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Graphite Oxidation Activities to include introduction, rate determination, strength after oxidation, penetration depth analysis, strategic partnership projects, and summary and continuing work.
This presentation summarizes work recently published in a Joule article, "The Curtailment Paradox in the Transition to High Solar Power Systems." Rising penetrations of variable renewable energy (VRE) in power systems are expected to increase the curtailment of these resources because of oversupply and operational constraints. We evaluate the effect on curtailment from various flexibility approaches, including storage, thermal generator flexibility, operating reserve eligibility rules, transmission constraints, and temporal resolution, by using a highly resolved realistic system. Results reveal two aspects of a curtailment paradox as the system evolves to higher solar penetration levels. First, thermal generator parameters, especially in restricting minimum operating levels and ramp rates, affect VRE curtailment more in mid-PV penetration levels (~25%–40%) but much less at lower (~20%) or higher (~45%) PV penetration levels. Second, although allowing VRE and storage to provide operating reserve results in significant operating costs and curtailment benefits, the price suppression effect from these resources reduces incentives for PV to provide operating reserves with curtailed energy.
Abstract Understanding the processes that produce high prograde metamorphic heating rates and the development of inverted metamorphic sequences in collisional thrust belts remains a fundamental challenge for tectonics and metamorphic petrology. New 2D finite element models of crustal‐scale thrusts with variable slip rates (10, 20, 35, 50 km Myr −1 ) are used to examine how thrust sheet emplacement contributes to these processes. In the models, average prograde heating rates of 31–118 °C Myr −1 are observed in the footwall, with maximum transient heating rates of ∼167 °C Myr −1 occurring at the highest slip rate. Also, thrust sheet emplacement produces an inverted thermal gradient in the model footwall. At slip rates of 10 km Myr −1 , heating magnitudes >200 °C are observed >7 km structurally beneath the thrust plane. At slip rates of 20–50 km Myr −1 , models produce thermal penetration depths of 4–5 km for similar heating magnitudes. Petrologically determined heating rates for thrust footwalls in the Scandian orogenic wedge of northern Scotland mostly yield rates consistent with model results (10–230 °C Myr −1 ). The model‐derived magnitude of inverted thermal gradients is also similar to those indicated in texturally determined deformation temperature transects across the Scandian orogenic wedge (100 °C–180 °C). Combined, these results indicate that high heating rates can be produced by fault slip at typical plate velocities. Additionally, this implies that crustal‐scale thrusts are likely to produce inverted metamorphic sequences in most systems, provided that P‐T conditions during slip allow for metamorphic or recrystallization processes that would preserve evidence for such features.
Consideration of thermal runaway heat output variability is paramount for the development of safe lithium-ion battery assemblies. This study utilizes data gathered from fractional thermal runaway calorimetry (FTRC) experiments to conduct a comparative analysis of thermal runaway heat output for three cell formats (18650, 21700, and 33600) as a function of trigger method (heaters, internal short-circuiting device, and nail penetration). The analysis is based on comparisons for the calculated total energy yield, fractional energy yield, heat rate, and heat flux. This study reveals that nail penetration tends to result in higher thermal runaway heat output for larger cells (21700 & 33600); these experiments also tended to result in higher fractions of the total energy being released through the cell body. The smaller cells (18650) did not appear to have significant variation in heat output as a function of trigger method. This finding suggests that, for this cell type, worst-case scenario heat output could be achievable in assembly level testing regardless of the utilized trigger method. This study also demonstrates successful translation of FTRC results, as recorded in the Battery Failure Databank, into meaningful analysis that breaks down the influence of specific conditions on thermal runaway heat output.
There are no drugs or treatment methods known to prevent the development of post-traumatic osteoarthritis (PTOA), a type of osteoarthritis (OA) that is triggered by traumatic joint injuries and accounts for ~12% of the nearly 600 million OA cases worldwide. Lack of effective drug delivery techniques remains a major challenge in developing clinically effective treatments, but cationic delivery carriers can help overcome this challenge. Scaling up treatments that are effective in in vitro models to achieve success in preclinical in vivo models and clinical trials is also a challenging problem in the field. Here we use a cationic green fluorescent protein (GFP) as a carrier to deliver Insulin-Like Growth Factor 1 (IGF-1), a drug considered as a potential therapeutic for PTOA. GFP-IGF-1 conjugates were first synthesized as fusion proteins with different polypeptide linkers, and their transport properties were characterized in human cartilage explants. In vitro experimental data were used to develop a predictive mathematical transport model that was validated using an independent in vitro experimental data set. In this study, the model was used to predict the transport of these fusion proteins upon intra-articular injection into human knee joints. The predictions included results for the rate and extent of fusion protein penetration into cartilage, and the maximum levels of fusion proteins that would escape into systemic circulation through the joint capsule. Together, our transport measurements and model set the stage for translation of such explant culture studies to in vivo preclinical studies and potentially clinical application.
Abstract. Unambiguous identification of past episodes of ice sheet thinning below the modern surface and grounding line retreat inboard of present requires recovery and exposure dating of subglacial bedrock. Such efforts are needed to understand the significance and potential future reversibility of ongoing and projected change in Antarctica. Here we evaluate the suitability for subglacial bedrock drilling of sites in the Hudson Mountains, which are located in the Amundsen Sea sector of West Antarctica. We use an ice sheet model and field data – geological observations, glaciological observations and bedrock samples from nunataks, and ground-penetrating radar from subglacial ridges – to rate each site against four key criteria: (i) presence of ridges extending below the ice sheet, (ii) likelihood of increased exposure of those ridges if the grounding line was inboard of present, (iii) suitability of bedrock for drilling and geochemical analysis, and (iv) accessibility for aircraft and drilling operations. Our results demonstrate that although no site in the Hudson Mountains is perfect for this study when assessed against all criteria, the accessibility, N–S orientation and basaltic bedrock lithology of Winkie Nunatak's southernmost ridge (74.86° S, 99.77° W) make it a feasible site both for drilling and subsequent cosmogenic nuclide analysis. Furthermore, the ridge is strewn with glacial erratics at all elevations, providing valuable constraints on its early Holocene deglacial history. Based on our experiences during this study, we conclude with a series of recommendations for assessing site suitability for future bedrock drilling campaigns. We emphasise the importance of consulting a range of expertise prior to drilling and ensuring that sufficient field reconnaissance is undertaken (including obtaining detailed grids of radar survey data and bedrock samples).
The molecular dynamics code LAMMPS was used to simulate the bombardment of a graphite structure by atomic boron with impact energies ranging from 50–250 eV. The transient structural evolution, penetration depth, and amorphous layer thickness were analyzed. Simulations show that larger impact energies lead to a greater volume of amorphization and penetration of boron, but that the growth rate of the amorphous layer decreases with increasing fluence. Furthermore, the change in surface chemistry of the amorphized structures was studied using the ReaxFF formalism, which found that the amorphization process introduces dangling bonds thus increasing reactivity in the amorphous region.
Na-based batteries have long been regarded as an inexpensive, sustainable candidate for large-scale stationary energy storage applications. Unfortunately, the market penetration of conventional Na-NiCl2 batteries is approaching its limit for several reasons, including limited rate capability and high Ni cost. Herein, a Na-FeCl2 battery operating at 190 °C is reported that allows a capacity output of 116 mAh g-1 at an extremely high current density of 33.3 mA cm-2 (˜0.6C). The superior rate performance is rooted in the intrinsically fast kinetics of the Fe/Fe2+ redox reaction. Furthermore, it is demonstrated that a small amount of Ni additive (10 mol%) effectively mitigates capacity fading of the Fe/NaCl cathode caused by Fe particle pulverization during long-term cycling. The modified Fe/Ni cathode exhibits excellent cycling stability, maintaining a discharge energy density of over 295 Wh kg-1 for 200 cycles at 10 mA cm-2 (˜C/5).
This in vitro skin study determined absorption, diffusion, and binding rates of four [14C]-labeled nanoparticles (NPs): 12 nm Fe 3 O 4 , 32 nm Fe 3 O 4 @SiO 2 , 33 nm SiO 2 , and 78 nm SiO 2 in each layer of human cadaver skin. In vitro microdialysis device and flow-through skin diffusion system were used to measure the binding affinity to the stratum corneum (SC) and permeability into/through skin layer of the four NPs with different physical–chemical properties, respectively, in short (30 min) and/or long (24 hours) exposures. Results show that NP size is an important factor affecting NP percutaneous absorption. The 12 nm Fe 3 O 4 NPs reached the SC and viable epidermis; 32 nm Fe 3 O 4 @SiO 2 core/shell NPs only reached SC. However, 33 nm and 78 nm silica NPs did not permeate SC. Similar patterns were observed for NP binding affinity to SC and dermatopharmacokinetic analysis using the tape stripping method. The binding affinity determination may be a useful method to efficiently screen skin penetration of NPs.
Momentary cessation refers to an inverter control mode. When the inverter terminal voltage falls below (or exceeds) a certain level, the inverter ceases to output any current, but attempts to maintain (or quickly regain) phase-locked loop synchronization to allow for quick reinjection of current when the voltage recovers to a certain point. This paper presents a photovoltaic (PV) momentary cessation model developed in PSS/E. Simulations are presented for a high voltage transmission line fault contingency in the Hawaiian island of Oahu power system on a validated PSS/E model, modified to include a custom distributed PV inverter model, and different near-future distributed PV penetration levels. Simulations for the island power system include different penetration levels of PV, and different recovery times (ramp rates and delays) after momentary cessation. The results indicate that during low voltage events, such as faults, momentary cessation can produce severe under frequency events, causing significant load shed and shortly thereafter, in some cases, over frequency events that cause generation to trip offline. The problem is exacerbated with higher penetration levels of PV. If momentary cessation is used (as is typically the case for distribution-connected resources), the recovery process after momentary cessation should be carefully considered to minimize impacts to bulk power system stability.
The onset of the 2019 novel coronavirus disease (COVID-19) led to a shortage of personal protective equipment (PPE), medical devices, and other medical supplies causing many stakeholders and the general public alike to turn to additive manufacturing (AM) as a stopgap when normally accessible devices were not available. However, without a method to test these AM constructs, there continued to be a disconnect between AM suppliers and the community’s needs. The objective of this study was to characterize the pressure drop and leakage of four different publicly available AM face mask models with two filter material combinations, as well as to investigate the impact of frame modification techniques including the use of foam strips and hot-water face forming to improve fit when the masks are donned on manikin head forms. AM face mask frame designs were downloaded from public repositories during the early stages of the COVID-19 pandemic. AM face masks were fabricated and tested on manikin head forms within a custom chamber containing dry aerosolized NaCl. Pressure drops, particle penetration, and leakage were evaluated for various flow rates and NaCl concentrations. Results indicated that filter material combination and frame modification played a major role in the overall performance of the AM face masks studied. Filter material combinations showed improved performance when high filtration fabric was used, and the cross-sectional area of the fabric was increased. AM frame modifications appeared to improve AM face mask leakage performance by as much as 69.6%.
This paper documents the design and application of ATLAS (Automobile and Technology Lifecycle-Based ASsignment), a comprehensive household vehicle transaction and technology adoption micro-simulator in the San Francisco Bay Area. ATLAS evolves the fleet mix of individual households by simulating the vehicle transaction and choice decisions in response to co-evolving demographics, land use, and vehicle technology simulations. While most existing literature has focused on the aggregate clean vehicle uptake, this paper differentiates distributional effects and decomposes the underlying mechanisms across heterogeneous sub-populations of households. Using scenarios and sensitivity simulations that vary vehicle technology and policy assumptions, we find that Zero Emission Vehicles (ZEVs) penetrate into higher income groups at a faster rate than into lower income groups, which is intuitive and aligns with expectations. Interestingly, the relative income disparity in ZEV ownership shrinks over time across all scenarios, with a ZEV mandate coupled with declining battery cost leading to the greatest reduction in disparity of ZEV ownership by 2050. Federal, state, and local financial incentives influence the redistribution of ZEV uptake across income groups and contribute to narrowing income disparity. Vehicle transaction frequency and new versus used market dynamics are found to be important factors contributing to the income disparity.
Understanding the safety profile of aged Li-ion batteries is essential for developing effective battery management and hazard mitigation strategies. However, most safety assessments have focused on fresh batteries, with just a few calorimetry studies on aged batteries with metal oxide positive electrodes. This study provides a broad assessment of commercial 18650-type Li-ion batteries with NCA, NMC, and LFP positive electrodes, both uncycled and aged under conditions that promoted solid electrolyte interphase (SEI) growth as the dominant degradation mechanism. The cells underwent mechanical (nail penetration, crush), electrical (overcharge, overdischarge), and thermal (accelerating rate calorimetry) abuse tests. Safety was rated on general characteristics such as mass loss, maximum temperature, and EUCAR (European Council for Automotive R&D) hazard level, as well as characteristics specific to individual abuse tests. Generally, aged cells with SEI growth exhibited similar or improved safety compared to uncycled cells, contrasting with our previous findings on NCA cells with Li plating as the dominant aging mechanism (Part I of this series). Yet, some tests and characteristics indicated reduced aged cell safety, such as earlier triggering of mechanical failure. These results emphasize the need to examine aged battery safety across diverse empirical techniques, degradation modes, and chemistries.
Here we perform numerical simulations of sequences of earthquake and aseismic slip on planar rate and state faults separating dissimilar material within the 2-D plane strain approximation. We resolve all stages of the earthquake cycle from aseismic slip to fast ruptures while incorporating full inertia effects during seismic event propagation. We show that bimaterial coupling results in favorable nucleation site and subsequent asymmetric rupture propagation. We demonstrate that increasing the material contrast enhances this asymmetry leading to higher slip rates and normal stress drops in the preferred rupture propagation direction. The normal stress drop, induced by the bimaterial effect, leads to strong dynamic weakening of the fault and may destabilize the creeping region on a heterogeneous rate and state fault, resulting in extended rupture propagation. Such rupture penetration into creeping patches may lead to more frequent opening of earthquake gates, causing increased seismic hazard. Furthermore, bimaterial coupling may lead to irregular seismicity pattern in terms of event length, peak slip rates, and hypocenter location, depending on the properties of the creeping patches bordering the seismogenically active part of the fault. Our results highlight robust characteristics of bimaterial interfaces that persist over long sequence of events and suggest the need for further exploration of the role of material contrast in earthquake physics and models of seismic hazard.
The penetration of distributed energy resources (DER) is growing at much higher rates than predicted 20 years ago. Far from being used only in residential settings, DER are now installed on distribution and transmission circuits. In this position, they do not have the same properties as traditional generators and are more flexible in many cases. The growing penetration and range of uses for DER motivate the need to reliably and safely integrate them into the grid. Operators must be able to rely on them not only for normal operation, but also during abnormal conditions like black starts or adverse cyber scenarios. To that end, we study the communications, device interfaces, and potential consequences of DER operation under abnormal and adversarial conditions. The weaknesses of communications networks are studied based on the industrial protocols used, and the benefits of security features are examined. The device interfaces are found to be vulnerable to attack based on the requirements in the IEEE-1547 standard for DER interconnection and interoperability, which is expected to be adopted in the next ten years. In addition to exploring the requirements of the standard, we show that these vulnerabilities and others do exist and can be used maliciously in a modern storage system DER. Consequences of these vulnerabilities range from exacerbated grid instability, to simultaneous loss of large portions of DER penetration, to physical damage to inverters or DER themselves and other sensitive equipment. We tie these outcomes to specific attacker actions in an effort to give operators a better threat intelligence view that allows them to prioritize mitigations. Finally, we discuss mitigations that could prevent many of the adversarial scenarios described. Some solutions can be added to existing infrastructure, while others may require longer term planning for grid modernization with consideration for security.
Superconducting electron linear accelerators open up new opportunities for advanced materials processing. High energy electrons penetrate deeper within materials, increase the processing depth and rate and enables production of far-from-equilibrium materials and selective processing within a material surface and subsurface. With support from the Office of Naval Research, NASA, and DoE, Mainstream Engineering commissioned a superconducting linear electron accelerator to investigate advanced materials processing and additive manufacturing. The goal of Mainstream's Electron Beam Enabled Advanced Manufacturing (EBEAM) center is to develop unique, far-from-equilibrium materials and alleviate significant technological deficiencies. We will present results of irradiating various metals and their unique material properties. Monte Carlo simulations electron beam and sample interaction were used to optimize the processing parameters and study far-from-equilibrium processing conditions. Applications include stainless steel additive manufacturing for small modular nuclear reactors and dissimilar metal bonding of corrosion-resistant cladding for next-generation molten salt reactors.
Abstract Although 2D Ti 3 C 2 T x is a good candidate for supercapacitors, the restacking of nanosheets hinders the ion transport significantly at high scan rates, especially under practical mass loading (>10 mg cm −2 ) and thickness (tens of microns). Here, Ti 3 C 2 T x ‐NbN hybrid film is designed by self‐assembling Ti 3 C 2 T x with 2D arrays of NbN nanocrystals. Working as an interlayer spacer of Ti 3 C 2 T x , NbN facilitates the ion penetration through its 2D porous structure; even at extremely high scan rates. The hybrid film shows a thickness‐independent rate performance (almost the same rate capabilities from 2 to 20 000 mV s −1 ) for 3 and 50 µm thick electrodes. Even a 109 µm thick Ti 3 C 2 T x ‐NbN electrode shows a better rate performance than 25 µm thick pure Ti 3 C 2 T x electrodes. This method may pave a way to controlling ion transport in electrodes composed of 2D conductive materials, which have potential applications in high‐rate energy storage and beyond.