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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

A measurement of the angular distribution of 5 eV atomic oxygen scattered off a solid surface in earth orbit

The angular distribution of 5 eV atomic oxygen scattered off a polished vitreous carbon surface was measured on a recent Space Shuttle flight. The experimental apparatus was of novel design, completely passive, and used thin silver films as the recording device for oxygen atoms. Most of the incident oxygen was contained in the reflected beam and remained in an active form and probably still atoms. Allowance was made for 12 percent loss of incident atoms which are converted to CO at the carbon surface. The scattered distribution which is wide lobular, peaking 15 deg in the forward direction, shows almost but not quite full accommodation.

Gregory, John C.↗

Friction and transfer behavior of pyrolytic boron nitride in contact with various metals

Sliding friction experiments were conducted with pyrolytic boron nitride in sliding contact with itself and various metals. Auger emission spectroscopy was used to monitor transfer of pyrolytic boron nitride to metals and metals to pyrolytic boron nitride. Results indicate that the friction coefficient for pyrolytic boron nitride in contact with metals can be related to the chemical activity of the metals and more particularly to the d valence bond character of the metal. Transfer was found to occur to all metals except silver and gold and the amount of transfer was less in the presence than in the absence of metal oxide. Friction was less for pyrolytic boron nitride in contact with a metal in air than in vacuum.

Buckley, D. H.↗

The 250AH/90A active lithium-thionyl chloride cell for Centaur-G application

A high rate active Li/SOCl2 cell was designed for use in a 28 volt, 250 amp-hour space battery system. The lithium battery is being considered as a replacement of its heavier silver-zinc counterpart on board the Centaur-G booster rocket which is used to launch payloads from the Space Shuttle cargo bay into deep-space. Basically a feasibility study, this development effort is demonstrating the ability of the lithium cell to deliver up to 90 amps safely at power densities of approximately 25 watts per pound. Test data on 4 prototype units is showing an energy density of 85 watt-hours per pound and 9.0 watt-hours/cu in. The cells tested typically delivered 280 to 300 amp-hours under ambient temperature test conditions using alternating continuous loads of 90, 55, and 20 amperes throughout life. Data from four cells tested are presented to demonstrate the capability of Li/SOCl2 technology for a C/3 discharge rate in active and hermetic cell units.

Zolla, A. E.↗

Thermally-Activated Metal-to-Glass Bonding

Hermetic seals formed easily by use of metallo-organic film. Metallo-organic film thermally bonded to glass and soldered or welded to form hermetic seal. Film applied as ink consisting of silver neodecanoate in xylene. Relative amounts of ingredients selected to obtain desired viscosity. Material applied by printing or even by scribing with pen. Sealing technique useful in making solar-cell modules, microelectronic packages, and other hermetic silicon devices.

Gallagher, B. D.↗

Development and testing of a high cycle life 30 A-h sealed AgO-Zn battery

A two-phase program was initiated to investigate design parameters and technology to develop an improved AgO-Zn battery. The basic performance goal was 100 charge/discharge cycles (22 h/2 h) at 50 percent depth of discharge following a six-month period of charged stand at room temperature. Phase 1, cell evaluation, involved testing 70 cells in five-cell groups. The major design variables were active material ratios, electrolyte concentrations, separator systems, and negative plate shape. Phase 1 testing showed that cycle life could be improved 10 percent to 20 percent by using greater ratios of zinc to silver oxide and higher electrolyte concentrations. Wedge-shaped negatives increased cycle life by nearly 100 percent. Phase 2 battery evaluation, which was initiated before the Phase 1 results were known completely, involved evaluation of six designs as 19-cell batteries. Only one battery exceeded 100 cycles following nine months charged stand.

Bogner, R. S.↗

Assessment of Microbiologically Influenced Corrosion Potential in the International Space Station Internal Active Thermal Control System Heat Exchanger Materials: A 6-Momths Study

The fluid in the Internal Active Thermal Control System (IATCS) of the International Space Station (ISS) is water based. The fluid in the ISS Laboratory Module and Node 1 initially contained a mix of water, phosphate (corrosion control), borate (pH buffer), and silver sulfate (Ag2SO4) (microbial control) at a pH of 9.5+/-0.5. Over time, the chemistry of the fluid changed. Fluid changes included a pH drop from 9.5 to 8.3 due to diffusion of carbon dioxide (CO2) through Teflon(reistered Trademark) (DuPont) hoses, increases in dissolved nickel (Ni) levels, deposition of silver (Ag) to metal surfaces, and precipitation of the phosphate (PO4) as nickel phosphate (NiPO4). The drop in pH and unavailability of a antimicrobial has provided an environment conducive to microbial growth. Microbial levels in the fluid have increased from >10 colony-forming units (CFUs)/100 ml to 10(exp 6) CFUs/100 ml. The heat exchangers in the IATCS loops are considered the weakest point in the loop because of the material thickness (=7 mil). It is made of a Ni-based braze filler/CRES 347. Results of a preliminary test performed at Hamilton Sundstrand indicated the possibility of pitting on this material at locations where Ag deposits were found. Later, tests have confirmed that chemical corrosion of the materials is a concern for this system. Accumulation of micro-organisms on surfaces (biofilm) can also result in material degradation and can amplify the damage caused by the chemical corrosion, known as microbiologically influenced corrosion (MIC). This paper will discuss the results of a 6-mo test performed to characterize and quantify the damage from microbial accumulation on the surface of the ISS/ATCS heat exchanger materials. The test was designed to quantify the damage to the materials under worst-case conditions with and without micro-organisms present at pH 8.3 and 9.5.

Roman, Monsi C.↗

MARE-l in Milan: Status and Perspectives

The international project MARE (Microcalorimeter Array for a Rhenium Experiment) aims at the direct and calorimetric measurement of the electron neutrino mass with sub-eV sensitivity. Although the baseline of the MARE project consists in a large array of rhenium based thermal detectors, a different option for the isotope is also being considered. The different option is Ho-163. The potential of using Re-187 for a calorimetric neutrino mass experiment has been already demonstrated. On the contrary, no calorimetric spectrum of Ho-163 has been so far measured with the precision required to set a useful limit on the neutrino mass. The first phase of the project (MARE-1) is a collection of activities with the aim of sorting out both the best isotope and the most suited detector technology to be used for the final experiment. One of the MARE-1 activities is carried out in Milan by the group of Milano-Bicocca in collaboration with NASA/GSFC and Wisconsin groups. The Milan MARE-l arrays are based on semiconductor thermistors, provided by the NASA/GSFC group, with dielectric silver perrhenate absorbers, AgReO4. The experiment, which is presently being assembled, is designed to host up to 8 arrays.

Ferri, E.↗

Electrocatalyst for oxygen reduction

The performance and costs of an electrochemical catalyst as compared to a pure platinum catalyst is evaluated. The catalysts are used to reduce oxygen in low temperature alkaline fuel cells. The electrochemical catalyst is composed of silver and platinum and is dispersed in a resinous inert binder to provide a cell electrode. The results indicate the electrochemical catalyst is superior structurally to the platinum one for high current density operation, and is at least as active as the platinum catalyst in other operations.

Swette, L. L.↗

Friction behavior of silicon in contact with titanium, nickel, silver and copper

Sliding friction experiments are conducted with the semiconductor silicon in contact with the metals titanium, nickel, copper, and silver. Sliding is on the (111) plane of single-crystal silicon in the 112 crystallographic direction both in dry and lubricated (mineral oil) sliding. The friction coefficient in dry sliding is controlled by adhesion and the surface chemical activity of the metal. The more active the metal the stronger the adhesion and the higher the friction. In lubricated sliding the lubricant absorbs to the surfaces and reduces the importance of metal chemical effects. In lubricated sliding, silicon ceases to behave in a brittle manner and undergoes plastic deformation under load.

Mishina, H.↗

Mineralogic variations in fluvial sediments contaminated by mine tailings as determined from AVIRIS data, Coeur D'Alene River Valley, Idaho

The success of imaging spectrometry in mineralogic mapping of natural terrains indicates that the technology can also be used to assess the environmental impact of human activities in certain instances. Specifically, this paper describes an investigation into the use of data from the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) for mapping the spread of, and assessing changes in, the mineralogic character of tailings from a major silver and base metal mining district. The area under investigation is the Coeur d'Alene River Valley in northern Idaho. Mining has been going on in and around the towns of Kellogg and Wallace, Idaho since the 1880's. In the Kellogg-Smelterville Flats area, west of Kellogg, mine tailings were piled alongside the South Fork of the Coeur d'Alene River. Until the construction of tailings ponds in 1968 much of these waste materials were washed directly into the South Fork. The Kellogg-Smelterville area was declared an Environmental Protection Agency (EPA) Superfund site in 1983 and remediation efforts are currently underway. Recent studies have demonstrated that sediments in the Coeur d'Alene River and in the northern part of Lake Coeur d'Alene, into which the river flows, are highly enriched in Ag, Cu, Pb, Zn, Cd, Hg, As, and Sb. These trace metals have become aggregated in iron oxide and oxyhydroxide minerals and/or mineraloids. Reflectance spectra of iron-rich tailing materials are shown. Also shown are spectra of hematite and goethite. The broad bandwidth and long band center (near 1 micron) of the Fe(3+) crystal-field band of the iron-rich sediment samples combined with the lack of features on the Fe(3+) -O(2-) charge transfer absorption edge indicates that the ferric oxide and/or oxyhydroxide in these sediments is poorly crystalline to amorphous in character. Similar features are seen in poorly crystalline basaltic weathering products (e.g., palagonites). The problem of mapping and analyzing the downriver occurrences of iron rich tailings in the Coeur d'Alene (CDA) River Valley using remotely sensed data is complicated by the full vegetation cover present in the area. Because exposures of rock and soil were sparse, the data processing techniques used in this study were sensitive to detecting materials at subpixel scales. The methods used included spectral mixture analysis and a constrained energy minimization technique.

Farrand, W. H.↗

International Space Station Internal Thermal Control System Lab Module Simulator Build-Up and Validation

As part of the Sustaining Engineering program for the International Space Station (ISS), a ground simulator of the Internal Thermal Control System (ITCS) in the Lab Module was designed and built at the Marshall Space Flight Center (MSFC). To support prediction and troubleshooting, this facility is operationally and functionally similar to the flight system and flight-like components were used when available. Flight software algorithms, implemented using the LabVIEW(Registered Trademark) programming language, were used for monitoring performance and controlling operation. Validation testing of the low temperature loop was completed prior to activation of the Lab module in 2001. Assembly of the moderate temperature loop was completed in 2002 and validated in 2003. The facility has been used to address flight issues with the ITCS, successfully demonstrating the ability to add silver biocide and to adjust the pH of the coolant. Upon validation of the entire facility, it will be capable not only of checking procedures, but also of evaluating payload timelining, operational modifications, physical modifications, and other aspects affecting the thermal control system.

Paul Wieland↗

Effects of the low Earth orbital environment on spacecraft materials

It is evident from space flights during the last three years that the low Earth orbital (LEO) environment interacts with spacecraft surfaces in significant ways. One manifestation of these interactions is recession of, in particular, organic-polymer-based surfaces presumably due to oxidation by atomic oxygen, the major component of the LEO environment. Three experiments have been conducted on Space Shuttle flights 5, 8 and 41-G to measure reaction rates and the effects of various parameters on reaction rates. Surface recession on these flights indicates reaction efficiencies approximately 3 x 10(-24) cu cm/atoms for unfilled organic polymers. Of the metals, silver and osmium are very reactive. Effects on spacecraft or experiment surfaces can be evaluated using the derived reaction efficiencies and a definition of the total exposure to atomic oxygen. This exposure is obtained using an ambient density model, solar activity data and spacecraft parameters of altitude, attitude and operational date. Oxygen flux on a given surface is obtained from the ambient density and spacecraft velocity and can then be integrated to provide the total exposure or fluence. Such information can be generated using simple computational programs and can be converted to various formats. Overall, the extent of damage is strongly dependent on the type of surface and total exposure time.

Leger, L. J.↗

Thermal Performance of Orion Active Thermal Control System With Seven-Panel Reduced-Curvature Radiator

The active thermal control system (ATCS) of the crew exploration vehicle (Orion) uses radiator panels with fluid loops as the primary system to reject heat from spacecraft. The Lockheed Martin (LM) baseline Orion ATCS uses eight-panel radiator coated with silver Teflon coating (STC) for International Space Station (ISS) missions, and uses seven-panel radiator coated with AZ 93 white paint for lunar missions. As an option to increase the radiator area with minimal impact on other component locations and interfaces, the reduced-curvature (RC) radiator concept was introduced and investigated here for the thermal perspective. Each RC radiator panel has 15 percent more area than each Lockheed Martin (LM) baseline radiator panel. The objective was to determine if the RC seven-panel radiator concept could be used in the ATCS for both ISS and lunar missions. Three radiator configurations the LM baseline, an RC seven-panel radiator with STC, and an RC seven-panel radiator with AZ 93 coating were considered in the ATCS for ISS missions. Two radiator configurations the LM baseline and an RC seven-panel radiator with AZ 93 coating were considered in the ATCS for lunar missions. A Simulink/MATLAB model of the ATCS was used to compute the ATCS performance. Some major hot phases on the thermal timeline were selected because of concern about the large amount of water sublimated for thermal topping. It was concluded that an ATCS with an RC seven-panel radiator could be used for both ISS and lunar missions, but with two different coatings STC for ISS missions and AZ 93 for lunar missions to provide performance similar to or better than that of the LM baseline ATCS.

Wang, Xiao-Yen J.↗

Fast, Large-Area, Wide-Bandgap UV Photodetector for Cherenkov Light Detection

Due to limited resources available for power and space for payloads, miniaturizing and integrating instrumentation is a high priority for addressing the challenges of manned and unmanned deep space missions to high Earth orbit (HEO), near Earth objects (NEOs), Lunar and Martian orbits and surfaces, and outer planetary systems, as well as improvements to high-altitude aircraft safety. New, robust, and compact detectors allow future instrumentation packages more options in satisfying specific mission goals. A solid-state ultraviolet (UV) detector was developed with a theoretical fast response time and large detection area intended for application to Cherenkov detectors. The detector is based on the wide-bandgap semiconductor zinc oxide (ZnO), which in a bridge circuit can detect small, fast pulses of UV light like those required for Cherenkov detectors. The goal is to replace the role of photomultiplier tubes in Cherenkov detectors with these solid-state devices, saving on size, weight, and required power. For improving detection geometry, a spherical detector to measure high atomic number and energy (HZE) ions from any direction has been patented as part of a larger space radiation detector system. The detector will require the development of solid-state UV photodetectors fast enough (2 ns response time or better) to detect the shockwave of Cherenkov light emitted as the ions pass through a quartz, sapphire, or acrylic ball. The detector must be small enough to fit in the detector system structure, but have an active area large enough to capture enough Cherenkov light from the sphere. The detector is fabricated on bulk single-crystal undoped ZnO. Inter - digitated finger electrodes and contact pads are patterned via photolithography, and formed by sputtered metal of silver, platinum, or other high-conductivity metal.

Wrbanek, John D.↗

Ultrasonically bonded value assembly

A valve apparatus capable of maintaining a fluid-tight seal over a relatively long period of time by releasably bonding a valve member to its seat is described. The valve member is bonded or welded to the seat and then released by the application of the same energy to the bond joint. The valve member is held in place during the bonding by a clamping device. An appropriate force device can activate the opening and closing of the valve member. Various combinations of material for the valve member and valve seat can be utilized to provide an adequate sealing bond. Aluminum oxide, stainless steel, inconel, tungsten carbide as hard materials and copper, aluminum, titanium, silver, and gold as soft materials are suggested.

Salvinski, R. J.↗

An overview of dredging operations in the Chesapeake Bay

Maintenance of the Baltimore and the Newport News/Norfolk harbors as well as of the Chesapeake and Delaware Canal is accomplished by different dredging operations which depend on the amount and type of material to be moved, water depth, and location of disposal sites. Methods for determining the physical or chemical-biological interactive effects of these activities on the environment and on the shellfish and finfish industries on the Bay are discussed. The types of dredges used are classed according to their mode of operation.

Silver, R. H.↗

Method of obtaining intensified image from developed photographic films and plates

A method is explained of obtaining intensified images from silver images on developed photographic films and plates. The steps involve converting silver of the developed film or plate to a radioactive compound by treatment with an aqueous alkaline solution of an organo-S35 compound; placing the treated film or plate in direct contact with a receiver film which is then exposed by radiation from the activated film; and developing and fixing the resulting intensified image on the receiver film.

Askins, B. S.↗

Evapotranspiration as a Regional Climate Priority: Results from a NASA/USDA Workshop

On April 5 to 7, 2011, the National Aeronautics and Space Administration (NASA) and the United States Department of Agriculture-Agricultural Research Service (USDA-ARS) sponsored a Workshop on Evapotranspiration (ET) in Silver Spring Maryland. The workshop was a response to a recommendation in the 2009-2011 GEO (Group on Earth Observations) Work Plan that a workshop on ET should be held to discuss issues related to ET products and services and the potential for incorporating ET activities into the 2012-2015 GEO Work Plan. The workshop had a regional emphasis, although there were several excellent international and global presentations including one on the GEWEX LANDFLUX project. The different scales of these activities suggests that a framework is needed that can accommodate both regional and global ET activities. Despite limitations with the workshop's scheduling, it attracted 76 experts who contributed informative presentations and insightful discussions. The goals of the workshop involved the exchange of information and ideas and the development of plans for providing more visibility for ET issues. Specific objectives included 1) defining the needs and requirements for evapotranspiration data in weather and climate studies, in natural and agro-ecoystem monitoring, and in water resource management; 2) reviewing the methods used to measure and model evapotranspiration; 3) assessing surface and satellite observation systems required to support ET measurement, modeling and evaluation; 4) assessing the feasibility of developing a proposal for a task on evapotranspiration for the 2012-2015 GEO Work Plan, and 5) exploring the level of support and consensus for developing a strategy for establishing evapotranspiration as an Essential Climate Variable (ECV) within the Global Climate Observing System (GCOS) framework The workshop featured a combination of oral presentations and breakout group sessions focused on the above objectives. There were also poster presentations providing opportunities for one-on-one discussions of ET modeling and measurement techniques. Presentations by users of ET data set the tone for the workshop. In the USA at the national and regional levels water rights issues represent a major opportunity for ET applications. ET data play a major role in estimating water loss due to irrigation, the largest cause of consumptive water loss in the USA, particularly in the West. Irrigation requirements are relatively specific since the needs are clearly defined by the geometry and number of the irrigation systems and can be monitored with high resolution satellite data. There was a strong consensus that land surface temperature (LST) at high resolution is critical for monitoring irrigation. State governments have made commitments to more efficient water management in the western US, but they need full access to improved and more timely ET data and applications to implement this plan. Water managers also reported that in spite of the recent development of. new techniques, the procedures used in some of the water balance calculations in some states are out of date and do not take advantage of new observational and data assimilation systems. The development of ET forecasts for water management is also seen as a priority. Although ET forecasts are currently being produced on an experimental basis these predictions could be improved by considering ET as a dynamic prediction variable in models and by increasing the time resolution of these ET predictions.

Lawford, Richard↗