Search NASA⌕ Search

SEARCH · Search NASA

Results for “serpentine”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 91 records · Page 5

Automated thin-film analyses of hydrated interplanetary dust particles in the analytical electron microscope

A 200 keV electron microscope was used to obtain elemental analyses from over 4000 points on thin sections of eight 'layer silicate' class interplanetary dust particles (IDPs). Major and minor element abundances from a volume approaching that of a cylinder 50 nm in diameter were observed. Mineral phases and their relative abundances in the thin sections were identified and petrographic characteristics were determined. Three of the particles contained smectite (1.0-1.2 nm basal spacing) and two contained serpentine (0.7 nm basal spacing). The point count analyses and Mg-Si-Fe ternary diagrams show that one of the serpentine-containing IDPs is similar to CI and CM chondritic meteorites. The IDPs exhibit evidence of aqueous processing, but they have typically experienced only short range, submicrometer scale alteration. The IDPs may provide a broad sampling of the asteroid belt.

Germani, M. S.↗

Hydrothermal alteration experiments of olivine with varying Fe contents: An attempt to simulate aqueous alteration of the carbonaceous chondrites

Hydrothermal alteration experiments of olivine powder with several Fe/Mg ratios were carried out under acidic and neutral conditions, and transition electron microscopy (TEM) observations were made on the run products. Well-developed tubular crystals of serpentine (chrysotile) were synthesized from Fo100 under both acidic and neutral conditions, and from Fo92 and Fo80 under acidic condition. Abundance and size of chrysotile apparenlty dependent on the Fe contents of olivine, i.e. with increasing Fe contents, less and smaller chrysotile was formed. Acidity of the solution plays an important role for the formation of chrysotile. Platy and fibrous crystals of phyllosilicate, probably serpentine, were obtained from Fo50 and Fo20 treated under acidic condition, which are most similar to the phyllosilicates in the CI and CM chondrites. Framboidal aggregates of Fe-rich grains (presumably Fe-hydroxide) were formed from Fa100 and Fo20, but no phyllosilicate was formed from Fa100.

Takatori, Koichi↗

A highly redundant robot system for inspection

The work on the serpentine inspection system at JPL is described. The configuration of the inspection system consists of 20 degrees of freedom in total. In particular, the design and development of the serpentine micromanipulator end-effector tool which has 12 degrees of freedom is described. The inspection system is used for application in JPL's Remote Surface Inspection project and as a research tool in redundant manipulator control.

Lee, Thomas S.↗

Impact degassing of water and noble gases from silicates

Previous shock experiments by Ahrens and his colleagues show that degassing of H2O and CO2 occurs at 8-65GPa from hydrous minerals such as serpentine. In early solar system, the impact degassing would have played an important part in the formation of primary-atmospheres of the terrestrial planets. However, degassing conditions of noble gases are not well-known because there are few experiments for them. We conducted some shock recovery experiments to investigate the degassing condition and to understand the degassing mechanisms of water and noble gases. We used natural richterites (Ri), amphibolites (Am), serpentines (Sep) and orthoclases (or) as target samples. These, except Sep, contain radiogenic noble gases such as (40)Ar. The samples were put in stainless steel containers, and were show by a rail gun at ISAS or single-stage powder guns at Nagoya or Tohoku University, Japan. We used two kinds of containers: 'open' type containers having a ventilating path for released volatiles for most of samples and 'closed' type ones for some samples for comparison. On Ri and Sep, we made shock experiments for pre-heated (at 400-500 C) and unheated targets, and for powdered and uncrushed samples. Water and noble gases were analyzed both for the recovered shocked samples and the unshocked original samples, and the fractions of the degassed volatiles were calculated by comparing them. Water content in the sample was analyzed by thermo-gravimetry. Noble gases were extracted by heating the samples under high vacuum and analyzed with a sector-type mass spectrometer.

Azuma, S.↗

Carbonaceous chondrite clasts in the howardites Bholghati and EET87513

Twenty-two carbonaceous chondrite clasts from the two howardites Bholghati and EET87513 were analyzed. Clast N from EET87513 is a fragment classified as CM2 material on the basis of texture, bulk composition, mineralogy, and bulk O isotopic composition. Carbonaceous chondrite clasts from Bholghati, for which less data are available because of their small size, can be divided into two petrologic types: C1 and C2. C1 clasts are composed of opaque matrix with rare coarse-grained silicates as individual mineral fragments; textures resemble CI meteorites and some dark inclusions from CR meteorites. Opaque matrix is predominantly composed of flaky saponite; unlike typical CI and CR meteorites, serpentine is absent in the samples we analyzed. C2 clasts contain chondrules, aggregates, and individual fragments of coarse-grained silicates in an opaque matrix principally composed of saponite and anhydrous ferromagnesian silicates with flaky textures similar to phyllosilicates. These anhydrous ferromagnesian silicates are interpreted as the product of heating of pre-existing serpentine. The carbonaceous chondrite clasts we have studied from these two howardites are, with one notable exception (clast N from EET87513), mineralogically distinct from typical carbonaceous chondrites. However, these clasts have very close affinities to carbonaceous chondrites and have also experienced thermal metamorphism and aqueous alteration, but to different degrees.

Buchanan, P. C.↗

Follow-the-Leader Control for the PIPS Prototype Hardware

This report describes the payload inspection and processing system (PIPS), an automated system programmed off-line for inspection of space shuttle payloads after integration and prior to launch. PIPS features a hyper-redundant 18-degree of freedom (DOF) serpentine truss manipulator capable of snake like motions to avoid obstacles. During the summer of 1995, the author worked on the same project, developing a follow-the-leader (FTL) algorithm in graphical simulation which ensures whole arm collision avoidance by forcing ensuing links to follow the same tip trajectory. The summer 1996 work was to control the prototype PIPS hardware in follow-the-leader mode. The project was successful in providing FTL control in hardware. The STS-82 payload mockup was used in the laboratory to demonstrate serpentine motions to avoid obstacles in a realistic environment.

Williams, Robert L. II↗

Derivation of Midinfrared (5-25 micrometers) Optical Constants of Some Silicates and Palagonite

The midinfrared 2000-400/ cm (5-25 microns) optical constants (real (n) and imaginary (k) indices of refraction) are presented for: (1) pyrophyllite; (2) kaolinite; (3) serpentine; (4) montmorillonite; (5) saponite; (6) palagonite; and (7) orthopyroxene. Comparison of the values derived here with those previously presented for serpentine, montmorillonite, and palagonite is generally quite good and discrepancies between values are probably due to either chemical differences between the actual samples or different techniques used to derive the values. For montmorillonite, saponite, and palagonite we were able to derive optical constants in the region of the H2O-bending fundamental near 6 microns. We find that if a pellet of pure material can be produced with a mirror-like surface then the optical constants of clays and other noncohesive materials can be readily derived.

Roush, T.↗

Lunar and Planetary Science XXXV: Organics and Alteration in Carbonaceous Chondrites: Goop and Crud

The session "Organics and Alteration in Carbonaceous Chondrites: Goop and Crud" included the following reports:Organics on Fe-Silicate Grains: Potential Mimicry of Meteoritic Processes?; Molecular and Compound-Specific Isotopic Study of Monocarboxylic Acids in Murchison and Antarctic Meteorites; Nanoglobules, Macromolecular Materials, and Carbon Sulfides in Carbonaceous Chondrites; Evidence for Terrestrial Organic Contamination of the Tagish Lake Meteorite; Nitrogen Isotopic Imaging of Tagish Lake Carbon Globules; Microscale Distribution of Hydrogen Isotopes in Two Carbonaceous Chondrites; The Nature and Origin of Aromatic Organic Matter in the Tagish Lake Meteorite; Terrestrial Alteration of CM Chondritic Carbonate; Serpentine Nanotubes in CM Chondrites; Experimental Study of Serpentinization Reactions; Chondrule Glass Alteration in Type IIA Chondrules in the CR2 Chondrites EET 87770 and EET 92105: Insights into Elemental Exchange Between Chondrules and Matrices; Aqueous Alteration of Carbonaceous Chondrites: New Insights from Comparative Studies of Two Unbrecciated CM2 Chondrites, Y 791198 and ALH 81002 ;and A Unique Style of Alteration of Iron-Nickel Metal in WIS91600, an Unusual C2 Carbonaceous Chondrite.

Source record↗

Forced air heat sink apparatus

A high efficiency forced air heat sink assembly employs a split feed transverse flow configuration to minimize the length of the air flow path through at least two separated fin structures. Different embodiments use different fin structure material configurations including honeycomb, corrugated and serpentine. Each such embodiment uses a thermally conductive plate having opposed exterior surfaces; one for receiving a component to be cooled and one for receiving the fin structures. The serpentine structured fin embodiment employs a plurality of fin supports extending from the plate and forming a plurality of channels for receiving the fin structures. A high thermal conductivity bondant, such as metal-filled epoxy, may be used to bond the fin structures to either the plate or the fin supports. Dip brazing and soldering may also be employed depending upon the materials selected.

Rippel, Wally E.↗

Andreyivanovite: A Second New Phosphide from the Kaidun Meteorite

Andreyivanovite (ideally FeCrP) is another new phosphide species from the Kaidun meteorite, which fell in South Yemen in 1980. Kaidun is a unique breccia containing an unprecedented variety of fragments of different chondritic as well as achondritic lithologies. Andreyivanovite was found as individual grains and linear arrays of grains with a maximum dimension of 8 m within two masses of Fe-rich serpentine. In one sample it is associated with Fe-Ni-Cr sulfides and florenskyite (FeTiP). Andreyivanovite is creamy white in reflected light, and its luster is metallic. The average of nine electron microprobe analyses yielded the formula Fe(Cr0.587 Fe0.150 V0.109 Ti0.081 Ni0.060 Co0.002)P. Examination of single grains of andreyivanovite using Laue patterns collected by in-situ synchrotron X-ray diffraction (XRD), and by electron backscattered diffraction revealed that it is isostructural with florenskyite; we were unable to find single crystals of sufficient quality to perform a complete structure analysis. Andreyivanovite crystallizes in the space group Pnma, and has the anti-PbCl2 structure. Previously-determined cell constants of synthetic material [a = 5.833(1), b = 3.569(1), c = 6.658(1) A] were consistent with our XRD work. We used the XPOW program to calculate a powder XRD pattern; the 5 most intense reflections are d = 2.247 (I = 100), 2.074 (81), 2.258 (46), 1.785 (43), and 1.885 A (34). Andreyivanovite is the second new phosphide to be described from the Kaidun meteorite. Andreyivanovite could have formed as a result of cooling and crystallization of a melted precursor consisting mainly of Fe-Ni metal enriched in P, Ti, and Cr. Serpentine associated with andreyivanovite would then have formed during aqueous alteration on the parent asteroid. It is also possible that the andreyivanovite could have formed during aqueous alteration, however, artificial FeTiP has been synthesized only during melting experiments, at low oxygen fugacity, and there is no evidence that a hydrothermal genesis is reasonable.

Zolensky, Michael↗

Chemical Evolution of Presolar Organics in Astromaterials

Sub-micron, hollow organic globules reported from several carbonaceous chondrites, interplanetary dust particles, and comet Wild-2 samples returned by NASA?s Stardust mission are enriched in N-15/N-14 and D/H compared with terrestrial materials and the parent materials [1-4]. These anomalies are ascribed to the preservation of presolar cold molecular cloud material from where H, C, and N isotopic constraints point to chemical fractionation near 10 K [5]. An origin well beyond the planet forming region and their survival in meteorites suggests submicrometer organic globules were once prevalent throughout the solar nebula. The survival of the membrane structures indicates primitive meteorites and cometary dust particles would have delivered these organic precursors to the early Earth as well as other planets and satellites. The physical, chemical, and isotopic properties of the organic globules varies to its meteorite types and its lithologies. For example, organic globules in the Tagish Lake meteorite are always embedded in fined grained (poorly crystallized) saponite, and hardly encapsulated in coarse grained serpentine, even though saponite and serpentine are both main components of phyllosilicate matrix of the Tagish Lake meteorite. The organic globules are commonly observed in the carbonate-poor lithology but not in the carbonate-rich one. In Tagish Lake, isolated single globules are common, but in the Bells (CM2) meteorite, globules are mostly aggregated. We will review the evolutions of the organic globules from its birth to alteration in the parent bodies in terms of its own physical and chemical properties as well as its associated minerals.

Nakamura-Messenger, K.↗

Carbon Isotope Systematics in Mineral-Catalyzed Hydrothermal Organic Synthesis Processes at High Temperature and Pressures

Observation of methane in the Martian atmosphere has been reported by different detection techniques. Reduction of CO2 and/or CO during serpentization by mineral surface catalyzed Fischer-Tropsch Type (FTT) synthesis may be one possible process responsible for methane generation on Mars. With the evidence a recent study has discovered for serpentinization in deeply buried carbon rich sediments, and more showing extensive water-rock interaction in Martian history, it seems likely that abiotic methane generation via serpentinization reactions may have been common on Mars. Experiments involving mineral-catalyzed hydrothermal organic synthesis processes were conducted at 750 C and 5.5 Kbars. Alkanes, alcohols and carboxylic acids were identified as organic compounds. No "isotopic reversal" of delta C-13 values was observed for alkanes or carboxylic acids, suggesting a different reaction pathway than polymerization. Alcohols were proposed as intermediaries formed on mineral surfaces at experimental conditions. Carbon isotope data were used in this study to unravel the reaction pathways of abiotic formation of organic compounds in hydrothermal systems at high temperatures and pressures. They are instrumental in constraining the origin and evolution history of organic compounds on Mars and other planets.

Fu, Qi↗

The Search for Life on Mars - Current Knowledge, Earth Analogues, and Principal Issues

For centuries, the planet Mars has been imagined as a possible abode for life. Serious searches for life's signatures began in the 19th century via ground-based visual astronomy that stimulated a vibrant fantasy literature but little lasting scientific knowledge. Modern scientific inquiry has emphasized the search for chemical signatures of life in the soil and rocks at the planet's surface, and via biomarker gases in the atmosphere. Today, investigations are based on high-resolution spectroscopy at Earth's largest telescopes along with planet orbiting and landed space missions. Methane has assumed central importance in these searches. Living systems produce more than 900/0 of Earth's atmospheric methane; the balance is of geochemical origin. Abundant methane is not expected in an oxidizing atmosphere such as Mars', and its presence would imply recent release - whether biological or geochemical. F or that reason, the quest for methane on Mars has been a continuing thread in the fabric of searches conducted since 1969. I will review aspects of the discovery and distribution of methane on Mars, and will mention ongoing extended searches for clues to its origin and destruction. On Earth, hydrogen (generated via serpentinization or radiolysis of water) provides an important 'fuel' for carbonate-reducing and sulphate-reducing biota (CH4 and H2S producers, respectively). Several such communities are known to reside at depth in continental domains (e.g., Lidy Hot Springs, Idaho; Witwatersrand Basin, S. Africa). If similar conditions exist in favourable locations on Mars, organisms similar to these could likely prosper there. Geologic (abiotic) production will also be mentioned, especially abiotic methane production associated with low-temperature serpentinization (e.g., terrestrial ophiolites). It is vitally important to pursue evidence for geochemical and biological production with equal vigour and intellectual weight lest unwanted and unintended bias contaminate the results. Finally, I will touch upon unresolved questions and issues posed by the methane detections.

Mumma, Michael J.↗

On-Chip Microfluidic Components for In Situ Analysis, Separation, and Detection of Amino Acids

The Astrobiology Analytical Laboratory at GSFC has identified amino acids in meteorites and returned cometary samples by using liquid chromatography-electrospray ionization time-of-flight mass spectrometry (LCMS). These organic species are key markers for life, having the property of chirality that can be used to distinguish biological from non-biological amino acids. One of the critical components in the benchtop instrument is liquid chromatography (LC) analytical column. The commercial LC analytical column is an over- 250-mm-long and 4.6-mm-diameter stainless steel tube filled with functionized microbeads as stationary phase to separate the molecular species based on their chemistry. Miniaturization of this technique for spaceflight is compelling for future payloads for landed missions targeting astrobiology objectives. A commercial liquid chromatography analytical column consists of an inert cylindrical tube filled with a stationary phase, i.e., microbeads, that has been functionalized with a targeted chemistry. When analyte is sent through the column by a pressurized carrier fluid (typically a methanol/ water mixture), compounds are separated in time due to differences in chemical interactions with the stationary phase. Different species of analyte molecules will interact more strongly with the column chemistry, and will therefore take longer to traverse the column. In this way, the column will separate molecular species based on their chemistry. A lab-on-chip liquid analysis tool was developed. The microfluidic analytical column is capable of chromatographically separating biologically relevant classes of molecules based on their chemistry. For this analytical column, fabrication, low leak rate, and stationary phase incorporation of a serpentine microchannel were demonstrated that mimic the dimensions of a commercial LC column within a 5 10 1 mm chip. The microchannel in the chip has a 75- micrometer-diameter oval-shaped cross section. The serpentine microchannel has four different lengths: 40, 60, 80, and 100 mm. Functionized microbeads were filled inside the microchannel to separate molecular species based on their chemistry.

Zheng, Yun↗

Flexible Volumetric Structure

A flexible volumetric structure has a first spring that defines a three-dimensional volume and includes a serpentine structure elongatable and compressible along a length thereof. A second spring is coupled to at least one outboard edge region of the first spring. The second spring is a sheet-like structure capable of elongation along an in-plane dimension thereof. The second spring is oriented such that its in-plane dimension is aligned with the length of the first spring's serpentine structure.

Cagle, Christopher M.↗

Metabolic Potential and Activity in Fluids of the Coast Range Ophiolite Microbial Observatory, California, USA

Metabolic potential and activity associated with hydrogen and carbon monoxide were characterized in fluids sampled from the the Coast Range Ophiolite Microbial Observatory (CROMO). CROMO consists of two clusters of science-dedicated wells drilled to varying depths up to 35m in the actively serpentinizing, Jurassic-age Coast Range Ophiolite of Northern California, along with a suite of pre-existing monitoring wells at the same site. Consistent with the fluid chemistry observed in other serpentinizing systems, CROMO fluids are highly alkaline, with pH up to 12.5, high in methane, with concentrations up 1600 micromolar, and low in dissolved inorganic carbon (DIC), with concentrations of 10's to 100's of micromolar. CROMO is conspicuous for fluid H2 concentrations that are consistently sub-micromolar, orders of magnitude lower than is typical of other systems. However, higher H2 concentrations (10's -100's of micromolar) at an earlier stage of fluid chemical evolution are predicted by, or consistent with: thermodynamic models for fluid chemistry based on parent rock composition equivalent to local peridotite and with water:rock ratio constrained by observed pH; the presence of magnetite at several wt% in CROMO drill cores; and concentrations of formate and carbon monoxide that would require elevated H2 if formed in equilibrium with H2 and DIC. Calculated Gibbs energy changes for reaction of H2 and CO in each of several metabolisms, across the range of fluid composition encompassed by the CROMO wells, range from bioenergetically feasible (capable of driving ATP synthesis) to thermodynamically unfavorable. Active consumption relative to killed controls was observed for both CO and H2 during incubation of fluids from the pre-existing monitoring wells; in incubations of freshly cored solids, consumption was only observed in one sample set (corresponding to the lowest pH) out of three. The specific metabolisms by which H2 and CO are consumed remain to be determined.

Hydrogen↗

Enigmatic Nodule-Bearing Rocks in the Mafic to Ultramafic Diana Mills Pluton, Piedmont Province, Virginia

The Silurian Diana Mills pluton is a metamorphosed mafic-ultramafic body in the Piedmont Province of Virginia. Major rock types in the pluton include metadiorite and chlorite‐amphibole rock, with lesser amounts of hornblendite. However, the most visually striking rocks, found at 4 locations, consist of tan‐weathering nodules in a dark green matrix. The purpose of this study was to investigate the origin of these nodular rocks. All rocks show evidence of greenschistfacies metamorphism, but relict igneous textures are preserved locally. Apart from the nodules, Ca‐amphibole is ubiquitous in all rock types. Nodules are dominated by serpentine or talc (+magnetite +/- chromite), and many show a thin (less than or equal to 5 mm) radially oriented shell of serpentine against adjacent matrix. The nodules are ultramafic (Mg# approx. 80-90, up to7,563 ppm Cr, up to 2,038 ppm Ni), and their normative mineralogy is dominated by olivine and orthopyroxene. Thus, they represent metamorphosed harzburgites and pyroxenites. Matrix minerals are dominantly amphibole + chlorite, along with variable amounts of talc + magnetite. Some matrix samples are chlorite‐rich, probably reflecting metasomatic reaction with nodules (i.e., they are small‐scale ''blackwalls''). Matrix samples are also ultramafic (high Mg#, Cr, and Ni). The matrix of the nodule‐bearing outcrops is essentially the same as other chlorite‐amphibole rocks elsewhere in the pluton. We consider these rocks to represent emplacement of an original hornblende peridotite crystal mush (a mixture of crystals and hydrous melt), which locally carried harzburgitic nodules. The nodules most likely represent the earliest‐formed cumulates from the Diana Mills parent magma.

Owens, Brent E.↗

The Mid-IR Spectral Effects of Darkening Agents and Porosity on the Silicate Surface Features of Airless Bodies

We systematically measured the mid-IR spectra of different mixtures of three silicates (antigorite, lizardite, and pure silica) with varying effective porosities and amounts of darkening agent (iron oxide and carbon). These spectra have broad implications for interpretation of current and future mission data for airless bodies, as well as for testing the capabilities of new instruments. Serpentines, such as antigorite and lizardite, are common to airless surfaces, and their mid-IR spectra in the presence of darkening agents and different surface porosities would be typical for those measured by spacecraft. Silica has only been measured in the plumes of Enceladus and presents exciting possibilities for other Saturn-system surfaces due to long range transport of E-ring material. Results show that the addition of the IR-transparent salt, KBr, to simulate surface porosity affected silicate spectra in ways that were not predictable from linear mixing models. The strengthening of silicate bands with increasing pore space, even when only trace amounts of KBr were added, indicates that spectral features of porous surfaces are more detectable in the mid-IR. Combining iron oxide with the pure silicates seemed to flatten most of the silicate features, but strengthened the reststrahlen band of the silica. Incorporating carbon with the silicates weakened all silicate features, but the silica bands were more resistant to being diminished, indicating silica may be more detectable in the mid-IR than the serpentines. We show how incorporating darkening agents and porosity provides a more complete explanation of the mid-IR spectral features previously reported on worlds such as Iapetus.

Young, Cindy L.↗