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Investigating Relationships Between Geochemistry and Physical Grain Characteristics Along a Glacio-Fluvial-Aeolian Sediment Transport Pathway Using µXRF

Iceland’s basaltic volcanic rocks and glacial, fluvial, and aeolian landscapes resemble those studied on Mars, which makes it an ideal location to study the evolution of basaltic landscapes, the weathering and alteration of basaltic sediments in cold and wet environments, and the generation of a basaltic sedimentary record. The SAND-E: Semi-Autonomous Navigation for Detrital Environments project examines physical and chemical changes in sediments transported through basaltic fluvial and aeolian environments, and tests operational scenarios, which include a drone and a robotic rover instrumented with autonomous terrain analysis software. As part of the SAND-E project, we examined a glacial outwash plain at Skjaldbreiðauhraun, in SW Iceland. This study uses micro X-ray fluorescence (μXRF) to examine the chemical and physical properties of unconsolidated sediment-size fractions from 710 μm to < 63 μm along a downstream transect from a glacial sourced watershed. μXRF is ideally suited for this task because it maps elemental distributions at sub-grain scales thereby allowing a direct correlation between grainsize, grain shape, and chemistry. It is also a good analog technique for the Mars 2020 mission equipped with the PIXL (Planetary Instrument for X-ray Lithochemistry) that will be deployed at Jezero Crater, Mars.

Champion, E.↗

On the Hunt for Detectable Biosignatures in Jezero Crater: What to Look for and Where

Introduction: The Perseverance rover, which is currently exploring Jezero crater on Mars, is equipped with seven instruments that allow for observation of textures, minerals, color, structure, and chemistry of rocks and sediments in order to search for signs of ancient life, understand the geologic history of the crater, and identify candidates for sample return (Farley et al. 2020). The first of these aims includes the direct detection of potential biosignatures, including textures, organic molecules, minerals, and elemental chemistries that are of biogenic origin (Mustard et al. 2013). The presence of these biosignatures will be constrained by the habitability of the local region, the preservation potential of the host rocks, and the sensitivity of the instrument suite, and their biogenicity will be investigated after return to Earth as part of the Mars Sample Return campaign. Here, we examine key targets on the three planned campaigns, potential biosignatures that may be present, and the capabilities of key rover instruments. High Potential Biosignature Sites in Jezero: To date, measurements have been made on multiple sites that both contain minerals known in terrestrial settings to preserve biosignatures and likely were habitable settings (Williford et al. 2021). Two examples include the fine-grained rocks at the base of the delta fan and the NW inner margin of the crater. Fine-grained Rocks at Base of Delta Fan. Fine-grained, clay-bearing rocks may have been deposited as muddy lake sediments that could have hosted life and preserved biosignatures settling out of the water column. The report of organic molecules by the Curiosity rover in the Sheepbed mudstone and Murray formation has highlighted this site in particular. Potential biosignatures in mudstones, especially those rich in silica (McMahon et al. 2018), microbialites and complex organics. NW Inner Margin of Crater. This unit, located along the inner margin of the crater, contains strong carbonate signatures and may have been the littoral zone of a lake (Horgan et al. 2020). The potential biosignatures here include microfossils, microbialites, biominerals, and complex organics. Detectability of Biosignatures by the Mars 2020 Instrument Suite: The Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC) instrument comprises a Deep UV spectrometer, context imager, and color camera to generate spatially resolved chemical maps (Bhartia et al. 2020). It is sensitive to trace organics as well as a range of minerals and can detect native fluorescence from aromatic organics; the WATSON and ACI cameras can be used to observe morphologies such as stromatolitic laminations or filaments ranging from the tens of micron to millimeter scale. SHERLOC can detect organics that may be present in either of the high potential biosignature targets, as well as detect carbonates in the latter. However, the presence of high amounts of iron, such as in iron-rich clays, would cause attenuation of spectral response through UV absorption. The Planetary Instrument for X-ray Lithochemistry (PIXL) comprises an X-ray fluorescence spectrometer and camera that can scan rock surfaces to generate elemental maps (Allwood et al. 2020). PIXL can detect chemical biosignatures such as spatial variations of elemental abundances that may have resulted from biological activity. PIXL would be particularly useful in detecting fine textures and elemental chemistries in either high potential biosignature target, but cannot directly detect minerals such as carbonate. The SuperCam instrument performs three types of spectroscopy, color imaging, and acoustic recording to remotely examine elemental composition, minerals, organics, and textures (Maurice et al. 2021). Using laser induced breakdown spectroscopy and time resolved luminescence spectroscopy, SuperCam can detect major elemental building blocks of organics (i.e., C, H, N, O, P, S) and conjugated organic structures, respectively, which may be found in either site. While in other contexts, luminescence is a useful tool for biosignature identification, luminescence generated by the 532 nm laser may obscure the Raman signal. Conclusion: The three instruments discussed can be used collaboratively to establish the presence of potential biosignatures in samples. These high-priority samples may then be returned to Earth for detailed laboratory analysis.

S. Sharma↗

NASA Planetary Science Division's Instrument Development Programs, PICASSO and MatISSE

The Planetary Science Division (PSD) has combined several legacy instrument development programs into just two. The Planetary Instrument Concepts Advancing Solar System Observations (PICASSO) program funds the development of low TRL instruments and components. The Maturation of Instruments for Solar System Observations (MatISSE) program funds the development of instruments in the mid-TRL range. The strategy of PSD instrument development is to develop instruments from PICASSO to MatISSE to proposing for mission development.

Instruments↗

A visible-infrared imaging spectrometer for planetary missions

This final report summarizes the design effort for the construction of a visible-infrared imaging spectrometer for planetary missions, funded by NASA under the Planetary Instrument Definition and Development Program. The goal was to design and develop a prototype brassboard pushbroom imaging spectrometer covering the 0.35 gm to 2.5 gm spectral region using a simplified optical layout that would minimize the size, mass and parts count of the instrument by using a single holographic grating to disperse and focus light from a single slit onto both the infrared and visible focal plane arrays. Design approaches are presented and analyzed, along with problems encountered and recommended solutions to those problems. In particular, a new type of grating, incorporating two sets of rulings and a filter in a layered structure, is presented for further development.

McCord, Thomas↗

A Miniature Solid-State Spectrometer for Space Applications: Field Tests

A solid state infrared spectrometer has been developed under the Planetary Instrument Definition and Development Program PIDDP to implement a small rugged spectrometer principally for landed applications. The instrument uses the high index of refraction and waveguide properties of a silicon slab to achieve good spectral resolution and high throughput in a small instrument footprint (less than 25 cm). Light enters the silicon slab and is reflected off a grating (Ebert configuration), utilizing the silicon index of refraction to achieve high dispersion. An array of microthermopiles is used to measure the amplitude of the dispersed light. Input optics are typically utilized to focus light on the input aperture and a chopper is used to compensate system drift.

Smythe, W. D.↗

Whispering Gallery Mode Resonator with Orthogonally Reconfigurable Filter Function

An optical resonator has been developed with reconfigurable filter function that has resonant lines that can be shifted precisely and independently from each other, creating any desirable combination of resonant lines. This is achieved by changing the axial distribution of the effective refractive index of the resonator, which shifts the resonant frequency of particular optical modes, leaving all the rest unchanged. A reconfigurable optical filter is part of the remote chemical detector proposed for the Mars mission (Planetary Instrument Definition and Development Program PIDDP), but it is also useful for photonic communications devices.

Maleki, Lute↗

Low Cost, Low Power, Passive Muon Telescope for Interrogating Martian Sub-Surface

It has been demonstrated on Earth that a low power, passive muon detector can penetrate deep into geological structures up to several kilometers in size providing high density images of their interiors. Muon tomography is an entirely new class of planetary instrumentation that is ideally suited to address key areas in Mars Science, such as: the search for life and habitable environments, the distribution and state of water and ice and the level of geologic activity on Mars today.

Muons↗

Amplifier Module for 260-GHz Band Using Quartz Waveguide Transitions

Packaging of MMIC LNA (monolithic microwave integrated circuit low-noise amplifier) chips at frequencies over 200 GHz has always been problematic due to the high loss in the transition between the MMIC chip and the waveguide medium in which the chip will typically be used. In addition, above 200 GHz, wire-bond inductance between the LNA and the waveguide can severely limit the RF matching and bandwidth of the final waveguide amplifier module. This work resulted in the development of a low-loss quartz waveguide transition that includes a capacitive transmission line between the MMIC and the waveguide probe element. This capacitive transmission line tunes out the wirebond inductance (where the wire-bond is required to bond between the MMIC and the probe element). This inductance can severely limit the RF matching and bandwidth of the final waveguide amplifier module. The amplifier module consists of a quartz E-plane waveguide probe transition, a short capacitive tuning element, a short wire-bond to the MMIC, and the MMIC LNA. The output structure is similar, with a short wire-bond at the output of the MMIC, a quartz E-plane waveguide probe transition, and the output waveguide. The quartz probe element is made of 3-mil quartz, which is the thinnest commercially available material. The waveguide band used is WR4, from 170 to 260 GHz. This new transition and block design is an improvement over prior art because it provides for better RF matching, and will likely yield lower loss and better noise figure. The development of high-performance, low-noise amplifiers in the 180-to- 700-GHz range has applications for future earth science and planetary instruments with low power and volume, and astrophysics array instruments for molecular spectroscopy. This frequency band, while suitable for homeland security and commercial applications (such as millimeter-wave imaging, hidden weapons detection, crowd scanning, airport security, and communications), also has applications to future NASA missions. The Global Atmospheric Composition Mission (GACM) in the NRC Decadel Survey will need low-noise amplifiers with extremely low noise temperatures, either at room temperature or for cryogenic applications, for atmospheric remote sensing.

Padmanabhan, Sharmila↗

Surface-Enhanced Raman Scattering Using Silica Whispering-Gallery Mode Resonators

The motivation of this work was to have robust spectroscopic sensors for sensitive detection and chemical analysis of organic and molecular compounds. The solution is to use silica sphere optical resonators to provide surface-enhanced spectroscopic signal. Whispering-gallery mode (WGM) resonators made from silica microspheres were used for surface-enhanced Raman scattering (SERS) without coupling to a plasmonic mechanism. Large Raman signal enhancement is observed by exclusively using 5.08-micron silica spheres with 785-nm laser excitation. The advantage of this non-plasmonic approach is that the active substrate is chemically inert silica, thermally stable, and relatively simple to fabricate. The Raman signal enhancement is broadly applicable to a wide range of molecular functional groups including aliphatic hydrocarbons, siloxanes, and esters. Applications include trace organic analysis, particularly for in situ planetary instruments that require robust sensors with consistent response.

Anderson, Mark S.↗

Updates of the KArLE Experiment: New Libs Calibration Under High Vacuum for the Quantification of Potassium in Basalt for In Situ Geochronology

In planetary exploration, in situ absolute geochronology is one of the main important measurements that needs to be accomplished. Until now, on Mars, the age of the surface is only determined by crater density counting, which gives relative ages. These ages can have a lot of uncertainty as they depend on many parameters. More than that, the curves must be ties to absolute ages. Thus far, only the lost lander Beagle 2 was designed to conduct absolute geochronology measurements, though some recent attempts using MSL Curiosity show that this investigation is feasible and should be strongly encouraged for future flight. Experimental: The Potassium (K)-Argon Laser Experiment (KArLE) is being developed at MSFC through the NASA Planetary Instrument Definition and Development Program (PIDDP). The goal of this experiment is to provide in situ geochronology based on the K-Ar method. A laser ablates a rock under high vacuum, creating a plasma which is sensed by an optical spectrometer to do Laser Induced Breakdown Spectroscopy (LIBS). The ablated material frees gases, including radiogenic 40Ar,which is measured by a mass spectrometer (MS). As the potassium is a content and the 40Ar is a quantity, the ablated mass needed in order to relate them. The mass is given by the product of the ablated volume by the density of this material. So we determine the mineralogy of the ablated material with the LIBS spectra and images and calculate its density. The volume of the pit is measured by using microscopy. LIBS measurement of K under high vacuum: Three independant projects [1, 2, 3] including KArLE, are developing geochronological instruments based on this LA-LIBS-MS method. Despite several differences in their setup, all of them have validated the methods with analyses and ages. However, they all described difficulties with the LIBS measurements of K [3,4]. At ambient pressure, the quantification of K by LIBS on geological materials can be accurate [5]. However the protocol of the LA-LIBS-MS experiment required hundreds of shots under high vacuum in order to free enough 40Ar* to be measured by the QMS. This long duration of ablation may induces significant changes in the LIBS spectra. The pressure may increases by orders of magnitudewithin the chamber and the laser pit geometry can change the effectiveness of ablation and intensity of plasma light received. These effects introduce variation between the first and last spectra and so the quantification of K is more complex. The ablation of one crater can give, depending on the protocol of acquisition, from tens to hundreds of spectra. Protocol and results: We are in the process of further characterizing the variation introduced into LIBS spectra by the use of hundreds of laser shots, and definining a protocol that can be used to ensure accuracy and reporoducibility in the results.We are using natural rock powder standards fused in a furnace, as well as mars analog samples with known K content. We will show the result of the calibration and some new statistical approaches in order to apprehend the effects of the long time ablation on rocks under high vacuum.

Devismes, D.↗

A Miniaturized Variable Pressure Scanning Electron Microscope (MVP-SEM) for In-Situ Mars Surface Sample Analysis

The Miniaturized Variable Pressure Scanning Electron Microscope (MVP-SEM) project, funded by the NASA Planetary Instrument Concepts for the Advancement of Solar System Observations (PICASSO) Research Opportunities in Space and Earth Sciences (ROSES), will build upon previous miniaturized SEM designs and recent advancements in variable pressure SEM's to design and build a SEM to complete analyses of samples on the surface of Mars using the atmosphere as an imaging medium. This project is a collaboration between NASA Marshall Space Flight Center (MSFC), the Jet Propulsion Laboratory (JPL), electron gun and optics manufacturer Applied Physics Technologies, and small vacuum system manufacturer Creare. Dr. Ralph Harvery and environmental SEM (ESEM) inventor Dr. Gerry Danilatos serve as advisors to the team. Variable pressure SEMs allow for fine (nm-scale) resolution imaging and micron-scale chemical study of materials without sample preparation (e.g., carbon or gold coating). Charging of a sample is reduced or eliminated by the gas surrounding the sample. It is this property of ESEMs that make them ideal for locations where sample preparation is not yet feasible, such as the surface of Mars. In addition, the lack of sample preparation needed here will simplify the sample acquisition process and allow caching of the samples for future complementary payload use.

Microscope↗

Highly Differentiated Basaltic Lavas Examined by PIXL in Jezero Crater

Textural, bulk chemical, and mineralogical data collected by PIXL(Planetary Instrument for X-ray Lithochemistry) indicate that the first rock unit (Cf-fr, Crater Floor-Fractured rough)examined by the M2020 Perseverance rover in Jezero crater is from a basaltic lava flow. This unit was originally mapped as volcanic flow[1]but has been reinterpreted as a clastic or volcaniclastic sediment[2].We here present evidence that it is a basalt flow, with implications for its petrogenesis as a highly differentiated basalt.

M E Schmidt↗

Development of 2.05 µm Fiber Lasers for CO2 DIAL Lidar Measuring Martian CO2 and Pressure

The Decadal Survey by the National Academy of Sciences in the United States and NASA’s Science Mission Directorate (SMD) Science Plan both require global CO 2 observations for the Martian atmospheric pressure, dynamics and chemistry. However, there are significant observational gaps in polar regions and during nighttime for global air pressure and CO 2 on Mars. Therefore, recently we proposed a new concept of Martian differential absorption lidar (DIAL) operating in the 2.05 µm CO 2 absorption band for global, including poles, atmospheric CO 2 and pressure observations day and night [1]. Based on the concept, we are awarded to develop 2.05 µm fiber lasers by the NASA Planetary Instrument Concepts for the Advancement of Solar System Observations (PICASSO) Program. The laser is designed to be an all-fiber master oscillator and power amplifier (MOPA) system with laser output of ~3 mJ at a repetition frequency of 2 kHz. The primary master oscillator (PMO) is locked to the center (2.0504280 µm) of the selected CO 2 absorption line. The frequency of a second MO (SMO) is locked to that of PMO. This SMO frequency is adjustable and switched between the online (2.05044156 µm) and offline (2.05050812 µm) wavelengths. The online wavelength is optimally selected so that the CO 2 absorption optical depth (AOD) is ~1.1 at 3 km and the measurement in the low Martian atmosphere has largest signal-to-noise ratio. The online wavelength can also be adjusted to a line slope location where AOD is larger to observe atmospheric pressure at higher altitudes. We will present more detail about this project and instrument development at the conference.

Zhaoyan Liu↗

Progress of 2.05 μm Fiber Laser Development for CO2 DIAL Measurements of Martian CO2 and Pressure

The Decadal Survey by the US National Academy of Sciences in the United States and NASA’s Science Mission Directorate (SMD) Science Plan both require global CO2 observations for the Martian atmospheric pressure, dynamics and CO2 variations. However, there are significant observational gaps in polar regions and during nighttime for global air pressure and CO2 on Mars. Therefore, recently we proposed a new concept of Martian differential absorption lidar (DIAL) operating in the 2.05 μm CO2 absorption band for global, including poles, atmospheric CO2 and pressure observations day and night. Based on the concept, we are awarded to develop 2.05 μm fiber lasers by the NASA Planetary Instrument Concepts for the Advancement of Solar System Observations (PICASSO) Program. The laser is designed to be an all-fiber master oscillator and power amplifier (MOPA) system with laser out put of ~3 mJ at a repetition frequency of 2 kHz. The primary master oscillator (PMO) is locked to the center (2.0504280 μm) of the selected CO2 absorption line. The frequency of a second MO (SMO) is locked to that of PMO. This SMO frequency is adjustable and switched between the online (2.05044156 μm) and offline (2.05050812 μm) wavelengths. The online wavelength is optimally selected so that the CO2 absorption optical depth (AOD) is ~1.1 at 3 km and the measurement in the low Martian atmosphere has largest signal-to-noise ratio. The online wavelength can also be adjusted to a line slope location where AOD is larger to observe atmospheric pressure at higher altitudes. We will present more details about this project and instrument development.

CO2↗

Diverse and Highly Differentiated Lava Suite in Jezero Crater, Mars: Constraints on Intracrustal Magmatism Revealed By Mars 2020 PIXL

The Jezero crater floor features a suite of related, iron-rich lavas that were examined and sampled by the Mars 2020 rover Perseverance , and whose textures, minerals, and compositions were characterized by the Planetary Instrument for X-ray Lithochemistry (PIXL). This suite, known as the Máaz formation (fm), includes dark-toned basaltic/trachy-basaltic rocks with intergrown pyroxene, plagioclase feldspar, and altered olivine and overlying trachy-andesitic lava with reversely zoned plagioclase phenocrysts in a K-rich groundmass. Feldspar thermal disequilibrium textures indicate that they were carried from their crustal staging area. Bulk and mafic minerals have very high FeO and low MgO to FeO total ratios, which are partially reproduced by thermodynamic models involving high-degree fractional crystallization of a gabbroic assemblage and possibly also assimilation of iron-rich basement. Together, these in situ constraints on petrogenesis provide a uniquely detailed record of intracrustal processes beneath Jezero crater during a time period not represented by Mars samples to date.

Jezero Crater floor↗

Training Early Career Scientists in Flight Instrument Design Through Experiential Learning: NASA Goddard's Planetary Science Winter School.

The NASA Goddard Planetary Science Winter School (PSWS) is a Goddard Space Flight Center-sponsored training program, managed by Goddard's Solar System Exploration Division (SSED), for Goddard-based postdoctoral fellows and early career planetary scientists. Currently in its third year, the PSWS is an experiential training program for scientists interested in participating on future planetary science instrument teams. Inspired by the NASA Planetary Science Summer School, Goddard's PSWS is unique in that participants learn the flight instrument lifecycle by designing a planetary flight instrument under actual consideration by Goddard for proposal and development. They work alongside the instrument Principal Investigator (PI) and engineers in Goddard's Instrument Design Laboratory (IDL; idc.nasa.gov), to develop a science traceability matrix and design the instrument, culminating in a conceptual design and presentation to the PI, the IDL team and Goddard management. By shadowing and working alongside IDL discipline engineers, participants experience firsthand the science and cost constraints, trade-offs, and teamwork that are required for optimal instrument design. Each PSWS is collaboratively designed with representatives from SSED, IDL, and the instrument PI, to ensure value added for all stakeholders. The pilot PSWS was held in early 2015, with a second implementation in early 2016. Feedback from past participants was used to design the 2017 PSWS, which is underway as of the writing of this abstract.

Flight↗

In Situ Instrumentation for Sub-Surface Planetary Geochemistry

Novel instrumentation is under development at NASA's Goddard Space Flight Center, building upon earth-based techniques for hostile environments, to infer geochemical processes important to formation and evolution of solid bodies in our Solar System. A prototype instrument, the Pulsed Neutron Generator Gamma Ray and Neutron Detectors (PNG-GRAND), has a 14 MeV pulsed neutron generator coupled with gamma ray and neutron detectors to measure quantitative elemental concentrations and bulk densities of a number of major, minor and trace elements at or below the surfaces with approximately a meter-sized spatial resolution down to depths of about 50 cm without the need to drill. PNG-GRAND's in situ a meter-scale measurements and adaptability to a variety of extreme space environments will complement orbital kilometer-scale and in-situ millimeter scale elemental and mineralogical measurements to provide a more complete picture of the geochemistry of planets, moons, asteroids and comets.

Bodnarik, J.↗