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Elucidating texture and grain morphology contributions to the micromechanical response of additively manufactured Inconel 625

Microstructural variation of additively manufactured (AM) metal components in comparison to wrought counterparts makes certification for critical applications a challenge. Microscale simulations leveraging modern computational tools may be used to supplement testing of AM microstructures, thus accelerating certification by reducing the number of experiments needed. However, as micromechanical response is closely tied to critical properties like fatigue-life and fracture, utilization of these simulations with macroscale experimental data alone is insufficient. One means to attain microscale experimental data is in situ diffraction data collected from synchrotron X-ray sources. In this work, such data were collected during in situ compression of AM Inconel 625 superalloy. Interpretation of experimental results was assisted by massive (8M element) complementary micromechanical simulations performed on sets of virtual microstructures generated using cellular automata. Together, micromechanical data from diffraction experiments and simulations were used to probe the effects of textured “track” microstructures generated during laser powder bed fusion and directional strength-to-stiffness on micromechanical response. Though fiber-averaged directional strength-to-stiffness ratios were expected to dominate given the high elastic anisotropy of the material, the combination of small variations in texture and specific grain configurations unique to AM microstructures lead to significant variability in micromechanical response after yield. The findings emphasize the importance of high-fidelity microstructural representation that captures key texture components and AM-specific morphology for property prediction of AM metals.

36 MATERIALS SCIENCE

International Workshop on Electronic Structure 2024 (ES 24)

The 36th annual Workshop on Recent Developments in Electronic Structure Theory commenced on June 2-5, 2024 at Boston University with 136 in-person and 75 virtual attendees. The organizing committee was composed of five faculty at Boston University with seven local area faculty comprising the greater Boston area advisory committee. On the first day, two hands-on workshops, NEXMD and ComDMFT were held on June 2, two full days of presentations were held on June 3-4 and one half day on June 5. There were 19 invited speakers who spoke about the state-of-the-art in electronic structure methods, including density functional theory, many-body perturbation theory, and the incorporation of machine learning into electronic structure calculations. In addition, 45 young scientists presented posters on June 4. Housing at a reduced rate was provided at the Boston University dormitories. This conference provided a valuable opportunity for scientists, students, postdocs, and senior researchers alike, to disseminate their latest research results, discuss their ideas and best practices, learn from each other, and form new collaborations.

42 ENGINEERING

Computational capacity in hydrodynamic real-time hybrid simulation applied to simulate the dynamic response of floating offshore wind turbines

Real-time hybrid simulation (RTHS) mitigates similitude distortions in model-scale tests of floating offshore wind turbines (FOWTs) by coupling physical experiments with numerical models in real time. The coupling requires faster-than-real-time numerical computations to satisfy temporal similitude with the physical experiment, presenting a bottleneck for using more complex numerical models in RTHS. This paper presents a hydrodynamic-RTHS (hydro-RTHS) framework for FOWTs that simulates the hydrodynamics physically and the aerodynamics numerically with sensor feedback from the physical testing. The framework adapts the three-loop hardware architecture to leverage greater computational resources and mitigate strict temporal requirements, enabling more computationally demanding numerical analyses in hydro-RTHS. The three-loop hardware architecture integrates multiple machines, each dedicated to either numerical analysis or RTHS controls, with a rate-transition algorithm to synchronize the tasks executed across the different machine processors. Virtual and physical tests verified and validated the hydro-RTHS framework, respectively. The ”virtual” tests, which approximates the physical domain numerically, verified the RTHS framework with respect to a numerical full-scale complete FOWT model simulated in the open-source software, OpenFAST. The virtual tests were able to maintain comparable control signals while enabling greater computational resources for the numerical calculations. Real-world physical tests demonstrated that the hydro-RTHS framework computes aerodynamic forces similar to the complete OpenFAST model, validating the hydro-RTHS framework using the three-loop hardware architecture. Findings show that the hydro-RTHS framework with the three-loop hardware architecture is computationally efficient, with reserve capacity to simulate more complex problems due to the customized software, hardware, and rate-transition algorithm.

17 WIND ENERGY

CRCNS21 Computational Models of Multisensory Integration by Upper Limb in Humanoids and Amputees

This international collaborative research project between Johns Hopkins University (JHU) and the Technical University of Munich (TUM) investigated how the human brain processes and integrates multiple types of sensory information, such as touch and force, with the goal of improving prosthetic limbs for amputees and advancing sensory capabilities in humanoid robots. The research advanced our understanding of how the brain responds to sensory feedback in upper-limb amputees. Through experiments in which amputees received electrical stimulation while performing phantom hand movements, we demonstrated that sensory feedback activates the cortical sensorimotor and multisensory regions, and that these regions communicate dynamically during stimulation. Experiments with intact-limb participants explored the integration of visual, haptic, and force feedback, as well as in virtual reality motor training, further showing how the brain processes multimodal sensory information. In addition, this research inspired work on examining the reliability of where amputees perceive sensations over time, which contributed to a successful doctoral fellowship for continued investigation. Our collaborators at TUM improved multimodal sensor technology combining tactile and thermal feedback for humanoid robots, demonstrating the feasibility of integrating multiple sensor types into a unified system for detecting and responding to environmental stimuli. The experimental methods and analysis techniques developed across both teams, including functional network analysis and multimodal sensor integration, provide a foundation for future research in prosthetics and robotics. This research benefits the public by generating knowledge about how amputees process restored sensory information. Advances in humanoid sensing contribute to safer human-robot interaction. The project also fostered international collaboration and cross-disciplinary training: one TUM doctoral student spent a summer at JHU working on multimodal sensor integration, while two JHU students traveled to TUM to host workshops on neuromorphic sensory encoding and sensory integration.

42 ENGINEERING

Model-based, in-situ, non-destructive qualification and certification of parts made by autonomous additive manufacturing

To address the significant productivity challenges associated with the qualification and certification (Q&C) tasks of additively manufactured (AM) parts, which have traditionally relied on rigorous post‐build inspection and testing, we propose an integrated framework that combines model‐based qualification and certification (MBQ&C) with autonomous additive manufacturing (AAM). MBQ&C employs high‐fidelity predictive models, developed within the Integrated Computational Materials Engineering (ICME) paradigm, to simulate process–structure–property–performance relationships for assessing a part’s fitness for use. Since predictive models are commonly machine learning (ML)-based or reduced-order surrogates of validated physics models, they run efficiently, enabling timely inference. In parallel, the self-driving AAM utilises ML-based adaptive, closed‐loop control strategies to avoid, mitigate, or repair defects and anomalies during fabrication, thereby increasing the likelihood of producing acceptable parts. A key feature of the combined AAM-MBQ&C framework is that predictive models explicitly incorporate defects or anomalies that persist after the build, using instance-specific data captured via in-situ sensing. This customisation enables a build‐specific assessment of fitness for use, rather than relying on nominal or generic parameters. Such individualised evaluation provides a robust basis for Q&C-related acceptance decisions relating to each build. Additionally, the rapid solution capabilities of ML or reduced-order models enable the determination of a part’s suitability for service shortly after build completion. As the framework matures, it has the potential to substantially reduce reliance on conventional point‐design approaches—such as time‐consuming post‐build computed tomography scanning and costly destructive testing. Thus, the AAM-MBQ&C framework represents a transformative, scalable strategy for quality assurance of AM components, as parts produced within a stable, validated, and certified envelope can be certified with reduced testing. Key benefits include: (1) significant gains in Q&C productivity through efficient, model-centric assessment; (2) performance-based classification of defects into critical and non-critical categories; (3) the ability to predict potential deviations in the performance of parts affected by real-time, adaptive process control interventions relative to those produced under a certified process, and (4) the enabling of virtual Q&C for service environments that are difficult, hazardous, or impractical to access or reproduce experimentally. Collectively, these capabilities strengthen the business case for AM, particularly for high‐consequence and mission‐critical applications. Finally, although this work focuses on powder-based AM, the proposed techniques could be extended to AM processes employing alternative feedstock forms.

Gunasegaram, Dayalan

STARTR: An Open-Source MARVEL model for the NRIC Virtual Test Bed [Poster]

The National Reactor Innovation Center (NRIC) seeks to improve the understanding of microreactor physics in industry and academia through the development of a Microreactor Applications Research Validation and Evaluation (MARVEL) reactor-based model, published on the Virtual Test Bed (VTB). To achieve this goal, the Sodium-cooled Thermal-spectrum Advanced Research Test Reactor (STARTR) model was built using publicly available MARVEL specifications where possible and approximations where applicable, and was optimized for fast runtimes for researchers to receive rapid simulation feedback. STARTR will fill a gap between stakeholder interest and available models, as the first Sodium-cooled Thermal Reactor (STR) hosted on the VTB with baseline performance sanctioned by INL. This project involved the definition of all materials used in the reactor, geometry and all reactor subcomponents, and assertion of tallies and simulation settings within OpenMC 0.13.3. This poster details a small subset of the overall reactor physics testing: the two-dimensional power peaking factors and the flux energy spectrum, as well as plots of the created geometry. Future work includes code-to-code verification between the OpenMC-based model and a separately designed MCNP 6.2-based model.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN

Modal Field Reconstruction in Resonant Cavities in the Fundamental and Undermoded Frequency Regimes

Theory, simulations, and experiments are presented that demonstrate reconstruction of electromagnetic fields in a cavity from sparse probe measurements. Such techniques are often referred to as virtual sensing, allowing fields at unobserved locations to be predicted. These methods are appropriate for the fundamental and undermoded regimes, providing the ability to estimate fields (and shielding effectiveness) throughout an arbitrarily shaped cavity from a few judiciously spaced probes. A modal simulation method is implemented that allows the response of arbitrarily shaped cavities to be rapidly computed with respect to varying probe locations and slot parameters, enabling statistical analysis of probe placement on reconstruction performance. A cylindrical vessel with numerous probe holes is developed for experiments, referred to as Perforated Vessel 2 (PV2). Experiments are performed on the vessel with and without a steel box inside, where transmit power is delivered into the vessel either through probes (probe injection) or through slots using an external antenna (slot excitation). Simulations and experiments illustrate that when the number of probes is minimal (equal to the number of mode coefficients to be estimated at each frequency), probe placement is critical to avoid missed peaks and to have acceptable reconstruction error. Probe placement becomes less important as the number of probes is increased, but care is still required to avoid probe locations giving poor performance.

42 ENGINEERING

Fast Response Temperature by airborne measurements over BNF

The original data were collected during the AAF Engineering Flights (AEF2025) in the vicinity of the ARM Bankhead National Forest (BNF) Atmospheric Observatory (https://www.arm.gov/capabilities/observatories/bnf ) in northwestern Alabama in March 2025. The ARM Aerial Facility ArcticShark uncrewed aerial system (UAS, https://www.arm.gov/capabilities/observatories/aaf/uas) was based at the public-use airport of Posey Field, Alabama (FAA LID: 1M4, 34.28027778° N, 87.60055556° W, 283m MSL) from March 9 through March 24, 2025. The ArcticShark UAS performed nine flights, including eight research flights over the AMF3 (BNF Main Site) and Supplemental Facilities to measure atmospheric state, turbulence, surface IR temperature and imagery, and aerosol number concentration and size distribution. The current data set presents fast response temperature in the atmospheric boundary layer and lower free troposphere measured on the airborne platform throughout the field campaign. The primary instruments used to create the current data set were the fine wire thermocouple probe, the Aircraft Integrated Meteorological Measurement System (AIMMS-30), the Pitot-static system (part of UAS flight control), and the infrared gas analyzer sensor for H2O and CO2 (LI-840). All parameters used in temperature calculations (static pressure, True Air Speed, and absolute humidity in form of dew point temperature) were included in the data set. For user convenience, one additional parameter was also included: the type of flight flag (level, up, down, turn, and combination of thereof).

Air temperature, fast response

Wind Power as a Virtual Synchronous Generator (WindVSG)

This project investigated the theory, implemented it in hardware, and validated the Wind as a Virtual Isochronous Generator (WindVSG) concept by combining the advantages of modern dynamic inverter technologies with static, dynamic, and transient electromechanical properties of synchronous machines. During this project we demonstrated how to control the inverters of wind turbine generators (wind alone or in parallel with other GFM sources, such battery energy storage) so that wind power behaves like a synchronous machine-based power plant with a conventional prime mover. For this purpose, testing was conducted at NLR ARIES facility with real 2.5 MW wind-turbine generator operating in GFM mode under dynamic and transient conditions. The team also developed models and conducted simulations for GFM wind power to evaluate stability impacts of GFM operation on power grid. This report describes efforts by the NLR team working in collaboration GE Vernova during 3-year project.

17 WIND ENERGY

Optical and Plasmonic Properties of High-Electron-Density Epitaxial and Oxidative Controlled Titanium Nitride Thin Films

The present paper reports on the fabrication, detailed structural characterizations, and theoretical modeling of titanium nitride (TiN) and its isostructural oxide derivative, titanium oxynitride (TiNO) thin films that have excellent plasmonic properties and that also have the potential to overcome the limitation of noble metal and refractory metals. The TiNO films deposited at 700 °C in high vacuum conditions have the highest reflectance (R = ~ 95%), largest negative dielectric constant (ε 1 = –161), and maximal plasmonic figure of merit (FoM = –ε 1 /ε 2 ) of 1.2, followed by the 600 °C samples deposited in a vacuum (R = ~ 85%, ε 1 = –145, FoM = 0.8) and 700 °C–5 mTorr sample (R = ~ 82%, ε 1 = –8, FoM = 0.3). To corroborate our experimental observations, we calculated the phonon dispersions and Raman active modes of TiNO by using the virtual crystal approximation. From the experimental and theoretical studies, a multilayer optical model has been proposed for the TiN/TiNO epitaxial thin films for obtaining individual complex dielectric functions from which many other optical parameters can be calculated. The advantages of oxide derivatives of TiN are the continuation of similar free electron density as in TiN and the acquisition of additional features such as oxygen-dependent semiconductivity with a tunable bandgap.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Steam generator model design parameter sensitivity study for small modular reactor system

Here, this study focuses on design parameter sensitivity studies pertaining to several Once-Through Steam Generator (OTSG) model cases both with and without a riser using python and advanced risk assessment and optimization tool, i.e. Risk Analysis Virtual Environment (RAVEN) developed at Idaho National Laboratory (INL), to support a Small Modular Reactor (SMR) system. The presented Steam Generator (SG) python-based model is a mathematical representation of a steam-generating unit for a Pressurized Water Reactor (PWR)-type SMR system, including fluid flow and heat transfer equations, models, and correlations. Design studies involve changing the model’s input design parameters (e.g., temperature, pressure, mass flow rate) to observe the resulting effects on the output of the system, such as the Heat Transfer Coefficient (HTC), Reynolds number, Nusselt number, and heat transfer performance. Sensitivity studies analyze the degree to which system output and/or desired parameters (e.g., HTC or heat transfer performance) are sensitive to changes in the input parameters. By using RAVEN, detailed design parametric sensitivity studies. Six input parameters—namely, the pressure, temperature, and mass flow rate for the inlet of the primary-side (hot fluid) and secondary-side (cold fluid) of the SG—were randomly perturbed via RAVEN’s Monte Carlo Sampler module, using uniform distributions (i.e., ±1%, ±5% and ±10 % relative changes) for 600 samples. The analysis results give valuable insights into SG system performance, and provide justification for further research and development such as optimized sensor placement, design verification, validation, and optimization.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS

Tailoring Growth Interfaces of Virtual Substrates for Power Electronics

Power electronics materials are poised to play a critical role in fulfilling next generation energy needs, with up to 90% of future energy demand predicted to flow through power electronics at some point. AlxGa1-xN ranks high among candidate materials, having bipolar dopability, thermal and chemical stability and an ultra-wide bandgap. However, AlGaN growth is limited by a lack of lattice-matched substrates, ultimately stunting material quality at higher thicknesses needed for power electronics applications. Further, high power applications increasingly call for fully vertical device structures, necessitating a conductive substrate. Recently our group identified the (111) plane of TaC as a conductive surface lattice-matched to Al0.55Ga0.45N, taking inspiration from prior work of AlN and GaN binaries on carbide and boride substrates. In this talk we demonstrate the growth of (111)-oriented TaC by RF sputtering. We investigate the interface of TaC with sapphire and SiC substrates and identify means to suppress competing Ta2C nucleation in order to stabilize (111)-oriented TaC. Potential stacking sequences are identified with respect to crystal structure and observed twinning in the TaC films. We next assess structural changes and film recrystallization that results from face-to-face annealing of TaC thin films at high temperatures above 1500 degrees C. Changes to grain structure and domain size are assessed by x-ray diffraction and surface morphology is explored using atomic force microscopy. Figure 1 shows significant improvements to in- and out-of-plane strain following annealing along with the formation of terraced step edges at the film surface. Strain as a function of material composition and thickness is considered, as this may play a major role in future nucleation of AlGaN layers. (1) R. J. in a face-to-face configuration, as illustrated in the schematic at left. Kaplar et al 2017, ECS J. Solid State Sci. Technol. 6 Q3061; (2) D. M. Roberts et al 2022, https://arxiv.org/abs/2208.11769; (3) T. Aizawa et al 2008, J Crys Growth 310, 1 22; (4) R. Liu et al 2002, Appl. Phys. Lett. 81, 3182-3184.

ENGINEERING

Multiplexing and Demultiplexing Signals for Radiography Application Using the Discrete Fourier Transform

Our goal is to develop an X-ray phase-contrast imaging system that can provide excellent soft tissue contrast of phase, attenuation, and small-angle scatter. We propose to replace the common system of G0, G1, and G2 gradings with a biprism array to replace the G1 grading and introduce a novel X-ray tube designed to replace the motion of the phase stepping grading G2. The proposed X-ray tube uses temporal multiplexing to provide simultaneous virtual “electronic phase stepping.” In this work the discrete Fourier transform is used to separate from the composite measurement individual X-ray phase contrast measurements sampled at different frequencies. The method performs a discrete Fourier transform of a composite refence sequence to obtain using the frequency amplitudes calibration factors needed to extract the X-ray phase contrast measurement amplitudes from the composite image. The composite reference sequence is the sum of the individual sequences, at different frequencies, with amplitudes of one. The method takes the discrete Fourier transform of this composite reference sequence; whereby, the amplitude of each frequency component is compared with the total sum of its stand-alone sequence amplitude. A calibration factor is determined so that the amplitude of this composite reference frequency times the calibration factor must equal the total sum of the sequence amplitude—the zero-frequency amplitude of the discrete Fourier transform of its stand-alone sequence. To demultiplex the composite measured signal these calibration factors are multiplied by the amplitudes of the frequency components of the discrete Fourier transform of the composite X-phase-contrast measurement to obtain the amplitude of each frequency encoded measurement. Using these calibration factors, we demonstrate with the discrete Fourier transform in Mathematica the extraction of individual images from a composite image that one would expect obtaining from our proposed new X-ray phase contrast imaging system. We then demonstrate as an example how using images from X-ray phase contrast data one can calculate phase, attenuation and the dark field images using grading phase step data supplied to use from Microworks, GmbH in Karlsruhe, Germany.

42 ENGINEERING

The Dynamic Networks Experiments: Virtual Experiments to Quantify Gains in Nuclear Explosion Monitoring

We describe an ongoing series of virtual experiments conducted collaboratively by four United States National Laboratories: Sandia National Laboratories, Los Alamos National Laboratory, Lawrence Livermore National Laboratory, and Pacific Northwest National Laboratory. These Dynamic Network Experiments (DNEs) provide an experimental framework to evaluate the potential impact of new research tools on nuclear explosion monitoring. The second DNE (DNE2), completed in 2024, exploited waveform data (seismic, infrasound, and electromagnetic) that was recorded by multi-modal sensors within and near the Nevada National Security Site and synthetic radionuclide signatures over multiple time periods. During the execution of DNE2, we processed and analyzed data through a multi-stage event processing pipeline that ingested raw data, performed quality control, detected signals, built events from these signals, located these events, and characterized the events’ source types and sizes. For each stage and over the entire event processing pipeline, we evaluated performance changes by comparing the performance of new data processing methods, models, and algorithms against a baseline. We also performed an additional execution phase to assess event processing pipeline function, speed, and efficiency against that of an expert analyst, including computational and manual efforts. Finally, we assessed the impact and effort of modern computing infrastructure on the monitoring pipeline. This paper describes key elements of the DNEs, from formulation through execution, as demonstrated in DNE2. The DNEs introduce several novel concepts to quantitatively measure the potential impact of new methods on explosion monitoring, including the collaborative design of multi-modal datasets, performance and logistical metrics, and integrated analyses.

42 ENGINEERING

Dielectron production in central Pb-Pb collisions at $\sqrt{s_{NN}}$ = 5.02TeV

The first measurement of the 𝑒 + ⁢𝑒 − pair production at midrapidity and low invariant mass in central Pb-Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV at the Large Hadron Collider is presented. The yield of 𝑒 + ⁢𝑒 − pairs is compared with a cocktail of expected hadronic decay contributions in the invariant mass (𝑚𝑒⁢𝑒) and pair transverse momentum (𝑝 T,𝑒⁢𝑒 ) ranges 𝑚 𝑒⁢𝑒 < 3.5 GeV/𝑐 2 and 𝑝 T,𝑒⁢𝑒 < 8 GeV/𝑐. For 0.18 < 𝑚 𝑒⁢𝑒 < 0.5 GeV/𝑐 2 the ratio of data to the cocktail of hadronic contributions amounts to 1.40 ± 0.11⁢(stat.) ± 0.23 ⁢(syst.) ± 0.16⁢ (cocktail) and 1.42 ± 0.11⁢ (stat.) ± 0.23 (syst.)$^{+0.24}_{−0.29}$ ⁢(cocktail), including or not including medium effects in the estimation of the heavy-flavor background, respectively. It is consistent with predictions from two different models for an additional contribution of thermal 𝑒+⁢𝑒− pairs from the hadronic and partonic phases. In the intermediate-mass range (1.2 < 𝑚 𝑒⁢𝑒 < 2.6 GeV/𝑐 2 ), the pair transverse impact parameter of the 𝑒 + ⁢𝑒 − pairs (DCA𝑒⁢𝑒, where “DCA” denotes “distance of closest approach”) is used for the first time in Pb-Pb collisions to separate displaced dielectrons from heavy-flavor hadron decays from a possible (thermal) contribution produced at the interaction point. The data are consistent with a suppression of 𝑒 + ⁢𝑒 − pairs from $𝑐\bar{𝑐}$ and an additional prompt component. Finally, the first direct-photon measurement in the 10% most central Pb-Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV is reported via the study of virtual direct photons in the transverse momentum range 1 < 𝑝 T < 5 GeV/𝑐. A model including prompt photons, as well as photons from the preequilibrium and fluid-dynamic phases, can reproduce the result, while being at the upper edge of the data uncertainties.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS

Development Fiber Optic Distributed System for Direct Detection of Subsurface Gases Leakages

Carbon, natural gas, and hydrogen gas storage is an emerging solution to safeguard us against pollution, support goals of negative carbon emission, and protect sources of renewable energy. Properly constructed storage wells provide a virtually impervious barrier to any unintended subsurface transmission. The ability to ensure the long-term integrity of such wells is vital to the success of any storage operation and be successful in the public eyes. Therefore, robust monitoring of any gas migration into the subsurface is highly sought. A fiber-optic distributed chemical sensor (DCS) enables monitoring of long-term well integrity along its depth, ensuring the success of any storage operation and bolsters public acceptance of the safety of the reservoir via leak early detection. The same technique can be applied to gas monitoring in pipeline networks and nuclear stockpile monitoring applications. Fiber based Raman spectroscopy enables DCS, as optical fibers can be deployed in virtually any environment and relay spectroscopic information over long distances back to the user. Hollow core fibers (HCF) make excellent DCSs as the air core of the fiber allows gas from the environment to diffuse into the core, which interacts with the laser signal that is carried in the air core. This work builds upon the previous LDRD project, Fiber Optic System for Direct Detection of Carbon Dioxide Leakage in Carbon Storage Wells (21-FS-003), in which the feasibility of Raman spectroscopy detection of Carbon Dioxide (CO2) in HCF detection was demonstrated. We mitigated the risk of this DCS technology by establishing and completing five objectives. The first objective was to model and optically characterize HCF uptake of CO2, establishing the relationship between HCF length, gas diffusion time, detectable gas concentration, and measured Raman intensity. In objective two, we developed a fiber core drilling recipe to enable additional diffusion ports in the fiber core and established a method for maintaining fiber strength and integrity post drilling. Objective three characterized the drilled fibers against the undrilled fibers, establishing the differences in the gas mechanics and optical properties and provided parameters to iterate the drilling process. In objective four, a fusion splicing technique was developed to join the HCF to conventional single-mode fibers, localizing the gas detection point at the drilled HCF hole, emulating a DCS. Lastly, objective five was the testing of the sensor in Edgar Mines at Colorado School of Mines on a CO2 pipeline with a simulated leak, to showcase the ability to detect CO2 leaks. This capstone result showed CO2 leak detection in < 10 minutes, raising the technology readiness level of HCF segments as deployable DCS.

organic

Ultrahigh pressure compaction-resistant thin film crosslinked composite reverse osmosis membranes

In this study, we present a class of thin-film crosslinked (TFX) composite reverse osmosis (RO) membranes that resist physical compaction at ultrahigh pressures (up to 200 bar). Since RO membranes experience compaction at virtually all pressure ranges, the ability to resist compaction has widespread implications for RO membrane technology. The process described herein involves crosslinking a phase inverted porous polyimide (PI) support membrane followed by interfacial polymerization of a polyamide layer, thereby forming a fully thermoset composite membrane structure. We explore a range of phase inversion membrane formation parameters such as PI concentration, solvent-cosolvent ratios, coagulation bath composition, and crosslinking methods in addition to interfacial polymerization reaction chemistry and conditions. Overall, TFX membranes exhibit significantly less compaction compared to hand-cast and commercial high-pressure RO membranes, experiencing less than 10% decline in water permeance and maintaining salt rejection over 99% for NaCl solutions up to 180,000 mg/L with 200 bar applied pressure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

NewLife Nuclear - An Environmentally and Economically Minded Solution for Fusion Energy Waste Handling

Energy demand is rising as a result of innovative and increasingly more energy intensive processes coming to fruition, particularly through the recent interest in the development of AI data centers as well as manufacturing with the push towards increasing domestic manufacturing interest. Fusion energy can provide virtually limitless energy to support this increase in energy demand. Fusion energy concepts, largely classified as magnetic fusion energy (MFE) and inertial fusion energy (IFE) are being pursued, each having unique challenges to overcome before the successful deployment of electricity to the grid. Achieving fusion ignition on the National Ignition Facility, first in December 2022, and eight times since, has demonstrated the scientific viability of the IFE approach. Meanwhile, MFE test stands continue to improve confinement times, making meaningful strides in progressing towards experimental scientific viability. In each of these approaches, an emphasis is placed on generating more power out of the system than what is required to power the system. An under-researched area applicable to both IFE and MFE is handling activated waste coming out of fusion energy systems, both in the course of normal daily operations, as well as in intermittent periods as structural materials may need to be replaced. In the context of an IFE plant system, commonly discussed plant designs suggest targets are ignited within a chamber at a rate of up to one million targets per day. Between each shot, the chamber housing the ignition event will clear a portion of the chamber – resulting in a mixture of vaporized target gas, target debris, and other materials being expelled from the chamber [source]. Additionally, IFE system concepts typically discuss the modularization of plant designs, which are expected to be replaced periodically as the components degrade over time. This would result in the irradiated chamber structure materials, likely metals and alloys, needing to be removed and safely stored. In MFE plant systems, while targets are not ignited at a repetition rate with the frequent chamber clearing as is expected in IFE plant systems, it is anticipated that portions of the confinement area interfacing with the hot plasma will need to be replaced periodically. In each system, without additional investment and research into alternative processing and recycling methods, the result is storing irradiated materials, and other elements in a safe containment area until they are no longer activated. – resulting in significant waste both economic and environmental.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS