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NASA NTRS1986

X-ray spectroscopy of five BL Lacertae objects

Five X-ray bright BL Lacertae objects were observed in the energy range 0.6-4.5 keV with the solid state spectrometer (SSS) of the Einstein Observatory. The 14 SSS spectra obtained represent most of the X-ray spectra of BL Lac objects with resolution better than approximately 3. These data do not reveal the presence of large amounts of thermal gas, with upper limits for the equivalent width of individual spectral features typically less that about 100 eV. However, the SSS spectra are the first set of X-ray data to indicate low-energy absorption in excess of that caused by the cold interstellar matter in the Galaxy. Comparison with contemporaneous, lower energy X-ray data implies that this absorption does not arise in cold neutral material, but in hotter, highly ionized material, probably intrinsic to the source. All five BL Lac objects have X-ray continua that are well fitted by power-law models, with power-law energy indices usually greater than about 1. In a few cases, a flattening at higher energies is observed; these and other data suggest that two-component X-ray spectra, steep at low energies and flat at high energies, are a common feature of BL Lac objects. Three of the five sources clearly vary between SSS observations, with time scales ranging from days to years. A historical synopsis of the X-ray spectral data confirms the tendency for BL Lacertae objects to be highly variable in the X-ray band but reveals no correlation between spectral and intensity changes.

Urry, C. M.↗
NASA NTRS1996

Synthesis, Structure, and Characterization of Cu4S10(4-methylpyridine)4

The title compound, Cu4S10(4-methylpyridine)(sub 4) (dot) 4-methylpyridine was prepared by three different reactions: the oxidation of copper powder by sulfur and the reaction of copper (I) sulfide (or CuBr (dot) SMe2) with excess sulfur, both in the coordinating solvent, 4-methylpyridine. Red crystals of the compound obtained by layering with hexanes were subjected to single crystal X-ray diffraction. The structure was refined to R = 0.026 and R(sub w) = 0.036 in a space group P1bar (No. 2), with Z = 2, a = 13.983 (2) A, b = 15.384 (2) A, c = 9.660 (1) A, alpha = 93.87 (1)deg., beta = 93.38 (1)deg., gamma = 99.78 (1)deg., V = 2037.9 (9) A(exp 3). The compound has approximate S(sub 4) symmetry and consists of two pentasulfide chains linking four Cu(I) ions, each with a corrdinating 2-methylpyridine. The infrared spectrum was dominated by absorption due to coordinated 4-methylpyridine with several low-energy peaks attributable to S-S stretches, which were also observed by Raman spectroscopy. A featureless electronic absorption spectrum yielded a single peak in the near ultraviolet upon computer enhancement (lambda = 334 nm, epsilon = 10,000), most likely an intraligand transition. Cyclic voltammetry indicates that the polysulfide complex undergoes irrversible oxidation and reduction at +0.04 and -0.34 V vs. SCE, respectively, at 298 K in 4-methylpyridine when swept at 20 mV/sec. The electrochemical behavior was unvaried even at sweep rates as high as 100 V/sec.

Hepp, Aloysius F.↗
NASA NTRS1986

High-resolution X-ray spectroscopy of the Crab Nebula and the oxygen abundance of the interstellar medium

The measurement and analysis of a high-resolution soft X-ray spectrum of the Crab Nebula obtained with the Focal Plane Crystal Spectrometer on the Einstein Observatory are reported. A hydrogen column density of 3.45 + or - 0.42 x 10 to the 21st/sq cm and an oxygen column density of 2.78 + or - 0.55 x 10 to the 18th/sq cm, corresponding to an oxygen abundance of 1.1 + or - 0.3 times solar, were obtained. The absence of any evident oxygen depletion effects suggests that most interstellar grains are reasonably transparent to soft X-rays, implying sizes of less than 0.4 micron. The detailed spectrum in the vicinity of the oxygen edge gives marginal evidence for a resonant absorption line and suggests an edge from singly ionized oxygen.

Schattenburg, M. L.↗
NASA NTRS1995

The spectral energy distribution of the z=3 quasar: HS 1946+7658

For the bright z = 3.02 radio-quiet quasar, HS 1946+7658, we have obtained radio to X-ray data within the past year: 5 GHz and 1415 MHz data from the Very Large Array (VLA); IR photometry at J, H, K, L prime (3.4 micrometers and N; IR spectroscopy; UBVRI photometry; optical spectrophotometry and high-resolution spectra; and an X-ray spectrum from the ROSAT Position Sensitive Proportional Counter (PSPC). The spectral energy distribution (SED) constructed from these data is compared to the mean SED for a set of low-redshift quasars, and while they appear generally similar, there are several differences. In relation to the low-redshift mean, the SED of HS 1946+7658 shows (1) only an upper limit at 10 micrometers (a rest wavelength of 2.5 micrometers, indicating that HS 1946+7658 does not have a strong near-IR excess such as hot dust would produce; (2) relatively weak Fe II and Balmer continuum emission at approximately 3000 A; and (3) a steeper turndown shortward of Ly alpha, even after correction for the Ly alpha forest absorption lines.

Kuhn, O.↗
NASA NTRS1989

X-ray spectroscopy of the ultrasoft transient 4U 1543 - 47

The X-ray transient 4U 1543 - 47 was observed in August 1983 by the Exosat observatory near the maximum of an outburst. The X-ray spectrum was measured using a gas scintillation proportional counter (GSPC) and a transmission grating spectrometer (TGS). A broad (FWHM about 2.7 keV) line at 5.9 keV is detected in the GSPC, which is interpreted as a redshifted and broadened iron K-alpha line. The line broadening and redshift may arise from either Compton scattering in a cool plasma with small optical depth and/or from Droppler and relativistic effects in the vicinity of compact object. The spectrum below 2 keV, obtained with the TGS, shows evidence for a broad emission feature at 0.74 keV, which may be an iron L-transition complex. However, such an emission feature could be an artifact caused by an anomalously low interstellar absorption by neutral oxygen. The contimuum emission is extremely soft and is well described by an unsaturated Comptonized spectrum from very cool plasma (kT = 0.84 keV) with large scattering depth.

Van Der Woerd, H.↗
NASA NTRS1987

Observations of absorption lines from highly ionized atoms

In the ultraviolet spectra of hot stars, absorption lines can be seen from highly ionized species in the interstellar medium. Observations of these features which have been very influential in revising the perception of the medium's various physical states, are discussed. The pervasiveness of O 6 absorption lines, coupled with complementary observations of a diffuse background in soft X-rays and EUV radiation, shows that there is an extensive network of low density gas (n approx. few x 0.001/cu cm) existing at coronal temperatures log T = 5.3 or 6.3. Shocks created by supernova explosions or mass loss from early-type stars can propagate freely through space and eventually transfer a large amount of energy to the medium. To create the coronal temperatures, the shocks must have velocities in excess of 150 km/sec; shocks at somewhat lower velocity (v = 100 km/sec) can be directly observed in the lines of Si3. Observations of other lines in the ultraviolet, such as Si 4V and C 5, may highlight the widespread presence of energetic UV radiation from very hot, dwarf stars. More advanced techniques in visible and X-ray astronomical spectroscopy may open up for inspection selected lines from atoms in much higher stages of ionization.

Jenkins, Edward B.↗
NASA NTRS1984

Observations of Absorption Lines from Highly Ionized Atoms

In the ultraviolet spectra of hot stars, absorption lines can be seen from highly ionized species in the interstellar medium. Observations of these features which have been very influential in revising the perception of the medium's various physical states, are discussed. The pervasiveness of O 6 absorption lines, coupled with complementary observations of a diffuse background in soft X-rays and EUV radiation, shows that there is an extensive network of low density gas (n approx. fewX 0.001/cucm) existing at coronal temperatures, 5.3 or = log T or = 6.3. Shocks created by supernova explosions or mass loss from early-type stars can propagate freely through space and eventually transfer a large amount of energy to the medium. To create the coronal temperatures, the shocks must have velocities in excess of 150 km/sec; shocks at somewhat lower velocity 9v or = 100 km/sec) can be directly observed in the lines of Si3. Observations of other lines in the ultraviolet, such as Si 4V and C 5, may highlight the widespread presence of energetic uv radiation from very hot, dward stars. More advanced techniques in visible and X-ray astronomical spectroscopy may open up for inspection selected lines from atoms in much higher stages of ionization.

Jenkins, E. B.↗
NASA NTRS1995

Observations of the X-ray Nova GRO J0422+32. 1: Outburst and the decay to quiescence

We present optical photometry and spectroscopy and Burst and Transient Source Experiment (BATSE) observations of the X-ray nova GRO J0422+32, obtained during outburst and its subsequent decay to quiescence. Although the X-ray and optical properties of GRO J0422+32 are broadly similar to those of other X-ray novae, it is unique in several respects. The unusually protracted decay to quiescence of the optical light curve has been punctuated by at least two minioutbursts of approximately 4 mag. The BATSE and optical outbursts are each separated by approximately 120 days. We find that the optical luminosity of GRO J0422+32 during the primary outburst is dominated by reprocessing of E greater than 10 keV X-rays. In contrast, the optical minioutbursts are most likely generated by an intrinsically bright disk rather than X-ray reprocessing: they do not appear to have any X-ray counterparts. Extremely broad (up to 6000 km/s FWZI) absorption lines have also been observed during both primary outbursts and minioutbursts. During the second minioutburst, H-alpha and H-beta emission was observed superposed on redshifted absorption features. We find that the interoutburst light curve of GRO J0422+32 may be inconsistent with an accretion disk instability as the origin of the minioutbursts. Finally, a transient 5.1/10.2 hr modulation, which may be related to the orbital period, has been observed during roughly half of our observations. However, confirmation of the orbital period must await observations in quiescence.

Callanan, Paul J.↗
NASA NTRS1990

Nature and origin of interstellar diamond from the Allende CV3 meteorite

Data and experimental evidence which support the contention that the C delta diamonds may result from grain-grain collisions in supernova shocks in the interstellar medium are presented. Fragments of the Allende CV3 chondrite were acid-treated. A whitish powder was obtained. For the Analytical Electron Microscopy (AEM) a small drop of ethanol suspension was transferred onto holey carbon support films on 3 mm EM grids. The AEM was performed on transmission-thin fragments of the material which overlay holes in the film, to eliminate interference from the substrate. Electron Spectroscopy for Chemical Analysis (ESCA) was performed on a large aliquot of C. Diamond was identified by selected area electron diffraction. Scanning Transmission Electron Microscope / Energy Dispersive X-ray (STEM-EDS) microanalyses of the C delta diamond, using a light-element detector, show that oxygen and possibly nitrogen are the only impurities consistently present. ESCA spectra from bulk C delta material confirm the presence of N at a level of 0.35 percent or less. Under UV irradiation a yellow-red fluorescence is observed, consistent with that of natural diamonds containing substitutional N. Electron Energy Loss Spectra (EELS) were recorded at 2 eV resolution from the C delta diamond, high pressure synthetic diamond, a diamond film produced in a low pressure plasma by chemical vapor deposition (CVD) on a heated silicon substrate (Roy, 1987), graphite, and amorphous arc sputtered carbon. Comparison of the carbon K edge shape and fine structure shows the Allende C delta phase to be largely diamond, but with a significant pre-edge absorption feature indicative of transitions of C 1s electrons into pi asterisk orbitals which are absent in the purely sp(3)-bonded diamond but present in graphite and amorphous carbon.

Blake, David↗
NASA NTRS1995

EUVE spectroscopy of epsilon Canis Majoris (B2 II) from 70 to 730 A

We present spectra of the brightest stellar source of extreme ultraviolet (EUV) radiation longward of 400 A, the B2 II star, epsilon CMa. These data were taken with the three spectrometers aboard the NASA Extreme Ultraviolet Explorer satellite (EUVE) during the first cycle of pointed observations. We report on our initial studies of the continuum and line spectrum of the stellar photosphere in the 320 to 730 A region, and on the wind emission lines observed in the 170-375 A region. This is the first EUV spectrum of an early-type star, and thus makes epsilon CMa the most comprehensively observed B star from the X-ray to infrared regimes. The radiation in both the H Lyman continuum and He I continuum (shortward of 504 A) are found to be significantly greater than predicted by both Local Thermodynamic Equilibrium (LTE) and non-LTE model atmospheres. Since epsilon CMa also exhibits a mid-infrared excess, this points to the outer layers being warmer than the models indicate. The anomalously large Lyman continuum flux, combined with the very low column density measured in the direction toward this star implies that it is the dominant source of hydrogen ionization of the local interstellar medium in the immediate vicinity of the sun. All of the lines predicted to be strong from model atmospheres are present and several wind absorption features are also identified. We have detected emission lines from highly ionized iron that are consistent with the ROSAT Position Sensitive Proportional Counter (PSPC) observations if a multi-temperature emission model is used, and the assumption is made that there is significant absorption beyond that of the neutral phase of the ISM. The spectrum shows strong O III 374 A line emission produced by the Bowen flourescence mechanism, which has not previously been observed in the spectra of hot stars.

Cassinelli, J. P.↗
NASA NTRS1976

Stellar crystal X-ray spectroscopy on OSO-8

The large-area graphite crystal X-ray spectrometer on the OSO-8 satellite is described, and its response to stellar line and continuum radiation is discussed. A high resolution X-ray spectrum of Sco X-1 obtained from a preliminary analysis of quick look data shows a strong, smooth continuum with an absence of emission or absorption features over the energy range 2.2 to 8 keV. Upper limits are set on narrow line emission from highly ionized states of S, Ca, and Fe.

Kestenbaum, H. L.↗
NASA NTRS1978

The case for a burst from 3U 0614+09

A single flare event with a rise time of about 7 s and a decay time of approximately 40 s was observed by the Goddard cosmic X-ray spectroscopy experiment on OSO-8 during observations of 3U 0614+09 in September 1975. The possibility is discussed that the source was 3U 0614+09, which has been compared with the low-mass binary Sco X-1. The spectra during the event could be fitted with blackbody (kT = 0.8-1.1 keV) or thermal bremsstrahlung (kT = 1.1-2.5 keV) models with absorption by cool material. In the blackbody model the source was of the order of 1 million cm in size.

Swank, J. H.↗
NASA NTRS1982

Einstein Observatory pulse-phase spectroscopy of Hercules X-1

Spectra of the Her X-1 pulsations from 0.15 to 4.5 keV have been obtained with the Objective-Grating and Solid State Spectrometers on the HEAO 2 Einstein Observatory. The spectra show no distinct atomic emission or absorption features, except for broad emission near 1 keV possibly due to unresolved Fe L shell emission lines. Spectrally resolved pulse waveforms show a dramatic 240 deg phase shift for E less than 0.85 keV. The soft X-rays are interpreted as the result of the reprocessing of the hard X-ray beam by the inner disk at the magnetospheric boundary of the neutron star, and several spectroscopic and phase observations are suggested which could provide further knowledge of these structures.

Mccray, R. A.↗
NASA NTRS1985

Analysis of TQCM surface contamination adsorbed during the Spacelab I Mission

The Temperature-Controlled Quartz Crystal Microbalance (TQCM) system was flown on the Spacelab I Mission as part of the Induced Environment Contamination Monitor to monitor surface contamination (SC) in the payload bay. SC on the five sensors of the TQCM was analyzed by means of IR spectroscopy, scanning electron spectroscopy, and energy dispersive X-ray fluorescence. The amount of SC ranged from 1.4 micrograms/sq cm for the -Z sensor to 39.9 micrograms/sq cm for the +X sensor. The IR analysis showed strong CH2, CH3, and carbonyl absorption bands, indicative of ester and polyester compounds found in adhesives, plasticizers, and tape. The particulates (mostly ranging from 1 micron to 20 microns in size) were mainly composed of Mg, Al, Al2O3, and Si, and probably originated in the solid rocket firings.

Mckeown, D.↗
NASA NTRS1987

Optical and UV spectroscopy of the black hole binary candidate LMC X-1

Both further optical spectroscopy of the binary star identified with LMC X-1, obtained between 1983 and 1985, and a series of IUE UV spectra taken during a 5 day interval in 1984 are presented. The optical data are used to refine the orbital period to 4.2288 days, and improved orbital parameters are derived. The velocity of the optical emission lines is antiphased with the absorption lines and has twice the velocity amplitude. These new results support the estimates of the masses in the system given earlier. The most probable component masses are approximately 20 solar masses for the primary and near 6 solar masses (for the x-ray star), suggesting the the latter may be a black hole. The UV spectra show very weak, low-velocity stellar-wind lines. It is suggested that much of the surrounding medium is highly ionized by the X-ray flux. The 'nonwind' UV spectral lines and the UV continuum temperature are consistent with the optical data, indicating a late O type star of M(bol) = -8.5. There is a weak modulation of absorption-line strengths with orbital phase, suggestive of a lack of axisymmetry in the X-irradiation of the primary star and indicative of a fairly low orbital inclination.

Hutchings, J. B.↗
NASA NTRS1990

Supernovae and supernova remnants at high energies

The physical phenomena that are observable with X- and gamma-ray observations of supernovae are discussed with respect to possible high-energy astrophysics experiments. Prompt photospheric emission and its echo are discussed, supernova radioactivity and neutron star effects are examined, and circumstellar and interstellar interaction are reviewed. The primary uncertainties are found to be the hardening of the spectrum by non-LTE effects and the amount of absorption of the radiation from the initial soft X-ray burst. The radioactivity in supernovae is theorized to lead to gamma-ray lines and continuum emission unless the event is low-mass type II. Gamma-ray observations are proposed to examine the efficiency of particle acceleration, and high-resolution spectroscopy can provide data regarding ionization, temperature, composition, and velocities of the X-ray-emitting gas.

Chevalier, Roger A.↗
NASA NTRS1991

Organometallic chemical vapor deposition and characterization of ZnGe(1-x)Si(x)P2-Ge alloys on GaP substrates

In this paper, we report the epitaxial growth of ZnGe(1-x)Si(x)P2-Ge alloys on GaP substrates by open tube OMCVD. The chemical composition of the alloys characterized by energy dispersive X-ray spectroscopy shows that alloys with x up to 0.13 can be deposited on (001) GaP. Epitaxial growth with mirror smooth surface morphology has been achieved for x less than or equals to 0.05. Selected area electron diffraction pattern of the alloy shows that the epitaxial layer crystallizes in the chalcopyrite structure with relatively weak superlattice reflections indicating certain degree of randomness in the cation sublattice. Hall measurements show that the alloys are p-type, like the unalloyed films; the carrier concentration, however, dropped about 10 times from 2 x 10 exp 18 to 2 x 10 exp 17/cu cm. Absorption measurements indicate that the band tailing in the absorption spectra of the alloy has been shifted about 0.04 eV towards shorter wavelength as compared to the unalloyed material.

Xing, G. C.↗
NASA NTRS1993

Organometallic chemical vapor deposition and characterization of ZnGe(1-x)Si(x)P2-Ge alloys on GaP substrates

The epitaxial growth of ZnGe(1-x)Si(x)P2-Ge alloys on GaP substrates by open tube organometallic chemical vapor deposition (OMCVD) is reported. The chemical composition of the alloys characterized by energy dispersive X-ray spectroscopy shows that alloys with x up to 0.13 can be deposited on (001) GaP. Epitaxial growth with mirror smooth surface morphology was achieved for x less than or equal to 0.05. Transmission electron microscopy (TEM) micrographs of these alloys show specular epitaxy and the absence of microstructural defects indicating a defect density of less than 10(exp 7) cm(sup -2). Selected area electron diffraction pattern of the alloy shows that the epitaxial layer crystallizes in the chalcopyrite structure with relatively weak superlattice reflections indicating certain degree of randomness in the cation sublattice. Hall measurements show that the alloys are p-type, like the unalloyed films; the carrier concentration, however, dropped about 10 times from 2 x 10(exp 18) to 2 x 10(exp 17) cm(sup -3). Absorption measurements indicate that the band tailing in the absorption spectra of the alloy was shifted about 0.04 eV towards shorter wavelength as compared to the unalloyed material. Diodes fabricated from the n(+)-GaP/p-ZnSiP2-ZnGeP2-Ge heterostructure at x = 0.05 have a reverse break-down voltage of -10.8 V and a reverse saturation current density of approximately 6 x 10(exp -8) A/sq cm.

Xing, G. C.↗