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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

Maps Suggest Transport and Source Processes of PM2.5 at 1 km x 1 km for the Whole San Joaquin Valley, Winter 2011 (Generalizations from DISCOVER-AQ)

We present interpreted data analysis using MAIAC (Multiangle implementation of Atmospheric Correction) retrievals and appropriate RAPid Update Cycle (RAP) meteorology to map respirable aerosol (PM2.5) for the period January and February, 2011. The San Joaquin Valley is one of the unhealthiest regions in the USA for PM2.5 and related morbidity. The methodology evaluated can be used for the entire moderate-resolution imaging spectrometer (MODIS, VIIRS) data record. Other difficult areas of the West: Riverside, CA, Salt Lake City, UT, and Doa Ana County, NM share similar difficulties and solutions. The maps of boundary layer depth for 1116 hr local time from RAP allows us to interpret aerosol optical thickness as a concentration of particles in a nearly well-mixed box capped by clean air. That mixing is demonstrated by DISCOVER-AQ data and afternoon samples from the airborne measurements, P3B (on-board) and B200 (HSRL2 lidar). This data and the PM2.5 gathered at the deployment sites allowed us to estimate and then evaluate consistency and daily variation of the AOT to PM2.5 relationship. Mixed-effects modeling allowed a refinement of that relation from day to day; RAP mixed layers explained the success of previous mixed-effects modeling. Compositional, size-distribution, and MODIS angle-of-regard effects seem to describe the need for residual daily correction beyond ML depth.We report on an extension method to the entire San Joaquin Valley for all days with MODIS imagery using the permanent PM2.5 stations, evaluated for representativeness. Resulting map movies show distinct sources, particularly Interstate-5 (at approx. 1km x 1km resolution) and the broader Bakersfield area. Accompanying winds suggest transport effects and variable pathways of pollution cleanout. Such estimates should allow morbiditymortality studies. They should be also useful for actual model assimilations, where composition and sources are uncertain. We conclude with a description of new work to extend these insights to similar regions, e.g. interior valleys of California, the Po Valley, the Mediterranean litoral, and the Ganges Plain.This work show generalizable use of remote sensing, a major goal of DISCOVER-AQ, Deriving Information on Surface Conditions from COlumn and VERtically Resolved Observations Relevant to Air Quality.

Chatfield, R.↗
NASA NTRS2010

Recent Advances in Laboratory Infrared Spectroscopy of Polycyclic Aromatic Hydrocarbons: PAHs in the Far Infrared

Over 25 years of observations and laboratory work have shown that the mid-IR spectra of a majority of astronomical sources are dominated by emission features near 3.3, 6.2, 7.7, and 11.2 microns, which originate in free polycyclic aromatic hydrocarbon (PAH) molecules. PAHs dominate the mid-IR emission from many galactic and extragalactic objects. As such, this material tracks a wide variety of astronomical processes, making this spectrum a powerful probe of the cosmos Apart from bands in the mid-IR, PAHs have bands spanning the Far-IR (FIR) and emission from these FIR features should be present in astronomical sources showing the Mid-IR PAH bands. However, with one exception, the FIR spectral characteristics are known only for a few neutral small PAHs trapped in salt pellets or oils at room temperature, data which is not relevant to astrophysics. Furthermore, since most emitting PAHs responsible for the mid-IR astronomical features are ionized, the absence of any experimental or theoretical PAH ion FIR spectra will make it impossible to correctly interpret the FIR data from these objects. In view of the upcoming Herschel space telescope mission and SOFIA's FIR airborne instrumentation, which will pioneer the FIR region, it is now urgent to obtain PAH FIR spectra. This talk will present an overview recent advances in the laboratory spectroscopy of PAHs, Highlighting the FIR spectroscopy along with some quantum calculations.

Mattioda, Andrew L.↗
DOE OSTI2023

Reducing impacts of artificial ponding in modeling salt marshes using a conductivity-formulated subgrid model

The landforms of salt marsh systems are rather complex, with meandering channel networks cutting through low-lying, extensive marsh platforms. Some small-scale topographic details are critical to flooding and draining processes but cannot be reflected in the Digital Elevation Model (DEM) due to limited measurement resolution and vegetation bias. Numerical models need a grid with high enough resolution to capture the small-scale connectivity to correctly model the small-scale flow processes, making the model computationally unaffordable. Here, in this study, we derived a subgrid model, which couples two flow components, one is the regular subgrid model for simulating the subgrid-resolved flows, and the other is a conductivity-formulated porous flow model for modeling small-scale gut flows unresolved at the subgrid level. The model validation was performed using an idealized case with a narrow slot that was unresolved in the coupled flow model. Model results were compared with a slot-resolved regular subgrid model where only surface flows are solved and suggested that, with a proper model parameterization, the coupled flow model is capable of reproducing flooding and draining processes similar to the slot-resolved subgrid model of surface flow. The model was applied to simulating flooding and draining processes in a meso-tidal salt marsh. The model results demonstrate that the coupled subgrid model can be used to reduce the impacts of artificial ponding that usually occur in numerical simulations of salt marshes with numerous narrow gullies and creeks.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Low-temperature electroplating of zirconium: Ionic mixture methods

Non-aqueous ionic mixture electroplating allows for room-temperature or near-room-temperature applications of thin metal films, typically metals for which aqueous solvents cannot be used. While there are many methods of plating zirconium, each has disadvantages that ionic liquid plating could correct. However, ionic liquid plating requires further research and development, as a new class of solvents were only developed a few years ago. Current ionic liquids cost several thousand dollars per liter, yet produce films with less than 90% surface coverage as well as deposition of salt species that enable interdiffusion through the Zr. Film coverage needs to be increased while maintaining approximate room temperatures and lower solvent costs. Current ionic liquid technology has suffered from poor surface wetting and limited Zr diffusivity leading to dendrite formation which inhibits total surface coverage. Zr electroplating can be improved by application of room-temperature ionic mixtures as the plating medium. We have successfully demonstrated the capability to plate high-quality metallic zirconium layers using deep eutectic solvents (DES) and DES-ionic liquid (IL) mixtures. Plating thicknesses of up to 6 microns have been achieved, and the coatings are conformal to the substrate and not dendritic, with low contamination from the plating solution. Our current method uses the DES ethaline (a 1:2 ratio of choline chloride and ethylene glycol) to complex zirconium (IV) ions (present via the addition of ZrF4). We pulse plate the Zr from a bath with an overabundance of LiF, in accordance with prior literature. We have also had success in mixing the DES with ILs, such as Triethylsulfonium bis(trifluoromethylsulfonyl)imide, 1-Butyl-3-methylpyridinium bis(trifluormethylsulfonyl)imide, Methyl-trioctylammonium bis(trifluoromethylsulfonyl)imide, and Diethylmethyl(2-methoxyethyl)ammonium bis(trifluoromethylsulfonyl)imide.

36 MATERIALS SCIENCE↗
NASA NTRS1973

Remote measurement of salinity in an estuarine environment.

The microwave emission of sea water is dependent upon salinity in the low microwave spectrum, and it appears possible to measure remotely surface salinity at 21-cm wavelength with an accuracy up to one part salt per thousand parts water (.1%) for a .5 to 3.5% salinity range. The dielectric constant of sea water can be represented by that of NaCl, except that the sea water conductivity is retained. The effects of the atmosphere, cosmic noise, sea surface roughness, and constant radiometer errors can be corrected by using surface calibration measurements. In experiments performed in Mississippi and Louisiana coastal waters salinity accuracies of .3 to .5 were obtained. It is believed that the accuracy was limited by the radiometer used.

Thomann, G. C.↗
DOE OSTI2025

Recent Improvements in Pronghorn for Advanced Reactor Modeling

Pronghorn is a thermal-hydraulics computational tool developed using the Idaho National Laboratory's Multiphysics Object-Oriented Simulation Environment (MOOSE). It is designed to support Computational Fluid Dynamics (CFD) modeling, ranging from subchannel and porous media analysis to Reynolds Averaged Navier-Stokes (RANS) turbulence modeling. As an integral part of the MOOSE-based suite of tools, Pronghorn seamlessly couples with other MOOSE-based applications to simulate a variety of physical phenomena. This article highlights recent significant enhancements to Pronghorn's CFD modeling capabilities and demonstrates their application to advanced nuclear reactor designs. The recent improvements in Pronghorn primarily focus on modifications to its turbulence modeling capabilities, near-wall corrections and numerical schemes. In terms of turbulence modeling, the two-equation $k-\epsilon$ and $k-\omega$ SST models have been implemented and validated with both equilibrium and non-equilibrium wall treatments. Additionally, corrections for wall roughness, and curvature, and wall-channeling in pebble beds have been introduced in the near-wall modeling. These developments enable more accurate simulations of advanced nuclear reactors. Two case studies are presented in this work: a pool-type Molten Chloride Reactor and a salt-cooled Pebble-Bed High Temperature Reactor. In both cases, the previous models in Pronghorn are compared with the new implementations, demonstrating the improved accuracy achieved with the updated models.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2025

Design Basis Document / Owner’s Technical Specification for Nitrate Salt Systems in CSP Projects (Final Technical Report)

The number of commercial coal, gas, and nuclear projects built over the past 100 years number in the thousands. As such, there is a large database, available to a wide range of commercial engineering contractors, on proven designs. In essence, unsuccessful designs have, through generations of iterations, been identified and then deleted from further consideration. In contrast, the number of commercial parabolic trough projects using nitrate salt for the thermal storage media is perhaps 60. Further, the number of commercial central receiver projects using nitrate salt as the working fluid is on the order of 20, including estimates for China. Given the relative immaturity of salt technology, and commercial pressures to successfully bid new solar projects into a mature electricity market, solar projects often promise more than has been delivered. The Design Basis Document / Owner’s Technical Specification is a first step in the iteration process. The report describes the successful features of commercial projects, outlines a range equipment and system failures in projects that didn’t operate as intended, and provides a draft set of design changes intended to correct the known problems. The product of the study is 3 volumes of technical material; one volume is on parabolic trough technologies; a second is on central receiver technologies, and the third is on potential design changes to parabolic trough and central receiver projects. The 3 volumes, which total some 590 pages, can be found at https://www.solardynllc.com/csp-plant-technologies. One of the principal topics in the report is the use of functional or prescriptive specifications. Functional specifications describe what the equipment needs to do, consistent with the minimum legal requirements of the local jurisdictions. The details of how this is to be accomplished is developed by the engineering contractor. Prescriptive specifications, which are developed by the Owner, prescribe to the engineering contractor how the functional requirements are to be met. This arrangement ensures that the favorable experience from a previous project is repeated. One example is the design code for the hot salt tank in central receiver projects. The closest design basis is API Standard 650 Welded Steel Tanks for Oil Storage. However, the maximum design temperature in API 650 is 260 °C. As such, solar projects have typically adopted a hybrid Code approach, in which allowable material stresses are taken from ASME Section II Materials. Further, since the tanks experience daily changes in temperature and in (static) pressure, and since portions of the tank can operate at stresses beyond the elastic range, the low cycle fatigue life of the tank is conducted using the rules of Section VIII Division 2. However, in a recent study by NREL, the principal damage mechanism was identified as creep rather than fatigue. Further, design stresses permitted under Section VIII Division 2, corresponding to a fatigue life of 30 years, result in projected creep lifetimes of only 2 to 5 years. An alternate design approach, prescribed by the Owner, would be based on Code sections intended for high temperature service in the creep regime. A candidate is Section III Division 5. Granted, this is a nuclear code section, and it’s use would not likely be mandated by local jurisdictions. However, the effects of creep have been deemed to be of sufficient importance that one nuclear project developer, and one central receiver project developer, have stipulated in the tank design specification that the equipment be designed to the requirements of Section III Division 5.

14 SOLAR ENERGY↗
DOE OSTI2024

Advancing Thermal-Hydraulic Modeling Capabilities for Molten Salt Reactors in Pronghorn

This is an M2 report for the NEAMS program. This work focuses on advancing the modeling and simulation capabilities for Molten Salt Reactors (MSRs) within Pronghorn, addressing key thermal-hydraulic challenges that must be addressed for the safe and efficient operation of these advanced reactors. This report summarizes the development and validation of the following new models in Pronghorn: (i) two-equation RANS turbulence models, (ii) near-wall turbulence corrections due to curvature and roughness, and (iii) multidimensional two-phase drift-flux models. For each of these cases, along with the experimental validation, an application study of interest to MSRs is presented. In addition, this report also presents recent improvements in the domain-overlapping coupling between Pronghorn and SAM to address the cases of weakly compressible flow and flow reversal. Finally, an MSR action that greatly simplifies the setup of MSR models using NEAMS tools is described.

42 ENGINEERING↗
NASA NTRS1989

Image-based terrain modeling with thematic mapper applied to resolving the limit of Holocene Lake expansion in the Great Salt Lake Desert, Utah, part 1

The LANDSAT Thematic Mapper (TM) scanner records reflected solar energy from the earth's surface in six wavelength regions, or bands, and one band that records emitted energy in the thermal region, giving a total of seven bands. Useful research was extracted about terrain morphometry from remote sensing measurements and this information is used in an image-based terrain model for selected coastal geomorphic features in the Great Salt Lake Desert (GSLD). Technical developments include the incorporation of Aerial Profiling of Terrain System (APTS) data in satellite image analysis, and the production and use of 3-D surface plots of TM reflectance data. Also included in the technical developments is the analysis of the ground control point spatial distribution and its affects on geometric correction, and the terrain mapping procedure; using satellite data in a way that eliminates the need to degrade the data by resampling. The most common approach for terrain mapping with multispectral scanner data includes the techniques of pattern recognition and image classification, as opposed to direct measurement of radiance for identification of terrain features. The research approach in this investigation was based on an understanding of the characteristics of reflected light resulting from the variations in moisture and geometry related to terrain as described by the physical laws of radiative transfer. The image-based terrain model provides quantitative information about the terrain morphometry based on the physical relationship between TM data, the physical character of the GSLD, and the APTS measurements.

Merola, John A.↗
NASA NTRS1995

Heterogeneous reactions of HNO3(g) + NaCl(s) yields HCl(g) + NaNO3(s) and N2O5(g) + NaCl(s) yields ClNO2(g) + NaNO3(s)

The heterogeneous reactions of HNO3(g) + NaCl(s) yields HCl(g) + NaNO3(s) (eq 1) and N2O5(g) + NaCl(s) yields ClNO2(g) + NaNO3(S) (eq 2) were investigated over the temperature range 223-296 K in a flow-tube reactor coupled to a quadrupole mass spectrometer. Either a chemical ionization mass spectrometer (CIMS) or an electron-impact ionization mass spectrometer (EIMS) was used to provide suitable detection sensitivity and selectivity. In order to mimic atmospheric conditions, partial pressures of HNO3 and N2O5 in the range 6 x 10(exp -8) - 2 x 10(exp -6) Torr were used. Granule sizes and surface roughness of the solid NaCl substrates were determined by using a scanning electron microscope. For dry NaCl substrates, decay rates of HNO3 were used to obtain gamma(1) = 0.013 +/- 0.004 (1sigma) at 296 K and > 0.008 at 223 K, respectively. The error quoted is the statistical error. After all corrections were made, the overall error, including systematic error, was estimated to be about a factor of 2. HCl was found to be the sole gas-phase product of reaction 1. The mechanism changed from heterogeneous reaction to predominantly physical adsorption when the reactor was cooled from 296 to 223 K. For reaction 2 using dry salts, gamma(2) was found to be less than 1.0 x 10(exp -4) at both 223 and 296 K. The gas-phase reaction product was identified as ClNO2 in previous studies using an infrared spectrometer. An enhancement in reaction probability was observed if water was not completely removed from salt surfaces, probably due to the reaction of N2O5(g) + H2O(s) yields 2HNO3(g). Our results are compared with previous literature values obtained using different experimental techniques and conditions. The implications of the present results for the enhancement of the hydrogen chloride column density in the lower stratosphere after the El Chichon volcanic eruption and for the chemistry of HCl and HNO3 in the marine troposphere are discussed.

Leu, Ming-Taun↗
DOE OSTI2024

Pivotal Roles of Triple Screening-Topological, Electrostatic, and Hydrodynamic-On Dynamics in Semidilute Polyelectrolyte Solutions

For semidilute polyelectrolyte solutions, it is generally assumed that topological, electrostatic, and hydrodynamic interactions are screened (called triple screening). Despite a large body of research focused on polyelectrolyte solutions, the concept of triple screening has never been rigorously verified. In this work, we test the concept by probing concentration fluctuations in aqueous solutions containing a well-studied polyelectrolyte, sodium poly(styrenesulfonate) (NaPSS) with neutron scattering, theory, and molecular dynamics simulations. Neutron spin–echo (NSE) and small-angle neutron scattering (SANS) data from semidilute solutions of NaPSS are presented at different polymer and salt (NaCl) concentrations. A combined theory for structure (J. Chem. Phys. 105, 5183 (1996)) and dynamics (J. Chem. Phys. 107, 2619 (1997)), which captures effects of hydrodynamic, topological, and electrostatic screening, is used to interpret the experimental results. Here, the theory quantitatively predicts the decay rate obtained from the NSE measurements while capturing the shape and concentration dependencies of the polyelectrolyte peak observed in the SANS spectra. Detailed comparisons of the theory and the experiments reveal that the wavevector-dependent decay rate of concentration fluctuations in semidilute solutions of polyelectrolytes is dictated by the screening of hydrodynamic, topological, and electrostatic interactions. This conclusion is corroborated by coarse-grained molecular dynamics simulations, executed without any hydrodynamic interactions, which fail to capture the correct wavevector dependence of the decay rate. These results highlight that the theories based on the concept of triple screening provide a quantitative framework for predicting a relation between the structure and dynamics of polyelectrolyte solutions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Off-design operation and performance of pumped thermal energy storage

In this article, we describe off-design models and control strategies for a Pumped Thermal Energy Storage (PTES) system that uses liquid thermal energy storage: specifically molten salt for hot storage and methanol for cold storage. Off-design conditions arise when load-following, or due to variations in storage tank temperatures or ambient temperatures. We propose a control strategy that uses inventory control to manage the mass flow rate in the thermodynamic cycles, which facilitates load following. We also propose a control strategy for the storage fluid mass flow rates, which are varied to ensure the molten salt is maintained at its design temperature. This maximizes efficiency and minimizes problems with salt freezing or degradation. The cold storage fluid mass flow rate is varied so that the cold tanks have the same state-of-charge as the hot tanks. This leads to variations in cold fluid temperature, but these variations are shown to be acceptably small (e.g. 7.5% increase), and this control method is shown to be simpler and more efficient than an alternative strategy where tanks become unbalanced. The ambient temperature and storage tank temperatures are moved ±50 °C from the design values and the impact on power, duration, and tank temperatures is quantified. Results demonstrate that the proposed control strategy is stable and self-correcting - that is, storage temperatures converge on stable values after two-to-three charge-discharge cycles. When inputs return to design values, the system returns to its design point after two charge-discharge cycles. We also demonstrate that inventory control enables delivery of the target power output even when off-design conditions exist that would normally reduce the power output.

25 ENERGY STORAGE↗
DOE OSTI2023

The outburst of the changing-look AGN IRAS 23226-3843 in 2019

IRAS 23226-3843 has previously been classified as a changing-look active galactic nucleus (AGN) based on observations taken in the 1990s in comparison to X-ray data (Swift, XMM-Newton, and NuSTAR) and optical spectra taken after a very strong X-ray decline in 2017. In 2019, Swift observations revealed a strong rebrightening in X-ray and UV fluxes. We aimed to study this outburst in greater detail. We took follow-up Swift, XMM-Newton, and NuSTAR observations of IRAS 23226-3843 together with optical spectra (SALT and SAAO 1.9 m telescope) from 2019 until 2021. IRAS 23226-3843 showed a strong X-ray and optical outburst in 2019. It varied in the X-ray continuum by a factor of 5 and in the optical continuum by a factor of 1.6 within two months. This corresponds to a factor of 3 after correction for the host galaxy contribution. The Balmer and Fe II emission-line intensities showed comparable variability amplitudes during the outburst in 2019. The Hα emission-line profiles of IRAS 23226-3843 changed from a blue-peaked profile in the years 1997 and 1999 to a broad double-peaked profile in 2017 and 2019. However, there were no major profile variations in the extremely broad double-peaked profiles despite the strong intensity variations in 2019. One year after the outburst, IRAS 23226-3843 changed its optical spectral type and became a Seyfert type 2 object in 2020. Blue outflow components are present in the optical Balmer lines and in the Fe band in the X-rays. A deep broadband XMM-Newton/NuSTAR spectrum was taken during IRAS 23226-3843’s maximum state in 2019. This spectrum is qualitatively very similar to a spectrum taken in 2017, but by a factor of 10 higher. The soft X-ray band appears featureless. The soft excess is well modeled with a Comptonization model. A broadband fit with a power-law continuum, Comptonized soft excess, and Galactic absorption gives a good fit to the combined EPIC-pn and NuSTAR spectrum. In addition, we see a complex and broadened Fe K emission-line profile in the X-rays. The changing-look character in IRAS 23226-3843 is most probably caused by changes in the accretion rate – based on the short-term variations on timescales of weeks to months.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Spectroscopic investigation of cation effects in U(VI)-NO3- complexation in aqueous solutions

Understanding and manipulating uranyl speciation in aqueous solutions is critical for advancing chemical separation, sensing, and understanding environmental transport of uranyl. We report on the significant enhancement in the complexation of uranyl with nitrate in aqueous solutions containing quaternary ammonium cations leading to the formation of anionic complexes. We base this on the comparative study of the effect of monovalent cations (Na+, Li+, NH4+, and N(CH3)4+) on the complexation equilibria of uranyl-nitrate in solutions, probed by time-resolved laser induced fluorescence spectroscopy (TRLFS). Lifetime-corrected spectra, obtained by extrapolating the time-resolved spectra to t = 0, were used to study speciation to mitigate the effects of variations in the fluorescence lifetimes that depend on extraneous factors such as dynamic quenching. We demonstrate that the lifetime-corrected spectra can be used to determine uranyl speciation in aqueous solutions where the mono-nitrate complex forms, and in acetonitrile with N(CH3)4NO3 where di-nitrate and tris-nitrato species are formed. Aqueous solutions containing N(CH3)4+ are shown to promote the formation of higher complexes of uranyl compared to other inorganic nitrate salts based on the higher redshift in the spectra, poor fits to the two-component model, and the higher apparent formation constants. Comparing the trends in uranyl speciation in the presence of N(CH3)4+ in aqueous and acetonitrile solutions, it is proposed that the quaternary ammonium cations (quats) promote the formation of anionic complexes of uranyl by the ion-association mechanism. These results provide a basis for designing quat-assisted separation systems that target anionic actinide species in aqueous solutions.

Nayak, Srikanth (ORCID:0000000302135796)↗
DOE OSTI2023

Demonstration of RANS models with wall functions in the spectral element code Nek5000

The spectral element based computational fluid dynamics (CFD) code Nek5000 has been traditionally used for high-fidelity applications, such as direct numerical simulation (DNS) and large eddy simulation (LES). These techniques require very fine numerical resolution to accurately capture turbulent fluctuations which can be prohibitively expensive for users without access to leadership class computing facilities. For broader application and adoption, significant effort has been invested to develop Reynolds-averaged Navier–Stokes (RANS) capabilities in Nek5000. Here, this work presents details of the implementation and demonstration of the standard wall functions for the κ–τ model in Nek5000. Results using the wall-modeled approach are compared to a wall-resolved approach for cases with negligible pressure gradient, viz., channel flow, pipe flow and flow in a reactor subchannel. Results show reasonably good agreement between the two approaches for friction factor and Nusselt number. Some expected differences are identified near the wall. These cases demonstrate the potential for significant computational savings by using much coarser meshes for the wall-modeled approach, with only minor differences between the predicted result. Additionally, several Reynolds numbers up to 1,000,000 are demonstrated for pipe flow and predicted friction factors and Nusselt numbers compared well to available correlations, with the worst below 10%. As the Reynolds number is increased, better agreement is observed between the correlations and the wall-modeled approach. In addition, flow in a molten salt fast reactor (MSFR) core is considered which features an adverse pressure gradient and flow separation. It showcases the inability of standard wall functions to accurately predict flows with adverse pressure gradients. The results, however, match reasonably well in trend in regions of the flow where the boundary layer is attached. Ongoing research is dedicated to include a pressure gradient correction to wall functions to improve the accuracy of flows with separation or reattachment and adverse or favorable pressure gradients.

42 ENGINEERING↗
NASA NTRS1973

Plan for the uniform mapping of earth resources and environmental complexes from Skylab imagery

The author has identified the following significant results. Below approximately 25% cover visual photointerpretation of vegetation analogs of Skylab 2 Sl9OA color infrared imagery is poor. Correct identifications of vegetation analogs in this category range from 28 to 57%. Good photointerpretation results (64 to 96%) were obtained on vegetation analogs with higher cover values. The four semidesert vegetation analogs (greasewood, saltbush, big sagebrush, and pinyon-juniper) are consistently distinguishable as a group. Photointerpretation accuracy equals 90.1%. When these same types are broken into two sub-groups (salt desert vegetation and shrub steppe/sparse pinyon-juniper vegetation) interpretation success drops to 76% and 85%, respectively. Band ratioing and transmittance differences between two forested analogs as imaged on Skylab 2 S19OA film shows significant differences. In the infrared wavelength both analogs have very similar transmittance characteristics while the visible wavelength shows separation between the two. Relative transmittance values for stands of ponderosa pine forestland and pinyon-juniper woodland are 719.3 + or - 65.9 and 223.6 + or - 48.1, respectively on negative transparencies. In image interpretation along the low-elevation fringe of forested regions these are the two forest analogs most frequently requiring separation.

Poulton, C. E.↗
DOE OSTI2024

Extraction, Scrub, and Strip Test Results for the IBC BOBCalix Solvent Samples

A second vendor for solvent extraction components has been chosen for use at the Salt Waste Processing Facility (SWPF). IBC Advanced Technologies (IBC) has provided samples of their BOBCalix, as well as complete solvent. These samples were tested for quality assurance purposes to ensure their use at SWPF is acceptable. Two Extraction, Scrub, and Strip (ESS) tests were performed on solvent samples from IBC. The purpose of testing these samples was to determine if the solvents are displaying the correct extraction and stripping behavior with cesium.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS2007

A New Sea Ice Model: Pancakes to Metrics

We are developing, testing, and validating a new sea ice dynamics model that treats the ice cover as an elastic/decohesive material in the permanent pack and includes the correct frazil/pancake behavior in the marginal zone. Two salient features of present ice dynamics models are that they do not: 1) reproduce the oriented fracture patterns of openings and closings in the pack ice, and 2) accurately model the effects of frazil/pancake ice formation in the ice margin. These poorly modeled areas account for a substantial portion of the ice growth, turbulent heat flux to the atmosphere, salt flux to the ocean, and energy dissipation due to slippage, ridging, and rafting, in the Arctic. Existing sea ice models have shown limited success in predicting the degree to which a lead will open for prescribed or observed forcing conditions. An important aspect of the new model we are developing is that the existence of cracks, along with their orientation, opening, and closing, is predicted. To put this effort in perspective a short history of ice dynamics modeling and data collection is presented. The RGPS data set is used to validate the model. As part of the testing and validation of the model, we are working on a new metric for comparing linear features (leads and ridges) in the data and model to be used in data assimilation for this model. The model framework is presented as well as some results showing the creation and development of leads in a simulation of ice dynamics in the Beaufort Sea. Other presentations by the authors will show other results from this effort.

Coon, M.↗