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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Unprecedented electrical performance of friction-extruded copper-graphene composites

Copper-graphene composites show remarkable electrical performance surpassing traditional copper conductors albeit at a micron scale; there are several challenges in demonstrating similar performance at the bulk scale. In this study, we used shear extrusion to synthesize macro-scale copper-graphene composites with a simultaneously lower temperature coefficient of resistance (TCR) and improved electrical conductivity over copper-only samples. We showed that the addition of 18 ppm of graphene decreased the TCR of C11000 alloy by nearly 11%. A suite of characterization tools involving scanning and transmission electron microscopy along with atom probe tomography were used to characterize the grain size, crystallographic orientation, structure, and composition of copper grains and graphene additives in the feedstock and processed samples. We posit that the shear extrusion process may have transformed some of the feedstock graphene additives into higher defect-density agglomerates while retaining the structure of others as mono-to-trilete flakes with lower defect density. The combination of these additives with heterogeneous structures may have been responsible for the simultaneous decrease in TCR and enhanced electrical conductivity of the copper-graphene ShAPE composites.

36 MATERIALS SCIENCE↗
DOE OSTI2024

The Influence of Microstructure on TCR for Inkjet-Printed Resistive Temperature Detectors Fabricated Using AgNO 3 /Ethylene-Glycol-Based Inks

This study investigated the influence of microstructure on the performance of Ag inkjet-printed, resistive temperature detectors (RTDs) fabricated using particle-free inks based on a silver nitrate (AgNO 3 ) precursor and ethylene glycol as the ink solvent. Specifically, the temperature coefficient of resistance (TCR) and sensitivity for sensors printed using inks that use monoethylene glycol (mono-EG), diethylene glycol (di-EG), and triethylene glycol (tri-EG) and subjected to a low-pressure argon (Ar) plasma after printing were investigated. Scanning electron microscopy (SEM) confirmed previous findings that microstructure is strongly influenced by the ink solvent, with mono-EG inks producing dense structures, while di- and tri-EG inks produce porous structures, with tri-EG inks yielding the most porous structures. RTD testing revealed that sensors printed using mono-EG ink exhibited the highest TCR (1.7 × 10 -3 /°C), followed by di-EG ink (8.2 × 10 -4 /°C) and tri-EG ink (7.2 × 10 -4 /°C). These findings indicate that porosity exhibits a strong negative influence on TCR. Sensitivity was not strongly influenced by microstructure but rather by the resistance of RTD. The highest sensitivity (0.84 Ω/°C) was observed for an RTD printed using mono-EG ink but not under plasma exposure conditions that yield the highest TCR.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Probing O 2 dependence of hydroperoxy-butyl reactions via isomer-resolved speciation

Degenerate chain-branching mechanisms of n-alkanes are centered on the formation of hydroperoxy-alkyl radicals ($\dot{Q}$OOH), formed via $\dot{R}$ + O 2 reactions, and the ensuing competition between unimolecular decomposition and second-O 2 -addition. Quantitative measurements of partially oxidized intermediates formed via reactions of $\dot{Q}$OOH provide critical constraints that are required for accurate modeling of combustion chemistry. To examine the influence of temperature and oxygen concentration on intermediates from unimolecular decomposition of $\dot{Q}$OOH, isomer-resolved speciation measurements were conducted on n-butane oxidation at 835 Torr in a jet-stirred reactor (JSR) from 500 – 900 K. Resulting from negative-temperature coefficient behavior, cyclic ether formation peaked at two temperatures, 650 K and 800 K, which were selected for separate experiments to quantify the O 2 -dependence of species profiles using O 2 concentrations of 4.2 · 10 17 – 1.1 · 10 19 molecules cm –3 . Utilizing vacuum-ultraviolet absorption spectroscopy and electron-impact mass spectrometry, cyclic ether isomers were quantified separately, including explicit resolution of cis– and trans– isomers of 2,3-dimethyloxirane. Stereoisomers of 2-butene were also quantified explicitly. For all cyclic ethers, a common trend in O 2 -dependence emerged: species concentrations reach a maximum near 3.0 · 10 18 molecules cm –3 (equivalence ratio of 0.5). Although quantitative disparities are evident, chemical kinetics modeling qualitatively reproduces the O 2 dependence of species at 650 K. However, at 800 K, weak dependence on O 2 is predicted, which is in contrast with the measurements. Two carbonyls, diacetyl and methyl vinyl ketone, were also quantified and follow similar dependence on [O 2 ] and temperature as the cyclic ethers, which indicates some fraction forms via $\dot{Q}$OOH-mediated reactions. The discrepancies between the measured and model-predicted species profiles indicate that sub-mechanisms for important intermediates may require additional elementary reactions, including stereochemical-specific reactions, to improve the fidelity of n-alkane combustion modeling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1973

Nondestructive testing of electro thermal devices

This paper describes the results of a recent investigation into 'thermal time constant' nondestructive testing of high reliability electrical fuses. The use of established nondestructive test technology for examining the quality and firing characteristics of electro-explosive devices has been successfully applied to the inspection and prediction of the functional performance of electrical fuses. The technique requires application of a low level current pulse to the electrical fuse with an oscilloscope display of the curve as generated by the temperature coefficient of resistance feedback. The heating curve of temperature vs time is composed of one predominant thermal time constant, which is the product of the test unit's thermal capacity and thermal resistance. It has been found that the quality of the individual electrical fuse, for instance, the relative condition of the critical internal weld or solder joint, can be examined nondestructively.

Earnest, J. E., Jr.↗
DOE OSTI2022

Multi-Physics Investigation of a Natural Circulation Molten Salt Micro-Reactor that Utilizes an Experimental In-Pile Device to Improve Core Physics and System Thermal-Hydraulic Performance.

INL employee PhD Dissertation - The Molten Salt Reactor (MSR) concept is a rapidly evolving Generation IV design that has recently attracted favorable attention due to the potential for reducing waste generation, realizing passive safety features, and seizing on the opportunity for cost effective economics. This thesis investigates the performance benefit of a new device invented by the doctoral candidate. The device is referred to as a Wrapped Helix around an Inclined Plane or WHIP. The WHIP is protected under a provisional patent filed with the USA Patent Office on 28 September 2021 under application number 63/261,776, BEA docket number BA-1254. The WHIP device can be located in-core or near-core to promoted enhanced thermal-hydraulics and neutronics performance. While the WHIP can be employed in a variety of solid or liquid fuel designs, this thesis investigates the device’s benefit in the application of a natural-circulation, micro-molten salt nuclear battery concept (MsNB). This thesis will specifically investigate the temperature coefficient of the MsNB fuel (FLiNaK) using novel temperature sensitivity techniques unique to Serpent particle transport code, evaluate the WHIP’s thermal-hydraulic and neutronic performance effects using both established (STAR-CCM+) and novel (Python code developed to estimate the circulation effective delayed neutron fraction, ßef f ) analytical and numerical methods, evaluate the neutron noise behavior of the MsNB and how the WHIP may alter the character of the MsNB’s transfer function, and how the WHIP affects the autonomous, load-following performance under transient power conditions using Python code developed by the candidate. The sum body of this work, in part, has been published in three journal articles as the timing of the provisional patent process has allowed. Results show that creative utilization of WHIP engineering design and function reduces reactor system volume, fuel loading, control/stability in the buoyant regime

buoyant flow↗
DOE OSTI2022

Chemical kinetic interactions and sensitivity analyses for 2-ethylhexyl nitrate-doped PRF91 using a reduced mechanism

A numerical and experimental investigation about the chemical kinetic interactions between 2-ethylhexylnitrate (EHN) and PRF91 was performed in this study. Rapid compression machine experiments were conducted to investigate the effect of EHN on the autoignition reactivity of the fuel, and a reduced chemical kinetic mechanism was developed including an EHN sub-model. Experiments showed that the ignition delay decreases as the fuel is doped with EHN, but the effect of the doping level of EHN on the ignition is highly non-linear. Moreover, experiments showed that the EHN effectiveness is lowest during the transition between the low-temperature regime and the negative temperature coefficient (NTC) regime, and it rapidly increases as the temperature increases. Both detailed and (developed) reduced mechanisms were validated against the experimental results, allowing a more in-depth EHN-fuel chemistry study. Additionally, ignition delay sensitivity and EHN effectiveness sensitivity analyses were performed with the reduced mechanism to identify the reactions that control the interaction between EHN and the fuel. As the result, EHN thermal decomposition is only relevant for very low temperatures. The chemistry of EHN-doped fuel is more sensitive to intermediate temperature reactions than that of straight fuel, especially at lower temperatures, due to the effect of EHN on the NTC behavior of the fuel. Finally, the chemistry of EHN-doped fuel is very sensitive to NO 2 -to-NO reactions, especially at high temperatures, because these reactions transform the NO 2 generated by EHN into NO, which is a very effective fuel reactivity enhancer.

2-ethylhexyl nitrate↗
NASA NTRS1975

Self-regulating proportionally controlled heating apparatus and technique

A self-regulating proportionally controlled heating apparatus and technique is provided wherein a single electrical resistance heating element having a temperature coefficient of resistance serves simultaneously as a heater and temperature sensor. The heating element is current-driven and the voltage drop across the heating element is monitored and a component extracted which is attributable to a change in actual temperature of the heating element from a desired reference temperature, so as to produce a resulting error signal. The error signal is utilized to control the level of the heater drive current and the actual heater temperature in a direction to reduce the noted temperature difference. The continuous nature of the process for deriving the error signal feedback information results in true proportional control of the heating element without the necessity for current-switching which may interfere with nearby sensitive circuits, and with no cyclical variation in the controlled temperature.

Strange, M. G.↗
NASA NTRS1961

A Satellite Borne Cadmium Sulfide Total Corpuscular Energy Detector

The properties of single crystals of cadmium sulfide as radiation detectors are described. It has been found possible to select crystals such that: (a) The ratio of increase of conductivity under irradiation to the rate of absorption of energy in the crystal is substantially independent of particle energy (over the examined ranges of 500 ev to 80 kev for electrons and 5 kev to 180 kev for protons) and of the magnitude of energy flux (over the range from.005 to 10 ergs/cm(sup 2 -sec); and (b) The above ration is substantially the same for protons, electrons, alpha particles, x-rays, and gamma-rays. For a driving voltage of 100 volts, typical crystal yield currents of 10(sup -7) to 10(sup- 6) amperes for each erg/cm(sup 2-sec) of energy absorbed by the crystal. The threshold of such crystal detectors (resulting from dark currents of the order of 10(sup 10 amp) is typically 10(sup -3) ergs/cm(sup 2- sec). For the selected crystals a response-temperature coefficient of -0.25% per degree centigrade is found for the temperature range -50 deg C to + 50 deg C. A description is given of a complete CdS total corpuscular energy detector for the study of geomagnetically trapped radiation by means of a satellite. The detector described has a dynamic range great than 10(sup 4), a solid angle of 10(exp -3) steradian, and a detection threshold of approximately 1 erg/cm(sup 2-sec-sterad). A similar detector employing a small magnet for the selective exclusion of electrons is also described. Noteworthy practical features of these detectors for satellite and space probe experiments are: (a) Use of bare crystals, without covering foils, in order to detect charged particles having energies as low as hundreds of electron volts. (b) Simplicity of electronic auxiliaries. (c) Compactness, lightweight and nechanical ruggedness. (d) Low electrical power requirements; and (e) Conversion of conduction current to the rate of a twostate relaxation oscillator in order to facilitate telemetric transmission of data. A pair of such detectors was flown as part of the s-46 satellite payload on March 23, 1960, but due to vehicular failure an orbit was not achieved and the operation of the CdS detectors was observed for only, six minutes of flight.

Freeman, John W.↗
NASA NTRS2015

Aspects of Cool-Flame Supported Droplet Combustion in Microgravity

Droplet combustion experiments performed on board the International Space Station have shown that normal-alkane fuels with negative temperature coefficient (NTC) chemistry can support quasi-steady, low-temperature combustion without any visible flame. Here we review the results for n-decane, n-heptane, and n-octane droplets burning in carbon dioxidehelium diluted environments at different pressures and initial droplet sizes. Experimental results for cool-flame burning rates, flame standoff ratios, and extinction diameters are compared against simplified theoretical models of the phenomenon. A simplified quasi-steady model based on the partial-burning regime of Lin predicts the burning rate, and flame standoff ratio reasonably well for all three normal alkanes. The second-stage cool-flame burning and extinction following the first-stage hot-flame combustion, however, shows a small dependence on the initial droplet size, thus deviating from the quasi-steady results. An asymptotic model that estimates the oxygen depletion by the hot flame and its influence on cool-flame burning rates is shown to correct the quasi-steady results and provide a better comparison with the measured burning-rate results.This work was supported by the NASA Space Life and Physical Sciences Research and Applications Program and the International Space Station Program.

cool flames↗
NASA NTRS2018

Three Stage Cool Flame Droplet Burning Behavior of n-Alkane Droplets at Elevated Pressure Conditions: Hot, Warm and Cool Flame

Transient, isolated n-alkane droplet combustion is simulated at elevated pressure for helium-diluent substituted-air mixtures. We report the presence of unique quasi-steady, three-stage burning behavior of large sphero-symmetric n-alkane droplets at these elevated pressures and helium substituted ambient fractions. Upon initiation of reaction, hot-flame diffusive burning of large droplets is initiated that radiatively extinguishes to establish cool flame burning conditions in nitrogen/oxygen “air” at atmospheric and elevated pressures. However, at elevated pressure and moderate helium substitution for nitrogen ( X He > 20%), the initiated cool flame burning proceeds through two distinct, quasi-steady-state, cool flame burning conditions. The classical “Hot flame ” ( ∼1500 K) radiatively extinguishes into a “Warm flame ” burning mode at a moderate maximum reaction zone temperature ( ∼ 970 K), followed by a transition to a lower temperature ( ∼765 K), quasi-steady “Cool flame ” burning condition. The reaction zone (“flame”) temperatures are associated with distinctly different yields in intermediate reaction products within the reaction zones and surrounding near-field, and the flame-standoff ratios characterizing each burning mode progressively decrease. The presence of all three stages first appears with helium substitution near 20%, and the duration of each stage is observed to be strongly dependent on helium substitutions level between 20–60%. For helium substitution greater than 60%, the hot flame extinction is followed by only the lower temperature cool flame burning mode. In addition to the strong coupling between the diffusive loss of both energy and species and the slowly evolving degenerate branching in the low and negative temperature coefficient (NTC) kinetic regimes, the competition between the low-temperature chain branching and intermediate-temperature chain termination reactions control the “Warm” and “Cool ” flame quasi-steady conditions and transitioning dynamics.

Droplet Combustion↗
DOE OSTI2021

Ultra-wide bandgap β-Ga 2 O 3 films: Optical, phonon, and temperature response properties

Optical and phonon interactions of Ga 2 O 3 thin films with nanocrystalline morphology were studied at extreme temperatures. The films were grown using a sputtering technique and analyzed via temperature response transmission, Raman scattering, and high-resolution deep-UV photoluminescence (PL). Raman modes indicated that the structure corresponds to the β-phase. The optical-gap at the range of 77–620 K exhibited a redshift of ~200 meV, with a temperature coefficient of ~0.4 meV/K. The optical-gap at room-temperature is 4.85 eV. The electron–phonon interaction model at that temperature range pointed to a low energy phonon, ~31 meV, that is involved in the thermal properties of the optical-gap. Detailed Urbach energy analysis indicated that defects are the dominant mechanism controlling the band-edge characteristics even at an elevated temperature regime where phonon dominance is usually expected. Defects are attributed to the disordered forms of graphite that were detected via Raman scattering and to the granular morphology of the film. A deep-UV laser with an above bandgap exaction line of 5.1 eV was employed to map the PL of the films. The highly resolved spectra, even at room-temperature, show a strong emission of ~3.56 eV attributed to self-trapped holes (STHs). The STH is discussed and modeled in terms of the self-trapped exciton. Moreover, a very distinct but low-intensity emission was found at 4.85 eV that agrees with the value of the optical-gap and is attributed to bandgap recombination. The intensity ratio between the STH and that of the bandgap was found to be 6:1.

36 MATERIALS SCIENCE↗
NASA NTRS1973

Implementation of a self-controlling heater

Temperature control of radiation sensors, targets, and other critical components is a common requirement in modern scientific instruments. Conventional control systems use a heater and a temperature sensor mounted on the body to be controlled. For proportional control, the sensor provides feedback to circuitry which drives the heater with an amount of power proportional to the temperature error. It is impractical or undesirable to mount both a heater and a sensor on certain components such as ultra-small parts or thin filaments. In principle, a variable current through the element is used for heating, and the change in voltage drop due to the element's temperature coefficient is separated and used to monitor or control its own temperature. Since there are no thermal propagation delays between heater and sensor, such control systems are exceptionally stable.

Strange, M. G.↗
NASA NTRS2004

Small Mercury Ion Clock for On-board Spacecraft Navigation

I.Small Ion Clock Approach and Heritage: a) No lasers, uwave cavities, cryogenics, atomic beams, etc. b) Ions are electrically shuttled between separate optical and microwave traps. II. Each trap is optimized for its task: quadrupole for optical state selection; multi-pole for microwave clock. a) Very good stability shown in USNO. Timescale running "open loop." III. "Open loop" operation means no self-measurements of frequency offsets: (Zeeman, ion temperature,... etc.) a) Fewer parts and procedures, produces stable output continuously. IV. Ion clock is not so sensitive to temperature fluctuations a) Measured u:nshielded temperature coefficient of few 10(exp -15) per C. b) No bulky temperature isolation needed.

Prestage, John D.↗
NASA NTRS1994

Characterization of path effects on the properties of balloon films

The effect of stress and temperature path on the mechanical properties of a balloon film material (Astrofilm E2) have been studied using two techniques. The first technique is based on uniaxial tensile measurements of prestrained strips of the film as a function of temperature. Data are analyzed in terms of two temperature coefficients, defined here as a stiffness coefficient and a strength coefficient; and by comparing the areas under the stress-strain curves. The second technique investigated the effect of stress and temperature path on inflated cylinders of the same material. The changes in the mechanical properties due to preconditioning in the biaxial stress state were evaluated using the ball burst test. Preliminary findings indicate that the material is stress and temperature path dependent. Changes in stiffness coefficient, draw strength and toughness were measured and discussed. The above techniques may be suitable to document path dependent changes, and to discriminate among films of different manufacture.

Said, Magdi A.↗
NASA NTRS1986

Temperature dependence of association of diatomic ions in diatomic gases

The present study compares the experimental rate coefficient temperature dependences for the association of diatomic ions in diatomic gases with the results of model calculations in which it is assumed that the stabilization of the initially formed unstable association complex occurs through the formation of a 'supercomplex'. The acceptable degree of agreement obtained between model and experimental data for the cases of four sample reactions, on the basis of a minimum of plausible assumptions, indicates that earlier theoretical models furnishing an accurate description of the formation and destruction of the association complex, but failing to reproduce experimental data, inadequately treated the temperature dependence of the stabilization step.

Johnsen, R.↗
DOE OSTI2020

A comparative reactivity study of 1-alkene fuels from ethylene to 1-heptene

In this work, a comparative reactivity study of 1-alkene fuels from ethylene to 1-heptene has been performed using ignition delay time (IDT) measurements from both a high-pressure shock tube and a rapid compression machine, at an equivalence ratio of 1.0 in ‘air’, at a pressure of 30 atm in the temperature range of 600–1300 K. At low temperatures (< 950 K), the results show that 1-alkenes with longer carbon chains show higher fuel reactivity, with 1-pentene being the first fuel to show negative temperature coefficient (NTC) behavior followed by 1-hexene and 1-heptene. At high temperatures (> 950 K), the experimental results show that all of the fuels except propene show very similar fuel reactivity, with the IDTs of propene being approximately four times longer than for all of the other 1-alkenes. To analyze the experimental results, a chemistry mechanism has been developed using consistent rate constants for these alkenes. At 650 K, flux analyses show that hydroxyl radicals add to the double bond, followed by addition to molecular oxygen producing hydroxy-alkylperoxy radicals, which can proceed via the Waddington mechanism or alternate internal H-atom isomerizations in chain branching similar to those for alkanes. We have found that the major chain propagation reaction pathways that compete with chain branching pathyways mainly produce hydroxyl rather than hydroperoxyl radicals, which explains the less pronounced NTC behavior for larger 1-alkenes compared to their corresponding alkanes. At 1200 K, flux analyses show that the accumulation of hydroperoxyl radicals is important for the auto-ignition of 1-alkenes from propene to 1-heptene. The rate of production of hydroperoxyl radicals for 1-alkenes from 1-butene to 1-heptene is higher than that for propene, which is due to the longer carbon chain facilitating hydroperoxyl radical formation via more efficient reaction pathways. This is the major reason that propene presents lower fuel reactivity than the other 1-alkenes at high temperatures.

1-Alkene↗
NASA NTRS1981

Low temperature latching solenoid

A magnetically latching solenoid includes a pull-in coil and a delatching coil. Each of the coils is constructed with a combination of wire materials, including material of low temperature coefficient of resistivity to enable the solenoid to be operated at cryogenic temperatures while maintaining sufficient coil resistance. An armature is spring-based toward a first position, that may extend beyond the field of force of a permanent magnet. When voltage is temporarily applied across the pull-in magnet, the induced electromagnetic forces overcome the spring force and pulls the armature to a second position within the field of the permanent magnet, which latches the armature in the pulled-in position. Application of voltage across the delatching coil induces electromagnetic force which at least partially temporarily nullifies the field of the permanent magnet at the armature, thereby delatching the armature and allowing the spring to move the armature to the first position.

Wang, W. S.↗
NASA NTRS1990

Thermocapillary flow and melt/solid interfaces in floating-zone crystal growth under microgravity

Computer simulation of steady-state axisymmetrical heat transfer and fluid flow was conducted to study thermocapillary flow and melt/solid interfaces in floating-zone crystal growth under microgravity. The effects of key variables on the extent of thermocapillary flow in the melt zone, the shapes of melt/solid interfaces and the length of the melt zone were discussed. These variables are: (1) the temperature coefficient of surface tension (or the Marangoni number), (2) the pulling speed (or the Peclet number), (3) the feed rod radius, (4) the ambient temperature distribution, (5) the heat transfer coefficient (or the Biot number), and (6) the thermal diffusivity of the material (or the Prandtl number).

Lan, C. W.↗