Search NASA⌕ Search

SEARCH · Search NASA

Results for “vibrational bands”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

O2 A Band Studies for Cloud Detection and Algorithm Improvement

Detection of cloud parameters from space-based spectrometers can employ the vibrational bands of O2 in the (sup b1)Sigma(sub +)(sub g) yields X(sub 3) Sigma(sup -)(sub g) spin-forbidden electronic transition manifold, particularly the Delta nu = 0 A band. The GOME instrument uses the A band in the Initial Cloud Fitting Algorithm (ICFA). The work reported here consists of making substantial improvements in the line-by-line spectral database for the A band, testing whether an additional correction to the line shape function is necessary in order to correctly model the atmospheric transmission in this band, and calculating prototype cloud and ground template spectra for comparison with satellite measurements.

Chance, K. V.↗
NASA NTRS1982

OH fluorescence in comets - Fluorescence efficiency of the ultraviolet bands

The present investigation is concerned with the calculation of the fluorescence efficiency of OH over a wide range of heliocentric radial velocities. Three vibrational states in each of the two lowest electronic states are included in these calculations, producing a total of nine vibrational bands in the ultraviolet. The attempt is made to reproduce observed, ultraviolet, cometary spectra of OH by utilizing the Swings fluorescence mechanism. The inclusion of four rotational states within each of the three vibrational states and a detailed solar atlas make it possible to match observations very well, although there remain some discrepancies. This ability to reproduce observations provides confidence that the more general results obtained for the fluorescence efficiency as a function of heliocentric radial velocity can be used in interpreting both previous and future observations of OH in comets.

Schleicher, D. G.↗
NASA NTRS1971

Vibrational population distributions in nonequilibrium nozzle expansion flows

Experimental measurements and theoretical calculations of the vibrational population distribution in nonequilibrium nozzle expansion flows of gas mixtures are reported. These studies were directed toward determining whether vibrational energy exchange pumping could lead to laser action on the vibrational bands of a diatomic molecule. Three different types of experiments were conducted. These showed (1) that vibrational energy was preferentially transferred from N2 to CO in supersonic nozzle flows containing these gases; (2) that under some conditions this vibrational energy exchange pumping mechanism created population inversions in the vibrational levels of CO; and (3) that at large expansion ratios the magnitude of these population inversions was sufficient to sustain lasing in the nozzle. A theoretical model was developed to calculate vibrational state population distributions in gas dynamic expansions of a mixture of diatomic gases. Although only isothermal calculations have been completed, these data indicate that population inversions are predicted for conditions similar to those obtained in the nozzle expansion flows.

Watt, W. S.↗
NASA NTRS1976

Intensity measurements for the /2, O/ gamma-band of O2, b 1Sigma-g/+/ - X 3Sigma-g/-/

Line intensities for the P sub P and P sub Q branches of the (2-O) vibrational band of the magnetic dipole electronic transition for the oxygen red system at 6280 A were measured, and the sum of the R sub R and R sub Q branch intensities was taken. A large number of repetitive spectral scans were required for accuracy, because of low absorption values even at optical path lengths from 300 to 600 m. A total of 557 individual measurements of P-branch lines yielded an intensity value for the P-branches, and equivalent widths for 24 spectral scans yielded an intensity value for the R-branch. R-branch to P-branch intensity ratios were taken for the A-band, B-band, and gamma-band (respectively, O-O at 7620 A, 1-O at 6880 A, and 2-O at 6280 A). Intensities for some rotational lines are found, and effects of combined rotation-vibration interaction are probed.

Miller, J. H.↗
NASA NTRS1986

Probing the inner regions of the coma by UV observations of CS in comets

New vibrational bands of CS have been identified in several comets. The relative intensities of these bands are in agreement with a simple model, based upon most of the CS radicals being in the lowest vibrational level. The present observational accuracy is not sufficient to decide between this simple model and an earlier radiative equilibrium model. The observed intensity ratios appear to be similar in different comets, which means that they cannot depend strongly upon the total gas production rates.

Butterworth, P. S.↗
NASA NTRS1988

The detection of a discrete outflow from the young stellar object GL 490

A high-resolution (0.059/cm) M-band spectrum has been obtained of the embedded young stellar object GL490. The spectrum shows interstellar absorption in the fundamental vibrational band, v = 1-0, of (C-12)O. Two strong and narrow (10 km/s) velocity components are present. One, at the velocity of GL490 (vLSR = -16 km/s), is likely gas in the molecular cloud within which GL490 is embedded. The other component is blueshifted by 13 km/s relative to GL490. An observation of emission from the J = 3-2 transition of HCO(+) using a 20-arcsec beam supports the view that the blueshifted gas is near the central object. The -29-km/s feature is interpreted as a recently ejected shell. It is conjectured that the extended outflows of cold molecular gas seen by millimeter CO emission observations are driven by sporadic outbursts rather than by continuous flows from the central object.

Mitchell, G. F.↗
NASA NTRS1992

Comparison of analysis and experiment for gearbox noise

Low contact ratio spur gears were tested in the NASA gear-noise rig to study the noise radiated from the top of the gearbox. Experimental results were compared with a NASA acoustics code to validate the code for predicting transmission noise. The analytical code is based on the boundary element method (BEM) which models the gearbox top as a plate in an infinite baffle. Narrow band vibration spectra measured at 63 nodes on the gearbox top were used to produce input data for the BEM model. The BEM code predicted the total sound power based on the measured vibration. The measured sound power was obtained from an acoustic intensity scan taken near the surface of the gearbox at the same 63 nodes used for vibration measurement. Analytical and experimental results were compared at four different speeds for sound power at each of the narrow band frequencies over the range of 400 to 3200 Hz. Results are also compared for the sound power level at meshing frequency plus three sideband pairs and at selected gearbox resonant frequencies. The difference between predicted and measure sound power is typically less than 3 dB with the predicted value generally less than the measured value.

Oswald, Fred B.↗
NASA NTRS1994

On the vertical thermal structure of Io's atmosphere

A radiative-thermal conduction model for the vertical thermal structure of Io's atmosphere is developed with solar heating by SO2 absorption in UV and near-IR bands and non-local thermodynamic equilibrium (LTE) cooling by SO2 nu(sub 1), nu(sub 2), nu(sub 3), vibrational bands and rotational lines. The model predicts the existence of a mesopause in Io's atmosphere when the surface pressure exceeds approximately 10 nbar. The radiative time constant for establishing a mesosphere/mesopause on Io is only approximately 20 min, whereas the thermospheric radiative time constant is about 1 hr. These time constants are significantly shorter than the diurnal time scale and competitive with dynamic time scales. In the thermosphere when solar UV heating dominates, the asymptotic thermospheric temperature is approximately 270 K, only 140 K greater than the surface temperature because at high altiudes non-LTE cooling by SO2 rotation lines exceeds cooling in the nu(sub 2) virbrational band. Solar-heating-only modles are incapable of generating warm enough atmospheres to satisfy the observational inferences from UV and especially millimeter-wave meausrements. Joule heating driven by the penetration of Jupiter's corotational electric field into Io's conducting ionosphere is demonstrated to be the dominant heating mechanism in the subnanobar regions of Io's atmosphere with tempertures ranging from 150 to 1000 K as a function of decreasing pressure from 1 to 0.1 nbar, The asymoptotic thermospheric temperature can attain a value as high as 1800 K.

Strobel, Darrell F.↗
NASA NTRS1980

Band analysis by spectral curve fitting

A method of estimating the values of the parameters in the models describing the positions, widths, and intensities of the lines in rotation-vibration bands of gases, without the need for line by line analysis, is described. To illustrate the technique, portions of the 1-0 bands of HCl and CO have been analyzed. The values of up to 27 parameters, their standard deviations, and the correlations between the parameters required to describe the spectra have been obtained.

Lin, C. L.↗
NASA NTRS1994

High-resolution spectra of Jupiter's northern auroral ultraviolet emission with the Hubble Space Telescope

The first spectroscopic observations of planetary aurora with the Hubble Space Telescope (HST) are reported. These include spectral regions centered on the H2 Lyman and Werner bands of a region of Jupiter's northern aurora. The observations were made with the Goddard High Resolution Spectrograph (GHRS) using the Large Science Aperture as part of a campaign to study Jupiter at the time of the Ulysses flyby. The individual rotational-vibrational bands are resolved and the observed emissions are essentially all from H2. A rotational-vibrational temperature for H2 of 530 +/- 100 K is derived, a value significantly less than the 850-1100 K reported for Jovian H3(+) in the near-infrared but consistent with the temperature reported for fundamental-band quadrupole H2 emission. Comparison with the Faint Object Camera (FOC) images shows that the observed region was not one of the hot spots of the aurora. The results are interpreted in trms of electron impact excitation of H2 from secondary particles generated by primaries precipitating into Jupiter's atmsophere from the magnetosphere. In the region of the aurora observed, the homopause level is found to be significantly hotter but not necessarily higher than observed at nonauroral latitudes. The equatorial H2 dayglow spectrum was also detected; its intensity was 3.2 kR or 13% of the strength of the observed auroral emission.

Trafton, L. M.↗
NASA NTRS1973

Active transmission isolation/rotor loads measurement system

Modifications were incorporated into a helicopter active transmission isolation system to provide the capability of utilizing the system as a rotor force measuring device. These included; (1) isolator redesign to improve operation and minimize friction, (2) installation of pressure transducers in each isolator, and (3) load cells in series with each torque restraint link. Full scale vibration tests performed during this study on a CH-53A helicopter airframe verified that these modifications do not degrade the systems wide band isolation characteristics. Bench tests performed on each isolator unit indicated that steady and transient loads can be measured to within 1 percent of applied load. Individual isolator vibratory load measurement accuracy was determined to be 4 percent. Load measurement accuracy was found to be independent of variations in all basic isolator operating characteristics. Full scale system load calibration tests on the CH-53A airframe established the feasibility of simultaneously providing wide band vibration isolation and accurate measurement of rotor loads. Principal rotor loads (lift, propulsive force, and torque) were measured to within 2 percent of applied load.

Kenigsberg, I. J.↗
DOE OSTI2025

Characterization of Two Positional Isomers of the Cs + Gly Complex Using Two-Color, IR–IR Photobleaching of the Cryogenically Cooled Ions

Metal ion binding to amino acid residues is an important interaction motif that controls the tertiary structures of oligopeptides. Analyses of the vibrational band patterns displayed by the amino acid scaffolds are commonly used to characterize the local docking motifs. Here we carry out two-color, IR-IR photobleaching measurements to obtain isomer-selective vibrational spectra of the Cs + Gly ion-molecule complex isolated in a cryogenically cooled, radiofrequency ion trap. The distinct band patterns of two non-interconverting isomers are observed and traced to different bidentate binding motifs between Cs + and the glycine scaffold. In one isomer, the ion attaches to the oxygen atoms of the carboxyl group whereas in the other it docks to the amino nitrogen and the carbonyl oxygen. Attachment to the acid head group yields a very diffuse absorption associated the OH group engaged in a strong intramolecular H-bond that closes a 5 membered ring. Furthermore, the band assignments, rearrangement pathways and electrostatic distortion of the electron density distributions in the glycine scaffold by the proximal ion are explored with electronic structure calculations and anharmonic theory.

Infrared spectroscopy↗
NASA NTRS1992

Structures of aspartic acid-96 in the L and N intermediates of bacteriorhodopsin: analysis by Fourier transform infrared spectroscopy

The light-induced difference Fourier transform infrared spectrum between the L or N intermediate minus light-adapted bacteriorhodopsin (BR) was measured in order to examine the protonated states and the changes in the interactions of carboxylic acids of Asp-96 and Asp-115 in these intermediates. Vibrational bands due to the protonated and unprotonated carboxylic acid were identified by isotope shift and band depletion upon substitution of Asp-96 or -115 by asparagine. While the signal due to the deprotonation of Asp-96 was clearly observed in the N intermediate, this residue remained protonated in L. Asp-115 was partially deprotonated in L. The C = O stretching vibration of protonated Asp-96 of L showed almost no shift upon 2H2O substitution, in contrast to the corresponding band of Asp-96 or Asp-115 of BR, which shifted by 9-12 cm-1 under the same conditions. In the model system of acetic acid in organic solvents, such an absence of the shift of the C = O stretching vibration of the protonated carboxylic acid upon 2H2O substitution was seen only when the O-H of acetic acid is hydrogen-bonded. The non-hydrogen-bonded monomer showed the 2H2O-dependent shift. Thus, the O-H bond of Asp-96 enters into hydrogen bonding upon conversion of BR to L. Its increased hydrogen bonding in L is consistent with the observed downshift of the O-H stretching vibration of the carboxylic acid of Asp-96.

NASA Discipline Exobiology↗
NASA NTRS1976

Sound radiation from randomly vibrating beams of finite circular cross section

The radiation of sound from vibrating cylindrical beams is analyzed based on the frequency of the beam vibrations and the physical characteristics of the beam and its surroundings. A statistical analysis of random beam vibrations allows this result to be independent of the boundary conditions at the ends of the beam. The acoustic power radiated by the beam can be determined from a knowledge of the frequency band vibration data without a knowledge of the individual modal vibration amplitudes. A practical example of the usefulness of this technique is provided by the application of the theoretical calculations to the prediction of the octave band acoustic power output of the picking sticks of an automatic textile loom. Calculations are made of the expected octave band sound pressure levels based on measured acceleration data. These theoretical levels are subsequently compared with actual sound pressure level measurements of loom noise.

Sutterlin, M. W.↗
NASA NTRS1978

Infrared band intensities of saturated hydrocarbons

Kramers-Kronig analysis is applied to measured values of spectral reflectance at near-normal incidence to determine the real and the imaginary parts of the complex index of refraction for methane, ethane, propane, n-butane, n-hexane, n-heptane, and n-decane in the liquid state. The results indicate that the strengths of the characteristic bands as measured by the integral of the imaginary part are roughly constant for all the liquid alkanes except for methane. The intensity of the CH valence vibration bands in the spectra of the alkanes except methane is directly proportional to the number of CH groups per unit volume. The relations for the intensity of the bands due to CH2 and CH3 deformations are examined. Characteristic band intensities of the type established for NH4(+) and SO4(2-) groups in solutions and crystals cannot be extended to the more closely coupled CH2 and CH3 groups in alkane molecules.

Pinkley, L. W.↗
NASA NTRS1992

Radiative lifetimes of the CN (A 2 Pi i) electronic state

Radiative lifetimes have been measured for CN (A 2 Pi i v-prime = 2...7). Ground-state radicals formed in the 193 nm photolysis of C2N2 and ClCN were excited to A 2 Pi i v-prime = 2...7 vibrational levels. The decay was monitored by following the fluorescence. Cascading effects were eliminated by working at low pressures and monitoring emission from a single vibrational band. Quenching rates and zero-pressure radiative lifetimes were obtained from Stern-Volmer plots. The lifetimes are significantly lower than previous measurements and theoretical calculations for vibrational states v-prime over 2.

Lu, Richang↗
NASA NTRS1993

Infrared spectroscopy of homogeneously nucleated hydrazine aerosols - Disordered and crystalline phases

It is shown that aerosols generated at low temperatures and high condensation rate spontaneously form in a highly crystalline state. The resonant absorption bands in the IR spectra of these highly crystalline particles are much sharper than any reported previously in the bulk, and reveal details in the N-H vibrational bands that have not been previously observed. A disordered phase is also observed at somewhat higher temperatures. These results are consistent with this being a supercooled liquid. The fact that the spectra associated with these two aerosol phases are quite different is important to any future attempts at detecting hydrazine aerosols in planetary atmospheres by remote sensing techniques.

Dunder, T.↗
NASA NTRS1988

The detection of high-velocity outflows from M8E-IR

A high-resolution (0.059/cm) M band (4.6 micron) spectrum of the embedded young stellar object M8E-IR is presented and discussed. The spectrum shows strong absorption to large blueshifts in the rotational lines of the fundamental vibrational band, v = 1-0, of CO. The absorption is interpreted as being due to gas near to, and flowing from, the central object. The outflowing gas is warm (95-330 K) and consists of discrete velocity components with the very high velocities of 90, 130, 150, and 160 km/s. On the basis of a simple model, it is estimated that the observed outflows are less than 100 yr old.

Mitchell, George F.↗