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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Pumped Storage Hydropower Augmented with Pressurized Air: The Ground-Level Integrated Diverse Energy Storage (GLIDES) System — GLIDES System Configurations and Use Cases

Energy storage is essential for cost-effective integration of variable renewable energy sources to support a low-carbon grid. It is also a key enabler of a modern grid infrastructure for demand management. However, several main challenges remain for different kind of energy storage technologies in grid scale deployment. Currently, the largest source of utility-scale storage and long-duration storage in the US is pumped storage hydropower (PSH). Prospect of growth in conventional PSH faces challenges that have limited its deployment over the last three decades, including high capital costs and long deployment timelines. Batteries have high energy densities and are the primary technology of choice for small-scale energy storage. Compressed air energy storage (CAES) is another large-scale energy storage technology, but there are few plants deployed worldwide. They suffer from their low round trip efficiency (RTE) due to the use of high-pressure air compressors. To address some of the challenges associated with these various storage technologies, the Ground-Level Integrated Diverse Energy Storage (GLIDES) is a modular PSH technology that was invented in 2015 at Oak Ridge National Laboratory. It utilizes gas compression to store electric energy. GLIDES stores energy by compressing gas using a liquid piston in high-pressure vessels. In doing so the vessels act as the upper reservoir in conventional PSH. Initially, the vessels are filled with gas to a prescribed pressure. To store energy, GLIDES uses a hydraulic piston pump to pump water into the pressurized vessels. As the water volume increases inside the vessels, water acts as a hydraulic piston compressing the gas on top of it. This process can be thought of as pumping water from the lower reservoir to the higher reservoir in PSH, increasing the water head. To dispatch the stored energy, the high-head water in the vessel is discharge through a high head Pelton hydraulic turbine that is connected to an electric generator. Employing high-pressure vessels enables GLIDES to reach water heads ~10-80 times higher than conventional PSH, achieving ~40 times higher energy densities, and overcomes the geographic limitation of conventional PSH. Although its energy density is much lower than that of batteries, GLIDES holds the potential advantages of having long service life, ease of system integration and being less hazardous over batteries. GLIDES prospective scalability could make it suitable for wide range of applications from behind the meter storage in buildings to grid-scale storage. It also makes it suitable for installations in densely populated urban areas where energy storage is most needed and real estate is limited. Over the last 5 years, work has focused on increasing GLIDES’ energy density, decreasing its initial capital cost of the system, and increasing its revenue potential. Several designs were developed and prototyped to verify and demonstrate the improvement in energy density. The latest prototype achieved energy density of 1.21 kWh/m 3 . Our analysis showed that it could achieve up to 1.7 kWh/m 3 with a mixture of air and carbon dioxide as the gas being compressed.

13 HYDRO ENERGY↗

Bench-Scale Development of Promoted High-Capacity Structured Sorbents (Final Technical Report)

The project objective was to develop high-capacity structured sorbent capable of achieving low CO 2 removal from air. The sorbent framework consists of an amine-functionalized onto hydrophobic polymer backbone with an added promoter. The functionalized amine provides high CO 2 capacity and adsorption rates and the polymer backbone to reduce water uptake. For the sorbent development, multiple functionalized amines and promoters were assessed to select a candidate that achieved high CO 2 capacity, high adsorption rate, and high stability. A sorbent-coated filter design was selected as the structured sorbent, which provides high sorbent loading capacity and contains an electrically conductive nonwoven filter substrate that can be Joule-heated to provide efficient utilization of available electricity for sorbent regeneration. A commercial partner operated a pilot filter manufacturing line to produce the filter panels coated with the developed sorbent. A 1 kg CO 2 /day bench unit was designed and fabricated to test the structured filter sorbent. The key achievements from the structured sorbent development activity were demonstrating that existing filter industrial-scale processes can be used for manufacturing Susteon’s structured sorbent and completing a proof-of-concept demonstration of the commercially manufactured structured sorbent filters for CO 2 capture from air with direct, Joule-heated regeneration. A techno-economic assessment with sensitivity analysis was conducted on a 100,000 TPY facility with 85% operating capacity. Through sorbent optimization and process design improvements, it is estimated that the cost of capture was reduced from $\$$349/tCO 2 to $\$$241/tCO 2 . The TEA projects further reductions to $165/tCO 2 through enhancements in CO 2 adsorption rate and sorbent capacity and reducing manufacturing and scale up risks. A life cycle analysis was conducted on the same 100,000 TPY facility and confirmed that the facility’s electricity demand drives its greenhouse gas impact. It was determined that electricity supplied through the current grid mix would result in net-positive CO 2 emissions and that achieving net-negative emissions is only possible by powering the system with renewable electricity or fossil fuel sources equipped with carbon capture and sequestration.

36 MATERIALS SCIENCE↗

Editorial: Separations for Energy and Environmental Applications

Climate change and global environmental impacts are challenging humanity as a whole, and particularly the scientific community, to rethink our approaches towards energy harvesting, storage, and utilization, and to formulate processes geared to restoring compromised environments. A large task in these efforts involves developing technologies that have low or no carbon footprint, enable the use of renewable energy sources, and minimize or eliminate contamination of water resources and generation of untreatable waste.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Utilizing high-resolution genetic markers to track population-level exposure of migratory birds to renewable energy development

With new motivation to increase the proportion of energy demands met by zero-carbon sources, there is a greater focus on efforts to assess and mitigate the impacts of renewable energy development on sensitive ecosystems and wildlife, of which birds are of particular interest. One challenge for researchers, due in part to a lack of appropriate tools, has been estimating the effects from such development on individual breeding populations of migratory birds. To help address this, we utilize a newly developed, high-resolution genetic tagging method to rapidly identify the breeding population of origin of carcasses recovered from renewable energy facilities and combine them with maps of genetic variation across geographic space (called ‘genoscapes’) for five species of migratory birds known to be exposed to energy development, to assess the extent of population-level effects on migratory birds. We demonstrate that most avian remains collected were from the largest populations of a given species. In contrast, those remains from smaller, declining populations made up a smaller percentage of the total number of birds assayed. Results suggest that application of this genetic tagging method can successfully define population-level exposure to renewable energy development and may be a powerful tool to inform future siting and mitigation activities associated with renewable energy programs.

14 SOLAR ENERGY↗

Renewable Polyurethanes from Sustainable Biological Precursors

Due to the depletion of fossil fuels, higher oil prices, and greenhouse gas emissions, the scientific community has been conducting an ongoing search for viable renewable alternatives to petroleum-based products, with the anticipation of increased adaptation in the coming years. New academic and industrial developments have encouraged the utilization of renewable resources for the development of ecofriendly and sustainable materials, and here, we focus on those advances that impact polyurethane (PU) materials. Vegetable oils, algae oils, and polysaccharides are included among the major renewable resources that have supported the development of sustainable PU precursors to date. Renewable feedstocks such as algae have the benefit of requiring only sunshine, carbon dioxide, and trace minerals to generate a sustainable biomass source, offering an improved carbon footprint to lessen environmental impacts. Incorporation of renewable content into commercially viable polymer materials, particularly PUs, has increasing and realistic potential. Biobased polyols can currently be purchased, and the potential to expand into new monomers offers exciting possibilities for new product development. This Review highlights the latest developments in PU chemistry from renewable raw materials, as well as the various biological precursors being employed in the synthesis of thermoset and thermoplastic PUs. We also provide an overview of literature reports that focus on biobased polyols and isocyanates, the two major precursors to PUs.

09 BIOMASS FUELS↗

Optimizing an Integrated Solar-Electrolysis System (CRADA CRD-18-749 Final Report)

Electrolysis powered by renewable sources provides a range of potential values such as carbon-free fuel for power, heat, or transportation; storage; and ancillary grid services. Each of these potential benefits has been studied as individual value streams. However, real-world demonstrations of these benefits working in concert are limited in the United States today as electrolyzers lack access to wholesale electricity prices. High power prices make electrolysis uncompetitive compared to traditional steam methane reformation (SMR). A potentially cost-effective way to demonstrate the value of renewable electrolysis is by powering an electrolyzer directly from a renewable generation source rather than from the electric grid. Integrated with a renewable generation source, the cost of fueling an electrolyzer is the opportunity cost of not selling power from the renewable plant to the grid - effectively, the wholesale electricity price. Additionally, an electrolyzer tied directly to a renewable generator potentially reduces excess generation and increases the value of the ancillary services that the renewable generator can provide to the grid.

08 HYDROGEN↗

Enhancing Site Screening for Underground Hydrogen Storage: Qualitative Site Quality Assessment - SHASTA: Subsurface Hydrogen Assessment, Storage, and Technology Acceleration Project

The global shift towards renewable energy sources to mitigate fossil fuel dependency and meet carbon emission targets by 2050 has underscored the importance of innovative solutions to address energy supply-demand imbalances. Underground Hydrogen Storage (UHS) has emerged as a promising strategy to store excess renewable energy in subsurface formations for future retrieval and utilization. This report focuses on enhancing the site screening process for UHS facilities. By drawing on insights from prior research to identify key criteria influencing site suitability, our objective is to present a comprehensive set of sixteen specific criteria essential for refining the selection of UHS sites. These criteria cover various aspects such as reservoir performance, legal access, regulatory compliance, economic viability, public acceptance, and safety and security considerations. Our proposed methodology allows users to evaluate potential sites using binary responses, transitioning from isolated factors to broader considerations that facilitate a qualitative assessment of site suitability. This method enables comparative analysis and informed decision-making, supporting stakeholders in the site selection process. Our approach is designed as a guiding framework rather than a rigid template for site screening, emphasizing the importance of customizing approaches to individual circumstances. As UHS site development project evolves, adopting a comprehensive selection methodology that integrates holistic evaluations will be essential for ensuring efficient and effective site screening processes tailored to specific project needs.

08 HYDROGEN↗

Enhancing Site Screening for Underground Hydrogen Storage: Qualitative Site Quality Assessment - SHASTA: Subsurface Hydrogen Assessment, Storage, and Technology Acceleration Project

The global shift towards renewable energy sources to mitigate fossil fuel dependency and meet carbon emission targets by 2050 has underscored the importance of innovative solutions to address energy supply-demand imbalances. Underground Hydrogen Storage (UHS) has emerged as a promising strategy to store excess renewable energy in subsurface formations for future retrieval and utilization. This report focuses on enhancing the site screening process for UHS facilities. By drawing on insights from prior research to identify key criteria influencing site suitability, our objective is to present a comprehensive set of sixteen specific criteria essential for refining the selection of UHS sites. These criteria cover various aspects such as reservoir performance, legal access, regulatory compliance, economic viability, public acceptance, and safety and security considerations. Our proposed methodology allows users to evaluate potential sites using binary responses, transitioning from isolated factors to broader considerations that facilitate a qualitative assessment of site suitability. This method enables comparative analysis and informed decision-making, supporting stakeholders in the site selection process. Our approach is designed as a guiding framework rather than a rigid template for site screening, emphasizing the importance of customizing approaches to individual circumstances. As UHS site development project evolves, adopting a comprehensive selection methodology that integrates holistic evaluations will be essential for ensuring efficient and effective site screening processes tailored to specific project needs.

08 HYDROGEN↗

More Than Recycling: How Should We Define Circularity Goals for PV in a Global Energy Transition? Preprint

Energy transition to carbon-free electricity is a crucial pillar of the Circular Economy. Renewable energy reduces environmental impacts and decarbonizes the production of other goods. But, manufacturing renewable energy sources, such as photovoltaic (PV) modules, require energy inputs that are currently carbon intensive. So, how do we decarbonize and circularize these critical technologies to achieve a sustainable energy transition? This work proposes that effective capacity-the installed capacity accounting for degradation rates and failures-is a critical metric to evaluate renewable energy technologies on the path toward circular economy and energy transitions. Our analyses also emphasize the importance of examining a suite of metrics incorporating mass and energy flows to identify potential tradeoffs and inform design or lifecycle management decisions holistically.

bifacial↗

More Than Recycling: The Importance of Multiple Metrics for a Circular Economy for PV in the Energy Transition

Energy transition to carbon-free electricity is a crucial pillar of the Circular Economy. Renewable energy reduces environmental impacts and decarbonizes the production of other goods. But, manufacturing renewable energy sources, such as photovoltaic (PV) modules, require energy inputs that are currently carbon intensive. So, how do we decarbonize and circularize these critical technologies to achieve a sustainable energy transition? This work proposes that effective capacity-the installed capacity accounting for degradation rates and failures-is a critical metric to evaluate renewable energy technologies on the path toward circular economy and energy transitions. Our analyses also emphasize the importance of examining a suite of metrics incorporating mass and energy flows to identify potential tradeoffs and inform design or lifecycle management decisions holistically.

bifacial↗

Observed impacts of large wind farms on grassland carbon cycling

Deployment of wind energy is an essential renewable energy source that mitigates climate change and reduces air pollution. Over the last several decades, wind energy development has increased worldwide, expanding from ~20 to ~900 GW (gigawatt) during 2001-2022. Nonetheless, researchers have identified unintended consequences of wind energy on microclimate via turbine-altered surface-atmosphere exchanges of energy, momentum, mass, and trace gases. Based on multi-source observations and models, researchers also have drawn some conclusions that wind farms could warm the land surface, especially at night, at regional and continental scales. Consequently, altered microclimates at wind farms may affect vegetation productivity and carbon sequestration, two critically important ecosystem services related to carbon dynamics; however, such potential impacts and driving mechanisms remain poorly understood. Wind energy deployment is increasing globally to meet carbon neutrality goals, with upscaling of onshore wind power capacity projected to grow from 542 GW in 2018 to 1787 and 5044 GW by 2030 and 2050, respectively. Furthermore, increased demand for wind energy deployment may lead to much larger wind farms in open, expansive landscapes. In turn, a large array of geographically clustered wind turbines could collectively modify local microclimate and amplify turbine-atmosphere interactions, which, if large enough, may produce detectable impacts on ecosystem dynamics. Thus, identifying and quantifying the potential impacts of wind farms on carbon-related ecosystem services may facilitate sustainable wind energy development globally.

17 WIND ENERGY↗

Metabolic rewiring and biomass redistribution enable optimized mixotrophic growth in Chlamydomonas

Aquatic photosynthetic systems account for approximately one-half of all global carbon assimilation and could be a significant source of renewable fuels and feedstocks. However, rapid growth and biomass production in algae have not always translated into high product yields, partly because central metabolism is context specific, with metabolic fluxes being influenced by nutrient conditions and other environmental factors. In the green microalga Chlamydomonas reinhardtii (Chlamydomonas), mixotrophic cultures (acetate + light) grow far faster than phototrophic (light only) or heterotrophic (acetate + dark) cultures, even though acetate partially suppresses photosynthesis. Here, an isotopic dilution strategy with unlabeled acetate was combined with 13 CO 2 transient labeling to perform isotopically nonstationary metabolic flux analysis (INST-MFA) and to directly compare autotrophic and mixotrophic metabolism in Chlamydomonas supported by data from transcriptomics, proteomics, and metabolomics. INST-MFA indicated that acetate induces a synergistic rewiring of metabolism, conserving carbon by using the glyoxylate cycle and suppressing gluconeogenesis, the latter of which was discordant with omics results and prior models. Additionally, our data provide a plausible rationale for the well-known suppression of photosynthesis by acetate. We propose that reduced total protein content in mixotrophic versus phototrophic cells, much of which is attributed to reduced levels of photosynthetic proteins, decreases the costly metabolic burden of protein synthesis and represents a growth rate optimization strategy.

59 BASIC BIOLOGICAL SCIENCES↗

Materials for electrification of everything: Moving toward sustainability

We report society is at a unique tipping point in a move from conventional fossil fuel based technologies to renewable sourced electrified technologies which can enable creating a carbon neutral or carbon negative energy economy. Many of the key approaches to achieving this transition in the critical areas of transportation, buildings and manufacturing depend on new materials and new approaches to rapidly increase electrification. This article reviews the overall energy landscape and highlights specific areas where new materials are critical to enabling transitions in energy storage, hydrogen utilization, transportation, buildings and the chemical industry and the articles on these topics that follow. How these transitions can be best integrated and the global societal impact of these transitions is also discussed. The development of new materials is instrumental in accelerating the move to a cleaner electrified society. The "electrification of everything" is increasingly important if we are to mitigate the adverse effects of climate change and materials will play a critical role realizing this goal.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

liionpack: A Python package for simulating packs of batteries with PyBaMM

Electrification of transport and other energy intensive activities is of growing importance as it provides an underpinning method to reduce carbon emissions. With an increase in reliance on renewable sources of energy and a reduction in the use of more predictable fossil fuels in both stationary and mobile applications, energy storage will play a pivotal role and batteries are currently the most widely adopted and versatile form. Therefore, understanding how batteries work, how they degrade, and how to optimize and manage their operation at large scales is critical to achieving emission reduction targets. The electric vehicle (EV) industry requires a considerable number of batteries even for a single vehicle, sometimes numbering in the thousands if smaller cells are used, and the dynamics and degradation of these systems, as well as large stationary power systems, is not that well understood. As increases in the efficiency of a single battery become diminishing for standard commercially available chemistries, gains made at the system level become more important and can potentially be realised more quickly compared with developing new chemistries. Mathematical models and simulations provide a way to address these challenging questions and can aid the engineer and designers of batteries and battery management systems to provide longer lasting and more efficient energy storage systems.

25 ENERGY STORAGE↗

Battery Energy Storage Scenario Analyses Using the Lithium-Ion Battery Resource Assessment (LIBRA) Model

Meeting aggressive carbon emission goals will entail widespread deployment of renewable sources of electricity. Because these sources are variable, there is a need to develop scalable energy storage technologies. The U.S. Department of Energy is supporting efforts to increase U.S. manufacturing and recycling capabilities for LIBs and to decrease costs of stationary storage batteries. Many factors influence the domestic manufacturing and cost of stationary storage batteries, including availability of critical raw materials (lithium, cobalt, and nickel), competition from various demand sectors (consumer electronics, vehicles, and battery energy storage), resource recovery (recycling), government policies, and learning in the industry, among other factors. Understanding how these factors interact and identifying synergies and bottlenecks is important for developing effective strategies for the LIB stationary energy storage system. We developed the Lithium-Ion Battery Resource Analysis (LIBRA) model as a tool to help stakeholders better understand the following types of questions: What are the roles of R&D, industrial learning, and scaling of demand in lowering the cost of battery energy storage system production? How do the intersections between the EV and stationary storage sectors affect the battery supply chain? For various stationary storage and EV penetration scenarios, what volumes of critical materials might be required and what role can resource recovery play? What does expected demand for both EVs and stationary storage portend for mineral resources and overall mineral scarcity? The LIBRA model is developed using a System dynamics (SD) modeling approach to represent interactions across the segments of the battery materials supply chain. System dynamics models can capture the complex interactions and feedback between the various system components that influence supply and demand. The LIBRA model is comprised of several interacting modules that represent specific portions of the LIB supply chain. The model tracks the buildout of the domestic LIB industry over time (2020 - 2050) and in the context of competing demands for raw materials, recycling, and markets for LIBs. The LIBRA model represents major systemic feedback loops and delays across the supply chain. This report provides a complete documentation for the LIBRA model, including model assumptions, data, scenario analysis results, and sensitivity analysis of the model's input space.

25 ENERGY STORAGE↗

Turning Food Waste into Biobased Products (CRADA Final Report)

As part of the Cyclotron Road program, the ZestBio project team investigated the production of chemical products from industrial agricultural byproducts and sustainable carbon sources. The goal of the research was to explore methods of manufacturing of new chemical products from renewable carbon that could address growing consumer and regulatory demands for environmentally-friendly and biobased chemicals. Previously, ZestBio and the technical founders developed enzymatic and chemical conversion technologies that transform abundant sugars found in these byproducts into value-adding, high performance chemicals.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Rheological Characterization of Biomass Feedstock for Alternative Energy Applications

With the increased necessity of alternative energy resources, bulk feedstock biomass materials were characterized with the purpose of replacing depleting energy supplies such as fossil fuels and other nonrenewable energy sources. Residual organic waste material (biomass) left over from agricultural processing and handling systems was recycled, and further investigated for renewable energy use. Understanding the scope of flowability for biomass material yielded more efficient, and economical crop harvesting, transporting, and storing method design for the agricultural industry. The effects of moisture on bulk solid flowability was investigated using a variety of parametric testing methods that measure basic flowability energy, and other properties such as compressibility and material resistance. In an industry where organic material is a wasteful byproduct, converting this biomass material into a new energy source and streamlining efficiently for innovative agricultural development supports a clean, renewable energy approach to everyday nonrenewable energy uses, such as oil, propane, and coal. As observed from the repeatable results from the investigated rheological material properties, biomass is an incredibly diverse material that requires modern engineering solutions to revolutionize biomass into a renewable energy source. Biomass will decarbonize petroleum (nonrenewable) derived fuels and chemicals, yielding recyclable carbon. This push to replace fossil fuels with recycled carbon is ideal because of the abundant, renewable, and otherwise agricultural waste of corn stover material. Decarburization, and reduction of C0 2 emissions reduces the effects of global warming.

09 BIOMASS FUELS↗

Energy catalysis needs ligands with high oxidative stability

Replacing fossil fuel-based energy by renewable sources is a transition that society needs to make to meet future energy demand and simultaneously address climate change. Coupling renewable energy sources with electrochemical catalysis provides a promising path to carbon-neutral fuels and chemicals when the necessary reducing equivalents and protons are harvested from water. Developing highly active, stable, and inexpensive electrocatalysts for the oxygen evolution reaction (OER) is accordingly a centerpiece of a renewable energy portfolio. Whereas viable OER catalysts are heterogeneous in nature, owing to their oxidative stability, the realization of stable molecular OER catalysts greatly expands the horizon of energy science with the ability to tune OER energetics and mechanisms with fidelity. In this perspective, current challenges in the field of molecular OER catalysis are addressed with promising lines of research that are directed to designing ligands that can withstand the harsh oxidizing environment of OER.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗