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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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The influence of electrospark alloying of regular-quality Ст.3 steel on its wear resistance is investigated. The tribological properties of the strengthened surface in dry friction are investigated as a function of the number of passes in electrospark alloying and the current in the graphite electrode.
The molecular dynamics code LAMMPS was used to simulate the bombardment of a graphite structure by atomic boron with impact energies ranging from 50–250 eV. The transient structural evolution, penetration depth, and amorphous layer thickness were analyzed. Simulations show that larger impact energies lead to a greater volume of amorphization and penetration of boron, but that the growth rate of the amorphous layer decreases with increasing fluence. Furthermore, the change in surface chemistry of the amorphized structures was studied using the ReaxFF formalism, which found that the amorphization process introduces dangling bonds thus increasing reactivity in the amorphous region.
Pramipexole (PMXL) belongs to the benzothiazole class of aromatic compounds and is used in treating Parkinson’s disease; however, overdosage leads to some abnormal effects that could trigger severe side effects. Therefore, it demands a sensitive analytical tool for trace level detection. In this work, we successfully developed an electrochemical sensor for the trace level detection of PMXL, using the voltammetric method. For the analysis, graphitic carbon nitride (gCN) was opted and synthesized by using a high-temperature thermal condensation method. The synthesized nanoparticles were employed for surface characterization, using transmission electron microscopy (TEM), X-ray diffraction (XRD), and atomic force microscopy (AFM) techniques. The electrochemical characterization of the material was evaluated by using the electrochemical impedance spectroscopy (EIS) technique to evaluate the solution–electrode interface property. The cyclic voltammetry (CV) behavior of PMXL displayed an anodic peak in the forward scan, indicating that PMXL underwent electrooxidation, and an enhanced detection peak with lower detection potential was achieved for gCN-modified carbon paste electrode (gCN·CPE). The influence of different parameters on the electrochemical behavior was analyzed, revealing the diffusion governing the electrode process with an equal number of hydronium ions and electron involvement. For the fabricated gCN·CPE, good linearity range was noticed from 0.05 to 500 µM, and a lower detection limit (L D ) of 0.012 µM was achieved for the selected concentration range (0.5 to 30 µM). Selectivity of the electrode in PMXL detection was investigated by conducting an interference study, while the tablet sample analysis demonstrates the sensitive and real-time application of the electrode. The good recovery values for the analysis illustrate the efficiency of the electrode for PMXL analysis.
Carbon-based functional nanocomposites have emerged as potent antimicrobial agents and can be exploited as a viable option to overcome antibiotic resistance of bacterial strains. In the present study, graphitic carbon nitride nanosheets are prepared by controlled calcination of urea. Spectroscopic measurements show that the nanosheets consist of abundant carbonyl groups and exhibit apparent photocatalytic activity under UV photoirradiation towards the selective production of singlet oxygen. Therefore, the nanosheets can effectively damage the bacterial cell membranes and inhibit the growth of bacterial cells, such as Gram-negative Escherichia coli, as confirmed in photodynamic, fluorescence microscopy, and scanning electron microscopy measurements. The results from this research highlight the unique potential of carbon nitride derivatives as potent antimicrobial agents.
Measurement of heat transfer in a graphite rod heat exchanger
It is the purpose of this paper to discuss the development of and to present some preliminary data results which were obtained during the operation of a high-pressure-high-temperature induction-type heat exchanger. The subjects to be covered are: (1) An overall description of the induction heater and the various graphite elements tested in the heater; (2) Effects of the mass rate of flow on stagnation temperature; (3) Heat-transfer data on one heater element; (4) Effect of power input on gas stagnation temperature, and (5) The evaluation of mass flow technique as a method for determining true gas stagnation temperature.
Pyrolytic graphite rocket thrust chamber
Graphite oxidation studies in oxygen and air at low temperature
Pyrolytic graphite deformation and structural transformation
Kinetics of graphitization of petroleum coke
Method for observing transition growth of graphite whiskers
Crystal structure, activation energy and heat treatment temperatures for petroleum coke and a pyrolytic carbon, showing lack of temperature dependence to degree of graphitization
Torsion effusion method for studying reaction of graphite with thorium and zirconium oxides, discussing thermodynamic properties of thorium carbide
Reaction of graphite and hydrogen in temperature range 1550 to 2260 deg C
Experimental control of oxygen fugacities by graphite-gas equilibria
Hypervelocity impact damage characteristics in beryllium and graphite plates and tubes
Graphite sensing elements for slug calorimeters and high temperature black body radiation source