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Tunable far-infrared spectroscopy was used to measure pressure broadening of the 118.455/cm rotational lines of OH by H2, He, N2, and O2. Broadening coefficients of H2 and He were measured for the temperature range of 296 to 80 K, and N2 and O2 broadening coefficients were measured for the 296-210 K temperature range.
Our present knowledge of the molecular universe has come primarily from radio observations [ I include here millimeter and submillimeter in this rubric]. There are a number of reasons for this but the primary one is the extremely high spectral resolution. The ease of observing emission from the volume of dense molecular clouds without significant attenuation by scattering from dust has shown this to be the powerful observational tool for molecular astronomy. Finally the relative simplicity of rotational compared to vibrational or electronic spectroscopy allows carrier identification as well as facile evaluation of cloud conditions such as density and temperature. These virtues become tenuous as the astronomical observations are pushed to higher frequencies for enhanced observational sensitivity. Thus precision rest frequencies are mandatory for the search for new species. We may inquire about which new species require particular attention, and which species may be relatively safely predicted on the basis of lower frequency laboratory measurements. For a rigid rotor the three rotational constants are sufficient to completely specify the transition frequencies. The intensities require the three components of the electric dipole moment. For semirigid species, where the centrifugal distortion, may be treated at the quartic level of angular momentum (Bunker et al. 1998), up to five additional constants are required (Watson 1967). There are a number of such species of considerable interest, where laboratory measurements are adequate for astronomical searches.
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A large flare was detected simultaneously with IUE and VLA on Gl 182 on October 5, 1983, this event showing the largest C IV flare enhancement yet observed by IUE. A smaller flare was also detected on October 4, although only with the IUE satellite. Line ratio and emission measure techniques are used to derive various physical parameters of the flares. The radiative losses in the temperature region log T(e) = 4.3-5.4 in the two flares are 2.9 x 10 to the 33rd and 8.4 x 10 to the 32nd ergs, respectively. Total radiative losses over the whole temperature range log T(e) = 4.0-8.0 are estimated to be of the order of 6.4 x 10 to the 34th and 1.1 x 10 to the 34th ergs, respectively. In the October 5, flare, a very strong ultraviolet continuum is present with a total energy of 1.9 x 10 to the 33rd ergs over the wavelength range 1250-1950 A.
Submillimeter/far-IR spectroscopy was used to detect and quantify organic molecules sublimated after the ultraviolet photolysis (at 12 K) and warm-up (up to 300 K) of a methanol (CH3OH) ice sample. Eleven sublimated photoproducts were uniquely identified: carbon monoxide (CO), formaldehyde (H2CO), ketene (C2H2O), acetaldehyde (CH3CHO), ethylene oxide (CH2OCH2), vinyl alcohol (CH2CHOH), ethanol (CH3CH2OH), dimethyl ether (CH3OCH3), methyl formate (HCOOCH3), glycolaldehyde (HOCH2CHO), and acetone ((CH3)2CO). Two additional products were detected in the photolyzed ice by Fourier-transform infrared (FTIR) spectroscopy: carbon dioxide (CO2) and methane (CH4). The rotational temperatures and gas densities were calculated for the organics containing two or more C atoms via a rotation diagram analysis, and the gas-phase submillimeter/far-IR technique was used in tandem with mass spectrometry and FTIR spectroscopy of the ice during photolysis. The abundance ratios of the sublimated species (normalized to methanol) were compared to those observed in hot cores (Orion-KL, Sagittarius B2(N), and IRAS 16293-2422(B)) and in comets C/2014 Q2 (Lovejoy) and 67P/Churyumov–Gerasimenko.
Submillimeter/far-IR spectroscopy was used to detect and quantify organic molecules sublimated after the ultraviolet photolysis (at 12 K) and warm-up (up to 300 K) of a methanol (CH3OH) ice sample. Eleven sublimated photoproducts were uniquely identified: carbon monoxide (CO), formaldehyde (H2CO), ketene (C2H2O), acetaldehyde (CH3CHO), ethylene oxide (CH2OCH2), vinyl alcohol (CH2CHOH), ethanol (CH3CH2OH), dimethyl ether (CH3OCH3), methyl formate (HCOOCH3), glycolaldehyde (HOCH2CHO), and acetone ((CH3)2CO). Two additional products were detected in the photolyzed ice by Fourier-transform infrared (FTIR) spectroscopy: carbon dioxide (CO2) and methane (CH4). The rotational temperatures and gas densities were calculated for the organics containing two or more C atoms via a rotation diagram analysis, and the gas-phase submillimeter/far-IR technique was used in tandem with mass spectrometry and FTIR spectroscopy of the ice during photolysis. The abundance ratios of the sublimated species (normalized to methanol) were compared to those observed in hot cores (Orion-KL, Sagittarius B2(N), and IRAS 16293-2422(B)) and in comets C/2014 Q2 (Lovejoy) and 67P/Churyumov–Gerasimenko.
Near-to-simultaneous ultraviolet and visual spectroscopy of two moderate nu(sin i) RS CVn systems, V815 Herculis (nu(sin i) = 27 km s(exp -1)) and LM Pegasi (nu(sin i) = 24 km s(exp -1)), are presented along with contemporaneous UBV (RI)(sub c) - band photometry. These data were used to probe inhomogeneities in the chromospheres and photospheres, and the possible relationship between them. Both systems show evidence for rotationally modulated chromospheric emission, generally varying in antiphase to the photospheric brightness. A weak flare was observed at Mg II for V815 Her. In the case of IM Peg, we use photometry and spectra to estimate temperatures, sizes, and locations of photospheric spots. Further constraints on the spot temperature is provided by TiO observations. For IM Peg, the anticorrelation between chromospheric emission and brightness is discussed in the context of a possible solar-like spot cycle.
Flexible metal seal permits rotation of object in vacuum chamber. Seal made from two cylindrical azimuthally fluted bellows attached to ends of cylindrical axially fluted bellows with connecting tubes at both ends. Designed for rotation of sample probes in electron spectroscopy for chemical analysis (ESCA), other applications likely.
Measurements were conducted at the University of Virginia Supersonic Combustion Facility of the flow in a constant-area duct downstream of a Mach 2 nozzle. The airflow was heated to approximately 1200 K in the facility heater upstream of the nozzle. Dual-pump coherent anti-Stokes Raman spectroscopy was used to measure the rotational and vibrational temperatures of N2 and O2 at two planes in the duct. The expectation was that the vibrational temperature would be in equilibrium, because most scramjet facilities are vitiated air facilities and are in vibrational equilibrium. However, with a flow of clean air, the vibrational temperature of N2 along a streamline remains approximately constant between the measurement plane and the facility heater, the vibrational temperature of O2 in the duct is about 1000 K, and the rotational temperature is consistent with the isentropic flow. The measurements of N2 vibrational temperature enabled cross-stream nonuniformities in the temperature exiting the facility heater to be documented. The measurements are in agreement with computational fluid dynamics models employing separate lumped vibrational and translational/rotational temperatures. Measurements and computations are also reported for a few percent steam addition to the air. The effect of the steam is to bring the flow to thermal equilibrium, also in agreement with the computational fluid dynamics.
Detailed analyses are performed of high-quality, phase-resolved CCD spectroscopy of the absorption-line spectrum throughout its rotation period of the new white dwarf PG 1031 + 234. The spectral variations are discussed and compared with new theoretical calculations of the behavior of hydrogen in strong magnetic fields. This analysis is then extended through a modeling procedure which produces a synthetic magnetically distorted spectrum for a star of arbitrary field strength and structure. The results confirm that PG 1031 + 234 possesses the strongest field yet detected on a white dwarf, with regions on the surface spanning the range of about 200 to nearly 1000 MG. The spectroscopic data reflect a field pattern containing a slightly offset global component of polar field strength of about 500 MG together with a localized magnetic 'spot' whose central field approaches 2000 MG.
We discuss airborne observations of rotational transitions of various hydride molecules in the interstellar medium, including H2O-18 and HCl. The detection of these transitions is now feasible with a new, sensitive submillimeter receiver which has been developed for the NASA Kuiper Airborne Observatory (KAO) over the past several years.
KELT-9 b is an ultra-hot Jupiter transiting a rapidly rotating, oblate early-A-type star in a polar orbit. We model the effect of rapid stellar rotation on KELT-9 b’s transit light curve using photometry from the Transiting Exoplanet Survey Satellite to constrain the planet’s true spin–orbit angle and to explore how KELT-9 b may be influenced by stellar gravity darkening. We constrain the host star’s equatorial radius to be 1.089±0.017 times as large as its polar radius and its local surface brightness to vary by∼38% between its hot poles and cooler equator. We model the stellar oblateness and surface brightness gradient and find that it causes the transit light curve to lack the usual symmetry around the time of minimum light. We take advantage of the light-curve asymmetry to constrain KELT-9b’s true spin–orbit angle (87degree+ -10degrees/-11degrees), agreeing with Gaudi et al. that KELT-9 b is in a nearly polar orbit. We also apply a gravity-darkening correction to the spectral energy distribution model from Gaudi et al. and find that accounting for rapid rotation gives a better fit to available spectroscopy and yields a more reliable estimate for the star’s polar effective temperature.
Volatile production rates, relative abundances, rotational temperatures, and spatial distributions in the coma were measured in C/2012 S1 (ISON) using long-slit high-dispersion (lambda/delta lambda approximately 2.5 times 10 (sup 4)) infrared spectroscopy as part of a worldwide observing campaign. Spectra were obtained on Universal Time 2013 October 26 and 28 with NIRSPEC (Near Infrared Spectrometer) at the W.M. Keck Observatory, and Universal Time 2013 November 19 and 20 with CSHELL (Cryogenic Echelle Spectrograph) at the NASA IRTF (Infrared Telescope Facility). H2O was detected on all dates, with production rates increasing markedly from (8.7 plus or minus 1.5) times 10 (sup 27) molecules per second on October 26 (Heliocentric Distance = 1.12 Astronomical Units) to (3.7 plus or minus 0.4) times 10 (sup 29) molecules per second on November 20 (Heliocentric Distance = 0.43 Astronomical Units). Short-term variability of H2O production is also seen as observations on November 19 show an increase in H2O production rate of nearly a factor of two over a period of about 6 hours. C2H6, CH3OH and CH4 abundances in ISON (International Scientific Optical Network) are slightly depleted relative to H2O when compared to mean values for comets measured at infrared wavelengths. On the November dates, C2H2, HCN and OCS abundances relative to H2O appear to be within the range of mean values, whereas H2CO and NH3 were significantly enhanced. There is evidence that the abundances with respect to H2O increased for some species but not others between October 28 (Heliocentric Distance = 1.07 Astronomical Units) and November 19 (Heliocentric Distance = 0.46 Astronomical Units). The high mixing ratios of H2CO to CH3OH and C2H2 to C2H6 on November 19, and changes in the mixing ratios of some species with respect to H2O between October 28 to November 19, indicates compositional changes that may be the result of a transition from sampling radiation-processed outer layers in this dynamically new comet to sampling more pristine natal material as the outer processed layer was increasingly eroded and the thermal wave propagated into the nucleus as the comet approached perihelion for the first time. On November 19 and 20, the spatial distribution for dust appears asymmetric and enhanced in the antisolar direction, whereas spatial distributions for volatiles (excepting CN) appear symmetric with their peaks slightly offset in the sunward direction compared to the dust. Spatial distributions for H2O, HCN, C2H6, C2H2, and H2CO on November 19 show no definitive evidence for significant contributions from extended sources; however, broader spatial distributions for NH3 and OCS may be consistent with extended sources for these species. Abundances of HCN and C2H2 on November 19 and 20 are insufficient to account for reported abundances of CN and C2 in ISON near this time. Differences in HCN and CN spatial distributions are also consistent with HCN as only a minor source of CN in ISON on November 19 as the spatial distribution of CN in the coma suggests a dominant distributed source that is correlated with dust and not volatile release. The spatial distributions for NH3 and NH2 are similar, suggesting that NH3 is the primary source of NH2 with no evidence of a significant dust source of NH2; however, the higher production rates derived for NH3 compared to NH2 on November 19 and 20 remain unexplained. This suggests a more complete analysis that treats NH2 as a distributed source and accounts for its emission mechanism is needed for future work.
The ionization potential of O2 was measured by the technique of high resolution photoelectron spectroscopy taking into account the influence of rotational structure on the shape of the vibrational bands. A value of 12.071 + or - .001 eV (1027.1 + or - 0.1 A) was found for the ionization potential. A lowering of the ionization potential caused by a branch-head when delta N = -2 gave an appearance potential for ionization of 12.068 + or - .001 eV (1027.4 + or - 0.1 A).
The Gas in Protoplanetary Systems (GASPS) Open Time Key Programme for the Herschel Space Observatory will be the first extensive, systematic survey of gas in circumstellar disks over the critical transition from gas-rich protoplanetary through to gas-poor debris. The brightest spectral lines from disks lie in the far-infrared and arise from radii spanning roughly 10 to 100 AU, where giant planets are expected to form. Herschel is uniquely able to observe this wavelength regime with the sensitivity to allow a large scale survey. We will execute a 2-phase study using the PACS instrument. Phase I is a spectroscopic survey about 250 young stars for fine structure emission lines of [CII] (at 157 microns) and [OI] (at 63 microns). In Phase II, the brightest sources will be followed up with additional PACS spectroscopy ([OI] at 145 microns and some rotational lines of water). We expect that the gas mass sensitivity will be more than an order of magnitude lower than that achieved by ISO and Spitzer or expected for SOFIA. We will also measure the dust continuum to an equivalent mass sensitivity. We will observe several nearby clusters with ages from 1 to 30 Myr, encompassing a wide range of disk masses and stellar luminosities. The sample covers disk evolution from protoplanetary disks through to young debris disks, i.e. the main epoch of planet formation. With this extensive dataset, the GASPS project will: 1) trace gas and dust in the planet formation region across a large multivariate parameter space, 2) provide the first definitive measurement of the gas dissipation timescale in disks, 3) elucidate the evolutionary link between protoplanetary and debris disks, 4) investigate water abundances in the planetforming regions of disks, and 5) provide a huge database of disk observations and models with long-lasting legacy value for follow-up studies.
The time-resolved IR double-resonance spectroscopy apparatus and procedures described by Millot et al. (1988) are used to measure the relaxation times of rotational levels in the v3 =1 state of O3. Findings reported include (1) total rotational cross sections about 20-70 percent larger than the Lennard-Jones collision cross section, consistent with an interaction dominated by dipole-dipole forces; (2) equal relaxation cross sections in the upper and lower vibrational states; (3) an estimated pressure-broadening cross section of 185 sq A, with less than 10 percent due to dephasing; (4) no strong Ka dependence of rotational relaxation rates at Ka = 4-8 in J of about 16; (5) a rate for J = 8 and Ka = 7 about 40 percent larger than the other values measured, in agreement with the pressure-broadening model of Gamache and Rothman (1985); and (6) a V-V energy-transfer rate between v3 = 1 and v1 = 1 of (2.5 + or - 0.5) x 10 to the 6th/torr sec.
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Pressure-broadening coefficients and pressure-induced lineshifts of several rotational-vibrational lines have been measured in the 727 nm absorption band of methane at temperatures of 77 and 296 K, using nitrogen, hydrogen, and helium as the foreign-gas collision partners. A technique involving intracavity laser spectroscopy is used to record the methane spectra. Average values of the broadening coefficients (/cm/atm) at 77 K are: 0.199, 0.139, 0.055, and 0.29 for collision partners N2, H2, He, and CH4, respectively. Typical average values of the pressure-induced lineshifts (/cm/atm) at 77 K and for the range of foreign gas pressures between 10 and 200 torr are -0.052 for N2, -0.063 for H2, and +0.031 for He. All the values obtained at 296 K are considerably different from the corresponding values at 77 K. This represents the first report of pressure-broadening and shifting coefficients for the methane transitions in a region where the delta nu(sub C-H) = 5 band occurs.