Task 8: Water Quality Monitoring, 1400
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Automated chemiluminescence and bioluminescence sensors were developed for the continuous monitoring of microbial levels in water supplies. The optimal chemical procedures were determined for the chemiluminescence system to achieve maximum sensitivity. By using hydrogen peroxide, reaction rate differentiation, ethylene diamine tetraacetic acid (EDTA), and carbon monoxide pretreatments, factors which cause interference were eliminated and specificity of the reaction for living and dead bacteria was greatly increased. By employing existing technology with some modifications, a sensitive and specific bioluminescent system was developed.
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The Tahoe basin occupies over 500 square miles of territory located in a graben straddling the boundary between California and Nevada. Lake Tahoe contains 126 million acre-feet of water. Since the 1950's the basin has experienced an ever increasing demand for land development at the expense of the natural watershed. Discharge of sediment to the lake has greatly increased owing to accelerated human interference, and alterations to the natural drainage patterns are evident in some areas. In connection with an investigation of the utility of a comprehensive system that takes into account the causes as well as the effects of lake eutrophication, it has been attempted to construct an integrated and workable data base, comprised of currently available data sources for the Lake Tahoe region. Attention is given to the image based information system (IBIS), the construction of the Lake Tahoe basin data base, and the application of the IBIS concept to the Lake Tahoe basin.
A total organic carbon (TOC) analysis system based on ultraviolet absorption is described. The equation for measuring the intensity of the absorbed radiation of the organic substances, which is based on the Lambert-Beer law, is given; the intensity of the absorption is proportional to the concentration of the solution. The operation of the UV-Absorption analyzer, which utilizes a split beam, two wvaelength method, is studied. The influences of the cell path length and specific compounds in the solution flowing through the cell on absorbances is discussed. The performance and response of the analyzer is evaluated; good correlation is observed between the absorption value and TOC. The advantage of the UV-Absorption as compared with the UV-Oxidation are examined.
Preprotype air revitalization and water reclamation subsystems (Mole Sieve, Sabatier, Static Feed Electrolyzer, Trace Contaminant Control, and Thermoelectric Integrated Membrane Evaporative Subsystem) were operated and tested independently and in an integrated arrangement. During each test, water and/or gas samples were taken from each subsystem so that overall subsystem performance could be determined. The overall test design and objectives for both subsystem and integrated subsystem tests were limited, and no effort was made to meet water or gas specifications. The results of chemical analyses for each of the participating subsystems are presented along with other selected samples which were analyzed for physical properties and microbiologicals.
The impetus of the Viking Mission to Mars led to the first miniaturization of a X-ray Fluorescence Spectrometer (XRFS). Two units were flown on the Viking Mission and successfully operated for two years analyzing the elemental composition of the Martian soil. Under a Bureau of Mines/NASA Technology Utilization project, this XRFS design was utilized to produce a battery powered, portable unit for elemental analysis of geological samples. This paper will detail design improvements and additional sampling capabilities that were incorporated into a second generation portable XRFS that was funded by the EPA/NASA Technology Utilization project. The unit, Environment Monitoring with Portable Analysis by X-ray (EMPAX), was developed specifically for quantitative determination of the need of EPA and and any industry affected by environmental concerns, the EMPAX fulfills a critical need to provide on-site, real-time analysis of toxic metal contamination. A patent was issued on EMPAX, but a commercial manufacturer is still being sought.
An electronic nose that uses an array of 32 polymer-carbon black composite sensors has been developed, trained, and tested. By selecting a variety of chemical functionalities in the polymers used to make sensors, it is possible to construct an array capable of identifying and quantifying a broad range of target compounds, such as alcohols and aromatics, and distinguishing isomers and enantiomers (mirror-image isomers). A model of the interaction between target molecules and the polymer-carbon black composite sensors is under development to aid in selecting the array members and to enable identification of compounds with responses not stored in the analysis library.
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The successful development showed an alternative to radiation-packaging of existing devices, which leaves Missions with expensive electronics that are few generations behind the state-of-the-art.
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Wildfire smoke has long-lasting impacts on public and environmental health. Currently, agencies that monitor smoke base their decisions on an analysis of how fires burn, the direction the smoke moves from the fire source, and unverified estimates of mixing height. Mixing heights describe the maximum altitude to which a smoke plume rises. Satellite imagery provides more continuous and accurate coverage of mixing heights than current in situ methods. Thus, the team developed a software tool that processes and extracts mixing height observations from Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) Vertical Feature Mask granules. The team partnered with the National Oceanic and Atmospheric Administration’s National Weather Service, the Bureau of Land Management’s National Interagency Fire Center, and the National Park Service’s Fire Management Program Center to analyze historic fire events in southern Idaho. To do so, they used Suomi National Polar-orbiting Partnership (Suomi NPP) Visible Infrared Imaging Radiometer Suite (VIIRS), and Terra and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) to verify where a CALIPSO pass intersects thermal anomalies and smoke plumes. The software extracts features of relevance from the hdf file of each CALIPSO transect to locate layers of continuous aerosols. The maximum altitude at which the aerosol ends is recorded as the mixing height, along with a matching latitude and longitude. The satellite-derived values can be used to validate past mixing height predictions and evaluate the accuracy and systematic bias of different estimation methods. These results may allow agencies to make better comparisons and subsequent smoke pollution management, prevention, and public health decisions if the spatial and temporal differences between predictions and observations can be resolved.
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