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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Characteristics of Electron Precipitation During 40 Energetic Electron Injections Inferred via Subionospheric VLF Signal Propagation

Energetic electron injection events are associated with energetic electron precipitation (EEP) through possible resonant wave-particle interactions. Previous studies confirm the impacts of injection-driven precipitation on observed amplitude/phase of subionospheric VLF (very low frequency) signals transmitted from distant artificial transmitters. Currently, there are substantial uncertainties on precipitation characteristics and flux during injection events. In this work we study 40 injection events selected by Van Allen Probes particle data to investigate the changes in amplitude and phase of VLF signals at ground receivers across Canada during particle injection events. We model the ionospheric effect of the EEP flux to find its impact on VLF propagation and characterize the injection events. Typically, we find a clear phase advance of ~40° in the received VLF signal at Fort Smith (Canada, L = 8) transmitted from U.S. Navy communication transmitter NAA at Maine (USA). Comparing to other VLF transmitter-receiver paths in North America leads us to conclude that effects are only seen on paths with adequately large range >>200 km) through L > 7. Modeling the VLF phase change indicates that in the majority of events (>90%), less than 10% of the strong scattering limit inferred from particle flux measurements at the Van Allen Probes is required to obtain the observed VLF phase signature. The median precipitating flux during energetic particle injections is less than 4 × 10 6 el/cm 2 s sr (<10% of the strong scattering rate) for electrons above ~40 keV extracted from trapped particles energy spectrum. This implies that strong scattering is not typical for these 40 selected energetic electron injection events.

79 ASTRONOMY AND ASTROPHYSICS↗

Control of the optical properties of gum and dentin tissue of a human tooth at laser spectral lines in the range of 200 – 800 nm

A change in the optical properties of the tissue of the gums and dentin of a human tooth is experimentally investigated in vitro with the application of a 99.5 % glycerol solution. The kinetics of the total transmittance in the spectral range of 200 – 800 nm on characteristic laser lines is studied. It is shown that the effectiveness of optical clearing, expressed as a relative increase in the total transmittance, for gum tissue in the laser radiation range of 200 – 800 nm can vary significantly (by an order of magnitude). In this case, the absolute values of optical transmittance in the UV region are relatively small due to the strong absorption by the endogenous chromophores of the studied tissues, and in the visible and NIR regions, on the contrary, they are significant, which is due to the absence of strongly absorbing chromophores. The effectiveness of dentin clearing in the entire visible and NIR spectral regions is on average 25 % for 300 minutes of immersion of the sample in a 99.5 % glycerol solution. The presented results are necessary for increasing the efficiency of laser therapy and methods for optical monitoring of morphological changes in biological tissues for the purpose of early diagnosis of diseases. (paper)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Unconventional optical properties of 2D Janus SMoSe induced by structural asymmetry

The Janus SMoSe monolayer that is best-known for its structural asymmetry is found to exhibit unconventional optical properties compared with its counterpart MoSe 2 . Optical transmittance measurements on monolayers that are directly synthesized on sapphire substrates reveal that the transmittance, as well as the real and imaginary parts of the optical dielectric constants of Janus SMoSe obtained from the Kramers–Kronig constrained analysis, show strong dependence on the polarization direction of the incident light. Meanwhile, the transmittance of the unpolarized light of Janus SMoSe becomes insensitive to light at incident angles up to 30°. The intrinsic dipoles induced by the structural asymmetry of Janus SMoSe are believed to produce these distinct optical properties. Finally, by estimating the optical absorption of the intrinsic dipoles and tracing their dependence on the light incident angles, we speculate that the dipoles are not perpendicularly aligned to the in-plane direction of the monolayer, but rather tilted by a small angle between 0° and 10°.

36 MATERIALS SCIENCE↗

Experimental decoy-state Bennett-Brassard 1984 quantum key distribution through a turbulent channel

In free-space quantum key distribution (QKD) in turbulent conditions, scattering and beam wandering cause intensity fluctuations which decrease the detected signal-to-noise ratio. This effect can be mitigated by rejecting received bits when the channel's transmittance is below a threshold. Thus, the overall error rate is reduced and the secure key rate increases despite the deletion of bits. In this work, we implement recently proposed selection methods focusing on the prefixed-threshold real-time selection (P-RTS) where a cutoff can be chosen prior to data collection and independently of the transmittance distribution. We perform finite-size decoy-state Bennett-Brassard 1984 QKD in a laboratory setting where we simulate the atmospheric turbulence using an acousto-optical modulator. We show that P-RTS can yield considerably higher secure key rates for a wide range of the atmospheric channel parameters. In addition, we evaluate the performance of the P-RTS method for a realistically finite sample size. We demonstrate that a near-optimal selection threshold can be predetermined even with imperfect knowledge of the channel transmittance distribution parameters.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Dynamic attenuation scheme in measurement-device-independent quantum key distribution over turbulent channels

Measurement-device-independent quantum key distribution (MDI QKD) offers great security in practice because it removes all detector side channels. However, conducting MDI QKD over free-space channels is challenging. One of the largest culprits is the mismatched transmittance of the two independent turbulent channels causing a reduced Hong-Ou-Mandel visibility and thus a lower secret key rate. Here we introduce a dynamic attenuation scheme, where the transmittance of each of the two channels is monitored in real time by transmitting bright light pulses from each users to the measurement device. Based on the measured channel transmittance, a suitable amount of attenuation is introduced to the low-loss channel at the measurement device. Our simulation results show a significant improvement of QKD performance, especially when using short raw keys.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Survival, healing, and swim performance of juvenile migratory sea lamprey ( Petromyzon marinus ) implanted with a new acoustic microtransmitter designed for small eel-like fishes

Background: Little is known about the transformer stage of the parasitic lampreys, a brief but critical period that encompasses juvenile out-migration from rivers to lakes or oceans to begin parasitic feeding. Information about this life stage could have significant conservation implications for both imperiled and invasive lampreys. We investigated tag retention, survival, wound healing, and swim performance of newly transformed sea lamprey (Petromyzon marinus) implanted with a new micro-acoustic transmitter, the eel–lamprey acoustic transmitter (ELAT), in a controlled laboratory environment. Results: The 61-day survival of our tagged subjects was 71%, within the range reported in similar studies of juvenile lampreys. However, survival was significantly lower in the tagged animals (vs control), with no effect statistically attributable to measures of animal length, mass, condition, or population of origin (Great Lakes vs. Atlantic drainage). Mortality in tagged fish was concentrated in the first four days post-surgery, suggesting injury from the surgical process. An unusually long recovery time from anesthesia may have contributed to the increased mortality. In a simple burst swim assay, tagged animals swam significantly slower (– 22.5%) than untagged animals, but were not significantly different in endurance swim tests. A composite wound healing score at day four was a significant predictor of maximum burst swim speed at day 20, and wound condition was related to animal mass, but not length, at the time of tagging. Conclusions: Impairments to survival and swim performance of juvenile sea lamprey implanted with the ELAT transmitter were within currently reported ranges for telemetry studies with small, difficult to observe fishes. Our results could be improved with more refined anesthesia and surgical techniques. The ability to track migratory movements of imperiled and pest populations of parasitic lampreys will improve our ability to estimate vital rates that underlie recruitment to the adult population (growth, survival) and to investigate the environmental factors that regulate the timing and rates of movement, in wild populations.

59 BASIC BIOLOGICAL SCIENCES↗

Broadband, millimeter-wave antireflection coatings for large-format, cryogenic aluminum oxide optics

Here, we present two prescriptions for broadband (~77 -252 GHz), millimeter-wave antireflection coatings for cryogenic, sintered polycrystalline aluminum oxide optics: one for large-format (700 mm diameter) planar and plano–convex elements, the other for densely packed arrays of quasi-optical elements—in our case, 5 mm diameter half-spheres (called “lenslets”). The coatings comprise three layers of commercially available, polytetrafluoroethylene-based, dielectric sheet material. The lenslet coating is molded to fit the 150 mm diameter arrays directly, while the large-diameter lenses are coated using a tiled approach. We review the fabrication processes for both prescriptions, then discuss laboratory measurements of their transmittance and reflectance. In addition, we present the inferred refractive indices and loss tangents for the coating materials and the aluminum oxide substrate. We find that at 150 GHz and 300 K the large-format coating sample achieves (97±2)% transmittance, and the lenslet coating sample achieves (94±3)% transmittance.

36 MATERIALS SCIENCE↗

Correcting thermal-emission-induced detector saturation in infrared spectroscopy

We found that temperature-dependent infrared spectroscopy measurements (i.e., reflectance or transmittance) using a Fourier-transform spectrometer can have substantial errors, especially for elevated sample temperatures and collection using an objective lens. These errors can arise as a result of partial detector saturation due to thermal emission from the measured sample reaching the detector, resulting in nonphysical apparent reduction of reflectance or transmittance with increasing sample temperature. Here, we demonstrate that these temperature-dependent errors can be corrected by implementing several levels of optical attenuation that enable convergence testing of the measured reflectance or transmittance as the thermal-emission signal is reduced, or by applying correction factors that can be inferred by looking at the spectral regions where the sample is not expected to have a substantial temperature dependence.

47 OTHER INSTRUMENTATION↗

High-Spectral Resolution Lidar (HSRL) Instrument Handbook

High-spectral-resolution lidar (HSRL) systems provide vertical profiles of optical depth, backscatter cross-section, depolarization, and backscatter phase function. All HSRL measurements are calibrated by reference to molecular scattering, which is measured at each point in the lidar profile. Like the Raman lidar (RL), but unlike simple backscatter lidars such as the micropulse lidar (MPL), this enables the HSRL to measure backscatter cross-sections and optical depths without prior assumptions about the scattering properties of the atmosphere. The depolarization observations allow robust discrimination between ice and water clouds. Rigorous error estimates can be computed for all measurements. A very narrow angular field of view reduces multiple scattering contributions. The small field of view, coupled with a narrow optical bandwidth, nearly eliminates noise due to scattered sunlight. The laser transmitter is a diode-pumped, frequency-doubled Nd:YAG laser. Narrow-band, single-frequency operation is provided by injection seeding with a single-frequency, cw-diode-pumped diode laser. The main laser cavity is maintained in resonance with the seed laser by adjusting the cavity length to minimize the time between the Q-switch trigger and the emission of the laser pulse. The emission wavelength is tuned via temperature control of the seed laser crystal and is locked to line #1109 of the iodine absorption spectra. Locking is accomplished by minimizing the transmission through a 2-cm-long iodine absorption cell. Use of a high-repetition-rate laser and expansion of the transmitted beam through a 400-mm telescope reduces the transmitted energy density to eye-safe levels. It is possible to look directly into the output beam without hazard. The receiver and transmitter use the same afocal telescope, simplifying the maintenance of stable alignment of the transmitter and receiver although the angular FOV is only 100 μrad. The small FOV and the 4-kHz repetition rate also limit the near-field signal strength, making it possible to record continuous profiles that start at an altitude of ~100 m and extend to 30 km using photon counting detectors. The small FOV also suppresses multiple scattering contributions.

54 ENVIRONMENTAL SCIENCES↗

Coherent Wavelength Switched Co-Packaged Optics to Disrupt Datacenters/HPC (AKA "QRock") (Final Report)

This project resulted in multiple first-of-a-kind demonstrations, including two generations of transmitters, a receiver, and a complete coherent link. The transmitter architecture, based on EAMs to generate QPSK modulation was first demonstrated in InP, which has limitations for scaling up to chips with multiple channels for full WDM architectures, and implementing the densities and level of integration needed to implement co-packaging with electronics. Our work resulted in the first demonstration of this architecture on a Si platform compatible with copackaging, and our working prototypes illustrated the potential of the approach. The link demonstration was also the first coherent optical link realized in a multi-micron waveguide platform. For the transmitters, integrating efficient III-V EAM devices into the large waveguide Si platform simultaneously enables significant reduction in driver power consumption while minimizing optical losses in routing and fiber coupling. On the receiver side, optical coupling and propagation losses are also minimized in the multi-micron platform, reducing required laser optical power which improves link energy efficiency. The measurement results presented in the final report demonstrate that we achieved the speed objectives for the program (112Gb/s: 56Gbaud QPSK), albeit at a higher BER than targeted. The report provides assessments of the low-powercoherent link architecture and associated components developed under the program from both technological and commercial viewpoints.

97 MATHEMATICS AND COMPUTING↗

Digital Grid Twin–Direct Communication Scheme Test Bed for Assessing Relay-to-Relay Radio Antenna and Optical Fiber Performance and Misoperations

This study introduces a novel “Digital Grid Twin–Direct Communication Scheme” test bed. This advanced platform evaluates point-to-point communication between transmitter and receiver relays with optical fiber and radio omnidirectional antenna systems, implemented at the Advanced Protection lab in the Grid Research Innovation and Development Center at Oak Ridge National Laboratory. The increased diversity of energy sources has led to more protective relay misoperations. In North America, microgrid protection schemes now use point-to-point communication along distribution lines between relays to implement advanced logic in nonradial grids that include both high- and low-inertia generators. This trend challenges utilities to minimize misoperations while ensuring rapid fault clearance and accurate selectivity coordination between primary and backup relays. This study assesses relay-to-relay communication schemes by introducing an advanced testing platform based on a digital grid twin protection test bed using a synchronized time source system. The platform evaluates the communication system using radio antennas or optical fiber links by integrating protective relays that operate breakers within the digital twin and record relay events and communication signals. In the experiments, transmitter and receiver relays were configured with inverse time overcurrent and breaker trip detection logic to assess the total time of the communication protection schemes based on the sum of the relay protection element operating time, radio latency, propagation delay, baud rate delay, and relay processing time. These delays were derived from recorded relay events and communication signals from the interface of a real-time simulator set as a digital grid twin. The test bed successfully simulated various electrical faults along a distribution line while ensuring effective and reliable point-to-point communication between transmitter and receiver relays. The radio antenna communication system exhibited latency because of the radio. This latency depends on the baud rate setting and type of radio application; in general, the higher the baud rate, the lower the radio latency. The measured radio latency (for Mirrored Bits with an encryption card at 9,600 bps) was about 9–10 ms. Additionally, calculated propagation delay per mile for radio antennas and optical fiber was 5.36 µs/mi and 8.04 µs/mi, respectively. Optical fiber communication did not demonstrate radio latency. Instead, the protection element operating time depends mainly on the protection logic function set in the relay, and the relay processing time depends on the processing rate of the relay in samples per power system cycle.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Fluid characterization using acoustics

A measurement system and a method for determining steam quality (i.e. vapor mass fraction) measurements of multiphase fluid flowing through pipes are described. An acoustic sensor device consists of an acoustic transmitter and an acoustic receiver that are designed to be attached to a pipe. The acoustic transmitter and the acoustic receiver are exposed to an interior space of the pipe through openings in a wall of the pipe. Acoustic waves generated by the transmitter and captured by the receiver traverse the multiphase fluid flowing into the pipe. Swept-frequency acoustic interferometry (SFAI) technique is used to measure ultrasonic acoustic properties of a fluid. Machine-learning techniques based on principal component analysis, support vector machine regression and support vector machine classification are used for determining steam quality.

47 OTHER INSTRUMENTATION↗

Adaptive materials and systems for manipulation of electromagnetic radiation

Fully artificial, adaptive composite materials and systems, having variable transmittance, reflectance, and/or absorptance to radiation in visible, infrared, or other desired region of the electromagnetic spectrum, and methods of the manufacture and use thereof are provided. The adaptive composite materials and systems possess an unprecedented combination of properties and are, therefore, poised to enable a broad range of practical applications. The adaptive composite material incorporates at least one size-variable active area having a variable transmittance, reflectance, and/or absorptance in at least a portion of the electromagnetic spectrum and comprises at least: an elastomer substrate, a texturizing layer disposed on top of the substrate, and an optional reflective coating disposed on top of the texturizing layer. In operation, the stretching and relaxation of the elastomer substrate causes changes in the surface morphology of the texturized layers (e.g., the change in the size and depth of surface features in the texturizing layer), this in turn results in the increased or decreased transmittivity, reflectivity, and/or absorptivity of the active area.

Gorodetsky, Alon A.↗

Design, characterization and indoor validation of the optical soiling detector “DUSST”

Nowadays, photovoltaic (PV) technology has reached a high level of maturity in terms of module efficiency and cost competitiveness in comparison with other energy technologies. As PV has achieved high levels of deployment, the development of devices that can help to reduce PV operation and maintenance costs has become a priority. Soiling can be cause of significant losses in certain PV plants and its detection has become essential to ensure a correct mitigation. For this reason, accurate and low-cost monitoring devices are needed. While soiling stations have been traditionally employed to measure the impact of soiling, their high cost and maintenance have led to the development of innovative low-cost optical sensors, such as the device presented in this work and named “DUSST” (Detector Unit for Soiling Spectral Transmittance). The thermal characterization of DUSST’s components and the methodology used to predict soiling transmittance losses are presented in this study. The results demonstrate that the losses can be predicted with an error lower than 1.4%. The method has been verified with an experimental campaign with naturally soiled coupons exposed outdoors in Jaén, Spain.

14 SOLAR ENERGY↗

Fibril Network Strategy Enables High‐Performance Semitransparent Organic Solar Cells

Abstract The development of semitransparent organic solar cells (ST‐OSCs) represents a significant step toward the commercialization of OSCs. However, the trade‐off between power conversion efficiency (PCE) and average visible transmittance (AVT) restricts further improvements of ST‐OSCs. Herein, it is demonstrated that a fibril network strategy can enable ST‐OSCs with a high PCE and AVT simultaneously. A wide‐bandgap polymer PBT1‐C‐2Cl that can self‐assemble into a fibril nanostructure is used as the donor and a near‐infrared small molecule Y6 is adopted as the acceptor. It is found that a tiny amount of PBT1‐C‐2Cl in the blend can form a high speed pathway for hole transport due to the well distributed fibril nanostructure, which increases the transmittance in the visible region. Meanwhile, the acceptor Y6 guarantees sufficient light absorption. Using this strategy, the optimized ST‐OSCs yield a high PCE of 9.1% with an AVT of over 40% and significant light utilization efficiency of 3.65% at donor/acceptor ratio of 0.25:1. This work demonstrates a simple and effective approach to realizing high PCE and AVT of ST‐OSCs simultaneously.

Xie, Yuanpeng↗

Transparent and Conductive Polyimide‐Ionene Hybrid Interlayers for High Performance and Cost‐Effective Semitransparent Organic Solar Cells

The contradiction between high transmittance and favorable conductivity poses a great challenge in developing effective cathode interlayer (CIL) materials with sufficient thickness tolerance, which hinders the further advancement of organic solar cells (OSCs). Herein, a completely new class of alcohol processable polyimide-ionene hybrids (PIIHs) is proposed by melding pyromellitic diimide (PMD) subunits into imidazolium-based ionenes backbone covalently. These PIIHs, named PMD-DI and PMD-PD, boast high transparency, suitable energy levels, and decent conductivity. A higher PMD content endows PMD-PD with improved work function tunability, electrical properties, and crystallinity, enabling PMD-PD as CIL material with excellent thickness-insensitive characteristics, while simultaneously improving device stability significantly. Furthermore, PMD-PD also exhibits good compatibility with various electrodes and active layers, offering solar cell efficiencies of up to 19.91% and 19.29% with Ag and Cu cathodes, respectively. More importantly, the application of PMD-PD can improve the performance of semi-transparent OSCs without losing transmittance, thereby drastically enhancing the light utilization efficiency to 4.04% with an ultrathin, low-cost Cu cathode, that competes with leading optical modulation-free semitransparent OSCs with expensive Ag cathodes. This work opens a pathway to realize transparent and conductive interlayers by strategic molecular design, leading to highly efficient, stable, and cost-effective OSCs suitable for diverse applications.

You, Zuhao↗

Infrared-Transparent Semiconductor Membranes for Electromagnetic Interference Shielding of Millimeter Waves

Here, it is demonstrated that single-crystalline and highly doped GaAs membranes are excellent candidates for realizing infrared-transparent shields of electromagnetic interference at millimeter frequencies. Measured optical transmittance spectra for the semiconductor membranes show resonant features between 750 and 2500 nm, with a 100% maximum transmittance. The shielding effectiveness of the membranes is extracted from measured scattering parameters between 65 and 85 GHz. Selected GaAs membranes and membranes/polyamide films exhibit shielding effectiveness ranging from 22 to 40 dB, which are suitable values to ensure the safe operation of infrared devices for commercial applications. Theoretical calculations based on a plane wave model show that the interplay of primary reflection and multiple internal reflections of the radio-frequency waves results in broadband shielding capabilities of the membrane between 10 and 300 GHz.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Deep Optical Switching on Subpicosecond Timescales in an Amorphous Ge Metamaterial

Active nanostructured optical components show promise as potential building blocks for novel light-based computing and data processing architectures. However, nanoscale all-optical switches that have low activation powers and high-contrast ultrafast switching have been elusive so far. Here, pump–probe measurements performed on amorphous-Ge-based micro-resonator metasurfaces that exhibit strong resonant modes in the mid-infrared are reported. Relative change is observed in transmittance of ΔT/T ≈ 1 with picosecond (down to τ ≈ 0.5 ps) free carrier relaxation rates, obtained with very low pump fluences of 50 μJ cm –2 . In this work, these observations are attributed to efficient free carrier promotion, affecting light transmittance via high quality-factor optical resonances, followed by an increased electron–phonon scattering of free carriers due to the amorphous crystal structure of Ge. Full-wave simulations based on a permittivity model that describes free-carrier damping through crystal structure disorder find excellent agreement with the experimental data. These findings offer an efficient and robust platform for all-optical switching at the nanoscale.

36 MATERIALS SCIENCE↗