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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Data Mining of Polymer Phase Transitions upon Temperature Changes by Small and Wide-Angle X-ray Scattering Combined with Raman Spectroscopy

The complex physical transformations of polymers upon external thermodynamic changes are related to the molecular length of the polymer and its associated multifaceted energetic balance. The understanding of subtle transitions or multistep phase transformation requires real-time phenomenological studies using a multi-technique approach that covers several length-scales and chemical states. A combination of X-ray scattering techniques with Raman spectroscopy and Differential Scanning Calorimetry was conducted to correlate the structural changes from the conformational chain to the polymer crystal and mesoscale organization. Current research applications and the experimental combination of Raman spectroscopy with simultaneous SAXS/WAXS measurements coupled to a DSC is discussed. In particular, we show that in order to obtain the maximum benefit from simultaneously obtained high-quality data sets from different techniques, one should look beyond traditional analysis techniques and instead apply multivariate analysis. Data mining strategies can be applied to develop methods to control polymer processing in an industrial context. Crystallization studies of a PVDF blend with a fluoroelastomer, known to feature complex phase transitions, were used to validate the combined approach and further analyzed by MVA.

36 MATERIALS SCIENCE↗

Phase effects from strong gravitational lensing of gravitational waves

Assessing the probability that two or more gravitational wave (GW) events are lensed images of the same source requires an understanding of the properties of the lensed images. For short enough wavelengths where wave effects can be neglected, lensed images will generically have a fixed relative phase shift that needs to be taken into account in the lensing hypothesis. For non-precessing, circular binaries dominated by quadrupole radiation these lensing phase shifts are degenerate with either a shift in the coalescence phase or a detector and inclination dependent shift in the orientation angle. This degeneracy is broken by the presence of higher harmonic modes with |m| ≠ 2 in the former and |m| ≠ l in the latter. The presence of precession or eccentricity will also break this degeneracy. This implies that a lensed GW image will not necessarily be consistent with (unlensed) predictions from general relativity (GR). Therefore, unlike the conventional scenario of electromagnetic waves, strong lensing of GWs can lead to images with a modified phase evolution that can be observed. However, we find that templates with a shifted orientation angle remain a good approximation, with signal-to-noise ratio differences of less than 1% for mass ratios up to 1/18, and less than 5% for precession parameters up to 0.5 and eccentricities up to 0.4. We conclude that an optimal strong lensing search strategy would incorporate phase information in all stages of the identification of strong-lensing, with an exact treatment in the final assessment of the probability of multiple lensed events. Here, this work clarifies the role that strong lensing plays in the phase evolution of GWs: how it can lead to apparent deviations from GR, how it can affect the detectability of GW events, and how it can be exploited to help identify cases of strong gravitational lensing of gravitational wave sources.

79 ASTRONOMY AND ASTROPHYSICS↗

Stress waves in transversely isotropic media: The homogeneous problem

The homogeneous problem of stress wave propagation in unbounded transversely isotropic media is analyzed. By adopting plane wave solutions, the conditions for the existence of the solution are established in terms of phase velocities and directions of particle displacements. Dispersion relations and group velocities are derived from the phase velocity expressions. The deviation angles (e.g., angles between the normals to the adopted plane waves and the actual directions of their propagation) are numerically determined for a specific fiber-glass epoxy composite. A graphical method is introduced for the construction of the wave surfaces using magnitudes of phase velocities and deviation angles. The results for the case of isotropic media are shown to be contained in the solutions for the transversely isotropic media.

Marques, E. R. C.↗

Physical analysis and second-order modelling of an unsteady turbulent flow - The oscillating boundary layer on a flat plate

The turbulent boundary layer under a freestream whose velocity varies sinusoidally in time around a zero mean is computed using two second order turbulence closure models. The time or phase dependent behavior of the Reynolds stresses are analyzed and results are compared to those of a previous SPALART-BALDWIN direct simulation. Comparisons show that the second order modeling is quite satisfactory for almost all phase angles, except in the relaminarization period where the computations lead to a relatively high wall shear stress.

Ha Minh, H.↗

Technologies for Maintaining Animals in Space: Lighting, Air Quality, Noise, Food and Water

In the terrestrial environment multiple time cues exist. Zeitgebers have been identified and studied for their ability to convey temporal information to various physiological systems, In the microgravity experiment it is necessary to define time cues within the flight hardware prior to flight. During flight if changes in the Circadian System (e.g., mean, phase angle, period) occur this would indicate that the gravity vector is important relative to biological timing. This presentation is concerned with the environmental parameters to support rodent experiments in microgravity. The Animal Enclosure Module (AEM) provides solid food bars and water via lixits ad libitum. Flight animals (Sprague-Dawley rats, 60 - 300g) when compared to ground controls show similar growth (mean growth per day, g +/- SD; flight 5.4 +/- 2.0, ground 5.9 +/- 2.1). Current AEMs use incandescent lighting (approx. 5 Lux). Light emitting diode (LED) arrays are being developed that provide a similar light environment as cool-white fluorescent sources (40 Lux). In ground based tests (12L:12D), these arrays show normal circadian entrainment (Tau = 24.0) with respect to the behavioral responses. measured (drinking, eating, gross locomotor activity). A newly developed ultra high efficiency filter system can entrap all feces, urine and odors from 6 rats for 24 days. Maximum sound level exposure limits (per octave band 22 Hz - 179 kHz) have been established. The AEM will effectively support animal experiments in microgravity.

Winget, C. M.↗

Technologies For Maintaining Animals In Space: Lighting, Air Quality, Noise, Food And Water

In the terrestrial environment multiple time cues exist. Zeitgebers have been identified and studied for their ability to convey temporal information to various physiological systems. In the microgravity experiment it is necessary to define time cues within the flight hardware prior to flight. During flight if changes in the Circadian System (e.g., mean, phase angle, period) occur this would indicate that the gravity vector is important relative to biological timing. This presentation is concerned with the environmental parameter: to support rodent experiments in microgravity. The Animal Enclosure Module (AEM) provides solid food bars and water via lixits and ad libitum. Flight animals (Sprague-Dawley rats, 60 - 300g) when compared to ground controls show similar growth (mean growth per day g, plus or minus SD; flight 5.4 plus or minus 2.0, ground 5.9 plus or minus 2.1). Current AEMs use incandescent lighting (approx. 5 Lux). Light emitting diode (LED) arrays are being developed that provide a similar light environment as cool-white fluorescent sources (40 Lux). In ground based tests (12L:12D), these arrays show normal circadian entrainment (Tau = 24.0) with respect to the behavioral responses, measured (drinking, eating, gross locomotor activity). A newly developed ultra high efficiency filter system can entrap all feces, urine and odors from 6 rats for 24 days. Maximum sound level exposure limits (per octave band 22 Hz - 179 kHz) have been established. The AEM will effectively support animal experiments in microgravity.

Winget, C. M.↗

Rocket Lab Venus - Enabling Low-Cost Interplanetary Missions

Rocket Lab’s mission to Venus [1], launching in January 2025, aims to demonstrate that small launch vehicles, such as Electron, and high-energy small spacecraft, such as Photon, can enable a new paradigm of regular, low-cost interplanetary missions. The Electron launch vehicle will deliver the Photon spacecraft carrying the entry probe into low earth orbit, at which point Photon will take over and put both itself and the attached probe on an Earth-Venus transfer trajectory, with assistance from a Lunar flyby. The primary science objective of the mission is to sample the Venusian cloud layers between atitudes of 45 and 60 km above the surface with an autofluorescing nephelometer. The ~1kg scientific instrument will be carried by a small ~17 kg direct entry probe which will separate from the Photon spacecraft approximately 30 minutes prior to atmospheric entry. The probe outer mould line is a scaled down version of the Deep Space 2 probes [2]. NASA’s newly developed 3D Woven Carbon Phenolic, a derivative of the Heatshield for Extreme Entry Environment Technology (HEEET) material [3], is an enabling technology for this mission, and it will comprise the probe forebody heat shield.The probe will communicate directly back to the Earth during its descent via a small on-board radio frequency (RF) antenna. The hyperbolic Venus encounter will see the probe enter the Venusia atmosphere at approximately 11 km/s with an entry flight path angle (EFPA) of about 10°. This relatively low entry angle was selected to increase the duration of the descent phase, reduce the peak deceleration, and reduce the sensitivity of the nominal entry environments to navigational errors. For reference, the Pioneer Venus probes entered at EFPAs varying from about 25° to 70°, resulting in peak decelerations between around 220 and 450 g’s and peak stagnation point heat fluxes ranging from about 40 to 75 MW/m2 [4]. In comparison, the Rocket Lab Venus probe will experience a lower preak deceleration of around 60 g’s and a lower peak stagnation point heat flux of about 15 MW/m2, at the cost of a greater total heat load and correspondingly higher thermal protection system (TPS) mass fraction. This paper recounts the development history of the TPS for the Rocket Lab Venus probe, with a focus on the unique requirements of the mission. In particular, the effect on the TPS design of the mission’s tight budget, short development timeline, slim mass and RF link margins, and mild but long duration entry heating. Rocket Lab’s initial investigations into a ‘hybrid’ TPS [5] based on a scaled version of the Pioneer Venus full-density carbon phenolic forebody shield, and the abandonment of this approach in favour of NASA’s 3D Woven Carbon Phenolic is presented. Additionally, the leveraging of previous testing under the HEEET project at higher conditions and the associated TPS margining strategy that was adopted to avoid the need for extensive mission-specific arc jet testing is discussed. Finally, this paper concludes with a brief consideration of the feasibility of a future low-cost aerocapture technology demonstrator mission based on the 2025 Rocket Lab Venus mission and entry probe.

Lyle Campbell↗

Instantaneous heat transfer coefficient based upon two-dimensional analyses of Stirling space engine components

Twelve different cases of multidimensional models of Stirling engine components for space applications have been numerically investigated for oscillating, incompressible laminar flow with heat transfer. The cases studied covered wide ranges of Valensi number (from 44 to 700), Re(max) number (from 8250 to 60,000), and relative amplitude of fluid motion of 0.686 and 1.32. The Nusselt numbers obtained from the present study indicate a very complex shape with respect to time and axial location in the channel. The results indicate that three parameters can be used to define the local Nusselt number variation, namely: time average, amplitude, and phase angle. These parameters could be correlated respectively using: Re(max), Va and Re(max), and the relative amplitude of fluid motion.

Ibrahim, Mounir↗

Venus - On the phase variation of CO2 line profiles

The shapes of Venus' CO2 profiles are found to vary with solar phase angle. High-resolution spectra of the P16 and P14 lines in the 8689- and 7820-A bands, respectively, are presented for phase angles ranging from 6 to 158 deg. The scattering mean free path at 80 mbar, approximately the effective pressure, is 1.7 km. Use of the van de Hulst (1974) similarity relations with simple parametric scattering models is inadequate to separate effects due to the scattering phase function from those due to inhomogeneities in depth when one attempts to determine the atmospheric structure by fitting a family of such models over a wide range of phase angles.

Macy, W., Jr.↗

Lightcurves and phase relations of the asteroids 82 Alkmene and 444 Gyptis

The asteroids 82 Alkmene and 444 Gyptis were observed photoelectrically at Table Mountain Observatory and at Torino Observatory during their 1979 opposition in order to determine their rotation periods and phase relations. The observations of 82 Alkmene yielded a rotation period of 12.999 h + or 0.002 h and an amplitude of variation of 0.55. The measured and corrected absolute magnitudes, when plotted against phase angle, is the best fit Lumme and Bowell (1981) theoretical phase function. The rotation period and amplitude of variation for 444 Gyptis are 6.214 h and 0.15, respectively. The phase relation of this asteroid is poorly fit by the Lumme and Bowell theory when only the multiple scattering parameter and the zero phase angle are treated as variables. A good fit can be obtained by adjusting some of the other parameters of their theory, but the physical interpretation is ambiguous.

Harris, A. W.↗

Octave-spanning terahertz quarter-wave plates based on over-coupled Fabry–Pérot resonances in reflective metal–dielectric–metal metasurfaces

Compact devices for broadband polarization control in the terahertz (THz) regime remain challenging to realize due to the intrinsic phase dispersion associated with birefringent materials and resonant structures. Here, we demonstrate achromatic THz quarter-wave plates with near-unity efficiency and operating under a wide range of incidence angles, based on over-coupled metal–dielectric–metal reflective metasurfaces. The devices operate as single-port anisotropic Fabry–Pérot cavities, in which the phase dispersion of the over-coupled resonances is engineered to maintain an approximately constant relative phase delay between orthogonal field components over a broad frequency range. Four complementary metasurface designs operating at an incidence angle of 45° collectively cover the 0.25–3 THz frequency range accessible to a typical THz time-domain spectroscopy system. Each device exhibits an approximately octave-wide operational bandwidth, with axial ratios below 3 dB and polarization-conversion efficiencies exceeding 80% across most of the operating band. Systematic structural optimization suppresses coupling to diffraction and guided-wave modes, thereby further extending the usable bandwidth while preserving the required phase relationship between orthogonal polarizations. The demonstrated metasurfaces are compatible with wafer-scale fabrication processes, and experimental results show excellent agreement with simulations. These findings establish over-coupled reflective metasurfaces as a robust, scalable, and versatile platform for broadband THz polarization control.

36 MATERIALS SCIENCE↗

A Study of the Opposition Phase Curve in Low Albedo Media

The Opposition Effect, the pronounced non-linear intensity increase in the reflectance phase curve with decreasing phase angle,theta , has long been observed in solar system bodies and in laboratory investigations of the angular scattering properties of particulate media. The size and shape of the phase curve, and the change in linear polarization with theta, have been related to the physical properties of planetary regolith scattering materials. Near zero degrees the increase in reflectance with decreasing phase angle has been attributed to two distinct processes. The first is the elimination of shadows cast between the regolith grains as the phase angle decreases. This is called the shadow hiding opposition effect (SHOE). The second is coherent constructive interference between rays of light traveling along identical but opposite paths in multiply scattering media. This is called the coherent backscattering opposition effect (CBOE).

Nelson, R. M.↗

MODIS Aerosol and Low‐Cloud Retrievals: Orographic Effects in the Wake of Macquarie Island

Abstract Visible/infrared imagery from passive satellites is commonly relied upon to study low cloud microphysics over oceanic regions, including for the Southern Ocean (SO), but relatively little validation has been undertaken for the SO. In this article, we compare low‐cloud effective radius ( r e ), cloud droplet number concentration ( N d ) and cloud liquid water path (LWP) retrievals from the NASA Moderate Imaging Spectroradiometer (MODIS) with surface measurements collected during the Macquarie Island Cloud and Radiation Experiment (MICRE). MODIS 3.7‐μm band retrievals show little bias and moderately good correlation relative to MICRE retrievals for liquid‐phase low clouds when restricted to Solar Zenith Angles <65° on spatial scales of 50–100 km. However, the low overall bias in 3.7‐μm band effective radius ( r e 3.7 ) retrievals partly results from cancellation of errors: r e 3.7 is overestimated for non‐to‐lightly precipitating clouds, and underestimated for heavier drizzling clouds by ∼1–1.5 μm. 1.6‐μm and 2.1‐μm band r e retrievals are biased high. N d may likewise be slightly under‐ or overestimated depending on the concentration, but there is insufficient data to provide confidence in this result. Interestingly, a composite of MODIS retrievals from 2002 to 2020 show a distinct region of enhanced cloud cover and N d (and lower r e ) in the wake of Macquarie Island associated with orographic cloud formation. MODIS retrievals of aerosol optical depth (AOD) and Angstrom Exponent (AE) upwind and downwind of the island do not differ significantly. Comparison with MICRE measurements suggests that MODIS Collection 6 AOD retrievals are reasonable, while AE is problematically large.

54 ENVIRONMENTAL SCIENCES↗

Charge balance functions for heavy-ion collisions at energies available at the CERN Large Hadron Collider

Heavy-ion collisions at the Large Hadron Collider provide the conditions to investigate regions of quark-gluon plasma that reach higher temperatures and that persist for longer periods of time compared with collisions at the Relativistic Heavy Ion Collider. This extended duration allows correlations from charge conservation to better separate during the quark-gluon plasma phase, and thus be better distinguished from correlations that develop during the hadron phase or during hadronization. Here, charge balance functions binned by relative rapidity and azimuthal angle and indexed by species are considered. A detailed theoretical model that evolves charge correlations throughout the entirety of an event is compared with preliminary results from the ALICE Collaboration. The comparison with experiment provides insight into the evolution of the chemistry and diffusivity during the collision. A ratio of balance functions is proposed to better isolate the effects of diffusion and thus better constrain the diffusivity.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Toward Realistic Dynamics of Rotating Orbital Debris, and Implications for Lightcurve Interpretation

Optical observations of rotating space debris near GEO contain important information on size, shape, composition, and rotational states, but these aspects are difficult to extract due to data limitations and the high number of degrees of freedom in the modeling process. For tri-axial rigid debris objects created by satellite fragmentations, the most likely initial rotation state has a large component of initial angular velocity directed along the intermediate axis of inertia, leading to large angular reorientations of the body on the timescale of the rotation period. This lends some support to the simplest possible interpretation of light curves -- that they represent sets of random orientations of the objects of study. However, effects of internal friction and solar radiation are likely to cause significant modification of rotation states within a time as short as a few orbital periods. In order to examine the rotational dynamics of debris objects under the influences of these effects, a set of seven first-order coupled equations of motion were assembled in state form: three are Euler equations describing the rates of change of the components of angular velocity in the body frame, and four describe the rates of change of the components of the unit quaternion. Quaternions are a four-dimensional extension of complex numbers that form a seamless, singularity-free representation of body orientation on S3. The Euler equations contain explicit terms describing torque from solar radiation in terms of spherical harmonics, and terms representing effects of a prescribed rate of internal friction. Numerical integrations of these equations of motion are being performed, and results will be presented. Initial tests show that internal friction without solar radiation torque leads to rotation about the maximum principal axis of inertia, as required, and solar radiation torque is expected to lead to spin-up of objects. Because the axis of maximum rotational inertia tends to be roughly coincident with the normal to the largest projected cross-sectional area, internal friction is expected to lead to reduced variation of light curve amplitudes at a given phase angle, but a large dependence of the same on phase angle. At a given phase angle, databases are generated which contain reflected intensities for comprehensive sets of equally-likely orientations, represented as unit quaternions. When projected onto three dimensions (S2) and color-coded by intensity, the set is depicted as points within a solid, semi-transparent unit sphere, within which all possible reflected intensities for an object at a given phase angle may be inspected simultaneously. Rotational sequences are represented by trajectories through the sphere. Databases are generated for each of a set of phase angles separately, forming a comprehensive dataset of reflected intensities spanning all object orientations and solar phase angles. Symmetries in the problem suggest that preferred rotation states are likely, defined relative to the object-sun direction in inertial space and relative to the maximum principal axis of inertia in the body coordinate system. Such rotation states may greatly simplify the problem of light curve interpretation by reducing the number of degrees of freedom in the problem.

Ojakangas, Gregory W.↗

Unfolder-based single-stage AC-AC conversion system

An power converter includes an unfolder connected to a three-phase source and has an output connection with a positive terminal, a negative terminal and a neutral terminal. The unfolder creates two unipolar piece-wise sinusoidal DC voltage waveforms offset by a half of a period. A three-input converter connected to the unfolder produces a quasi-sinusoidal output voltage across output terminals. Switches of the converter selectively connect the positive, negative and neutral inputs across the output terminals. A PWM controller controls a first duty ratio and a second duty ratio for the converter based on a phase angle of the source and a modulation index generated from an error signal related to a control variable. The duty ratios are time varying with a fundamental frequency of the source. The modulation index relates to output voltage of the converter, peak voltage or current of the source and/or peak current at the output terminals.

Teeneti, Chakridhar Reddy↗

Unfolder-based single-stage AC-AC conversion system

A power converter includes an unfolder connected to a three-phase source and has an output connection with three output terminals. A three-input converter connected to the unfolder produces a quasi-sinusoidal output voltage across converter output terminals. Switches of the converter selectively connect each of the three output terminals across the converter output terminals. A pulse-width modulation controller controls a first duty ratio and a second duty ratio for the converter based on a phase angle of the source and a modulation index generated from an error signal related to a control variable. The duty ratios are time varying at a rate related to a fundamental frequency of the source. The modulation index relates to output voltage of the converter, peak voltage or current of the source and/or peak current at the output terminals.

Teeneti, Chakridhar Reddy↗

The atom-molecule reaction D plus H2 yields HD plus H studied by molecular beams

Collisions between deuterium atoms and hydrogen molecules were studied in a modulated crossed beam experiment. The relative signal intensity and the signal phase for the product HD from reactive collisions permitted determination of both the angular distribution and HD mean velocity as a function of angle. From these a relative differential reactive scattering cross section in center-of-mass coordinates was deduced. The experiment indicates that reactively formed HD which has little or no internal excitation departs from the collision anisotropically, with maximum amplitude 180 deg from the direction of the incident D beam in center-of-mass coordinates, which shows that the D-H-H reacting configuration is short-lived compared to its rotation time. Non reactive scattering of D by H2 was used to assign absolute values to the differential reactive scattering cross sections.

Geddes, J.↗