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NASA NTRSDate not supplied

Case Study for Lunar ISRU Systems Utilizing Polar Water

In-Situ Resource Utilization (ISRU) is key to long term presence at any extraterrestrial destination. Current NASA direction is to achieve a sustainable presence on the lunar surface by 2028. Mission plans currently target the lunar South Pole to leverage the extended periods of solar illumination and allows for potential access to water ice in the permanently shadowed areas around the poles. With water, it is possible to produce both fuel and oxidizer to fully refuel a vehicle. In order to address ISRU infusion into mission planning, a study of an end-to-end ISRU propellant production system was initiated to assess ISRU architectures and obtain mass and power estimates for each. The results of these case studies will be presented. For this study, The ISRU system architecture involved two sites; the mine site in a shadowed crater where water ice is excavated and extracted from the regolith and the propellant production site at an illuminated ridge where the water is processed into liquefied O2 and H2 propellants. Fixed hardware would be emplaced at each site, with two alternating water tankers to transport water between them. Notional lunar sites were identified for this architecture for baseline environmental parameters. Technology solutions for each subsystem were selected based on those with the highest fidelity models or those that have empirical laboratory data to anchor to. While power needs were identified for each location, a power solution was not prescribed, therefore the masses presented do not include surface power systems. The baseline case in this study assumed that 10 mT of oxygen, along with enough hydrogen to support a propulsion mixture ratio of 6, must be produced in 225 days. Therefore 15 mT of water would need to be collected and processed. The baseline solution resulted in a system mass of5 mT and a total required power of 68kW. The majority of the mass was split between the ridge site system and the two water tankers (2.6 mTand 1.8mTrespectively). The majority of the required power was with three subsystems at approximately 20 kW each: hydrogen liquefaction, electrolysis, and the water extractor subsystem. Trades for four key variables are also presented, namely production rate, water concentration, dry overburden depth, and number of water transport trips. This can be compared to a system that targets oxygen from the minerals in the surface regolith material. A carbothermal reduction reactor system was used for this comparison. The use of direct solar thermal energy to process the regolith and the ease of access of the resource resulted in significantly lower values for the oxygen case: approximately 2.7 mT and 11.8 kW. However, the mass trade would favor the water case over successive missions where the hydrogen up-mass of 2 mT per mission will accrue against the oxygen system.1Aerospace Research Engineer, Chemical and Thermal Propulsion Systems Branch, Senior Member.2Mechanical Engineer, Propulsion and Power Division/Energy Conversion Systems, 2101 Nasa Pkwy/Mailcode EP3 Houston, TX 77058, AIAA member.

Lunar↗
NASA NTRS1978

SAM-2 ground-truth plan: Correlative measurements for the Stratospheric Aerosol Measurement-2 (SAM 2) sensor on the Nimbus G satellite

The SAM-2 will fly aboard the Nimbus-G satellite for launch in the fall of 1978 and measure stratospheric vertical profiles of aerosol extinction in high latitude bands. The plan gives details of the location and times for the simultaneous satellite/correlative measurements for the nominal launch time, the rationale and choice of the correlative sensors, their characteristics and expected accuracies, and the conversion of their data to extinction profiles. The SAM-2 expected instrument performance and data inversion results are presented. Various atmospheric models representative of polar stratospheric aerosols are used in the SAM-2 and correlative sensor analyses.

Russell, P. B.↗
NASA NTRS1994

Magnetospheric-ionospheric Poynting flux

Over the past three years of funding SRI, in collaboration with the University of Texas at Dallas, has been involved in determining the total electromagnetic energy flux into the upper atmosphere from DE-B electric and magnetic field measurements and modeling the electromagnetic energy flux at high latitudes, taking into account the coupled magnetosphere-ionosphere system. This effort has been very successful in establishing the DC Poynting flux as a fundamental quantity in describing the coupling of electromagnetic energy between the magnetosphere and ionosphere. The DE-B satellite electric and magnetic field measurements were carefully scrutinized to provide, for the first time, a large data set of DC, field-aligned, Poynting flux measurement. Investigations describing the field-aligned Poynting flux observations from DE-B orbits under specific geomagnetic conditions and from many orbits were conducted to provide a statistical average of the Poynting flux distribution over the polar cap. The theoretical modeling effort has provided insight into the observations by formulating the connection between Poynting's theorem and the electromagnetic energy conversion processes that occur in the ionosphere. Modeling and evaluation of these processes has helped interpret the satellite observations of the DC Poynting flux and improved our understanding of the coupling between the ionosphere and magnetosphere.

Thayer, Jeffrey P.↗
NASA NTRS2004

MER SPICE Interface

MER SPICE Interface is a software module for use in conjunction with the Mars Exploration Rover (MER) mission and the SPICE software system of the Navigation and Ancillary Information Facility (NAIF) at NASA's Jet Propulsion Laboratory. (SPICE is used to acquire, record, and disseminate engineering, navigational, and other ancillary data describing circumstances under which data were acquired by spaceborne scientific instruments.) Given a Spacecraft Clock value, MER SPICE Interface extracts MER-specific data from SPICE kernels (essentially, raw data files) and calculates values for Planet Day Number, Local Solar Longitude, Local Solar Elevation, Local Solar Azimuth, and Local Solar Time (UTC). MER SPICE Interface was adapted from a subroutine, denoted m98SpiceIF written by Payam Zamani, that was intended to calculate SPICE values for the Mars Polar Lander. The main difference between MER SPICE Interface and m98SpiceIf is that MER SPICE Interface does not explicitly call CHRONOS, a time-conversion program that is part of a library of utility subprograms within SPICE. Instead, MER SPICE Interface mimics some portions of the CHRONOS code, the advantage being that it executes much faster and can efficiently be called from a pipeline of events in a parallel processing environment.

Sayfi, Elias↗
NASA NTRS1973

Diurnal polar motion

An analytical theory is developed to describe diurnal polar motion in the earth which arises as a forced response due to lunisolar torques and tidal deformation. Doodson's expansion of the tide generating potential is used to represent the lunisolar torques. Both the magnitudes and the rates of change of perturbations in the earth's inertia tensor are included in the dynamical equations for the polar motion so as to account for rotational and tidal deformation. It is found that in a deformable earth with Love's number k = 0.29, the angular momentum vector departs by as much as 20 cm from the rotation axis rather than remaining within 1 or 2 cm as it would in a rigid earth. This 20 cm separation is significant in the interpretation of submeter polar motion observations because it necessitates an additional coordinate transformation in order to remove what would otherwise be a 20 cm error source in the conversion between inertial and terrestrial reference systems.

Mcclure, P.↗
NASA NTRS1990

Fourier transform infrared studies of model polar stratospheric cloud surfaces - Growth and evaporation of ice and nitric acid/ice

Fourier-transform infrared surface studies are used to probe the microphysical properties of nitric acid trihydrate (NAT) and ice films representative of type I and II polar stratospheric clouds (PSC). Experiments indicate that, on initial exposure to 1.8 microtorr of HNO3, a layer of ice is quantitatively converted to NAT. However, conversion of ice to NAT does not proceed indefinitely, but rather the system reaches saturation. For longer exposures or higher HNO3 pressures, NAM becomes the dominant nitric acid containing species on the surface. Evaporation studies were performed to test the feasibility of a recent denitrification mechanism. The results indicate that ice coated with 0.20 micron of NAT evaporates at a temperature of about 4 C higher than uncoated ice.

Tolbert, Margaret A.↗
NASA NTRS2023

New York Ecological Conservation: Evaluating Agricultural Conservation Easement Impact Using Earth Observations to Examine Avoided Soil Carbon Loss to Development

Farmland provides ecosystems and communities with services ranging from habitat conservation to food security. As total U.S. farmland continues to decline, agricultural lands near urban areas are especially vulnerable. Our project partners—Finger Lakes Land Trust, Genesee Land Trust, and Saratoga Preserving Land and Nature (PLAN)—can use study results to better profile farmland vulnerability, issuing conservation easements to protect maximum acreage in Saratoga County and the Finger Lakes Region of New York. Multiple existing studies effectively use remote sensing imagery to analyze historical land cover and forecast future change. This study examined soil carbon stocks and land cover change to estimate avoided soil carbon loss. We also predicted farmland vulnerability. We completed these analyses using European Space Agency (ESA) and NASA Earth observations that include Landsat 5 Thematic Mapper (TM), Landsat 8 Operational Land Imager (OLI), Landsat 9 OLI-2, Sentinel-2 Multispectral Instrument (MSI), and Suomi National Polar-Orbiting Partnership (NPP) Visible Infrared Imaging Radiometer Suite (VIIRS) for nighttime lights data that aided in the land change model analysis. We determined that the conversion of agriculture to development from 1990 to 2022 occurred at rates of 0.91% (Finger Lakes) and 7% (Saratoga). Urban development is predicted to increase surrounding urban centers through 2030 and 2050. We also estimate that between 26.5 and 348,101 kilotons (Finger Lakes) and 3.7 and 58,006 kilotons (Saratoga) of soil carbon losses have been avoided through agricultural easements. Findings from this study will support our partners in determining agricultural conservation easement benefits and prioritizing the acquisition of future easement sites.

Agriculture↗
NASA NTRS1998

Corrosion Studies of 2195 Al-Li Alloy and 2219 Al Alloy with Differing Surface Treatments

Corrosion studies of 2195 Al-Li and 2219 Al alloys have been conducted using the scanning reference electrode technique (SRET) and the polarization resistance (PR) technique. The SRET was used to study corrosion mechanisms, while corrosion rate measurements were studied with the PR technique. Plates of Al203 blasted, soda blasted and conversion coated 2219 Al were coated with Deft primer and the corrosion rates studied with the EIS technique. Results from all of these studies are presented.

Danford, M. D.↗
NASA NTRS1987

Relativistic electromagnetic waves in an electron-ion plasma

High power laser beams can drive plasma particles to relativistic energies. An accurate description of strong waves requires the inclusion of ion dynamics in the analysis. The equations governing the propagation of relativistic electromagnetic waves in a cold electron-ion plasma can be reduced to two equations expressing conservation of energy-momentum of the system. The two conservation constants are functions of the plasma stream velocity, the wave velocity, the wave amplitude, and the electron-ion mass ratio. The dynamic parameter, expressing electron-ion momentum conversation in the laboratory frame, can be regarded as an adjustable quantity, a suitable choice of which will yield self-consistent solutions when other plasma parameters were specified. Circularly polarized electromagnetic waves and electrostatic plasma waves are used as illustrations.

Chian, Abraham C.-L.↗
NASA NTRS2011

The Advanced Energetic Pair Telescope (AdEPT}: A Future Medium-Energy Gamma-Ray Balloon (and Explorer?) Mission

Gamma-ray astrophysics probes the highest energy, exotic phenomena in astrophysics. In the medium-energy regime, 0.1-200 MeV, many astrophysical objects exhibit unique and transitory behavior such as the transition from electron dominated to hadron dominated processes, spectral breaks, bursts, and flares. Medium-energy gamma-ray imaging however, continues to be a major challenge particularly because of high background, low effective area, and low source intensities. The sensitivity and angular resolution required to address these challenges requires a leap in technology. The Advance Energetic Pair Telescope (AdEPT) being developed at GSFC is designed to image gamma rays above 5 MeV via pair production with angular resolution of 1-10 deg. In addition AdEPT will, for the first time, provide high polarization sensitivity in this energy range. This performance is achieved by reducing the effective area in favor of enhanced angular resolution through the use of a low-density gaseous conversion medium. AdEPT is based on the Three-Dimensional Track Imager (3-DTI) technology that combines a large volume Negative Ion Time Projection Chamber (NITPC) with 2-D Micro-Well Detector (MWD) readout. I will review the major science topics addressable with medium-energy gamma-rays and discuss the current status of the AdEPT technology, a proposed balloon instrument, and the design of a future satellite mission.

Hunter, Stanley D.↗
NASA NTRS1978

Surfactant-assisted liquefaction of particulate carbonaceous substances

A slurry of carbonaceous particles such as coal containing an oil soluble polar substituted oleophilic surfactant, suitably an amine substituted long chain hydrocarbon, is liquefied at high temperature and high hydrogen presence. The pressure of surfactant results in an increase in yield and the conversion product contains a higher proportion of light and heavy oils and less asphaltene than products from other liquefaction processes.

Hsu, G. C.↗
NASA NTRSDate not supplied

AMEGO: Exploring the Extreme Multimessenger Universe

The All-sky Medium Energy Gamma-ray Observatory (AMEGO) is a Probe-class mission concept that will provide essential contributions to multimessenger astrophysics in the next decade. AMEGO operates both as a Compton and pair telescope to achieve unprecedented sensitivity between 200 keV and>5 GeV. The instrument consists of four subsystems. A double-sided strip silicon Tracker gives a precise measure of the first Compton scatter interaction and tracks of pair-conversion products. A novel CdZnTe Low Energy Calorimeter with excellent position and energy resolution surrounds the bottom and sides of the Tracker to detect the Compton-scattered photons which enhances the polarization and narrow-line sensitivity. A thick CsI High Energy Calorimeter contains the high-energy Compton and pair events. The instrument is surrounded by aplastic anti-coincidence detector to veto the cosmic-ray background. We have performed detailed simulations to predict the telescope performance and are currently building a prototype instrument. The AMEGO prototype, known as ComPair, will be tested at the High Intensity Gamma-Ray Source in 2021, followed by a balloon flight in Fall of 2022. In this presentation we will give an overview of the science motivation, a description of the observatory, and an update of the prototype instrument development.

Carolyn Ann Kierans↗
NASA NTRS1989

Barotropic instability of basic states with a realistic jet and a wave

The stability of basic states consisting of a jet similar to the stratospheric polar night jet and a traveling wave with a single zonal wavenumber is examined in a linearized nondivergent barotropic model on a sphere. Basic state waves are chosen to resemble observed traveling and stationary features in the winter stratosphere. Results are presented for disturbance growth rates, propagation characteristics, and energy conversion as a function of the basic state wave amplitude. The effects of small amplitude basic state waves on unstable disturbances arising from a zonally symmetric jet are discussed; results are shown where a small amplitude basic state wave dramatically affects the stability characteristics. Evidence is shown that the presence of a traveling wave may favor the appearance of disturbances that include other zonal wavenumbers which move with the basic state wave; this result is discussed in relation to the origin of observed quasi-nondispersive features in the polar winter stratosphere. Results for a stationary wavenumber 1 basic state wave suggest that a distorted polar vortex may be unstable to disturbances that would lead to further distortion. An unstable disturbance for a basic state with an eastward moving wavenumber 2 has components which resemble, in period and location, traveling waves that are observed in the winter stratosphere.

Manney, Gloria L.↗
NASA NTRS2011

Multi-Wavelength, Multi-Beam, and Polarization-Sensitive Laser Transmitter for Surface Mapping

A multi-beam, multi-color, polarized laser transmitter has been developed for mapping applications. It uses commercial off-the-shelf components for a lowcost approach for a ruggedized laser suitable for field deployment. The laser transmitter design is capable of delivering dual wavelengths, multiple beams on each wavelength with equal (or variable) intensities per beam, and a welldefined state of polarization. This laser transmitter has been flown on several airborne campaigns for the Slope Imaging Multi-Polarization Photon Counting Lidar (SIMPL) instrument, and at the time of this reporting is at a technology readiness level of between 5 and 6. The laser is a 1,064-nm microchip high-repetition-rate laser emitting energy of about 8 microjoules per pulse. The beam was frequency-doubled to 532 nm using a KTP (KTiOPO4) nonlinear crystal [other nonlinear crystals such as LBO (LiB3O5) or periodically poled lithium niobiate can be used as well, depending on the conversion efficiency requirements], and the conversion efficiency was approximately 30 percent. The KTP was under temperature control using a thermoelectric cooler and a feedback monitoring thermistor. The dual-wavelength beams were then spectrally separated and each color went through its own optical path, which consisted of a beam-shaping lens, quarterwave plate (QWP), and a birefringent crystal (in this case, a calcite crystal, but others such as vanadate can be used). The QWP and calcite crystal set was used to convert the laser beams from a linearly polarized state to circularly polarized light, which when injected into a calcite crystal, will spatially separate the circularly polarized light into the two linear polarized components. The spatial separation of the two linearly polarized components is determined by the length of the crystal. A second set of QWP and calcite then further separated the two beams into four. Additional sets of QWP and calcite can be used to further split the beams into multiple orders of two. The spatially separated beams had alternating linearly polarization states; a half-wave plate (HWP) array was then made to rotate the alternating states of A multi-beam, multi-color, polarized laser transmitter has been developed for mapping applications. It uses commercial off-the-shelf components for a lowcost approach for a ruggedized laser suitable for field deployment. The laser transmitter design is capable of delivering dual wavelengths, multiple beams on each wavelength with equal (or variable) intensities per beam, and a welldefined state of polarization. This laser transmitter has been flown on several airborne campaigns for the Slope Imaging Multi-Polarization Photon Counting Lidar (SIMPL) instrument, and at the time of this reporting is at a technology readiness level of between 5 and 6. The laser is a 1,064-nm microchip high-repetition-rate laser emitting energy of about 8 microjoules per pulse. The beam was frequency-doubled to 532 nm using a KTP (KTiOPO4) nonlinear crystal [other nonlinear crystals such as LBO (LiB3O5) or periodically poled lithium niobiate can be used as well, depending on the conversion efficiency requirements], and the conversion efficiency was approximately 30 percent. The KTP was under temperature control using a thermoelectric cooler and a feedback monitoring thermistor. The dual-wavelength beams were then spectrally separated and each color went through its own optical path, which consisted of a beam-shaping lens, quarterwave plate (QWP), and a birefringent crystal (in this case, a calcite crystal, but others such as vanadate can be used). The QWP and calcite crystal set was used to convert the laser beams from a linearly polarized state to circularly polarized light, which when injected into a calcite crystal, will spatially separate the circularly polarized light into the two linear polarized components. The spatial separation of the two linearly polarized components is determined by the length of the crystal. A cond set of QWP and calcite then further separated the two beams into four. Additional sets of QWP and calcite can be used to further split the beams into multiple orders of two. The spatially separated beams had alternating linearly polarization states; a half-wave plate (HWP) array was then made to rotate the alternating states of

Yu, Anthony W.↗
NASA NTRS1994

The Fraternal Twins of Quartet O4(+)

Eleven stationary geometries of quartet O4(+) have been studied by ab initio methods. The geometries were optimized at the Complete Active Space Self-Consistent Field (CASSCF) level of theory and the energies were calculated by the multiconfigurational second order pertubation method (CASPT2), using Double-Zeta Plus polarization (DZP), Triple-Zeta Plus Double Polarization (TZ2P), average Atomic Natural Orbital (ANO) (5s4p2d) and average ANO (6s5p3d2f) basis sets. The rectangular and trans-planar structures are found to be the most stable, with an energy barrier to conversion between the two at the threshold of dissociation. Both have a delocalized hole and are stable relative to separated 02 and 02(+)by 11.0 and 11.5 kcal/mol for the rectangular and the 2 trans-planar structure, respectively, compared with the experimentally deduced energy in the range of 9.2 to 10.8 kcal/mol. The adiabatic ionization potentials of 04 and 02 are computed to be 11.67 and 12.21 eV, while experimental values are 11.66 and 12.07 eV, respectively. The vibrational frequencies have been computed for all degrees of freedom at the CASSCF level of theory. Symmetry breaking is found to be a particular problem in the computation of the antisymmetric stretch frequency for the delocalized structures at the CASSCF level of theory. Attempts to rectify these problems using the restricted active space self-consistent field (RASSCF) method leads to additional difficulties, but further analysis yields insight into the symmetry breaking and problems with earlier calculations. Finally, a nonorthogonal configuration interaction (CI) calculation based on the interaction of localized CASSCF wave functions using the Complete Active Space State Interation (CASSI) method leads to a balanced treatment of the antisymmetric stretch which is free from symmetry breaking. The study explains the four most prominent absorption frequencies observed in the partially unassigned IR spectrum of O4(+) isolated in solid neon as the antisymmetric OO stretch, and the combination band of the symmetric and antisymmetric 00 stretch of both the rectangular and trans-planar structures.

Lindh, Roland↗
NASA NTRS2004

A Gravity Analysis of the Subsurface Structure of the Utopia Impact Basin

The large, shallow, circular depression in Utopia Planitia has been identified as a huge impact basin, based on both geological evidence and detailed analysis of MOLA topography. Its diameter (approximately 3000 km) is equivalent to that of the Hellas basin, as is its inferred age (early Noachian). However, there the similarity ends. Their appearance, both surficially and geophysically, are virtually polar opposites. Whereas Hellas is extremely deep with rough terrain and large slopes, high-precision MOLA measurements were required to unambiguously define the smooth, shallow, almost imperceptible bowl of the Utopia basin. Conversely, Utopia displays one of the largest (non-Tharsis-related) positive geoid anomalies on Mars, in contrast to a more subdued negative anomaly over Hellas. As these two features presumably formed roughly contemporaneously by similar mechanisms, it is reasonable to assume that they were originally quite similar, and that their differences are due largely to different paths of subsequent modification. The obvious source for these differences is in their elevations: Hellas is located in the southern highlands at a rim elevation of about 3km, whereas Utopia is in the lowlying northern plains, at an average elevation of 4 km. Thus Utopia has been in an especially gravitationally favorable position to be subjected to infilling, for example, by lava flows, sedimentation, or water. In fact, its floor was almost certainly the lowest point on the planet at one time, and it would have been the termination point for down-slope drainage from over two-thirds of Mars. Thus the nature of the material filling this basin has strong connections to the sedimentary and/or volcanic processes acting on Mars in the Noachian and Early Hesperian periods. In particular, it may be able to shed some light on amount and persistence of water on early Mars in general and in the Utopia basin in particular. In this study I will use the inferred early correspondence between Hellas and Utopia to investigate Utopia's subsurface structure.

Barnerdt, W. B.↗
NASA NTRS1977

Localized induced electric field within the magnetotail

The conversion of magnetic energy, stored within the magnetotail during the growth phase, into particle kinetic energy is studied by taking induced electric fields, due to explicit time dependence of magnetic fields, into consideration. The polarization of a plasma in the presence of such a field is discussed, and the topological difference between a polarized and an induced electric field, namely that one is irrotational and the other is not, is pointed out. A localized perturbation in neutral sheet current is also discussed.

Heikkila, W. J.↗
NASA NTRS1977

Asymmetric photolysis of /RS/-leucine with circularly polarized ultraviolet light

(RS)-leucine in 0.1 M HCl solution has been subjected to photolysis with 212.8-nm right (R-) and left circularly polarized light (LCPL) obtained from a laser source. RCPL preferentially photolyzed the (R)-leucine component and LCPL the (S)-leucine component of the RS substrate. The enantiomeric excess produced were 1.98% for the 59% conversion with RCPL and 2.50% for the 75% conversion with LCPL. These 'equal and opposite' effects represent the second highest enantiomeric enrichments yet reported for an asymmetric photolysis and the first ever reported for a prebiotically important substrate - an amino acid. Implications regarding the origin of optical activity are briefly discussed.

Flores, J. J.↗