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At least 91 records · Page 5

Surface roughness effect on finite oil journal bearings

A theoretical study of the performance of finite oil journal bearings is made, considering the surface roughness effect. The total load supporting ability under such a condition derives from the hydrodynamic as well as asperity contact pressure. These two components of load are calculated separately. The average Reynolds equation for partially lubricated surfaces is used to evaluate hydrodynamic pressure. An analytical expression for average film thickness is obtained and introduced to modify the average Reynolds equation. The resulting differential equation is then solved numerically by finite difference methods for mean hydrodynamic pressure, which in turn gives the hydrodynamic load. Assuming the surface height distribution as Gaussian, the asperity contact pressure is found. The effect of surface roughness parameter, surface pattern, eccentricity ratio, and length to diameter ratio on hydrodynamic load and on side leakage is investigated. It is shown that hydrodynamic load increases with increasing surface roughness when both journal and bearing surfaces have identical roughness structures or when the journal only has a rough surface. The trend of hydrodynamic load is reversed if the journal surface is smooth and the bearing surface is rough.

Majumdar, B. C.↗

Remote sensing of soils, land forms, and land use in the northern great plains in preparation for ERTS applications

Research to determine the optimum time or season for obtaining imagery to identify and map soil limitations was conducted in the proposed Oahe irrigation project area in South Dakota. The optimum time for securing photographs or imagery is when the soil surface patterns are most apparent. For cultivated areas similar to the study area, May is the optimum time. The fields are cultivated or the planted crop has not yet masked soil surface features. Soil limitations in 59 percent of the field of the flight line could be mapped using the above criteria. The remaining fields cannot be mapped because the vegetation or growing crops do not express features related to soil differences. This suggests that imagery from more than one year is necessary to map completely the soil limitations of Oahe area by remote sensing techniques. Imagery from the other times studied is not suitable for identifying and mapping soil limitations of Oahe area by remote sensing techniques. Imagery from the other times studied is not suitable for identifying and mapping soil limitations because the vegetative cover masked the soil surface and does not reflect soil differences.

Frazee, C. J.↗

Drag measurements in tubular structure elements. Part 3: Effect of diameter and surface structure on the drag of cylindrical tubes

Measurements on five cylinders with different surfaces show that the supercritical drag coefficient tends to 0.5 for smooth cylinders with maximum critical Re number 4.16 times 10 to the -5 power and to 0.6 for point pattern surfaces with Re number reduced to 2.16 times 10 to the -5 power. For the other surfaces, with increasing roughness the critical Re number decrease while both minimum supercritical drag coefficients increase.

Schulz, G.↗

Reexamining supercritical gas adsorption theories in nano-porous shales under geological conditions

Adsorption is an important phenomenon in surface chemistry, especially for nano-porous shales. In the shale gas-in-place, adsorbed gas could contribute up to 85%. However, adsorption is hard to quantitatively characterize due to different adsorption mechanisms, patterns, surfaces, and pore sizes. Moreover, key thermodynamic parameters, such as the enthalpy of adsorption, are challenging to determine due to uncertainties in adsorbed gas densities used in constructing absolute isotherms. In this paper, we revisit the Brunauer, Emmett, and Teller (BET) model, analytically simplify Ono-Kondo (OK) models for subsurface shales, and compare commonly used mono- and multilayer adsorption models (e.g., Langmuir, supercritical Dubinin-Radushkevich (SDR), supercritical BET (SBET), and simplified OK (OKs) models) with recently proposed pressure-dependent adsorption densities to develop a practical and reliable methodology that can be used in the supercritical state, typical for subsurface black shale conditions.Three independent data sets were used for nitrogen and methane adsorption isotherms at different temperatures. Furthermore, we demonstrate that adsorption predicted by the SDR model is comparable or lower than that predicted by the SBET model, but higher than the amounts predicted by Langmuir and OK models. The nitrogen BET method tends to underestimate the accessible SSA for methane. Measurement of isosteric heat of adsorption is suggested instead of the experimental fitting method, due to the significant difference between the calculated results by two commonly used methods. Experimental fitting and simulation methods are also briefly reviewed to guide future research on shale gas adsorption.

58 GEOSCIENCES↗

Geology of Utah and Nevada by ERTS imagery

The author has identified the following significant results. Two ancient watercourses have been observed on ERTS-1 imagery. These lie in the Waterpocket Fold area, north of the Marble Canyon section of the Colorado River, in Arizona and Utah. A third old watercourse of interest is an ancient canyon of the Colorado and is located on image no. 1156-17260. Image no. 1051-17414 contains some very useful information concerning the hydrology, sedimentology, and biology of Great Salt Lake and Bear Lake in Utah. In Great Salt Lake, there is a sharp line between the portion of the lake north of the railroad causeway and that south of the causeway. There is a marked difference in salinity across the causeway, and this is reflected in different algal species. On the same image, sediment plumes in Bear Lake clearly delineate the circulation pattern, and provide excellent indications of bottom contours over much of the area. Image no. 1051-17420 contains part of Great Salt Lake and all of Utah Lake. The latter displays a very interesting surface pattern which is probably due to an algal bloom which has been swirled into a spiral by the circulation of the lake.

Jensen, M. L.↗

Frictional heating due to asperity interaction of elastohydrodynamic line-contact surfaces

A numerical solution of an elastohydrodynamically lubricated (EHL) line contact between two long, rough-surface cylinders that considers the frictional heating of asperities was obtained. Pressure distribution, temperature distribution, film thickness and EHL load for given speeds, lubricant properties, material properties of surfaces, and surface roughness parameters were theoretically solved by simultaneous solution of the elasticity equation and the Reynolds equation for two partially lubricated rough surfaces. The pressure due to asperity contact was calculated by assuming a Gaussian distribution of surface irregularities. The elastic deformation used for film thickness computation was found from the two kinds of pressure by plane strain analysis. The temperature rise in the contact zone was calculated by using the Blok-Jaeger flash temperature model. The effects of surface roughness on EHL load for various slide-role ratios, surface roughness parameters, surface patterns, and temperature parameters was studied. It was found that the maximum temperature rise in most cases occurred in the inlet zone, and that the minimum film thickness decreased and the maximum temperature increased as the surface roughness was increased.

Majumdar, B. C.↗

Long-term variability of solar magnetic-fields

Studies of the variations of the solar magnetic field are reviewed. Consideration is given to the study of 600 Myr-old Australiain varve data showing the 22-yr magnetic cycle and variations with 300-400 yr periods (Williams, 1981 and Bracewell, 1985). Methods of interpreting the organization of large-scale solar field patterns are discussed. Other studies examined include the interpretation of modal structure in the photospheric field by Stenflo et al. (1988), and the study of Sheeley et al. (1987) showing that much of the large-scale surface pattern can be deduced from the measured emerging flux.

Hoeksema, J. Todd↗

On the use of the hole-drilling technique for residual stress measurements in thin plates

The strain gage blind hole-drilling technique may be used to determine residual stresses at and below the surface of components. In this paper, the hole-drilling analysis methodology for thick plates is reviewed, and experimental data are used to evaluate the methodology and to assess its applicability to thin plates. Data on the effects of gage pattern, surface preparation, hole spacing, hole eccentricity, and stress level are also presented.

Hampton, R. W.↗

Influence of Terminal Carboxyl Groups on the Structure and Reactivity of Functionalized m-Carboranethiolate Self-Assembled Monolayers

The structure and function of self-assembled monolayers (SAMs) at the nanoscale are determined by the steric and electronic effects of their building blocks. Carboranethiol molecules form pristine monolayers that provide tunable two-dimensional systems to probe lateral and interfacial interactions. Additional ω-functionality, such as carboxyl groups, can be introduced to change the properties of the exposed surfaces. Here, two geometrically similar isomeric m-carborane analogues of m-mercaptobenzoic acid, 1-COOH-7-SH-1,7-C 2 B 10 H 10 and racem-1-COOH-9-SH-1,7-C 2 B 10 H 10 , are characterized and their SAMs on Au{111} are examined. The latter isomer belongs to the rare group of chiral cage molecules and becomes, to our knowledge, the first example assembled on Au{111}. Although different in symmetry, molecules of both isomers assemble into similar hexagonal surface patterns. The nearest-neighbor spacing of 8.4 ± 0.4 Å is larger than that of non-carboxylated isomers, consistent with the increased steric demands of the carboxyl groups. Computational modeling reproduced this spacing and suggests a tilt relative to the surface normal. However, tilt domains are not observed experimentally, suggesting the presence of strong lateral interactions. Analyses of the influence of the functional groups through the pseudo-aromatic m-carborane skeleton showed that the thiol group attached to either carbon or boron atoms increases the carboxyl group acidity in solution. In contrast, the acidity of the exposed carboxyl group in the SAMs decreases upon surface attachment; computational analyses suggest that the driving force of this shift is the dielectric of the environment in the monolayer as a result of confined intermolecular interactions, proximity to the Au surface, and partial desolvation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Satellite detection of air pollutants

NASA's ERTS-1 satellite, with its high resolution and multispectral capabilities, has been found useful in the detection and analysis of smoke from large point sources (power plants, steel mills, etc.), and widespread atmospheric turbidity associated with atmospheric stagnations. Smoke plumes from the Chicago-Northern Indiana industrial complex have been tracked over Lake Michigan for over 100 km. Experience has shown that smoke plumes are relatively easy to detect over water (in the 0.6-0.7 micrometer band) but much more difficult over land surfaces. Pattern recognition techniques (cluster analysis) were applied to the digital ERTS data, and it was found that the smoke plumes indeed had a unique spectral signature. Studies are currently underway to use measured plume geometries to obtain quantitative estimates of diffusion over water surfaces.

Lyons, W. A.↗

Experimental Investigation of Hexcomb-Pattern Roughness Effects on Transition Onset and Turbulent Heating Augmentation at Mach 6

An experimental investigation of hexcomb-patterned surface roughness effects on boundary-layer transition and turbulent heating has been performed. Two representative entry vehicle geometries, a spherical- cap aeroshell and a sphere-cone aeroshell, were considered. Multiple cast ceramic models of each geometry were fabricated with varying roughness pattern densities and depths that simulated an ablated hexcomb-structure thermal protection system. Wind tunnel testing was performed at Mach 6 over a range of Reynolds numbers sufficient to produce laminar, transitional, and turbulent flow. Aeroheating and boundary-layer transition onset data were obtained using global phosphor thermography. The experimental heating data are presented herein, as are comparisons to laminar and turbulent smooth-w ll heat transfer distributions from computational flow field simulations.

Hollis, Brian R.↗

Water color and circulation southern Chesapeake Bay, part 1

Satellite imagery from two EREP passes over the Rappahannock Estuary of the Chesapeake region is analyzed to chart colored water types, to delineate color boundaries and define circulatory patterns. Surface observations from boats and helicopters concurrent with Skylab overpass define the distributions of suspended sediment, transparency, temperature, salinity, phytoplankton, color of suspended material and optical ratio. Important features recorded by the imagery are a large-scale turbidity maximum and massive red tide blooms. Water movement is revealed by small-scale mixing patterns and tidal plumes of apparent sediment-laden water. The color patterns broadly reflect the bottom topography and the seaward gradient of suspended material between the river and the bay. Analyses of red, green and natural color photos by microdensitometry demonstrate the utility of charting water color types of potential use for managing estuarine water quality. The Skylab imagery is superior to aerial photography and surface observations for charting water color.

Nichols, M. M.↗

Hexcomb Pattern Roughness Effects on Blunt Body Transition and Heating

An experimental investigation of hexcomb pattern surface roughness effects on boundary-layer transition and convective heating has been performed. Two representative entry vehicle geometries, a spherical-cap aeroshell and a sphere-cone aeroshell, were considered. Multiple cast ceramic models of each geometry were fabricated with various roughness pattern densities and depths that simulated an ablated hexcomb-structure thermal protection system. Wind tunnel testing was performed at Mach 6 over a range of Reynolds numbers sufficient to produce laminar, transitional, and turbulent flow. Aeroheating and boundary-layer transition onset data were obtained using global phosphor thermography. The experimental heating data are presented herein, as are comparisons to laminar and turbulent smooth-wall heat transfer distributions from computational flow field simulations. The experimental data were used to develop a unified boundary-layer transition correlation for both sandgrain distributed roughness and hexcomb pattern roughness.

Brian R Hollis↗

Towards Spatial Control of Reaction Selectivity on Photocatalysts using Area Selective Atomic Layer Deposition on Model Dual Site Electrocatalyst Platform

Photocatalytic water splitting is a promising route to low-cost H2; however, this approach is currently limited by solar-to-hydrogen (STH) conversion efficiencies in the sub-10% range. Z-scheme water splitting, in which H2 and O2 evolving particles are operated in separate compartments and electronically coupled by a soluble redox mediator, offers improvements in STH efficiency but introduces high rates of undesired side and back reactions. Nanoscopic oxide coatings (e.g., CrOx, and SiOx) have previously been used to selectively block undesired reactants from reaching active sites; however, a coating encapsulating the entire photocatalyst particle limits activity as the particle can no longer facilitate both half reactions. In contrast to photodeposition, which may produce non-uniform overlayers due to the difficulty of controlling local electrochemical reactivity on the surface, area-selective atomic layer deposition (AS-ALD) can be used to deposit conformal ultrathin oxide coatings while preserving access to non-growth areas of a substrate surface. To develop this technique for Z-scheme photocatalysts, we performed AS-ALD of TiO2 on a dual site planar electrocatalyst based on interdigitated arrays of Pt and Au. Self-assembled monolayers of 1-octadecanethiol (ODT) were used to block growth on the Au array, resulting in a patterned surface in which only the Pt sites were encapsulated with TiO2. These electrocatalysts demonstrated localized reaction selectivity for hydrogen evolution reaction (HER) over the TiO2/Pt sites, while the uncoated Au sites retained activity towards Fe(II)/Fe(III) redox (FeRR). Under independent potential control, these microelectrodes showed that selectively deposited TiO2 coatings can suppress the rate of back reactions on neighboring active sites by an order of magnitude compared to uncoated control samples.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Reynolds number effects on surface shear stress patterns around isolated hemispheres

Obstacles projecting into the wind stream alter the shear stress on the surface around them, thus altering the erosion, transportation, and deposition of aeolian sediment. The effect of Reynolds number on the pattern of shear stress on the surface around an isolated hemisphere was investigated. An understanding of Reynolds number effects is necessary if wind tunnel results are to be scaled up to natural situations for meaningful applications. The experiment shows that the surface shear stress pattern is strongly affected by Reynolds number, at least within the range of Re used (1360 to 2977). This is presumably due to a decrease in flow around the sides of the hemisphere and an increase in flow over the object as the Reynolds number increases.

Lee, J. A.↗

Demonstration of nearly pinhole-free epitaxial aluminum thin films by sputter beam epitaxy

Superconducting resonators with high quality factors have been fabricated from aluminum films, suggesting potential applications in quantum computing. Improvement of thin film crystal quality and removal of void and pinhole defects will improve quality factor and functional yield. Epitaxial aluminum films with superb crystallinity, high surface smoothness, and interface sharpness were successfully grown on the c-plane of sapphire using sputter beam epitaxy. This study assesses the effects of varying substrate preparation conditions and growth and prebake temperatures on crystallinity and smoothness. X-ray diffraction and reflectivity measurements yield extensive Laue oscillations and Kiessig thickness fringes for films grown at 200 °C under 15 mTorr Ar, indicating excellent crystallinity and surface smoothness; moreover, an additional substrate preparation procedure which involves (1) a modified substrate cleaning procedure and (2) prebake at 700 °C in 20 mTorr O 2 is shown by atomic force microscopy to yield nearly pinhole-free film growth while maintaining epitaxy and high crystal quality. The modified cleaning procedure is environmentally friendly and eliminates the acid etch steps common to conventional sapphire preparation, suggesting potential industrial application both on standard epitaxial and patterned surface sapphire substrates.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Shuttle ascent and shock impingement aerodynamic heating studies

The collection and analysis of aerodynamic heating data obtained from shock impingement experimental investigation were completed. The data were categorized into four interference areas; fin leading edge, wing/fuselage fin/plate corners, and space shuttle configurations. The effects of shock impingement were found to increase the heating rates 10 to 40 times the undisturbed values. A test program was completed at NASA/Langley Research Center to investigate the magnitudes and surface patterns of the mated shock interference flowfield. A 0.0065 scale thin-skin model of the MDAC 256-20 space shuttle booster mated with a Stycast model of the MDAC Internal tank orbiter was tested in the 20-inch M=6 tunnel, the 31-inch M=10 tunnel, and the 48-inch Unitary Plan Tunnel. The gap region of the ascent configuration was the principal area of interest where both thermocouple and phase-change paint data were obtained. Pressure and heat transfer distributions data on the leeward surface of a 75-degree sweep slab delta wing are presented. The effects of surface roughness on boundary layer transition and aerodynamic heating were investigated.

Lanning, W. D.↗

Wind abrasion on Mars

Aeolian activity was predicted for Mars from earth based observations of changing surface patterns that were interpreted as dust storms. Mariner 9 images showed conclusive evidence for aeolian processes in the form of active dust storms and various aeolian landforms including dunes and yardangs. Windspeeds to initiate particle movement are an order of magnitude higher on Mars than on Earth because of the low atmospheric density on Mars. In order to determine rates of abrasion by wind blown particles, knowledge of three factors is required: (1) particle parameters such as numbers and velocities of windblown grains as functions of windspeeds at various heights above the surface; (2) the susceptibility to abrasion of various rocks and minerals; and (3) wind frequencies and speeds. For estimates appropriate to Mars, data for the first two parameters can be determined through lab and wind tunnel tests; data for the last two factors are available directly from the Viking Lander meteorology experiments for the two landing sites.

Greeley, Ronald↗