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The Hopper: A Wearable Robotic Device Testbed for Micro-Gravity Bone-Loading Proof-of-Concept

Wearable robotic systems are showing increased potential for addressing crew countermeasures needs. Wearable robots offer a compactness, programmability, and eccentric loading capability not present in more conventional exercise equipment. Correspondingly, advancements in the man to machine interface has progressed, allowing for higher loads to be applied directly to the person in new and novel ways. Recently, the X1 exoskeleton, a lower extremity wearable robot originally designed for mobility assistance and rehabilitation, underwent human subject testing to assess its potential as a knee dynamometer. This was of interest to NASA physiologists because currently strength is not assessed in flight due to hardware limitations, and thus there is a poor understanding of the time course of in-flight changes to muscle strength. The study concluded that the X1 compared well with the Biodex, the "gold standard" in terrestrial dynamometry, with coefficients of variation less than 6.0%. In a following study, the X1 powered ankle was evaluated for its efficacy in exercising calf muscles. Current on-orbit countermeasures equipment does not adequately protect the calf from atrophy. The results of this study were also positive (targeted muscle activity demonstrated via comparing pre- and post-exercise magnetic resonance imaging T2 measurements), again showing the efficacy of wearable robotic devices for addressing the countermeasure needs of our astronauts. Based on these successes and lessons learned, the Grasshopper was co-developed between IHMC (Florida Institute for Human and Machine Cognition) and NASA. The Grasshopper, or the Hopper for short, is a wearable robotic device designed to address muscle and bone density loss for astronauts spending extended periods of time in micro-gravity. The Grasshopper connects to the user's torso like a hiking backpack, over the shoulders and around the waist. At the feet are footplates that strap to the user. There are two actuators, one at each "knee" joint, which are capable of high fidelity torque control. Because the Hopper uses motors instead of gravity to create the load on the user, the device is suited for use on space missions. Exercise in zero-gravity conditions is critical to maintain muscle strength and bone mass. In operation, the actuators try to fold up, or collapse, the device, putting a compressive load between the user's feet and torso. This force is similar to carrying a heavy backpack. The user then bends and extends his or her knees, replicating a weightlifting squat exercise. The applied load is precisely controlled by a computer, and can be programmed to simulate gravitation loads or any desired load prescription, such as free-weight squat exercise. It is even possible to perform eccentric exercises, or negatives, without the need for a spotter. Because the hip joints, as well as the spine and long leg bones, are in the applied load path, there is the potential to stimulate bone growth, countering the typical bone loss when astronauts return from extended duration space travel.

Beck, C. E.↗

Use of the NASA Giovanni Data System for Geospatial Public Health Research: Example of Weather-Influenza Connection

The NASA Giovanni data analysis system has been recognized as a useful tool to access and analyze many different types of remote sensing data. The variety of environmental data types has allowed the use of Giovanni for different application areas, such as agriculture, hydrology, and air quality research. The use of Giovanni for researching connections between public health issues and Earths environment and climate, potentially exacerbated by anthropogenic influence, has been increasingly demonstrated. In this communication, the pertinence of several different data parameters to public health will be described. This communication also provides a case study of the use of remote sensing data from Giovanni in assessing the associations between seasonal influenza and meteorological parameters. In this study, logistic regression was employed with precipitation, temperature and specific humidity as predictors. Specific humidity was found to be associated (p 0.05) with influenza activity in both temperate and tropical climate. In the two temperate locations studied, specific humidity was negatively correlated with influenza; conversely, in the three tropical locations, specific humidity was positively correlated with influenza. Influenza prediction using the regression models showed good agreement with the observed data (correlation coefficient of 0.50.83).

public health↗

Predictive Thermal Control (PTC) Technology to Enable Thermally Stable Telescopes: First Two Year Status

Predictive Thermal Control Technology (PTCT) development project is a multiyear effort initiated in Fiscal Year (FY) 2017, to mature the Technology Readiness Level (TRL) of critical technologies required to enable ultra-thermally-stable ultraviolet/optical/infrared (UVOIR) space telescope primary-mirror assemblies for ultra-high-contrast observations of exoplanets. Key accomplishments of 2017 to 2019 include: creating a high-fidelity STOP (Structural, Thermal, and Optical Performance) model of the AMTD-2 (Advance Mirror Technology Development) 1.5-meter Ultra-Low Expansion (ULE®) mirror (manufactured by Harris Corp) by merging 3D X-Ray computed tomography data of the ‘as-built’ mirror and coefficient of thermal expansion (CTE) data maps for each of the 18 core elements; partially validating this model by measuring the mirror’s response to bulk temperature changes and lateral thermal gradients; designed and built (with PTC partner Harris Corp) a 1.5-meter enclosure with 26 actively-control thermal zones; and defined specifications for a potential 4-meter primary mirror thermal enclosure for the Habitable Exoplanet (HabEx) Imager mission.

Astrophysics↗

End-User Assessment of the NASA SPoRT Lightning AI Product

The NASA Short-term Prediction Research and Transition (SPoRT) Center has begun to develop products to address operational challenges and enhance safety during the lifecycle of lightning activity, and conduct evaluations in concentrated R2O/O2R efforts. The product evaluated for this study is Lightning Artificial Intelligence (A.I.), which predicts the probability of lightning out to 15 minutes in advance and spatially maps it using filled color contours. Lightning A.I. uses reflectivity, differential reflectivity, and correlation coefficient data from a subset of radars within the NEXRAD network to generate lightning probabilities at approximately 2 km resolution. The domains, spanning 145 x 145 km are centered over NASA-affiliated centers across the CONUS and use radar data which are closest in proximity. Lightning A.I. was developed with intended use by emergency managers at NASA centers. However, National Weather Service (NWS) offices are also often tasked with monitoring and forecasting the threat for lightning within their County Warning Areas for various impact-based decision support services. These forecasts are typically provided for aviation operations and large-scale, outdoor events, which may have varying safety requirements for decision-making based on lightning proximity and recency. The NASA SPoRT center conducted an assessment of the operational uses of Lightning A.I by various collaborative NWS Offices from late July into early September. This assessment included feedback from participants on both the product itself as well as its accessibility within the new, interactive NASA SPoRT Lightning Viewer. This presentation will include background information about Lightning A.I. and highlight results from this assessment. The feedback from the assessment will be used to inform research on any necessary modifications to this and future lightning products to assist end users.

Kelley Murphy↗

Ab initio thermal rate coefficients for H + NH 3 ⇌ H 2 + NH 2

The reversible reaction NH 3 + H ⇌ H 2 + NH 2 , which plays an important role in NH3 fuel combustion, is studied with a theoretical approach that combines the high-accuracy extrapolated ab initio thermochemistry (HEAT) protocol with semiclassical transition state theory (SCTST). The calculated forward reaction is endothermic by 11.8 ± 1 kJ/mol, in nearly perfect agreement with the active thermochemical tables (ATcT) value of 11.5 ± 0.2 kJ/mol. Using this improved thermochemistry yields better rate constants, especially at low temperatures. Experimental rate constants available from 400 to 2000 K for the forward and reverse reaction pathways can be reproduced (within 20%) by the calculations from first principles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Multiscale porosity characterization in additively manufactured polymer nanocomposites using micro-computed tomography

Extrusion-based additive manufacturing (AM) of polymer composites exhibits complex thermally driven phenomena that introduce severe discontinuities in the internal structure across length scales, especially voids or porosity. This study utilizes a high-throughput porosity characterization technique to analyze large datasets from numerous micro-computed tomography (mu CT) scans to capture the influence of AM print parameters on the size, shape, and location of porosity across multiple print layers (up to a few cm) on fused granular fabrication (FGF) printers. The materials investigated include nanocomposite formulations based on commercially relevant nylon-12 and polyether ketone ketone (PEKK) materials comprising nano- or micro- sized fillers. The estimated global porosity follows an inverse linear correlation against the bulk density of the printed samples. Increasing the extrusion multiplier (EM) and the nozzle temperature while decreasing the print speeds reduces the global porosity. Outlier analyses (local porosity morphology) show that faster print speeds and higher extrusion rates result in long, slender inter-layer voids, while lower nozzle temperatures lead to large, symmetrical, inter-bead voids (at the bead junction). Lack of active chamber temperature increases inter-layer and intra-bead voids with a two-fold increase in global porosity. Overall, the micro filler-reinforced composites exhibit higher global porosity than nanofiller-reinforced composites, which is attributed to the increased mismatch in the thermal expansion coefficient between the filler and the polymers used in the study.

36 MATERIALS SCIENCE↗

Development of a UiO-Type Thin Film Electrocatalysis Platform with Redox-Active Linkers

Metal-organic frameworks (MOFs) as electro- catalysis scaffolds are appealing due to the large concentration of catalytic units that can be assembled in three dimensions. To harness the full potential of these materials, charge transport to the redox catalysts within the MOF has to be ensured. Here in this paper, we report the first electroactive MOF with the UiO/PIZOF topology (Zr(dcphOH-NDI)), i.e., one of the most widely used MOFs for catalyst incorporation, by using redox-active naphthalene diimide-based linkers (dcphOH-NDI). Hydroxyl groups were included on the dcphOH-NDI linker to facilitate proton transport through the material. Potentiometric titrations of Zr(dcphOH-NDI) show the proton-responsive behavior via the -OH groups on the linkers and the bridging Zr-μ 3 -OH of the secondary building units with pK a values of 6.10 and 3.45, respectively. When grown directly onto transparent conductive fluorine-doped tin oxide (FTO), 1 μm thin films of Zr(dcphOH-NDI)@FTO could be achieved. Zr(dcphOH-NDI)@FTO displays reversible electrochromic behavior as a result of the sequential one-electron reductions of the redox-active NDI linkers. Importantly, 97% of the NDI sites are electrochemically active at applied potentials. Charge propagation through the thin film proceeds through a linker-to-linker hopping mechanism that is charge-balanced by electrolyte transport, giving rise to cyclic voltammograms of the thin films that show characteristics of a diffusion-controlled process. The equivalent diffusion coefficient, D e , that contains contributions from both phenomena was measured directly by UV/vis spectroelectrochemistry. Using KPF 6 as electrolyte, De was determined to be D e (KPF 6 ) = (5.4 ± 1.1) × 10 -11 cm 2 s -1 , while an increase in countercation size to n-Bu 4 N + led to a significant decrease of D e by about 1 order of magnitude (D e (n-Bu 4 NPF 6 ) = (4.0 ± 2.5) × 10 -12 cm 2 s -1 ).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Groundwater management of a highly dynamic karst by assessing baseflow and quickflow with a rainfall-discharge model (Dardennes springs, SE France)

This paper aims at characterizing the groundwater flow in a highly dynamic karst aquifer using a global modeling approach based on rainfall and spring discharge time series. The Dardennes aquifer (SE France) was studied as it is used for drinking water supply and it also produces karst flash floods that increase the flood hazard downstream in urban areas. Three years of data were available, including a normal rainy year, a wet year and a dry year. Modeling was performed with the new platform KarstMod, a rainfall-discharge model with calibration tools. The Dardennes aquifer model was structured with three interconnected reservoirs: Epikarst, Matrix, and Conduit. Using this modeling approach, we were able to determine the groundwater hydrograph separation of the karst spring discharge, at the annual scale and at the event scale (flood). This gives insight into the low flow (Matrix) available for the drinking water demand and the fast flow (Conduit) that generates flash floods. In such a dynamic aquifer, part of the water budget cannot be accounted for by water resources as fast flow is not stored within the aquifer and is not available for the drinking water demand. The results were compared with the current groundwater management to determine whether the withdrawal is sustainable. Depending on whether it is a wet or a dry year, the proportion of slow flow ranges from 27 to 61% of the total discharge, respectively. During floods in high water periods, the proportion of quickflow increases drastically up to more than 90% of the spring discharge. In the case of a 300 mm/d simulated Mediterranean rainfall event, the mean daily peak value may reach 74 m 3 /s. This discharge can be reduced if the aquifer is previously depleted, which increases the storage within the aquifer. Coupling the geological context and the model results opens up future perspectives for the active management of the karst aquifer.

58 GEOSCIENCES↗

Charged-particle transport in high energy density plasmas

This Special Topic Collection grew out of two gatherings of researchers active in the high energy density (HED) physics community: a mini-conference on charged-particle transport in HED plasma held during the 64th annual meeting of the American Physical Society's Division of Plasma Physics (Spokane, WA, November 2022) and a dedicated charged-particle transport coefficient code comparison workshop (Livermore, CA, July 2023). These gatherings provided opportunities for theoretical, computational, and experimental researchers to discuss the state of the field, including current capabilities and methods, needs of hydrodynamic simulations, and frontiers for future research. Finally, this special issue collects a total of 13 research and review articles on charged-particle transport in HED plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Probing enhanced lithium-ion transport kinetics in 2D holey nanoarchitectured electrodes

Nanostructuring has been proved effective towards improving many energy storage and conversion devices, and is feasible for a wide range of materials. In particular, secondary nanoarchitectured materials exhibit collective advantages compared with nano-sized primary building blocks. Despite the manifold efforts in designed nanoarchitectures and synthetic routes, the underlying ion diffusion kinetics and phase transformation behaviours within nanoarchitectures still remain less explored. Herein, we probed enhanced lithium-ion transport behaviours using 2D holey zinc ferrite (ZFO) nanosheets as a model material, to demonstrate how self-assembled 2D holey nanoarchitectured electrodes can feature efficient ion diffusion channels, robust yet continuous electron transfer framework, and enlarged surface area, contributing to the superior performance over the ZFO nanoparticles without secondary structures. By revealing kinetic parameters through combined spectroscopic measurements and electrochemical techniques, our study manifests increased lithium-ion diffusion coefficients, higher capacitive charge storage contribution and reduced charge transfer impedance in holey nanosheets compared to randomly aggregated nanoparticles. Furthermore, our results promote deeper understanding of significantly enhanced electrochemical energy storage properties of these 2D holey nanoarchitectured electrodes resulted from more uniform and complete phase transformation and better active material utilization.

25 ENERGY STORAGE↗

A correlative study of magnetic flux transfer in the magnetosphere

The applied magnetic flux of the southward component of the IMF in GSM coordinates (Bz-) which impinges upon the sunward magnetopause is compared to the time integral of the auroral AL index during 56 intervals within a 3-month period in 1969 when interplanetary records from Heos 1 and Explorer 35 were available. The periods of magnetic activity were those for which Bz was greater than 0 and AL was less than 20gamma at the beginning and end of the interval. It was found that for these intervals, the time integral of the AL index was proportional to the applied magnetic flux with a correlation coefficient of 0.94. In addition, the empirical relationships between magnetic flux transfer, applied southward flux, and the time integral of AL arrived at by Holzer and Slavin (1978) on the basis of expansion and contractions of the forward magnetosphere observed with OGO 5 are reexamined and improved.

Holzer, R. E.↗

Sunspots and the physics of magnetic flux tubes. VIII - Overstability in a magnetic field in a downdraft

The dynamical properties of convective overstability in a vertical magnetic field with a downdraft are considered. A variety of effects is illustrated. The overstability produces Alfven waves propagating both upward or downward along the magnetic field. The favored direction of emission may be upward or downward depending upon the magnitude of the heat transport coefficient. The largest asymmetry is produced by a difference in reflectivity between the upper and lower boundaries. It is shown that a very modest reflection coefficient of the upper boundary, with no reflection at the lower boundary, causes most of the waves to be emitted downward, and vice versa. Applying these results to the flux tubes extending up through the convective zone of the Sun, it follows that those flux tubes are dynamically active beneath the surface, as suggested earlier by ourselves and others, but there is no reason to expect any significant wave flux to appear in the field above the surface. The waves propagate downward into the Sun and are presumably dispersed there by the nonlinear interaction with the turbulent convection, etc.

Parker, E. N.↗

End region and current consolidation effects upon the performance of an MHD channel for the ETF conceptual design

The effects of MHD channel end regions on the overall power generation were considered. The peak plant thermodynamic efficiency was found to be slightly lower than for the active region (41%). The channel operating point for the peak efficiency was shifted to the supersonic mode (Mach No., M sub c approx. 1.1) rather than the previous subsonic operation (M sub c approx. 0.9). The sensitivity of the channel performance to the B-field, diffuser recovery coefficient, channel load parameter, Mach number, and combustor pressure is also discussed. In addition, methods for operating the channel in a constant-current mode are investigated. This mode is highly desirable from the standpoint of simplifying the current and voltage consolidation for the inverter system. This simplification could result in significant savings in the cost of the equipment. The initial results indicate that this simplification is possible, even under a strict Hall field constraint, with resonable plant thermodynamic efficiency (40.5%).

Wang, S. Y.↗

Thermal/structural analyses of several hydrogen-cooled leading-edge concepts for hypersonic flight vehicles

The aerodynamic heating at high flight Mach numbers, when shock interference heating is included, can be extremely high and can exceed the capability of most conventional metallic and potential ceramic materials available. Numerical analyses of the heat transfer and thermal stresses are performed on three actively cooled leading-edge geometries (models) made of three different materials to address the issue of survivability in a hostile environment. These analyses show a mixture of results from one configuration to the next. Results for each configuration are presented and discussed. Combinations of enhanced internal film coefficients and high material thermal conductivity of copper and tungsten are predicted to maintain the maximum wall temperature for each concept within acceptable operating limits. The exception is the TD nickel material which is predicted to melt for most cases. The wide range of internal impingement film coefficients (based on correlations) for these conditions can lead to a significant uncertainty in expected leading-edge wall temperatures. The equivalent plastic strain, inherent in each configuration which results from the high thermal gradients, indicates a need for further cyclic analysis to determine component life.

Gladden, Herbert J.↗

Thermal/structural analyses of several hydrogen-cooled leading-edge concepts for hypersonic flight vehicles

The aerodynamic heating at high flight Mach numbers, when shock interference heating is included, can be extremely high and can exceed the capability of most conventional metallic and potential ceramic materials available. Numerical analyses of the heat transfer and thermal stresses are performed on three actively cooled leading-edge geometries (models) made of three different materials to address the issue of survivability in a hostile environment. These analyses show a mixture of results from one configuration to the next. Results for each configuration are presented and discussed. Combinations of enhanced internal film coefficients and high material thermal conductivity of copper and tungsten are predicted to maintain the maximum wall temperature for each concept within acceptable operating limits. The exception is the TD nickel material which is predicted to melt for most cases. The wide range of internal impingement film coefficients (based on correlations) for these conditions can lead to a significant uncertainty in expected leading-edge wall temperatures. The equivalent plastic strain, inherent in each configuration which results from the high thermal gradients, indicates a need for further cyclic analysis to determine component life.

Gladden, Herbert J.↗

Low-frequency spectral representation of Space Shuttle flight data

The present digital processing of 18 accelerograms associated with Space Shuttle liftoffs splits each of the accelerograms into three time-slices, respectively representing (1) SSME thrust buildup, (2) the period immediately following the SRBs' ignition, and (3) the subsequent period of intense acoustical activity due to the exhaust plume's interactions with the launch pad. The spectral treatment of these data involve the use of autoregressive and autoregressive-moving-average filters that furnish analytical representations of the spectra for all three time-slices in terms of a set of coefficients; these coefficients are applicable to the synthesis of artificial acceleration time-histories.

Spanos, Pol D.↗

High-Temperature Properties of Piezoelectric Langatate Single Crystals

Langasite type crystals belong to non-polar point group of 32 and do not show any phase transformations up to the melting temperature. Langatate (La3Ga(5.5)Ta(0.5)O14) demonstrates piezoelectric activity better than quartz and possesses attractive properties for high temperature sensors, resonators and filter applications. High-quality and colorless langatate crystals were grown by the Czochralski technique. The electromechanical and electrical properties of langatate crystals in different crystallographic directions were characterized at elevated temperature. The piezoelectric coefficient along x-axis was 7 pC/N as measured by a Berlincourt meter for a plate geometry with an aspect ratio of 10:1. The dielectric constant did not exhibit any significant temperature dependence (K33 approx. 21 at 30 C and K33 approx. 23 at 600 C). Loss tangent at 100 kHz remained <0.003 up to 300 C and <0.65 at 600 C. The dielectric properties along the y-axis were similar and its temperature dependence was analogous to the x-axis. Electromechanically, the inactive z-axis exhibited no resonance with K33 approx. 84 at room temperature, decreasing down to approx. 49 at 600 C. Resistivity of these crystals along x-axis decreased from approx. 6x10(exp 11) omega-cm at room temperature, to approx. 1.6x10(exp 6) omega-cm at 600 C.

Sehirlioglu, Alp↗

A Piezoelectric PZT Ceramic Mulitlayer Stack for Energy Harvesting Under Dynamic Forces

Piezoelectric energy harvesting transducers (PEHTs) are commonly used in motion/vibration energy scavenging devices. To date, most researchers have focused on energy harvesting at narrow bandwidths around the mechanical resonance frequency, and most piezoelectric harvesting devices reported in the literature have very low effective piezoelectric coefficient (d(sub eff)) (< 10(exp 4) pC/N). For instance, more than 80% of PEHT related papers are on transverse "31" mode cantilever beam type PEHTs (CBPEHTs) having piezoelectric coefficients of about 100 pC/N. The level of harvested electrical power for CBPEHTs is on the order of microW even at resonance mode. In order to harvest more electrical energy across broader bandwidth, high effective piezoelectric coefficient structures are needed. In this study, we investigate a "33" longitudinal mode, piezoelectric PZT ceramic multilayer stack (PZT-Stack) with high effective piezoelectric coefficient for high-performance PEHTs. The PZT-Stack is composed of 300 layers of 0.1 mm thick PZT plates, with overall dimensions of 32.4 mm X 7.0 mm X 7.0 mm. Experiments were carried out with dynamic forces in a broad bandwidth ranging from 0.5 Hz to 25 kHz. The measured results show that the effective piezoelectric coefficient of the PZT-stack is about 1 X 10(exp 5) pC/N at off-resonance frequencies and 1.39 X 10(exp 6) pC/N at resonance, which is order of magnitude larger than that of traditional PEHTs. The effective piezoelectric coefficients (d(sub eff)) do not change significantly with applied dynamic forces having root mean square (RMS) values ranging from 1 N to 40 N. In resonance mode, 231 mW of electrical power was harvested at 2479 Hz with a dynamic force of 11.6 N(sub rms), and 7.6 mW of electrical power was generated at a frequency of 2114 Hz with 1 N(sub rms) dynamic force. In off-resonance mode, an electrical power of 18.7 mW was obtained at 680 Hz with a 40 N(sub rms) dynamic force. A theoretical model of energy harvesting for the PZT-Stack is established. The modeled results matched well with experimental measurements. This study demonstrated that high effective piezoelectric coefficient structures enable PEHTs to harvest more electrical energy from mechanical vibrations or motions, suggesting an effective design for high-performance low-footprint PEHTs with potential applications in military, aerospace, and portable electronics. In addition, this study provides a route for using piezoelectric multilayer stacks for active or semi-active adaptive control to damp, harvest or transform unwanted dynamic vibrations into useful electrical energy.

Xu, Tian-Bing↗