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NASA NTRS1997

The Planet Mercury Surface Spectroscopy and Analysis from the Kuiper Airborne Observatory and Analysis and Modeling to Determine Surface Composition

We had two successful flights to observe Mercury from the Kuiper Airborne Observatory (KAO) using High-efficiency Infrared Faint-Object Grating Spectrograph (HIFOGS). Flights were May 8, 1995 (eastern elongation) and July 6, 1995 (western elongation) For the observations one half of the primary mirror was covered to prevent sunlight from entering the telescope. All equipment and the airplane and its crew performed well. These flights were historical firsts for the KAO and for spectroscopy of Mercury in that it was the first time any spectroscopic observations of Mercury from above the Earth's atmosphere had been made. It was the first time the KAO had been used to @bserve an object less than 30 degrees from the Sun. Upon completion of the basic data reduction it became obvious that extensive modeling and analysis would be required to understand the data. It took three years of a graduate student's time and part time the PI to do the thermal modeling and the spectroscopic analysis. This resulted in a lengthy publication. A copy of this publication is attached and has all the data obtained in both KAO flights and the results clearly presented. Notable results are: (1) The observations found an as yet unexplained 5 micron emission enhancement that we think may be a real characteristic of Mercury's surface but could have an instrumental cause; (2) Ground-based measurements or an emission maximum at 7.7 microns were corroborated. The chemical composition of Mercury's surface must be feldspathic in order to explain spectra features found in the data obtained during the KAO flights.

Sprague, Ann↗
NASA NTRSDate not supplied

Electron Bombardment on Dione: Surface Compositional Effects and Temperature Anomalies

Saturn’s icy moons are composed primarily of water ice with minor other “contaminants,” such as CO2 ice, and a dark component thought to be organics, hematite and/or metallic Fe. The space weathering process of electron bombardment is expected to be particularly important on the surfaces of Saturn’s inner moons (Mimas, Tethys, Dione, and Rhea), as they orbit within Saturn’s inner magnetosphere. Terrains exhibiting thermal anomalies (i.e., colder temperatures in the day and warmer temperatures at night than surrounding areas) correspond to regions of high energy electron bombardment. Energetic electrons impact the surfaces, sintering ice grains together, and this process becomes more effective for increasing particle energies. Solar UV radiation, cosmic rays, dust in-fall, and cold plasma particles trapped in Saturn’s magnetic field also play an important role in altering the nature and the structure of the native surface ices by the implantation of contaminants, ionization, sputtering, and dissociation of water ice molecules. Additionally, CO2 could be sourced from irradiation of dark organic material. Many of these surface alterations are observable in Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) spectra. We used similar methodologies as have been employed in previous works to derive surface temperatures from Cassini’s Composite Infrared Spectrometer (CIRS), which helped to isolate areas where space weathering due to electron bombardment is more predominant. The subtle changes in VIMS spectra were investigated using machine learning techniques. We present here our results for Dione.

C L Young↗
NASA NTRSDate not supplied

Electron Bombardment on Dione: Surface Compositional Effects and Temperature Anomalies

Saturn’s icy moons are composed primarily of water ice with minor other “contaminants,” such as CO2 ice, and a dark component thought to be organics, hematite and/or metallic Fe [1]. The space weathering process of electron bombardment is expected to be particularly important on the surfaces of Saturn’s inner moons (Mimas, Tethys, Dione, and Rhea), as they orbit within Saturn’s inner magnetosphere. Terrains exhibiting thermal anomalies (i.e., colder temperatures in the day and warmer temperatures at night than surrounding areas) correspond to regions of high energy electron bombardment [2; 3; 4; 5]. Energetic electrons impact the surfaces, sintering ice grains together, and this process becomes more effective for increasing particle energies [6]. Solar UV radiation, cosmic rays, dust in-fall, and cold plasma particles trapped in Saturn’s magnetic field also play an important role in altering the nature and the structure of the native surface ices by the implantation of contaminants, ionization, sputtering, and dissociation of water ice molecules [7]. Additionally, CO2 could be sourced from irradiation of dark organic material [8]. Many of these surface alterations are observable in Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) spectra [9]. We used similar methodologies as have been employed in previous works [e.g., 10] to derive surface temperatures from Cassini’s Composite Infrared Spectrometer (CIRS), which helped to isolate areas where space weathering due to electron bombardment is more predominant. The subtle changes in VIMS spectra were investigated using machine learning techniques. We present here our results for Dione.

Cindy Lee Young↗
NASA NTRSDate not supplied

Electron Bombardment on Dione: Surface Compositional Effects and Temperature Abnormalities

Saturn’s icy moons are composed primarily of water ice with minor other “contaminants,” such as CO2 ice, and a dark component thought to be organics, hematite and/or metallic Fe [1]. The space weathering process of electron bombardment is expected to be particularly important on the surfaces of Saturn’s inner moons (Mimas, Tethys, Dione, and Rhea), as they orbit within Saturn’s inner magnetosphere. Terrains exhibiting thermal anomalies (i.e., colder temperatures in the day and warmer temperatures at night than surrounding areas) correspond to regions of high energy electron bombardment [2; 3; 4; 5]. Energetic electrons impact the surfaces, sintering ice grains together, and this process becomes more effective for increasing particle energies [6]. Solar UV radiation, cosmic rays, dust in-fall, and cold plasma particles trapped in Saturn’s magnetic field also play an important role in altering the nature and the structure of the native surface ices by the implantation of contaminants, ionization, sputtering, and dissociation of water ice molecules [7]. Additionally, CO2 could be sourced from irradiation of dark organic material [8]. Many of these surface alterations are observable in Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) spectra [9]. We used similar methodologies as have been employed in previous works [e.g., 10] to derive surface temperatures from Cassini’s Composite Infrared Spectrometer (CIRS), which helped to isolate areas where space weathering due to electron bombardment is more predominant. The subtle changes in VIMS spectra were investigated using machine learning techniques. We present here our results for Dione. [1] Clark, R. N., et al. (2012) Icarus, 218, 831–860 [2] Howett, C. J. A., et al. (2020) Icarus, 113745 [3] Nordheim, T. A., et al. (2017) Icarus, 286, 56-68 [4] Paranicas, C., et al. (2012) Planetary and Space Science, 61, 60–65 [5] Paranicas, C., et al. (2014) Icarus, 234, 155–161 [6] Schaible, M. J., et al. (2016) Icarus, 0, 1–13 [7] Baragiola, R. A., et al., (2013) Astrophysics and Space Science Library, vol. 356. Springer [8] Mennella, V., et al. (2006) The Astrophysical Journal, 643(2), 923 [9] Scipioni, F., et al. (2017) Icarus, 290, 183-200 [10] Howett, C. J. A., et al. (2014) Icarus, 241, 239-247

C L Young↗
NASA NTRS2004

Palagonitic Mars: A Basalt Centric View of Surface Composition and Aqueous Alteration

Palagonitic tephra from certain areas on Mauna Kea Volcano (Hawaii) are well-established spectral and magnetic analogues of high-albedo regions on Mars. By definition, palagonite is "a yellow or orange isotropic mineraloid formed by hydration and devitrification of basaltic glass." The yellow to orange pigment is nanometer-sized ferric oxide particles (np-Ox) dispersed throughout the hydrated basaltic glass matrix. The hydration state of the np-Ox particles and the matrix is not known, but the best Martian spectral analogues contain allophane-like materials and not crystalline phyllosilicates. Martian low-albedo regions are also characterized by a palagonite-like ferric absorption edge, but, unlike the highalbedo regions, they also show evidence for absorption by ferrous iron. Thermal emission spectra (TES) obtained by the Mars Global Surveyor Thermal Emission Spectrometer suggest that basaltic (surface Type 1) and andesitic (surface Type 2) volcanic compositions preferentially occur in southern (Syrtis Major) and northern (Acidalia) hemispheres, respectively. The absence of a ferric-bearing component in the modeling of TES spectra is in apparent conflict with VNIR spectra of Martian dark regions, as discussed above. However, the andesitic spectra have also been interpreted as oxidized basalt using phyllosilicates instead of high-SiO2 glass as endmembers in the spectral deconvolution of surface Type 2 TES spectra. We show here that laboratory VNIR and TES spectra of rinds on basaltic rocks are spectral endmembers that provide a consistent explanation for both VNIR and TES data of Martian dark regions.

Morris, R. V.↗
NASA NTRS1974

On the surface composition of Io

The wavelength dependence of the reflectivity of Io indicates the presence of two materials on the surface of this satellite of Jupiter. These materials are sulfur and an unspecified material (R1) which shows a wavelength dependence of its reflectivity for wavelengths from 0.3 to 1.0 micron similar to the non-H2O frost spectrum of the rings of Saturn. A 60/40 admixture of these two spectra matches the observed reflection spectrum of Io from 0.3 to 3.0 microns, if the spectrum of R1 is featureless for wavelengths above 1 micron. Sulfur will give rise to a posteclipse brightening. The variation with wavelength of the temperature dependence of the reflectivity of sulfur will allow an observational confirmation of the presence of sulfur on Io. The material R1 should show a large geometrical albedo. The translucency of sulfur is consistent with the polarization-phase curve of Io. The material R1 is also required to be translucent.

Wamsteker, W.↗
NASA NTRS1982

Martian dust mantling and surface composition - Interpretation of thermophysical properties

The goal of the study presented here is to use the diurnal variation of the differences in the brightness temperatures between each of the four surface-sensing IRTM (infrared thermal mapper) wavelength bands to separate the average grain size determined by the thermal inertia into the surface block population and the inertia of the fine component. It is noted that the thermal emissivity of the surface can also be determined and that this in turn can be used to estimate compositional variations. What is more, the atmospheric dust content can be estimated and used to infer sources and sinks of airborne dust. Owing to the number of unknowns, observations at more than one time of day are necessary to determine each of these parameters independently. The data discussed here were obtained by the IRTM, which had five thermal channels centered at 7, 9, 11, 15, and 20 microns and one channel that measured solar reflectance for from 0.3 to 3.0 microns.

Christensen, P. R.↗
NASA NTRS1987

Spectral reflectance of SNC meteorites: Relationships to Martian surface composition

The spectral signatures of each of the Shergottite-Nakhlite-Chassignite (SNC) meteorite types measured to date are unique among extraterrestrial materials. Reflectance spectra of dark regions of Mars show evidence of basaltic composition. Analytic analysis of absorption band positions and widths in reflectance spectra of SNC meteorites will permit comparisons with spectra from approximately 600 km sized regions for which high-quality, near-IR spectra are available. Multi-spectral mapping data from orbital spacecraft is expected to provide the necessary spectra to determine basaltic compositions of smaller regions on Mars provided fresh, unaltered basalts can be observed or the effects of Martian weathering can be understood and removed from the spectra. With modeling of spectral weathering and mixing of SNC meteoritic assemblages it should be possible with the Mars Observer data to test for the presence of SNC analogs on the Martian surface. Before the relationship between the basaltic composition of units on Mars and the SNC meteorites can be addressed, it is necessary to analyze the absorption band parameters of the SNC reflectance spectra and to acquire high resolution spectral data on smaller regions of the Martian surface.

Mcfadden, L. A.↗
NASA NTRS1992

Reflectance Spectroscopy of Palagonite and Iron-Rich Montmorillonite Clay Mixtures: Implications for the Surface Composition of Mars

Mixtures of a Hawaiian palagonite and an iron-rich, montmorillonite clay (15.8 +/- 0.4 wt% Fe as Fe2O3) were evaluated as Mars surface spectral analogs from their diffuse reflectance spectra. The presence of the 2.2 microns absorption band in the reflectance spectrum of clays and its absence in the Mars spectrum have been interpreted as indicating that highly crystalline aluminous hydroxylated clays cannot be a major mineral component of the soil on Mars. The palagonite sample used in this study does not show this absorption feature in its spectrum. In mixtures of palagonite and iron-rich montmorillonite, the 2.2 microns Al-OH clay lattice band is not seen below 15 wt% montmorillonite. This suggests the possibility that iron-rich montmorillonite clay may be present in the soil of Mars at up to 15 wt% in combination with palagonite, and remain undetected in remotely sensed spectra of Mars.

Orenberg, James↗
NASA NTRS1980

The surface composition of Amalthea

It is proposed that charged particles from the Jovian magnetosphere, contaminants such as sulfur from Io, and high-velocity micrometeoritic matter, combine to darken, redden, and alter the surface of Amalthea revealed by Voyager; whose few isolated bright spots have a distinct greenish spectrum. A major finding of this analysis is that available spectral reflectance data contain little information about the bulk composition of the satellite. The effects of contamination by sulfur and its allotropes are shown to redden a variety of bulk compositions: carbonaceous material, refractory minerals, iron and iron sulfides, and moderate temperature silicates. The bright, greenish spots probably identify locations in which atypical alteration processes occur, such as variations in the amount of contaminant sulfur in micrometeoritic glasses or in the relative abundances of certain sulfur allotropes.

Gradie, J.↗
NASA NTRS1992

Reflectance spectroscopy of palagonite and iron-rich montmorillonite clay mixtures - Implications for the surface composition of Mars

The diffuse reflectance spectra of Hawaiian palagonite mixtures with an Fe-rich montmorillonite have prompted their present use as spectral analogs of the Martian surface. Like the Mars spectrum and unlike clays, the 2.2-micron reflectance spectrum absorption band is not present in the palagonite sample; neither is the 2.2-micron Al-OH clay lattice band seen in palagonite-montmorillonite mixtures, where the latter component remains below 15 wt pct. Fe-rich montmorillonite clay may therefore be present in Mars, in combination with palagonite, while remaining undetected in remotely sensed spectra.

Orenberg, James↗
NASA NTRS1987

Surface composition of Mars: A Viking multispectral view

A new method of analyzing multispectral images takes advantage of the spectral variation from pixel to pixel that is typical for natural planetary surfaces, and treats all pixels as potential mixtures of spectrally distinct materials. For Viking Lander images, mixtures of only three spectral end members (rock, soil, and shade) are sufficient to explain the observed spectral variation to the level of instrumental noise. It was concluded that a large portion of the Martian surface consists of only two spectrally distinct materials, basalt and palgonitic soil. It is emphasized, however, that as viewed through the three broad bandpasses of Viking Orbiter, other materials cannot be distinguished from the mixtures.

Adams, John B.↗
NASA NTRS1977

Asteroid surface compositions from infrared spectroscopic observations - Results and prospects

Advances in IR detector technology, the increased availability of large aperture telescopes, and the techniques of Fourier transform spectroscopy now permit IR (with wavelengths greater than 1 micron) spectroscopic observations of asteroid surfaces. Asteroids already observed include Ceres, Vesta, and Eros. These initial results demonstrate that such studies can contribute new data concerning asteroid compositions. Some of the most diagnostic features of mineral spectra are in the IR spectral region, and for featureless spectra characterized only by slopes the extension of the spectral reflectivity curve into the IR provides tighter constraints on possible mineralogies. A systematic study of additional asteroids should exploit even further this new observational link to problems of meteorite origin and solar system evolution.

Larson, H. P.↗
NASA NTRS1990

Sputter-produced plasma as a measure of satellite surface composition - The Cassini mission

Measurements of the co-orbiting neutral cloud or the plasma produced by sputtering of the icy Saturnian satellites can be used to determine the relative abundance of a minority surface species which would be difficult to determine from reflectance spectra. This is due to the fact that the sputter source rates, hence the plasma supply rates, are directly proportional to the bulk concentrations of mixed solids or clathrates, although the surface grains may be depleted in the most volatile species.

Johnson, R. E.↗
NASA NTRS1979

Surface composition of Pluto

Broadband (J, H, K and L) and narrowband (1.5- to 3.7-micron) infrared photometry of Pluto has been conducted in order to check previous ambiguous observations of methane frost on the planet's surface. In detail, the match between a laboratory spectrum of methane frost and the observed spectrum of Pluto is not good. Nevertheless, the photometric observations suggest the presence of methane in some form.

Lebofsky, L. A.↗
NASA NTRS1976

Surface compositions of the satellites of Saturn from infrared photometry

JHKL photometry (1.2-3.5 microns) of Rhea, Dione, Tethys, and the high-albedo side of Iapetus reveals broadband spectral signatures essentially identical to those of the water-ice-covered surfaces of Ganymede and the rings of Saturn, although significantly different from either the surface of Europa or laboratory measurements of pure water ice. The dark side of Iapetus has more neutral infrared colors, indicative of a nonicy surface.

Morrison, D.↗
NASA NTRS1996

Near-Infrared Spectral Geometric Albedos of Charon and Pluto: Constraints on Charon's Surface Composition

The spectral geometric albedos of Charon and Pluto are derived at near-infrared wavelengths (1.4-2.5 jAm) from measurements obtained in 1987. Comparisons of these to theoretical calculations are used to place constraints on the identity and relative abundances of surface ices on Charon. These compari- sons suggest that widespread regions of pure CH4 ice do not occur on Charon and that if CH4 is abundant on Charon then it is large grained (-5 mm) and is likely mixed at the granular level with H20 ice, and possibly C02 ice.

Roush, Ted L.↗