbonate. The 2012 Mars Science Laboratory (MSL) rover (Gale Crater) through X-ray diffraction detected plagioclase feldspar, pyroxene, magnetite, hematite, anhydrite, and quartz, with the balance being composed of Si/Fe-containing amorphous (30 to 40 wt.%) material. MSL evolved gas analysis detected (per)chlorate (0.4 wt.% ClO4), nitrate (0.23 wt.%), along with minor Fe/Mg sulfate and oxidized organic C (~2000 gC/g). Limited pedogenesis may have occurred at the 2018 InSight landing site and in one Gusev Crater soil (MER-B) which have 3 to 10 cm-thick duricrust horizons consistent with atmospheric water vapor interactions with soil salts. Martian soil primary mineralogy was derived mostly from local rock (volcanic, sedimentary) that is largely basaltic planet wide. Secondary minerals [e.g., sulfate, chloride, perchlorate, nitrate, carbonate, Fe-(hydr)oxides] in martian soils formed from oxidative aqueous alteration processes and were likely derived from a combination of local sedimentary rock sources and the global bright dust. The Mars 2020 mission will collect soil for Earth return to enable a thorough assessment of the nature and origin of martian soil.

Mars↗
NASA NTRSDate not supplied

Coupling of Dust Mineralogy to Radiation in NASA GISS ModelE: Impact Upon Dust Optical Properties and Direct Radiative Effect

Estimates of dust direct radiative effect (DRE) are still largely uncertain mainly due to the poor constraining of regional variations of dust absorption, whose known connection with mineral composition is still largely neglected by most Earth System Models. The inaccurate knowledge of soil mineralogy and insufficient measurements of dust physical and optical properties still present the main challenges for a proper representation of the dust-radiation interaction in climate models. We recently upgraded the coupling of dust minerals to shortwave radiation in the NASA GISS ModelE. In particular, we extended the interaction to online-calculated minerals and implemented two different mixing configurations: i) external mixing of three main mineral components and ii) internal mixing of all minerals, allowing a dynamic fraction of iron oxides. We used a semi-empirical approach for the optical calculations, mostly based on aerosol chamber measurements from natural soils, aiming to reduce the influence of uncertain assumptions on the optical properties and mixing state of individual minerals. In this contribution, we present the results of our first calculations of dust optical properties and DREs based on different mixing configurations of interactive minerals. We show the changes to dust optical depth and single scattering albedo, with respect to the control case using homogeneous dust composition, and the consequent global and regional variations in dust DREs at the top of atmosphere and at surface. We also compare the model optical properties with AERONET data, filtered to identify dust scenes. We find that accounting for the diverse properties of dust minerals modifies the pattern of regional dust absorption and therefore its impact upon climate. We also show that the mineralogy effect is sensitive to the assumed mixing state of minerals.

dust direct radiative effect↗
NASA NTRS1973

Lunar Science Conference, 4th, Houston, Tex., March 5-8, 1973, Proceedings. Volume 1 - Mineralogy and petrology. Volume 2 - Chemical and isotope analyses. Organic chemistry. Volume 3 - Physical properties

The mineralogy, petrology, chemistry, isotopic composition, and physical properties of lunar materials are described in papers detailing methods, results, and implications of research on samples returned from eight lunar landing sites: Apollo 11, 12, 14, 15, 16, 17, and Luna 16 and 20. The results of experiments conducted or set up on the lunar surface by the astronauts are also described along with observations taken from Command Modules and subsatellites. Major topics include general geology, soil and breccia studies, petrologic studies, mineralogic analyses, elemental compositions, radiometric age determinations, rare gas chemistry, radionuclides, organogenic compounds, particle track records, thermal properties, seismic studies, resonance studies, orbital mapping, lunar atmosphere, magnetic studies, electrical studies, optical properties, and microcratering. Individual items are announced in this issue.

Gose, W. A.↗
NASA NTRS1975

Mineralogy of the Ibitira eucrite and comparison with other eucrites and lunar samples

Single crystal X-ray and energy dispersive electron-probe techniques are used to study the mineralogy and track history of Ibitira. The mineralogical features of the Ibitire eucrite are described and examined in relation to data for other eucrites and howardites and lunar samples. The processes which transformed a presumed igneous texture into a more complex one are discussed.

Steele, I. M.↗
NASA NTRS1976

Mineralogy of the Ibitira eucrite and comparison with other eucrites and lunar samples

The mineralogy of the Ibitira meteorite is studied using single-crystal X-ray and energy-dispersive electron-probe techniques. It is shown that this strongly metamorphosed unbrecciated vesicular eucrite has a primary variolitic and secondary hornfelsic texture dominated by equant grains of pale-brown pyroxene (60%) set in an irregular matrix of plagioclase (30%). Minor phases are detected which indicate igneous crystallization, a prolonged metamorphic history, and vapor deposition. The following sequence of events is suggested as the simplest explanation for the mineralogical features observed: (1) crystallization of the meteorite in a lava flow; (2) prolonged annealing, reduction of primary spinel, and vapor deposition; (3) strong shock sufficient to modify the texture of the plagioclase grains; and (4) sufficient annealing to allow crystallization of the plagioclase as a subparallel mosaic and partial conversion to the low structural state. Evidence for this sequence is examined in detail, particularly in relation to the general features of eucrites, howardites, and mesosiderites

Steele, I. M.↗
NASA NTRS1977

Geochemical and mineralogical interpretation of the Viking inorganic chemical results

The current status of geochemical, mineralogical, petrological interpretation of refined Viking Lander data is reviewed, and inferences that can be drawn from data on the composition of Martian surface materials are presented. The materials are dominantly fine silicate particles admixed with, or including, iron oxide particles. Both major element and trace element abundances in all samples are indicative of mafic source rocks (rather than more highly differentiated salic materials). The surface fines are nearly identical in composition at the two widely separated Lander sites, except for some lithologic diversity at the 100-m scale. This implies that some agency (presumably aeolian processes) has thoroughly homogenized them on a planetary scale. The most plausible model for the mineralogical constitution of the fine-grained surface materials at the two Lander sites is a fine-grained mixture dominated by iron-rich smectites, or their degradation products, with ferric oxides, probably including maghemite and carbonates (such as calcite), but not such less stable phases as magnesite or siderite.

Toulmin, P., III↗
NASA NTRS1977

Mineralogy, petrology and chemistry of ANT-suite rocks from the lunar highlands

Anorthositic-noritic-troctolitic (ANT) rocks are the oldest and most abundant rocks of the lunar surface, and comprise about 90% of the suite of the lunar highlands. Consideration is given to the mineralogy, petrology, bulk chemistry, and origin of ANT-suite rocks. Problems associated in classifying and labeling lunar highland rocks because of textural complexities occurring from impact modifications are discussed. The mineralogy of ANT-suite rocks, dominated by plagioclase, olivine and pyrozene, and containing various minor minerals, is outlined. The petrology of ANT-suite rocks is reviewed along with the major element bulk composition of these rocks, noting that they are extremely depleted in K2O and P2O5. Various models describing the origin of ANT-suite rocks are summarized, and it is suggested that this origin involves a parental liquid of high-alumina basalt with low Fe/Fe+Mg.

Prinz, M.↗
NASA NTRS1977

Asteroid surface materials - Mineralogical characterizations and cosmological implications

The theoretical basis for the interpretation of diagnostic spectral features is examined and previous characterizations of asteroid surface materials are considered. A summary is provided of results reported by Gaffey and McCord (1977) who have utilized the most sophisticated interpretive techniques available to interpret the spectral reflectance data of about 65 asteroids for mineralogic and petrologic information. Cosmological implications related to the study of asteroid surface materials are also considered, taking into account source bodies for the meteorites, postaccretionary thermal history, significant factors of asteroid thermal history, and the Apollo and Amor asteroids. It is found that the asteroids exhibit surface materials made up of assemblages of meteoritic minerals. The relative abundance of meteorite types reaching the earth's surface is very different from the population of mineralogic types on asteroid surfaces. The earth-crossing or -approaching asteroids apparently derive from a restricted source region or population which is very strongly depleted in the C2-like assemblages that dominate the belt as a whole.

Gaffey, M. J.↗
NASA NTRS1979

Remote spectroscopic identification of carbonaceous chondrite mineralogies Applications to Ceres and Pallas

High-resolution spectroscopic observations of asteroids Ceres and Pallas have been obtained in the 1.0- to 2.6-micron region. Combined with previous spectral measurements at other wavelengths, this work presents the broadband spectral reflectances of these asteroids over the 0.4- to 3.6-micron region. This extended coverage permits new analyses of the surface mineralogies of these objects. Using laboratory comparison spectra of meteorites and mixtures of terrestrial minerals, the surfaces of Ceres and Pallas are consistent with mixtures of opaques and hydrated silicates, such as are found in types C1 and C2 meteorites. This research emphasizes the importance of the 3-micron spectral region for studying by remote methods the relationship of carbonaceous chondrite mineralogies to asteroid surfaces.

Larson, H. P.↗