Results for “predictive thermodynamics” — Page 5

NASA NTRS2021

The Effect of Transfer Line Length and Heat Rejection Temperature Distribution on the Thales Linear Pulse Tube (LPT) Cryocoolers

Four Thales LPT9310 and four Thales LPT9510 commercial off-the-shelf (COTS) cryocoolers were parametrically performance tested. The LPT9310 coolers had transfer lines of various lengths while the LPT9510 coolers all had the same transfer line geometry. The LPT9510 test results revealed unit-tounit thermodynamic performance variation, quantified the effect of compressor temperature on thermodynamic performance and quantified the heat flow distribution between the compressor and expander as a function of their temperature distribution. The LPT9310 test results revealed the optimal drive frequency as a function of transfer line length, quantified the effect of heat rejection temperature distribution on thermodynamic performance and enabled the development and verification of a thermodynamic performance prediction tool that accounted for cold tip temperature, heat lift, heat rejection temperature and transfer line length.

Rodriguez, J.I.↗

NASA NTRSDate not supplied

Evaluating GXS Impact in the Context of International Coordination

The proposed NOAA/NASA Geostationary eXtended Observations (GeoXO) program plans to include a hyperspectral infrared (IR) sounder on its central satellite. Expected to launch in the mid-2030s, the GeoXO Sounder (GXS) will join international counterparts in a geostationary orbit. Ahead of launch, the NASA Global Modeling and Assimilation Office (GMAO) assessed the potential effectiveness of GXS both as a single GEO IR sounder and as part of a global ring of such instruments, including those already being built by international agencies. Using an observing system simulation experiment (OSSE) framework, GXS was assessed from a global numerical weather prediction (NWP) perspective. The ability of GXS, both alone and as part of a global ring of GEO sounders, to improve weather prediction of thermodynamic variables was evaluated globally and regionally. Compared to a control, GXS dominated regional analysis and forecast improvements, and contributed significantly to global increases in forecast skill. However, more sustained global improvements on the order of 4 days rely on international partnerships. Using the FSOI metric over CONUS, the GXS observations provide the strongest radiance impact on the moist energy error norm reduction. Additionally, GXS shows the capability to improve hurricane forecast track errors, resulting in improved forecast warnings. Overall, the persistent atmospheric profile information from GXS over much of the western hemisphere provide an opportunity to improve the representation of weather systems and their forecasts.

Erica McGrath-Spangler↗

NASA NTRSDate not supplied

Evaluating the Impact of Geostationary Sounders in the Context of International Coordination

The proposed NOAA/NASA Geostationary eXtended Observations (GeoXO) program plans to include a hyperspectral infrared (IR) sounder (GXS) on its central satellite, joining international counterparts. Ahead of launch, the NASA Global Modeling and Assimilation Office (GMAO) assessed the potential effectiveness of GXS both as a lone sounder in a GEO orbit and as part of a global ring of such instruments. Using an observing system simulation experiment (OSSE) framework from a global numerical weather prediction (NWP) perspective, the ability of GXS and the global ring to improve weather prediction of thermodynamic variables was assessed both globally and regionally. GXS dominated regional analysis and forecast improvements and contributed significantly to global increases in forecast skill. However, more sustained global improvements on the order of 4 days rely on international partnerships. Over CONUS, the FSOI metric showed the GXS observations provide the strongest radiance impact on the moist energy error norm reduction. Additionally, GXS shows the capability to improve hurricane forecast track errors, resulting in improved forecast warnings. Overall, the persistent atmospheric profile information from GXS over much of the western hemisphere provide an opportunity to improve the representation of weather systems and their forecasts.

Erica L. McGrath-Spangler↗

NASA NTRSDate not supplied

Investigating Fifth Oxide Effect on CMXAS Glass Properties

Coatings for hot section aero turbine engine structural materials are subject to thermochemical degradation after interacting with calcium-magnesium-aluminosilicates (CMAS). Molten CMAS viscosity is the primary glass property of importance, correlating with coating infiltration and reaction depth. CMAS viscosity was measured using a spindle-dipped viscometer at temperatures between 1300-1550°C in 25°C increments. Experimental data were compared to Thermo-Calc and FactSage computational models, which showed good agreement with experimental trends. CMXAS compositions, where X denotes a fifth oxide, of Ca30.75-Mg9-X5-Al13-Si42.25 (single cation oxide mol%) for X = Fe2+, Fe3+, Gd3+, Hf4+, Na1+, Ti4+, Y3+, Yb3+, Zr4+ additions were used. Oxide precipitation was observed in X = Hf4+ , Zr4+ CMXAS specimens, indicating coating dissolution is an increased threat for T ≥ 1390°C. Molten CMAS and CMXAS viscosity measurements were shown to correlate with net cation field strength, offering an alternative in property prediction where thermodynamic data are unavailable.

Clark Avery Luckhardt↗

NASA NTRSDate not supplied

Evaluating the Impact of Geostationary Sounders in the Context of International Coordination

The proposed NOAA/NASA Geostationary eXtended Observations (GeoXO) program plans to include a hyperspectral infrared (IR) sounder (GXS) on its central satellite, joining international counterparts. Ahead of launch, the NASA Global Modeling and Assimilation Office (GMAO) assessed the potential effectiveness of GXS both as a lone sounder in a GEO orbit and as part of a global ring of such instruments. Using an observing system simulation experiment (OSSE) framework from a global numerical weather prediction (NWP) perspective, the ability of GXS and the global ring to improve weather prediction of thermodynamic variables was assessed both globally and regionally. GXS dominated regional analysis and forecast improvements and contributed significantly to global increases in forecast skill. However, more sustained global improvements on the order of 4 days rely on international partnerships. Over CONUS, the FSOI metric showed the GXS observations provide the strongest radiance impact on the moist energy error norm reduction. Additionally, GXS shows the capability to improve hurricane forecast track errors, resulting in improved forecast warnings. Overall, the persistent atmospheric profile information from GXS over much of the western hemisphere provide an opportunity to improve the representation of weather systems and their forecasts.

Erica McGrath-Spangler↗

NASA NTRSDate not supplied

Evaluating GXS Impact in the Context of International Coordination

The proposed NOAA/NASA Geostationary eXtended Observations (GeoXO) program plans to include a hyperspectral infrared (IR) sounder on its central satellite. Expected to launch in the mid-2030s, the GeoXO Sounder (GXS) will join international counterparts in a geostationary orbit. Ahead of launch, the NASA Global Modeling and Assimilation Office (GMAO) assessed the potential effectiveness of GXS both as a single GEO IR sounder and as part of a global ring of such instruments, including those already being built by international agencies. Using an observing system simulation experiment (OSSE) framework, GXS was assessed from a global numerical weather prediction (NWP) perspective. The ability of GXS, both alone and as part of a global ring of GEO sounders, to improve weather prediction of thermodynamic variables was evaluated globally and regionally. Compared to a control, GXS dominated regional analysis and forecast improvements, and contributed significantly to global increases in forecast skill. However, more sustained global improvements on the order of 4 days rely on international partnerships. Using the FSOI metric over CONUS, the GXS observations provide the strongest radiance impact on the moist energy error norm reduction. Additionally, GXS shows the capability to improve hurricane forecast track errors, resulting in improved forecast warnings. Overall, the persistent atmospheric profile information from GXS over much of the western hemisphere provide an opportunity to improve the representation of weather systems and their forecasts.

Erica McGrath-Spangler↗

NASA NTRS2020

Computational Design of Eutectic Molten Salt Mixtures: What Can Thermodynamic Models Do?

In the search for efficient energy storage battery technologies, designing stable electrolytes has been a long-standing challenge. Electrolytes based on molten salt eutectics are known for their stability with minimum parasitic reactions when compared to their widely used organic counterparts. However, the operating temperatures of these molten salt electrolyte-based batteries are dictated by the melting point of the eutectic mixtures. Design and high throughput screening of low melting temperature eutectic molten salt mixtures have been hindered by the lack of computational models. In this work, we develop thermodynamic models to predict the eutectic points of several molten salt mixtures. The framework of the COSMO-SAC model is used for the predictions and is compared with experimental data and other thermodynamic approaches. Rapid thermodynamics-based approaches, as shown in this study, can accelerate the discovery of new materials, complementing experimental techniques.

Ashwin Ravichandran↗

NASA NTRS1996

Computation of Kinetics for the Hydrogen/Oxygen System Using the Thermodynamic Method

A new method for predicting chemical rate constants using thermodynamics has been applied to the hydrogen/oxygen system. This method is based on using the gradient of the Gibbs free energy and a single proportionality constant D to determine the kinetic rate constants. Using this method the rate constants for any gas phase reaction can be computed from thermodynamic properties. A modified reaction set for the H/O system is determined. A11 of the third body efficiencies M are taken to be unity. Good agreement was obtained between the thermodynamic method and the experimental shock tube data. In addition, the hydrogen bromide experimental data presented in previous work is recomputed with M's of unity.

Marek, C. John↗

NASA NTRS2012

A Thermodynamically-Based Mesh Objective Work Potential Theory for Predicting Intralaminar Progressive Damage and Failure in Fiber-Reinforced Laminates

A thermodynamically-based work potential theory for modeling progressive damage and failure in fiber-reinforced laminates is presented. The current, multiple-internal state variable (ISV) formulation, enhanced Schapery theory (EST), utilizes separate ISVs for modeling the effects of damage and failure. Damage is considered to be the effect of any structural changes in a material that manifest as pre-peak non-linearity in the stress versus strain response. Conversely, failure is taken to be the effect of the evolution of any mechanisms that results in post-peak strain softening. It is assumed that matrix microdamage is the dominant damage mechanism in continuous fiber-reinforced polymer matrix laminates, and its evolution is controlled with a single ISV. Three additional ISVs are introduced to account for failure due to mode I transverse cracking, mode II transverse cracking, and mode I axial failure. Typically, failure evolution (i.e., post-peak strain softening) results in pathologically mesh dependent solutions within a finite element method (FEM) setting. Therefore, consistent character element lengths are introduced into the formulation of the evolution of the three failure ISVs. Using the stationarity of the total work potential with respect to each ISV, a set of thermodynamically consistent evolution equations for the ISVs is derived. The theory is implemented into commercial FEM software. Objectivity of total energy dissipated during the failure process, with regards to refinements in the FEM mesh, is demonstrated. The model is also verified against experimental results from two laminated, T800/3900-2 panels containing a central notch and different fiber-orientation stacking sequences. Global load versus displacement, global load versus local strain gage data, and macroscopic failure paths obtained from the models are compared to the experiments.

Pineda, Evan J.↗

NASA NTRSDate not supplied

Molten Salt Electrolytes: Computational Analysis of Transport, Electrochemical Properties and Designing New Mixtures

Electric aircraft propulsion has gained a traction over the last decade due to possible high-energy density electrochemistries with reasonable cycle life and identification of non-flammable chemistries that can guarantee much better safety. Commercial Li-ion batteries cannot reach such high capacities because of weight limitations that arise from the widely used intercalation electrodes. Also, use of organic electrolytes make them highly susceptible to fire on exposure to air and humidity. Currently, use of Lithium metal anode along with conversion electrochemistries such as Li-O2 and Li-S are being pursued to achieve such high energy densities. Safer inorganic solid-state electrolytes, recently discovered Water-in-Salt electrolytes, molten salt electrolytes are some of the alternatives being pursued for a safer/non-flammable battery. Of these safer alternatives, molten-salt electrolytes offer some attractive properties: liquid at operating temperatures resulting in better electrode-wetting, stable interface with Li-metal anodes and good ionic conductivity; their only drawback being high operating temperatures. In this talk, we will discuss some of the computational studies, driven via atomistic simulations, of the properties of molten-salt electrolytes including transport mechanism and interface stability. We will also discuss predicting electrochemical properties of these high-temperature electrolytes. Further, we will discuss a thermodynamic approach to predicting new molten-salt eutectics with lower melting points.

Molten Salt Electrolytes↗

NASA NTRS2011

Comparison of Ablation Predictions for Carbonaceous Materials Using CEA and JANAF-Based Species Thermodynamics

In most previous work at NASA Ames Research Center, ablation predictions for carbonaceous materials were obtained using a species thermodynamics database developed by Aerotherm Corporation. This database is derived mostly from the JANAF thermochemical tables. However, the CEA thermodynamics database, also used by NASA, is considered more up to date. In this work, the FIAT code was modified to use CEA-based curve fits for species thermodynamics, then analyses using both the JANAF and CEA thermodynamics were performed for carbon and carbon phenolic materials over a range of test conditions. The ablation predictions are comparable at lower heat fluxes where the dominant mechanism is carbon oxidation. However, the predictions begin to diverge in the sublimation regime, with the CEA model predicting lower recession. The disagreement is more significant for carbon phenolic than for carbon, and this difference is attributed to hydrocarbon species that may contribute to the ablation rate.

Milos, Frank S.↗

NASA NTRS1986

Low-gravity experiments in critical phenomena

Studies of anomalous thermodynamic, transport, and structural phenomena in multibody systems near critical points are reviewed. The nomenclature used to describe critical points is explained; theoretical predictions of the thermodynamic properties of bulk systems are presented; and experimental tests of these predictions systems are discussed, considering equilibration and gravity effects in fluid systems and emphasizing the value of experiments conducted in a reduced-gravity environment. Several such experiments are described, and the available academic-research opportunities are briefly surveyed.

Moldover, Michael R.↗

NASA NTRS1989

Proton production in relativistic heavy ion collisions; comparison with a thermodynamical model

Experimental results concerning proton production in nuclear collisions, obtained at Saturne with the Diogene 4 pi facility, are compared with the predictions of a thermodynamical model, using collective velocity distributions combined with a statistical thermodynamics in local rest frames. Experimental differential cross sections for alpha + nucleus and Neon + nucleus central collisions at incident energies between 200 and 800 MeV per nucleon are well reproduced by the model, for an angular range 30-110 degrees in the laboratory system. Extracted values of the temperatures are compared with those given by other authors.

NASA Program Biomedical Research↗

NASA NTRS2006

Upper Stage Tank Thermodynamic Modeling Using SINDA/FLUINT

Modeling to predict the condition of cryogenic propellants in an upper stage of a launch vehicle is necessary for mission planning and successful execution. Traditionally, this effort was performed using custom, in-house proprietary codes, limiting accessibility and application. Phenomena responsible for influencing the thermodynamic state of the propellant have been characterized as distinct events whose sequence defines a mission. These events include thermal stratification, passive thermal control roll (rotation), slosh, and engine firing. This paper demonstrates the use of an off the shelf, commercially available, thermal/fluid-network code to predict the thermodynamic state of propellant during the coast phase between engine firings, i.e. the first three of the above identified events. Results of this effort will also be presented.

Schallhorn, Paul↗

NASA NTRS1975

Task 3 Milestone Report, Kennedy Space Center (KSC) LOX Loading Facility Analyses

Transient thermodynamic analyses have been made for the Kennedy Space Center (KSC) LOX loading system proposed for the space shuttle. The primary objective of these analyses is to predict the sensitivity of system performance to operating procedures, flow rate, temperature, and quality at the orbiter (ORB)/ground service equipment (GSE) interface. A further objective is to establish required system chill-down times. These analyses also include the prediction of transient thermodynamic conditions for the facility vent line, shuttle main engine (SSME) feed line entrance, ORB/ET interface, and the ET entrance (tank bottom).

Glasgow, V. L.↗

NASA NTRS1999

SiC and Si3N4 Recession Due to SiO2 Scale Volatility Under Combustor Conditions

Silicon carbide (SiC) and Si3N4 materials were tested in various turbine engine combustion environments chosen to represent either conventional fuel-lean or fuel-rich mixtures proposed for high-speed aircraft. Representative chemical vapor-deposited (CVD), sintered, and composite materials were evaluated by furnace and high-pressure burner rig exposures. Although protective SiO2 scales formed in all cases, the evidence presented supports a model based on paralinear growth kinetics (i.e., parabolic growth moderated simultaneously by linear volatilization). The volatility rate is dependent on temperature, moisture content, system pressure, and gas velocity. The burner tests were thus used to map SiO2 volatility (and SiC recession) over a range of temperatures, pressures, and velocities. The functional dependency of material recession (volatility) that emerged followed the form A[exp(-Q / RT)](P(sup x)v(sup y). These empirical relations were compared with rates predicted from the thermodynamics of volatile SiO and SiOxHy reaction products and a kinetic model of diffusion through a moving boundary layer. For typical combustion conditions, recession of 0.2 to 2 micrometers/hr is predicted at 1200 to 1400 C, far in excess of acceptable long-term limits.

Smialek, James L.↗

NASA NTRS1999

SiC and Si3N4 Recession Due to SiO2 Scale Volatility Under Combustor Conditions

SiC and Si3N4 materials were tested under various turbine engine combustion environments, chosen to represent either conventional fuel-lean or fuel-rich mixtures proposed for high speed aircraft. Representative CVD, sintered, and composite materials were evaluated in both furnace and high pressure burner rig exposure. While protective SiO2 scales form in all cases, evidence is presented to support paralinear growth kinetics, i.e. parabolic growth moderated simultaneously by linear volatilization. The volatility rate is dependent on temperature, moisture content, system pressure, and gas velocity. The burner tests were used to map SiO2 volatility (and SiC recession) over a range of temperature, pressure, and velocity. The functional dependency of material recession (volatility) that emerged followed the form: exp(-QIRT) * P(exp x) * v(exp y). These empirical relations were compared to rates predicted from the thermodynamics of volatile SiO and SiO(sub x)H(sub Y) reaction products and a kinetic model of diffusion through a moving, boundary layer. For typical combustion conditions, recession of 0.2 to 2 micron/h is predicted at 1200- 1400C, far in excess of acceptable long term limits.

Smialek, James L.↗

NASA NTRS2015

TankSIM: A Cryogenic Tank Performance Prediction Program

Accurate prediction of the thermodynamic state of the cryogenic propellants in launch vehicle tanks is necessary for mission planning and successful execution. Cryogenic propellant storage and transfer in space environments requires that tank pressure be controlled. The pressure rise rate is determined by the complex interaction of external heat leak, fluid temperature stratification, and interfacial heat and mass transfer. If the required storage duration of a space mission is longer than the period in which the tank pressure reaches its allowable maximum, an appropriate pressure control method must be applied. Therefore, predictions of the pressurization rate and performance of pressure control techniques in cryogenic tanks are required for development of cryogenic fluid long-duration storage technology and planning of future space exploration missions. This paper describes an analytical tool, Tank System Integrated Model (TankSIM), which can be used for modeling pressure control and predicting the behavior of cryogenic propellant for long-term storage for future space missions. It is written in the FORTRAN 90 language and can be compiled with any Visual FORTRAN compiler. A thermodynamic vent system (TVS) is used to achieve tank pressure control. Utilizing TankSIM, the following processes can be modeled: tank self-pressurization, boiloff, ullage venting, and mixing. Details of the TankSIM program and comparisons of its predictions with test data for liquid hydrogen and liquid methane will be presented in the final paper.

Bolshinskiy, L. G.↗