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At least 91 records · Page 5

The Grand Geochemistry of 4 Vesta: First Results

On 12-Dec-2011, the Dawn spacecraft commenced low altitude mapping of the giant asteroid, 4 Vesta (264-km mean radius). Dawn's roughly circular, polar, low altitude mapping orbit (LAMO) has a mean radius of 470 km, placing the spacecraft within about 210 km of Vesta's surface. At these altitudes, Dawn s Gamma Ray and Neutron Detector (GRaND) is sensitive to Vesta's elemental com-position (Fig. 1). GRaND will acquire data in LAMO for up to 16 weeks, which is sufficient to map the elemental composition of the entire surface of Vesta. The timing of LAMO enables us to report the first results of our geochemistry investigation at this conference. In this abstract, we present an overview of our initial observations, based on data acquired at high altitude and during the first weeks of LAMO. GRaND overview. A detailed description of the GRaND instrument, science objectives and prospective results is given in [1]. At low altitudes, GRaND is sensitive to gamma rays and neutrons produced by cosmogenic nuclear reactions and radioactive decay occurring within the top few decimeters of the surface and on a spatial scale of a few hundred kilometers. From these nuclear emissions, the abundance of several major- and minor-elements, such as Fe, Mg, Si, K, and Th can be determined. Assuming the howardite, eucrite, and diogenite (HED) meteorites are representative of Vesta s crustal composition [2], then GRaND will be able to map the mixing ratios of whole-rock HED end-members, enabling the determination of the relative proportions of basaltic eucrite, cumulate eucrite, and diogenite as well as the proportions of mafic and plagioclase minerals [1,3]. GRaND will also search for compositions not well-represented in the meteorite collection, such as evolved, K-rich lithologies [4], and outcrops of olivine from Vesta s mantle or igneous intrusions in major impact basins [5]. The search for a possible mesosiderite source region is described in [6]. GRaND will globally map the abundance of H, providing constraints on the delivery of H by solar wind and the infall of carbonaceous chondrite materials.

Prettyman, T. H.↗

Evaluation of Systematic Errors on Polarization Parameters from POLDER Instrument Data for Use In CLARREO Pathfinder-VIIRS Intercalibration

One of the CLARREO Pathfinder (CPF) mission’s science objectives is to intercalibrate the reflective solar bands of the NOAA-20 VIIRS instrument against high-accuracy CPF measurements utilizing coincident, co-angled, and co-located footprints acquired over diverse Earth targets. To alleviate the effect of high polarization sensitivity of select VIIRS channels on intercalibration analysis, the CPF team will limit the intercalibration footprints over low-polarized scene types, which will be identified based on an empirical estimation of their degree and angle of polarization (DOP and AOP) using POLDER data. This paper describes the methodology for evaluating systematic errors in the estimation of DOP and AOP for Earth-reflected radiances using POLDER’s polarized bands and investigates their potential impact on CPF-VIIRS intercalibration uncertainty. The systematic errors were found to be less than 0.01 for DOP and less than 2.2 deg. for AOP, which will have a negligible impact on CPF-VIIRS intercalibration uncertainty.

polarization↗

Degree and direction of polarization of multiple scattered light. II - Earth's atmosphere with aerosols.

The radiance, polarization, and direction of polarization of the radiation reflected and transmitted through the atmosphere are calculated by a Monte Carlo method on the basis of a realistic model of the atmosphere. The calculated polarization is shown to depend on the aerosol amount and to have normally a value intermediate between that for pure Rayleigh and pure aerosol scattering. The polarization for multiple scattered photons is usually less than the value calculated for single scattering, but may be larger in low-polarization regions near other regions of high polarization. The direction of polarization shows little variation with either the aerosol amount or the value of the surface albedo.

Plass, G. N.↗

Evaluation studies on carbon supported catalysts for oxygen reduction in alkaline medium

This paper describes tests designed to predict the performance of fuel cell electrodes, as applied to an alkaline oxygen-fuel cell having specially fabricated porous-carbon electrodes with various amounts of dispersed platinum or gold as active catalysts. The tests are based on information obtained from the techniques of cyclic voltammetry and polarization. The parameters obtained from cyclic voltammetry were of limited use in predicting fuel cell performance of the cathode. On the other hand, half-cell polarization measurements offered close simulation of the oxygen electrode, although a predictor of the electrode life is still lacking. The very low polarization of the Au-10 percent Pt catalytic electrode suggests that single-phase catalysts should be considered.

Srinivasan, Vakula S.↗

Local Strain and Polarization Mapping in Ferrielectric Materials

CuInP 2 S 6 (CIPS) is a van der Waals material that has attracted attention because of its unusual properties. Recently, a combination of density functional theory (DFT) calculations and piezoresponse force microscopy (PFM) showed that CIPS is a uniaxial quadruple-well ferrielectric featuring two polar phases and a total of four polarization states that can be controlled by external strain. In this study, we combine DFT and PFM to investigate the stress-dependent piezoelectric properties of CIPS, which have so far remained unexplored. The two different polarization phases are predicted to differ in their mechanical properties and the stress sensitivity of their piezoelectric constants. This knowledge is applied to the interpretation of ferroelectric domain images, which enables investigation of local strain and stress distributions. The interplay of theory and experiment produces polarization maps and layer spacings which we compare to macroscopic X-ray measurements. We found that the sample contains only the low-polarization phase and that domains of one polarization orientation are strained, whereas domains of the opposite polarization direction are fully relaxed. The described nanoscale imaging methodology is applicable to any material for which the relationship between electromechanical and mechanical characteristics is known, providing insight on structural, mechanical, and electromechanical properties down to ~10 nm length scales.

36 MATERIALS SCIENCE↗

Implications of the 1400 MHz flare emission from AD Leo for the emission mechanism and flare environment

High brightness temperature spikes have been observed during a radio flare on the M-dwarf flare star AD Leo (Lang et al., 1983). Their high brightness temperature (greater than 10 to the 13th K) and circular polarization indicate that a coherent radiation mechanism must be responsible for the spike emission. The underlying flare emission, which is identified with a low polarization, gradual component, was found not to be spiky to within the 200 ms time resolution of the observations. This note is concerned primarily with this nonspiky emission.

Holman, G. D.↗

Observations of the Earth in polarized light from the US Space Shuttle

During the four American Space Shuttle missions of year 1985, the crewmembers took pictures of the Earth in polarized light. Different problems were encountered in the quantitative use of the data: induced polarization by the shuttle window, lack of calibration correction of the window polarization and enveloped in flight calibration methods. The analysis of the selected data first confirmed the previous observation over snow and sand. A low polarization on these surfaces was observed. On the other hand, the measurements show the potentiability of the polarization for agricultural inventory. Contamination of the atmosphere is well characterized.

Roger, Jean-Claude↗

Observations of charged particle precipitation over the auroral zone during a magnetic substorm

An array of sensitive electrostatic analyzers was launched on the satellite INJUN 5 into a nearly polar, low altitude orbit. A series of three traversals of the northern auroral zone in the local evening sector on 3 December 1968 has provided high energy- and time-resolution observations of low-energy proton and electron intensities within the energy range 50 smaller than E smaller than 15,000 eV before, during and after a polar magnetic substorm. The region of high intensities of plasma-sheet electrons expanded dramatically during the substorm, extending 3.5 deg farther poleward and approximately 4.5 deg farther equatorward relative to that of the preceding pass.

Ackerson, K. L.↗

Limits on X-Ray Polarization at the Core of Centaurus A as Observed with the Imaging X-Ray Polarimetry Explorer

We present measurements of the polarization of X-rays in the 2–8 keV band from the nucleus of the radio galaxy Centaurus A (Cen A), using a 100 ks observation from the Imaging X-ray Polarimetry Explorer (IXPE). Nearly simultaneous observations of Cen A were also taken with the Swift, NuSTAR, and INTEGRAL observatories. No statistically significant degree of polarization is detected with IXPE. These observations have a minimum detectable polarization at 99% confidence (MDP 99 ) of 6.5% using a weighted, spectral model-independent calculation in the 2–8 keV band. The polarization angle ψ is consequently unconstrained. Spectral fitting across three orders of magnitude in X-ray energy (0.3–400 keV) demonstrates that the SED of Cen A is well described by a simple power law with moderate intrinsic absorption (N H ~ 10 23 cm -2 ) and a Fe Kα emission line, although a second unabsorbed power law is required to account for the observed spectrum at energies below 2 keV. This spectrum suggests that the reprocessing material responsible for this emission line is optically thin and distant from the central black hole. Our upper limits on the X-ray polarization are consistent with the predictions of Compton scattering, although the specific seed photon population responsible for the production of the X-rays cannot be identified. The low polarization degree, variability in the core emission, and the relative lack of variability in the Fe Kα emission line support a picture where electrons are accelerated in a region of highly disordered magnetic fields surrounding the innermost jet.

79 ASTRONOMY AND ASTROPHYSICS↗

A Search for Polarized Thermal Emission from Directly Imaged Exoplanets and Brown Dwarf Companions to Nearby Stars

Aerosols in the atmospheres of cloudy gas giant exoplanets and brown dwarfs scatter and polarize these objects’ thermal emission. If such an object has an oblate shape or nonuniform cloud distribution, the net degree of linear polarization can show an increase ranging from several tenths of a percent to a few percent. Modern high-contrast imaging polarimeters are now poised to detect such low-polarization signals, opening up a new window into the rotational velocities and cloud properties of substellar companions to nearby stars. In this paper, we present the results of a near-IR survey searching for linearly polarized thermal emission from a sample of two planetary-mass companions and five brown dwarf companions using GPI and SPHERE-IRDIS. We probe the subpercent linear polarization regime that typifies polarized free-floating brown dwarfs and place limits on each object’s degree of linear polarization. We relate our upper limits on each target’s degree of linear polarization to its rotation rate, and place our results in the context of rotation rates measured using high-resolution spectroscopy.

79 ASTRONOMY AND ASTROPHYSICS↗

CLARREO Pathfinder as a SI-traceable Reference for Satellite Intercalibration

The Climate Absolute Radiance and Refractivity Observatory (CLARREO) Pathfinder (CPF) consists of an Earthviewing reflected solar (RS) spectrometer that will measure the Earth-reflected solar radiation from International Space Station with an SI-traceable radiometric uncertainty of 0.3% (1-sigma). The high-accuracy CPF measurements will provide an in-orbit reference for intercalibrating other spaceflight RS instruments. The CPF intercalibration team has been tasked to develop a state-of-the-art approach to calibrate the shortwave channel (300-5000 nm) of the Clouds and the Earth’s Radiant Energy System (CERES) instrument and the reflective solar bands (RSB) of the Visible Infrared Imaging Radiometer Suite (VIIRS) instrument, both onboard the NOAA-20 satellite, against the CPF benchmark measurements. The aimed intercalibration methodology uncertainty for both the target instruments is also 0.3%. To meet this stringent intercalibration accuracy, the CPF team has developed methods for mitigating the impacts of spatial, spectral, and angular differences between the intercalibration footprints from the CPF and target instruments. To further alleviate uncertainty, the CPF team will employ Polarization Distribution Models (PDMs) to characterize the polarization state of the Earth-reflected radiance as a function of the intercalibration footprint scene type, solar and viewing geometry, and wavelength. The PDMs will assist in identifying low-polarized scene radiances for meticulously intercalibrating the polarization sensitive VIIRS instrument against the significantly-less polarization-sensitive CPF instrument. This paper will highlight the CPF mission overview, the details of the CPF intercalibration approach, and additional outcomes of the CPF intercalibration studies that may benefit the broader remote sensing community.community.

Hyperspectral↗

Polarity-Tolerant Chloride Binding in Foldamer Capsules by Programmed Solvent-Exclusion

Persistent anion binding in a wide range of solution environments is a key challenge that continues to motivate and demand new strategies in synthetic receptor design. Though strong binding in low-polarity solvents has become routine, our ability to maintain high affinities in high-polarity solvents has not yet reached the standard set by nature. Anions are bound and transported regularly in aqueous environments by proteins that use secondary and tertiary structure to isolate anion binding sites from water. Inspired by this principle of solvent exclusion, we created a sequence-defined foldameric capsule whose global minimum conformation displays a helical folded state and is preorganized for 1:1 anion complexation. The high stability of the folded geometry and its ability to exclude solvent were supported by solid-state and solution phase studies. This capsule then withstood a 4-fold increase in solvent dielectric constant (εr) from dichloromethane (9) to acetonitrile (36) while maintaining a high and solvent-independent affinity of 10 5 M –1 ; ΔG ~ 28 kJ mol –1 . This behavior is unusual. More typical of solvent-dependent behavior, Cl – affinities were seen to plummet in control compounds, such as aryl-triazole macrocycles and pentads, with their solvent-exposed binding cavities susceptible to dielectric screening. Finally, dimethyl sulfoxide denatures the foldamer by putative solvent binding, which then lowers the foldamer’s Cl – affinity to normal levels. Furthermore, the design of this capsule demonstrates a new prototype for the development of potent receptors that can operate in polar solvents and has the potential to help manage hydrophilic anions present in the hydrosphere and biosphere.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Assessment of VIIRS on-orbit polarization sensitivity and its impact on CLARREO pathfinder inter-calibration

The primary objective of the CLARREO Pathfinder (CPF) mission is to demonstrate essential measurement technologies to enable highly accurate decadal change observations traceable on-orbit to SI standards. Another important objective of the CPF is to demonstrate inter-calibration with the VIIRS sensor and to show that such high-accuracy reference inter-calibration is achievable. To satisfy this requirement, it is important to understand and quantify uncertainties in VIIRS sensor measurements. Based on prelaunch test results, the reflective solar bands of both SNPP and NOAA-20 VIIRS have exhibited polarization sensitivities in the shortest wavelength bands, with an unexpectedly larger sensitivity observed for NOAA-20 VIIRS, particularly in bands M1 to M4. In this study, we use VIIRS Level-1B reflectance data collected over the Pseudo-Invariant Calibration Sites over North African desert region to examine the polarization associated uncertainty for these four bands. Impact due to BRDF on the reflectance data is considered by comparing baseline results obtained from the same viewing and solar zenith angles under relatively low polarization sensitivity. Impact due to detector relative difference in polarization sensitivity is examined by normalizing reflectances by the value of the middle detector. Results of this study provide useful information on VIIRS uncertainty contribution due to polarization when conducting CPF and VIIRS inter-calibration.

VIIRS↗

Wavelength dependence of polarization. XXXV - Vertical structure of scattering layers above the visible Venus clouds

Results of multiple-scattering computations based on whole-disk and Digicon polarization observations are presented which indicate vertical inhomogeneity in the upper atmosphere of Venus. It is shown that the whole-disk observations support a thin upper haze layer of 0.18-micron particles and that the low polarization observed near the limb and terminator requires a haze of slightly larger particles. The Digicon polar regions are found to exhibit increased polarization, which is compatible with CO2 absorption measurements and is explained by increased molecular scattering above the clouds. The decrease in cloud-top height for latitudes greater than 45 deg is estimated to be approximately 1.4 km.

Lane, W. A.↗

Trends in measurement of solar vector magnetic fields using the Zeeman effect

Trends in spectropolarimetry as applied to the problem of Zeeman effect measurement are discussed. The use of detector arrays to improve observing efficiency is obtained. Which required new polarization modulation schemes that match the time required to read detector arrays. Another significant trend is narrowband filters, to improve angular and temporal coverage, and to Fourier transform spectrometers, to improve spectral coverage and precision. Low-polarization designs and improved methods for compensating instrumental polarization were developed. A requirement for high angular resolution suggests using adaptive optical devices to subdue the effects of bad seeing. The ultimate strategy to beat the seeing is to loft the telescope above the atmosphere such as is planned with a 30-cm telescope in 1985 and a 1250-cm telescope in 1990.

Harvey, J. W.↗

The ultraviolet excess of quasars 3: The highly polarized quasars PKS 0736+017 and PKS 1510-089

Ultraviolet/optical/infrared spectrophotometry of the highly-polarized quasars (HPQ's) PKS 0736+017 and PKS 1510-089 is analyzed. A blazar continuum component like that in BL Lac objects (e.g. with violent variability, high polarization, and a steep power-law shape) contributes about half the visual light of 1510-089, and at least three-quarters of that in 0736+017. The remaining light has the same spectrum as normal (low-polarization) quasars, including an ultraviolet excess or blue bump, which is easily detected in the IUE spectra of 1510-089, and weakly detected in 0736+017. The line fluxes do vary, but not as much as the continuum. The ratios of the broad emission lines, and the Balmer continuum are normal in both quasars.

Malkan, M. A.↗

The ultraviolet excess of quasars. III - The highly polarized quasars PKS 0736 + 017 and PKS 1510 - 089

Ultraviolet/optical/infrared spectrophotometry of the highly-polarized quasars (HPQ's) PKS 0736 + 047 and PKS 1510 089 is analyzed. A blazer continuum component like that in BL Lac objects (e.g. with violent variability, high polarization, and a steep power-law shape) contributes about half the visual light of 1510 - 089, and at least three-quarters of that in 0736 + 017. The remaining light has the same spectrum as normal (low-polarization) quasars, including an ultraviolet excess or blue bump, which is easily detected in the IUE spectra of 1510 - 089, and weakly detected in 0736 + 017. The line fluxes do vary, but not as much as the continuum. The ratios of the broad emission lines, and the Balmer continuum are normal in both quasars.

Malkan, M. A.↗

Revisiting a minimally destructive analytic approach for determining electrochemical kinetic parameters: Measuring aluminum corrosion across a wide pH range based on the Butler-Volmer equation

Here, this study revisits the three-point sampling of the simplified Butler-Volmer equation to address the limitations of strong potentiodynamic polarization, which can introduce irreversible damage and uncertainty in corrosion analysis. The method extracts electrochemical kinetic parameters while minimizing polarization effects, evaluates noise sensitivity relative to overpotential, and accounts for errors from signal noise, OCP drift, ohmic resistance, and mass-transfer constraints. Verified against the Tafel extrapolation method for aluminum corrosion across a wide pH range, this low-polarization approach enables accurate evaluations with specific error estimates, offering a robust alternative to linear polarization resistance methods that assume constant Tafel slopes.

36 MATERIALS SCIENCE↗