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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Effects of ingested nanocellulose on intestinal microbiota and homeostasis in Wistar Han rats

Micron scale crystalline and fibrillar cellulose materials are “generally regarded as safe” (GRAS) as binders and thickeners in food products. Yet, partly due to a lack of relevant toxicological data, nanocellulose (NC) materials, which have unique properties that can be exploited to improve food quality and safety, have yet to receive FDA approval as food ingredients. Results of in vitro and in vivo toxicological studies of ingested NC, detailed in a recent companion report, revealed minimal acute in vitro cytotoxicity, and no toxicity in a subacute rat gavage model, suggesting that NC materials are non-hazardous. However, ingested materials may also modulate gut microbial populations, or alter aspects of intestinal function not evaluated in standard totoxicity testing, which could have important health implications. Here, we report the results of studies of the effects of ingested cellulose nanofibrils (CNF) on the fecal microbiome and metabolome, intestinal (ileal) epithelial cell mRNA expression of cell junction genes, and ileal cytokine production. Feces, plasma, and ileum samples were collected from Wistar Han rats before and after five weeks of biweekly gavages of water or cream, with or without 1% w/w CNF. Analysis of fecal microbial populations revealed that CNF caused changes in both genus and species diversity, with specific effects on species that produce short chain fatty acids, and that have been associated with increased IgA production and elevation of insulin levels. Fecal metabolomic analysis revealed relatively few effects of CNF, with significant changes in the levels of only ten metabolites out of 366 measured. Exposure to CNF also caused differential regulation of mRNA expression of several genes involved in epithelial cell junctions, and increased production of cytokines that both promote and inhibit proliferation of CD8 T cells. These perturbations in intestinal homeostasis contrast somewhat with the absence of in vitro and in vivo toxicity observed previously but would appear to represent minor effects. Additionally, the gut microbiome is highly sensitive to ingested substances, and such disturbances of the intestinal microbial ecosystem do not necessarily represent or predict meaningful pathology. Further studies, including chronic feeding studies, are needed to assess the real health implications, if any, of these changes.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Establishing a silica gel zone in well annulus and evaluating its performance in blocking vertical water flow

Wells are often constructed for monitoring purposes with relatively long screen lengths (e.g., >10 m). Vertical water flows can occur within the artificial or natural filterpack annulus that surrounds the screened interval, bypassing packer assemblies installed inside the wellbore. Attempts to isolate discrete vertical zones during groundwater sampling are unsuccessful when annular flow occurs and lead to remedy decisions based on biased or incorrect interpretations. Blocking vertical annular water flow and contaminant transport will help obtain more accurate concentrations of contaminants from sampling in targeted depth intervals. The application of silica gels formed from the injected colloidal silica CS suspensions is a novel approach to minimize or prevent movement of vertical movement of groundwater in the surrounding filterpack annulus. In this work, we tested the feasibility of injecting CS suspensions to target locations and developed a modified CS formulation that is injectable and prevents gravity sinking. We studied the distribution and penetration of silica gel at laboratory scale in mock well annulus with surrounding formations. We evaluated the performance of the silica gel in blocking vertical water flow in the annulus and in minimizing chemical transport through the gel zone. CS suspension formulations have been defined that are ready for injection, stay in target locations, and form gel within desired time frames. Injection of CS suspensions achieved uniform distribution in a well annulus filter pack, fully occupied the annulus pore space, and penetrated the formation surrounding the filter packer with a sufficient distance to create a hydraulic annular seal when the injection was applied at a sufficient rate. The depth of penetration into the formation was dependent on the permeability contrast between the filter pack and the surrounding formation. Silica gel that formed in the annulus blocked vertical water flow and stopped the chemical transport through the gel zone. In conclusion, this research reveals that using CS suspension injection and sequential gelation (CS-GEL) is a promising technology for blocking vertical water flow and chemical transport through the filter pack in targeted zones within the annulus of long-screened well systems.

Colloidal silica suspension↗
NASA NTRS1998

Ma'adim Vallis Estuarine Delta in Elysium Basin and Its Relevance as a Landing Site for Exobiology Exploration on Mars

The debouche of Ma'adim Vallis in the Elysium Basin generated a transitional transported sediment structure, which planimetric shape is controlled by the enclosing topography of a deep reentrant gulf of the Basin into the highland. We defined it as an estuarine delta. The location and the importance of this estuarine delta is supported by the theoretical model of graded profile constructed for Ma'adim Vallis, and by two approaches: (i) the reconstruction of Ma'adim Vallis downstream course from Gusev to Elysium Basin, and (ii) the survey of the sediment deposit in the alleged estuary. The longitudinal graded profile of Ma'adim Vallis finds its base-level in the Elysium Basin, at a about 1000 m elevation, which is in agreement with the observed Basin shoreline. This model is supported by observational evidence of flow between the northern rim of Gusev crater, and the Elysium Basin shoreline. This downstream course of Ma'adim Vallis can be divided into three hydrogeologic regions. into three hydrogeologic regions. (a) The first region is a flooded plain (Zephiria Mensae), consisting in chaotic terrain formed by highland rocks, and disintegrated lava of the western flank of Apollinaris. Morphologic indicators of the flood process are: (1) the sediment deposit over the Gusev crater northern rim that reflects the overspilling of the crater-lake water through a 40-km wide gap provided by an ancient impact crater, (2) the tear-drop shaped feature on the northeastern flank of Apollinaris Patera, and (3) the chaotic terrain that suggest the emergence of ground water generated by the seepage of the crater lake through high-permeable broken rampart material. This underground water circulation sustained by the hydrostatic pressure of the crater-lake has likely generated a hydrothermal system in the volcanic environment of Apollinaris Patera. The stratigraphy of the flooded area is identified as Hesperian age, with occurrences of Noachian hilly individual features, and as Amazonian flooded plain and chaotic material, (b) The second region is located on the western flank of Apollinaris Patera. It is surrounded by relics of deep valleys that suggest a former downstream course of Ma'adim Vallis. The geologic setting of this region (Lucus Planum) is interpreted to be an Amazonian formation composed by the middle and lower members of the Medusae Formation., c) The third region corresponds to the convergence of the west and east branches of Ma'adirn Vallis into a deep re-entrant wide gulf that penetrates about 100 km into the highland. This topographic depression is delineated by the 1000 in elevation contour. This gulf has formed an estuarine configuration centered at 3S/190W within the Elysium Basin. This configuration has favored the formation of a estuarine sedimentary delta, because of topographically controlled lateral migration. This estuarine structure is strongly dominated by the incoming supply of Ma'adim Vallis fluvial sediment extracted from Zephiria Mensae and Lucus Planum. The obtuse-angle geometry of the estuary increases the sedimentation rate, which is higher than in the course of the channel. The sediment deposition process is governed by the estuarine water circulation. The inflowing loaded fluvial water enters the estuary as a bottom current, and mixes with the relatively less-loaded water of the receiving basin. When they mixed. the inflowing fluvial material, and the landward basin circulating water generate an accumulation of highly-diversified estuarine deposit stratification. This accumulation of material is mostly centered in the transitional zone of the delta. The sediment trapping efficiency of the estuary is function of the energy balance between the inflowing fluvial water, and the ingoing basin current. The submergence of the delta by the rising of the water-level increases the estuary water-depth, and consequently the sediment entrapment is favored. The locus of sediment accumulation moves landward in the zone of inflowing fluvial water. This results in the rising of the channel base-level, thus in the increase of the length of the longitudinal graded-profile. The sediment deposit facies of the zone A shows a generally smooth surface. The longitudinal deposit is bordered by alluvial terraces that reflect the variations of the channel level. The waning of the Elysium Basin caused the erosion of the Basin estuarine zone by small channels, this episode being characterized by dissected tear-drop shaped mesa-like morphologies in the delta. Our estuarine delta model predicts a lithostratigraphic depositional sequence associated with the water submergence and the transgression of Elysium Basin. The thickness of the estuarine sediment corresponds to the Elysium Basin levels changes relatively to the bed floor of the estuary, The depositional sequence of Ma'adim Vallis are described: (1) a pro-current filled region (A), where fluvial are longitudinally accumulated by the inflowing water, (2) inverse current from Elysium Basin (B), where fluvial and lacustrine sediments are accumulated, and (3) zone of current equilibrium (C), where the sediments are distributed as a shoreline at the boundary of the estuarine delta. The estuary sedimentology dynamics collects and keeps the record of the geologic unit material crossed by Ma'adim Vallis, and those of the lakebed deposit of Elysium Basin. The predicted mixed stratigraphic sequence from fluvial and lacustrine sediment makes this site an exceptional environment to concentrate potential multi-origin biologic records. We envision four possible strategies to explore this sedimentologic record: (1) longitudinal surface and subsurface traverses in region A to investigate outcrop levees, (2) exploration of the mesa walls in region B, (3) deep drilling hole lodging of the sequential deposits in the zones A and B, and (4) surface and subsurface exploration of the shoreline delta. The expected results for each of these strategies are: (1) in the deepest layers of region A are predicted frequent and abundant coarse material, sandy lenses lamination grading downward from sand to cobbles. Volcanic debris from the Noachian crustal Plateau unit material, hydrothermal altered rocks, carbonates, Hesperian and possibly Amazonian volcanic material, from Apollinaris Patera, altered rocks and carbonates from Zephiria Mensae are expected. As a favorable environment for inception of life, possible biological records are expected in transported rock, (2) At the surface, and subsurface (<=100 m), large deposits sandy to silted material from Elysium paleolake basin mixed with fine-grained sediments from Ma'adim Vallis are expected mostly in the upstream part of region B, (3) on the shoreline of the estuarine delta, abundant fine material from Elysium paleolake basin (evaporites, carbonates), mostly Amazonian in age are expected. The Ma'adini estuary is a favorable landing site for all the above mentioned science aspects, and .for its location. The site lies near the equator, which is favorable for the rover solar power supply, and at 1000m elevation, which is a favorable configuration for the descent system braking. Another advantage is the extent of the area of high scientific interest (33,000 sq km), which provides a good ellipse, and potential long study traverses.

Grin, E. A.↗
DOE OSTI2015

Carbon Dioxide Shuttling Thermochemical Storage Using Strontium Carbonate

Phase I concludes with significant progress made towards the SunShot ELEMENTS goals of high energy density, high power density, and high temperature by virtue of a SrO/SrCO 3 based material. A detailed exploration of sintering inhibitors has been conducted and relatively stable materials supported by YSZ or SrZO 3 have been identified as the leading candidates. In 15 cycle runs using a 3 hour carbonation duration, several materials demonstrated energy densities of roughly 1500 MJ/m 3 or greater. The peak power density for the most productive materials consistently exceeded 40 MW/m 3 —an order of magnitude greater than the SOPO milestone. The team currently has a material demonstrating nearly 1000 MJ/m 3 after 100 abbreviated (1 hour carbonation) cycles. A subsequent 8 hour carbonation after the 100 cycle test exhibited over 1500 MJ/m 3 , which is evidence that the material still has capacity for high storage albeit with slower kinetics. Kinetic carbonation experiments have shown three distinct periods: induction, kinetically-controlled, and finally a diffusion-controlled period. In contrast to thermodynamic equilibrium prediction, higher carbonation temperatures lead to greater conversions over a 1 hour periods, as diffusion of CO 2 is more rapid at higher temperatures. A polynomial expression was fit to describe the temperature dependence of the linear kinetically-controlled regime, which does not obey a traditional Arrhenius relationship. Temperature and CO 2 partial pressure effects on the induction period were also investigated. The CO 2 partial pressure has a strong effect on the reaction progress at high temperatures but is insignificant at temperatures under 900°C. Tomography data for porous SrO/SrCO 3 structures at initial stage and after multiple carbonation/decomposition cycles have been obtained. Both 2D slices and 3D reconstructed representations have been obtained from the raw data. Porosity and surface area have been computed based on tomography. The two parameters, permeability and Forchheimer constants, in the Darcy’s law for linear and non-linear range have been obtained from the fluid dynamics simulation. The structure is nearly isotropic from the hydrodynamics point of view. Thermal conductivity at elevated temperature has been obtained from the 3-D pore-scale simulations. The computed thermal conductivities of the structure compare well with an existing correlation. Computational models have been developed for solving the energy and mass transport equations with chemical reaction on the surface and inside the particles. The chemical kinetics or rate law is needed on the particle scale; however it is generally measured using a lumped model based on the average of reacted as well as unreacted mass. Many simulations have been conducted on a 2-D model to determine the effects of those pore scale parameters on the heat release based on the measured data. The simulation results using 2-D model show that average volumetric heat flow rate of 4 MW/m 3 in the first 5 minutes can be obtained. The insight gained from the 2-D simulation will be useful for the next stage simulation based on realistic 3-D structures. A probabilistic analysis has been conducted on the baseline system of recovering heat from the hot CO 2 evolved from the endothermic reaction and compressing the cooled CO 2 into a storage tank at 20-21 bar. Using a Monte Carlo simulation using 2,000,000 samples and both uniform and triangular probability distributions of four variables (heat exchanger pinch points, compressor efficiency, and power block efficiency), exergetic efficiency of 90% appears to be very likely.

14 SOLAR ENERGY↗
NASA NTRS1993

Properties and processing characteristics of low density carbon cloth phenolic composites

Ply-lift and pocketing are two critical anomalies of carbon cloth phenolic composites (CCPC) in rocket nozzle applications. Ply lift occurs at low temperatures when the A/P and in-plane permeabilities of the composite materials are still very low and in-plane porous paths are blocked. Pocketing occurs at elevated temperatures when in-plane permeability is reduced by the A/P compressive stress. The thermostructural response of CCPC in a rapid heating environment involves simultaneous heat, mass, and momentum transfer along with the degradation of phenolic resin in a multiphase system with temperature- and time-dependent material properties as well as dynamic processing conditions. Three temperature regions represent the consequent chemical reactions, material transformations, and property transitions, and provide a quick qualitative method for characterizing the thermostructural behavior of a CCPC. In order to optimize the FM5939 LDCCP (low density carbon cloth phenolic) for the nozzle performance required in the Advanced Solid Rocket Motor (ASRM) program, a fundamental study on LDCCP materials was conducted. The cured composite has a density of 1.0 +/- 0.5 gm/cc which includes 10 to 25 percent void volume. The weight percent of carbon microballoon is low (7-15 percent). However, they account for approximately one third of the volume and historically their percentages have not been controlled very tightly. In addition, the composite properties show no correlation with microballoon weight percent or fiber properties (e.g. fiber density or fiber moisture adsorption capacity). Test results concerning the ply-lift anomaly in the MNASA motor firings were: (1) Steeper ply angle (shorter path lenght) designs minimized/eliminated by lifting, (2) material with higher void volume ply lifted less frequently, (3) materials with high (greater than 9 percent) microballoon content had a higher rate of ply lifting, and (4) LDCCP materials failed at microballoon-resin interfaces. The objectives of this project are: (1) to investigate the effects of carbon microballoon and cabosil fillers as well as fiber heat treatment on plylift-related mechanical properties, (2) to develop a science-based thermostructural process model for the carbon phenolics. The model can be used in the future for the selection of the improved ASRM materials, (3) to develop the micro-failure mechanisms for the ply-lift initiation and propagation processes during the thermoelastic region of phenolic degradation, i.e. postcuring and devolatilization.

Wang, C. Jeff↗
DOE OSTI2015

Modeling earthquake effects on groundwater levels: evidences from the 2012 Emilia earthquake (Italy)

Changes in water level are commonly reported in regions struck by a seismic event. The sign and amplitude of such changes depend on the relative position of measuring points with respect to the hypocenter, and on the poroelastic properties of the rock. We apply a porous media flow model (TOUGH2) to describe groundwater flow and water-level changes associated with the first M L 5.9 mainshock of the 2012 seismic sequence in Emilia (Italy). We represent the earthquake as an instantaneous pressure step, whose amplitude was inferred from the properties of the seismic source inverted from geodetic data. The results are consistent with the evolution recorded in both deep and shallow water wells in the area and suggest that our description of the seismic event is suitable to capture both timing and magnitude of water-level changes. Finally, we draw some conclusions about the influence of material heterogeneity on the pore pressure evolution, and we show that to reproduce the observed maximum amplitude it is necessary to take into account compaction in the shallow layer.

2012 Emilia earthquake↗
DOE OSTI2024

Synthesis of results for Brine Availability Test in Salt (BATS) DECOVALEX-2023 Task E

In the 2023 phase of the international collaborative DECOVALEX modeling project, Task E focused on understanding thermal, hydrological, and mechanical (THM) processes related to predicting brine migration in the excavation damaged zone around a heated excavation in salt. Salt is attractive as a disposal medium for radioactive waste because it is self-healing and is essentially impermeable and non-porous in the far field. Investigation of the short-term, near-field behavior is important for radioactive waste disposal because this early period strongly controls the amount of inflowing brine. Brine leads to corrosion of waste forms and waste packages, and possible dissolution of radionuclides with brine transport being a potential transport vector to the accessible environment.The Task was divided into steps. Step 0 included matching unheated brine inflow data from boreholes at the Waste Isolation Pilot Plant (WIPP) and matching temperature observations during a Brine Availability Test in Salt (BATS) heater test. Step 1 included validation of models against a thermo-poroelastic analytical solution, and two-phase flow around an excavation. Finally, Step 2 required all the individual components covered in steps 0 and 1 to come together to match observed brine inflow behavior during the same BATS heater test.There were a range of approaches from the teams, from mechanistic to prescriptive. Given the uncertainties in the problem, some teams used one- or two-dimensional models of the processes, while other teams included more geometrical complexity in three-dimensional models. Task E was a learning experience for the teams involved, and feedback from the modeling teams has led to changes in follow-on BATS experiments at WIPP. The primary Task E lessons learned were the impact of hydrologic initialization methods (wetting up vs. drying down), the difference between confined and unconfined thermal expansion, and the large changes in permeability associated with heating and cooling.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2016

Analysis of the transport properties of thermally rearranged (TR) polymers and polymers of intrinsic microporosity (PIM) relative to upper bound performance

A critical analysis comparing the diffusion selectivity, solubility selectivity, diffusivity, and solubility coefficients of thermally rearranged (TR) polymers and polymers of intrinsic microporosity (PIM), two types of polymers which consistently perform at or beyond the polymer upper bound for certain gas pairs (O 2 /N 2 and CO 2 /CH 4 ), is reported in this paper. Although most polymers in these two classes exhibit transport properties in the range of typical glassy polymers, several variants offer exceptional performance. The diffusivity selectivity for O 2 /N 2 and CO 2 /CH 4 for TR polymers and PIM lies outside the range of the glassy polymer database. The solubility coefficients for O 2 are at the upper end of the range of both TR and PIM polymers, as is also the case for CO 2 solubility coefficients for PIM polymers. The O 2 /N 2 and CO 2 /CH 4 solubility selectivities for both PIM and TR polymers are in the range of typical glassy polymers. Thus, unique separation values for these polymers are a manifestation of maximizing diffusivity selectivity combined with very high gas solubility. Additionally, the previously determined diffusion gas kinetic diameters, d g , were found to correlate best with diffusion coefficients of PIM and TR polymers and serve to better analyze transport properties of upper bound materials.

36 MATERIALS SCIENCE↗
NASA NTRS2000

Advanced Methods for Aircraft Engine Thrust and Noise Benefits: Nozzle-Inlet Flow Analysis

In this project, we continue to develop the previous joint research between the Fluid Mechanics and Acoustics Laboratory (FM&AL) at Hampton University (HU) and the Jet Noise Team (JNT) at the NASA Langley Research Center (NASA LaRC). The FM&AL was established at Hampton University in June of 1996 and has conducted research under two NASA grants: NAG-1-1835 (1996-99), and NAG-1-1936 (1997-00). In addition, the FM&AL has jointly conducted research with the Central AeroHydrodynamics Institute (TsAGI, Moscow) in Russia under a Civilian Research and Development Foundation (CRDF) grant #RE2-136 (1996-99). The goals of the FM&AL programs are twofold: (1) to improve the working efficiency of the FM&AUs team in generating new innovative ideas and in conducting research in the field of fluid dynamics and acoustics, basically for improvement of supersonic and subsonic aircraft engines, and (2) to attract promising minority students to this research and training and, in cooperation with other HU departments, to teach them basic knowledge in Aerodynamics, Gas Dynamics, and Theoretical and Experimental Methods in Aeroacoustics and Computational Fluid Dynamics (CFD). The research at the HU FM&AL supports reduction schemes associated with the emission of engine pollutants for commercial aircraft and concepts for reduction of observables for military aircraft. These research endeavors relate to the goals of the NASA Strategic Enterprise in Aeronautics concerning the development of environmentally acceptable aircraft. It is in this precise area, where the US aircraft industry, academia, and Government are in great need of trained professionals and which is a high priority goal of the Minority University Research and Education (MUREP) Program, that the HU FM&AL can make its most important contribution. The main achievements for the reporting period in the development of concepts for noise reduction and improvement in efficiency for jet exhaust nozzles and inlets for aircraft engines are as follows: (1) Publications- The AIAA Paper #99-1924 has been presented at the 5th AIAA/CEAS Aeroacoustics Conference, May 10-12, 1999, Seattle, WA; the AIAA Paper #00-3315 has been accepted for the 36th AIAA/ASME/ SAE/ASEE Joint Propulsion Conference, 17-19 July, 2000, Huntsville, AL; and another paper has been accepted for the International Environmental Congress, 14-16 June, 2000, St.-Petersburg, Russia. (2) Two patents were granted on July 20, 1999, and January 12, 2000. (3) Three reports/presentations at the NASA LaRC and GRC (06/22199, 09/26/ 99, and 06/25/00). (4) Grants and Proposals: Four proposals were submitted to the NASA and CRDF; a NASA Faculty Award was granted on January, 2000. A CRDF Young Investigator Program Award was granted for a 3 months visit of the Russian scientist to the HU FM&AL (03/99-05/99). (5) Theory and Numerical Simulations- Analytical theory, numerical simulation, comparison of theoretical with experimental results, and modification of theoretical approaches, models, grids etc. have been conducted for several complicated 2D and 3D nozzle and inlet designs using NASA codes based on full Euler and Navier-Stokes solvers: CFL3D, CRAFT, GODUNOV, and others. New approach for environmental monitoring via infrasound. (6) Experimental Tests: Experimental acoustic tests at the TsAGI, Moscow, with nozzles having Screwdriver or Axisymmetric Plug and Permeable Shells. A small scale working model of the NASA Low Speed Wind Tunnel (LSWT) has been installed in the Experimental Hall of the HU FM&AL (June, 1999). Preliminary preparations for experimental tests were made. (7) Students Research Activity: Involvement of the two graduate students as research assistants in the current research project.

Gilinsky, Mikhail↗
DOE OSTI2024

Techno-Economic Analysis and Market Potential of Geological Thermal Energy Storage (GeoTES) Charged With Solar Thermal and Heat Pumps

In this project, we developed a techno-economic analysis (TEA) model that can be used to evaluate the viability of a proposed Geological Thermal Energy Storage (GeoTES) design. This MATLAB-based model integrates distinct subsystem models for the reservoir, wells, power cycle, and solar field to capture their distinct characteristics. It applies this approach in simulating GeoTES storage and dispatch operations for durations ranging from hourly to seasonal. Using cases studies based on GeoTES designs provided by industry partners - Premier Resource Management (PRM) and EarthBridge Energy - we validated the TEA model estimations of system performance and costs (such as thermal and electrical power/energy inflow and outflow, capital costs, and levelized costs of energy and storage) for both concentrating solar thermal (CST) and Carnot Battery (CB) pairings with GeoTES (CST-GeoTES and CB-GeoTES). For the CST-GeoTES case, the model was validated against the proposed system designed by PRM. It showed good agreement with PRM's estimations when well and pump costs derived from PRM's estimations were used. When GETEM-based costs were used, there was a slight overprediction due to GETEM's project/site agnostic assumption of these costs. From a sensitivity analysis perspective, the levelized cost of electricity (LCOE) of the CST-GeoTES case was most sensitive to well flow rate and the charging temperature. An optimal design scenario resulted in an LCOE of 0.11 $\$$/kWhe. CST-GeoTES can also provide a source of heat to meet seasonal demands. With 12-hour and 24-hour levelized cost of heat (LCOH) of 0.018 $\$$/kWhth and 0.022 $\$$/kWhth, respectively, CST-GeoTES could be competitive in the California market with an average industrial price of natural gas in California between 0.041-0.047 $\$$/kWhth. The levelized cost of storage (LCOS) for CST-GeoTES depends on the energy storage duration. Although the LCOS is relatively higher for shorter durations (e.g., ~0.50 $\$$/kWhe for 1 hour of storage), it is an order of magnitude lower (0.06 $\$$/kWhe) for longer storage durations and competitive with lithium-ion batteries (beyond 12 hours of storage) and molten-salt thermal energy storage (beyond 32 hours). Energy. Three options were explored and applied to the EarthBridge case study: (1) A Carnot Battery design using R125 working fluid with both hot and cold storage; (2) A Carnot Battery design using R125 working fluid with only hot storage; (3) A Carnot Battery using a commercially available heat pump with carbon dioxide (CO2) working fluid and hot storage only. The CB-GeoTES with cold storage only had a slight (round-trip) efficiency advantage over the system without (43.4% vs. 42.8%). This is because the cold storage is limited by the freezing point of water, so the cold storage is not much colder than the environment. The system using commercially available technologies was the least efficient - partly because different cycles were used in the heat pump (CO2) and heat engine (binary cycle) which leads to some inefficiencies. Using the commercially available design, the levelized cost of energy (LCOS) from the model (0.10 $\$$/kWhe) was higher than that estimated by EarthBridge (0.068 $\$$/kWhe). This is because of the low round-trip (38.7%) efficiency of the commercially available design. Sensitivity analysis reveals that the model is most sensitive to electricity price. Including electricity price in the TEA for CB-GeoTES leads to an increase in LCOS from the base value to 0.25 $\$$/kWhe. To determine storage sites suitable for GeoTES, we gathered and analyzed geological, petrophysical, and geophysical data of oil and gas reservoir and aquifers in California and Texas. We down-selected possible sites based on cut-off values for site characteristics (e.g., reservoir temperature, formation thickness, permeability, porosity, depth, and brine salinity) and preliminary costs. Using this approach, the Carrizo-Wilcox, Yegua-Jackson, and Dockum brackish aquifers in Texas were identified as having the highest suitability. Similarly, in the central California region, the White Wolf, Belridge South Tulare, and Belridge South Reef Ridge were the most suitable. Going further, we assessed the storage potential in the selected sites. To do this we developed distributions of reservoir characteristic data and applied a Monte Carlo-based analysis to account for intrinsic uncertainty in the acquired data. The analysis revealed that the Carrizo-Wilcox aquifer had the highest storage potential with a mean capacity of 554 TWhth (i.e., 63 TWhe). The estimated capacity serves as an upper limit of storage potential given that not all fields in the basin will be developed. We participated in multiple outreach activities including conference presentations, panel session discussions, and the facilitation of a GeoTES workshop at the NREL Golden campus.

15 GEOTHERMAL ENERGY↗
DOE OSTI2017

Modeling and Analysis of Coupled Flow Through Packed Beds as a Diagnostic Tool for Packed Bed Reactor Health - 17172

The US Department of Energy, Office of River Protection, is building the Waste Treatment and Immobilization Plant (WTP) in Richland, Washington, to immobilize the hundreds of millions of liters of radioactive waste stored at the Hanford Site in Washington state. The offgas generated during vitrification of these wastes requires treatment to remove and/or destroy chemical and radioactive hazardous components before release to the atmosphere. In particular, volatile and semi-volatile hydrocarbon components are to be catalytically oxidized to carbon dioxide and water, whereas nitrogen oxides (NOx) are to be catalytically reduced to nitrogen and water. These tasks are accomplished in a series of packed bed reactors. Achieving the requisite Destruction/Removal Efficiency (DRE) for each of the tracked components is highly dependent on the flow characteristics of the offgas through the packed beds. The flow kinetics may be monitored and characterized during the initial warm-up of the system. The gases, initially at 76 deg. C (169 deg. F), (a) flow through one side of a countercurrent heat exchanger to recover heat from the exiting gases (which have already passed through the catalytic beds), (b) are then further heated electrically to approximately 400 deg. C (750 deg. F; the preferred operating temperature of the Thermo Catalytic Oxidizer (TCO)), (c) pass through the TCO where the reduced components of the offgas are oxidized over a supported Pt catalyst bed, (d) are partially cooled to approximately 315 deg. C (600 deg. F) by addition of approximately 25% (by weight) diluted ammonia/air mixture, (e) pass through the Selective Catalytic Reducer (SCR) where the NOx components are converted to N{sub 2} and H{sub 2}O over a supported V2O{sub 5}/TiO{sub 2} catalyst bed, and (f) exit through the hot side of the countercurrent heat exchanger. The electrical heater is not powerful enough to raise the temperature of the offgas to the desired 400 deg. C without the contribution of the heat recovered in the heat exchanger. Moreover, the thermal mass of the beds and housings of the TCO and SCR require a significant input of thermal energy to reach the desired operating temperatures; the better part of a day is required to bring the unit from ambient temperatures to operating temperatures. Therefore, the temperature of the stream during the initial warm-up of the system at each point in the system is dependent upon the thermal mass, flow dispersion, and permeability of the components, quantified as characteristic/representative volumes and residence times. By monitoring the temperature of the offgas as it enters and exits each portion of the system during this warm-up period one may model the system as a series of small Continuously Stirred Tank Reactors (CSTR)s (referred to as 'CSTRlets') to explain the flow kinetics through the catalyst beds. These component CSTRlets are adjustable in size and number, that one may model the flow profile of the gases through the catalyst beds. For example, a single large CSTR will present an effluent temperature profile with a simple exponential decay shape. Concatenating more CSTRlets generate more complex sigmoidal responses. Concatenating one CSTRlet significantly larger than the others in the train also alters the shape of the effluent temperature profile, in a fashion not replicable by a train of equal-sized CSTRlets. The ultimate goal is to accurately emulate the entire system as a representative CSTRlet train. Once accomplished, this characterization may be used in subsequent warm-ups (following shutdown for catalyst maintenance, for example) or by an intentional step change in inlet offgas temperature to detect/diagnose anomalies in flow through the beds (e.g., channeling or partial blockage.) This work presents development of this model through analytical, calculational, and empirical means. - The analytic model is accomplished by Laplace transform analysis of each component to recover component process transfer functions. - The calculational portion is performed via brute force finite element calculation. - Fitting empirical data from the warm-up of the TCO skid allows one to select the hypothetical CSTRlet trains which best fit the TCO and SCR beds for the analytical and finite element calculations. The first portion of this paper presents the development of the analytical (Laplace space) model of the coupled system. Estimated values for the initial temperature, mass, specific heat, electrical heat, and relative quantities of the offgas, catalyst beds, stainless steel housings, and ammonia dilution stream are used to generate expected temperature profiles at several selected junctures of the system. The number and size of the component hypothetical CSTRlets are calculated from the analytical model and are used to predict temperature profiles at the exit of the system and at intermediate junctions between system components (where thermocouples are present in the actual unit.) The finite element calculations employ a series of CSTRlet volumes to produce a similar suite of temperature profiles, for comparison with the analytical model results. Finally, empirical data from the Factory Acceptance Test system warm-up are used to select and compare the results from each modeling strategy to select the CSTRlet train(s) which best model the behavior of the actual system. This work presents a novel method of system component characterization, of value to the WTP plant and similar vitrification facilities as well as chemical process industries unrelated to waste management. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

Geocellular model of St. Peter Sandstone for University of Illinois at Urbana-Champaign DDU Feasibility Study

The geocellular model of the St. Peter Sandstone was constructed for the University of Illinois at Urbana-Champaign DDU feasibility study. Starting with the initial area of review (18.0 km by 18.1 km [11.2 miles by 11.3 miles]) the boundaries of the model were trimmed down to 9.7 km by 9.7 km (6 miles by 6 miles) to ensure that the model enclosed a large enough volume so that the cones of depression of both the production and injection wells would not interact with each other, while at the same time minimizing the number of cells to model to reduce computational time. The grid-cell size was set to 61.0 m by 61.0 m (200 feet by 200 feet) for 160 nodes in the X and Y directions. The top surface of the St. Peter Sandstone was provided by geologists working on the project, and the average thickness of the formation was taken from the geologic prospectus they provided. An average thickness of 68.6 m (225 feet) was used for the St. Peter Sandstone, resulting in 45 layers for the model. Petrophysical data was taken from available rotary sidewall core data (Morrow et al., 2017). As geothermal properties (thermal conductivity, specific heat capacity) are closely related to mineralogy, specifically the percentage of quartz, available mineralogical data was assembled and used with published data of geothermal values to determine these properties (Waples and Waples, 2004; Robertson, 1988). The St. Peter Sandstone was divided into facies according to similar geothermal and petrophysical properties, and distributed according to available geophysical log data and prevailing interpretations of the depositional/diagenetic history (Will et al. 2014). Petrophysical and geothermal properties were distributed through geostatistical means according to the associated distributions for each lithofacies. The formation temperature was calculated, based on data from continuous temperature geophysical log from a deep well drilled into the Precambrian basement at the nearby Illinois Basin Decatur Project (IBDP) where CO2 is currently being sequestered (Schlumberger, 2012). Salinity values used in the model were taken from regional studies of brine chemistry in the St. Peter Sandstone, including for the IBDP (e.g., Panno et al. 2018). After being reviewed by the project's geologists, the model was then passed onto the geological engineers to begin simulations of the geothermal reservoir and wellbores.

15 GEOTHERMAL ENERGY↗
NASA NTRS1995

The circum-Chryse region as a possible example of a hydrologic cycle on Mars: Geologic observations and theoretical evaluation

The transection and superposition relationships among channels, chaos, surface materials units, and other features in the circum-Chryse region of Mars were used to evaluate relative age relationships and evolution of flood events. Channels and chaos in contact (with one another) were treated as single discrete flood-carved systems. Some outflow channel systems form networks and are inferred to have been created by multiple flood events. Within some outflow channel networks, several separate individual channel systems can be traced to a specific chaos which acted as flood-source area to that specific flood channel. Individual flood-carved systems were related to widespread materials units or other surface features that served as stratigraphic horizons. Chryse outflow channels are inferred to have formed over most of the perceivable history of Mars. Outflow channels are inferred to become younger with increasing proximity to the Chryse basin. In addition, outflow channels closer to the basin show a greater diversity in age. The relationship of subsequent outflow channel sources to the sources of earlier floods is inferred to disfavor episodic flooding due to the progressive tapping of a juvenile near-surface water supply. Instead, we propose the circum-Chryse region as a candidate site of past hydrological recycling. The discharge rates necessary to carve the circum-Chryse outflow channels would have inevitably formed temporary standing bodies of H2O on the Martian surface where the flood-waters stagnated and pooled (the Chryse basin is topographically enclosed). These observations and inferences have led us to formulate and evaluate two hypotheses: (1) large amounts of the sublimated H2O off the Chryse basin flood lakes precipitated (snowed) onto the flood-source highlands and this H2O was incorporated into the near surface, recharging the H2O sources, making possible subsequent deluges; and (2) ponded flood-water in Chryse basin drained back down an anti basinward dipping subsurface layer accessed along the southern edge of the lake, recharging the flood-source aquifers. H2O not redeposited in the flood-source region was largely lost to the hydrologic cycle. This loss progressively lowered the vitality of the cycle, probably by now killing it. Our numerical evaluations indicate that of the two hypotheses we formulated, the groundwater seep cycle seems by far the more viable. Optimally, approx. 3/4 of the original mass of an ice-covered cylindrical lake (albedo 0.5, 1 km deep, 100-km radius, draining along its rim for one quarter of its circumference into substrata with a permeability of 3000 darcies) can be modeled to have moved underground (on timescales of the order of 10(exp 3) years) before the competing mechanisms of sublimation and freeze down choked off further water removal. Once underground, this water can travel distances equal to the separation between Chryse basin and flood-source sites in geologically short (approx. 10(exp 6) year-scale) times. Conversely, we calculate that optimally only approx. 40% of the H2O carried from Chryse can condense at the highlands, and most of the precipitate would either collect at the base of the highlands/lowlands scarp or sublimate at rates greater than it would accumulate over the flood-source sites. Further observations from forthcoming missions may permit the determination of which mechanisms may have operated to recycle the Chryse flood-waters.

Moore, Jeffrey M.↗
NASA NTRS1995

The Circum-Chryse Region as a Possible Example of a Hydrologic Cycle on Mars: Geologic Observations and Theoretical Evaluation

The transection and superposition relationships among channels, chaos, surface materials units, and other features in the circum-Chryse region of Mars were used to evaluate relative age relationships and evolution of flood events. Channels and chaos in contact (with one another) were treated as single discrete flood-carved systems. Some outflow channel systems form networks and are inferred to have been created by multiple flood events. Within some outflow channel networks, several separate individual channel systems can be traced to a specific chaos which acted as flood-source area to that specific flood channel. Individual flood-carved systems were related to widespread materials units or other surface features that served as stratigraphic horizons. Chryse outflow channels are inferred to have formed over most of the perceivable history of Mars. Outflow channels are inferred to become younger with increasing proximity to the Chryse basin. In addition, outflow channels closer to the basin show a greater diversity in age. The relationship of subsequent outflow channel sources to the sources of earlier floods is inferred to disfavor episodic flooding due to the progressive tapping of a juvenile near-surface water supply. Instead, we propose the circum-Chryse region as a candidate site of past hydrological recycling. The discharge rates necessary to carve the circum-Chryse outflow channels would have inevitably formed temporary standing bodies of H2O on the Martian surface where the flood-waters stagnated and pooled (the Chryse basin is topographically enclosed). These observations and inferences have led us to formulate and evaluate two hypotheses: (1) large amounts of the sublimated H2O off the Chryse basin flood lakes precipitated (snowed) onto the flood-source highlands and this H2O was incorporated into the near surface, recharging the H2O sources, making possible subsequent deluges; and (2) ponded flood-water in Chryse basin drained back down an anti basinward dipping subsurface layer accessed along the southern edge of the lake, recharging the flood-source aquifers. H2O not redeposited in the flood-source region was largely lost to the hydrologic cycle. This loss progressively lowered the vitality of the cycle, probably by now killing it. Our numerical evaluations indicate that of the two hypotheses we formulated, the groundwater seep cycle seems by far the more viable. Optimally, approximately 3/4 of the original mass of an ice-covered cylindrical lake (albedo 0.5, 1 km deep, 100-km radius, draining along its rim for one quarter of its circumference into substrata with a permeability of 3000 darcies) can be modeled to have moved underground (on timescales of the order of 10(exp 3) years) before the competing mechanisms of sublimation and freeze down choked off further water removal. Once underground, this water can travel distances equal to the separation between Chryse basin and flood-source sites in geologically short (approximately 10(exp 6) year-scale) times. Conversely, we calculate that optimally only approximately 40% of the H2O carried from Chryse can condense at the highlands, and most of the precipitate would either collect at the base of the highlands/lowlands scrap or sublimate at rates greater than it would accumulate over the flood-source sites. Further observations from forthcoming missions may permit the determination of which mechanisms may have operated to recycle the Chryse flood-waters.

Moore, Jeffrey M.↗
DOE OSTI2018

Geocellular Model of Mt. Simon Sandstone for University of Illinois at Urbana-Champaign DDU feasibility study

The geocellular model of the Mt. Simon Sandstone was constructed for the University of Illinois at Urbana-Champaign DDU feasibility study. Starting with the initial area of review (18.0 km by 18.1 km [11.2 miles by 11.3 miles]) the boundaries of the model were trimmed down to 9.7 km by 9.7 km (6 miles by 6 miles) to ensure that the model enclosed a large enough volume so that the cones of depression of both the production and injection wells would not interact with each other, while at the same time minimizing the number of cells to model to reduce computational time. The grid-cell size was set to 61.0 m by 61.0 m (200 feet by 200 feet) for 160 nodes in the X and Y directions. Within the model, 67 layers are represented that are parameterized with their sediment/rock properties and petrophysical data. The top surface of the Mt. Simon Sandstone was provided by geologists working on the project, and the average thickness of the formation was taken from the geologic prospectus they provided. An average thickness of 762 m (2500 feet) was used for the Mt. Simon Sandstone, resulting in 60 layers for the model. Petrophysical data was taken from available rotary sidewall core data (Morrow et al., 2017). As geothermal properties (thermal conductivity, specific heat capacity) are closely related to mineralogy, specifically the percentage of quartz, available mineralogical data was assembled and used with published data of geothermal values to determine these properties (Waples and Waples, 2004; Robertson, 1988). The Mt. Simon Sandstone was divided into three separate units (lower, middle, upper) according to similar geothermal and petrophysical properties, and distributed according to available geophysical log data and prevailing interpretations of the depositional/diagenetic history (Freiburg et al. 2016). Petrophysical and geothermal properties were distributed through geostatistical means according to the associated distributions for each lithofacies. The formation temperature was calculated, based on data from continuous temperature geophysical log from a deep well drilled into the Precambrian basement at the nearby Illinois Basin Decatur Project (IBDP) where CO2 is currently being sequestered (Schlumberger, 2012). Salinity values used in the model were taken from regional studies of brine chemistry in the Mt. Simon Sandstone, including for the IBDP (e.g., Panno et al. 2018). After being reviewed by the project's geologists, the model was then passed onto the geological engineers to begin simulations of the geothermal reservoir and wellbores.

15 GEOTHERMAL ENERGY↗
NASA NTRS1999

Novel Approaches to Cellular Transplantation from the US Space Program

Research in the treatment of type I diabetes is entering a new era that takes advantage of our knowledge in an ever increasing variety of scientific disciplines. Some may originate from very diverse sources, one of which is the Space Program at National Aeronautics and Space Administration (NASA). The Space Program contributes to diabetes-related research in several treatment modalities. As an ongoing effort for medical monitoring of personnel involved in space exploration activities NASA and the extramural scientific community investigate strategies for noninvasive estimation of blood glucose levels. Part of the effort in the space protein crystal growth program is high-resolution structural analysis insulin as a means to better understand the interaction with its receptor and with host immune components and as a basis for rational design of a "better" insulin molecule. The Space Program is also developing laser technology for potential early cataract detection as well as a noninvasive analyses for addressing preclinical diabetic retinopathy. Finally, NASA developed an exciting cell culture system that affords some unique advantages in the propagation and maintenance of mammalian cells in vitro. The cell culture system was originally designed to maintain cell suspensions with a minimum of hydrodynamic and mechanical sheer while awaiting launch into microgravity. Currently the commercially available NASA bioreactor (Synthecon, Inc., Houston, TX) is used as a research tool in basic and applied cell biology. In recent years there is continued strong interest in cellular transplantation as treatment for type I diabetes. The advantages are the potential for successful long-term amelioration and a minimum risk for morbidity in the event of rejection of the transplanted cells. The pathway to successful application of this strategy is accompanied by several substantial hurdles: (1) isolation and propagation of a suitable uniform donor cell population; (2) management of host immune rejection; (3) protection from the autoimmune component of the disease; and (4) anatomic placement of the engrafted cells that permits timely response to blood sugar levels as well as effective release and deployment of insulin. Bioreactor technology may provide some critical advances for surmounting some of these scientific hurdles. The NASA bioreactor is a horizontally rotating cylinder that is completely filled with culture medium. Gaseous exchange is maintained by a concentric cylinder of permeable silicon. In slow rotation (15-25 rpm) particles of small mass such as cells and tissue aggregates remain suspended in the rotating body of fluid. This novel approach suspends cells without stirring thus, allowing objects of different size mass to colocate and interact in a very low shear environment. In fact, analysis of the forces acting on individual cells in the rotating bioreactor reveals that the cells are continuously falling through the fluid medium. The conditions in the bioreactor permit assembly of cells into aggregates. three-dimensional tissue growth, synthesis of intercellular matrix,10 differentiation, and some sinusoid formations that may serve as a surrogate vasculature for larger tissue segments.

Pellis, Neal R.↗
DOE OSTI2020

Highly Insulated Wall Systems with Exterior Insulation of Polyisocyanurate under Different Facer Materials: Material Characterization and Long-Term Hygrothermal Performance Assessment

The application of exterior insulation in both new construction and retrofits is a common practice to enhance the energy efficiency of buildings. In addition to increased thermal performance, the rigid insulation can serve to keep the sheathing board warm and serve as a water-resistive barrier to keep moisture-related problems due to condensation and wind-driven rain. Polyisocyanurate (PIR) rigid boards have a higher thermal resistance in comparison to other commonly used exterior insulation boards. However, because of its perceived lower permeance, its use as exterior insulation is not very common. In this study, the hygrothermal property of PIR boards with different facer types and thicknesses is characterized. The material data obtained through experimental test and extrapolation is used in a long term hygrothermal performance assessment of a wood frame wall with PIR boards as exterior insulation. Results show that PIR with no facer has the smallest accumulated moisture on the sheathing board in comparison to other insulation boards. Walls with a bigger thickness of exterior insulation perform better when no vapor barrier is used. The PIR exterior insulation supports the moisture control strategy well in colder climates in perfect wall scenarios, where there is no air leakage and moisture intrusion. In cases where there is trapped moisture, the sheathing board has a higher moisture content with PIR boards with both aluminum or fiberglass type facers. An innovative facer material development for PIR boards can help efforts targeting improved energy-efficient and durable wall systems.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Associations between regional blood-brain barrier permeability, aging, and Alzheimer’s disease biomarkers in cognitively normal older adults

Background Increased blood-brain barrier permeability (BBBp) has been hypothesized as a feature of aging that may lead to the development of Alzheimer’s disease (AD). We sought to identify the brain regions most vulnerable to greater BBBp during aging and examine their regional relationship with neuroimaging biomarkers of AD. Methods We studied 31 cognitively normal older adults (OA) and 10 young adults (YA) from the Berkeley Aging Cohort Study (BACS). Both OA and YA received dynamic contrast-enhanced MRI (DCE-MRI) to quantify K trans values, as a measure of BBBp, in 37 brain regions across the cortex. The OA also received Pittsburgh compound B (PiB)-PET to create distribution volume ratios (DVR) images and flortaucipir (FTP)- PET to create partial volume corrected standardized uptake volume ratios (SUVR) images. Repeated measures ANOVA assessed the brain regions where OA showed greater BBBp than YA. In OA, K trans values were compared based on sex, Aβ positivity status, and APOE4carrier status within a composite region across the areas susceptible to aging. We used linear models and sparse canonical correlation analysis (SCCA) to examine the relationship between K trans and AD biomarkers. Results OA showed greater BBBp than YA predominately in the temporal lobe, with some involvement of parietal, occipital and frontal lobes. Within an averaged ROI of affected regions, there was no difference in K trans values based on sex or Aβ positivity, but OA who were APOE4carriers had significantly higher K trans values. There was no direct relationship between averaged K trans and global Aβ pathology, but there was a trend for an Ab status by tau interaction on K trans in this region. SCCA showed increased K trans was associated with increased PiB DVR, mainly in temporal and parietal brain regions. There was not a significant relationship between K trans and FTP SUVR. Discussion Our findings indicate that the BBB shows regional vulnerability during normal aging that overlaps considerably with the pattern of AD pathology. Greater BBBp in brain regions affected in aging is related to APOE genotype and may also be related to the pathological accumulation of Aβ.

Science & Technology - Other Topics↗