Materials Design via Optimized Intramolecular Noncovalent Interactions for High-Performance Organic Semiconductors
Abstract not provided
Guo, Xiaojie↗
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Results for “electrical conversion efficiency”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Photovoltaic conversion of laser power to electrical power
Photovoltaic laser to electric converters are attractive for use with a space-based laser power station. This paper presents the results of modeling studies for a silicon vertical junction converter used with a Nd laser. A computer code was developed for the model and this code was used to conduct a parametric study for a Si vertical junction converter consisting of one p-n junction irradiated with a Nd laser. These calculations predict an efficiency over 50 percent for an optimized converter.
Walker, G. H.↗
Quantum limits of superconducting-photonic links and their extension to millimeter waves
Photonic addressing of superconducting circuits has been proposed to overcome wiring complexity and heat-load challenges. However, such superconducting-photonic links suffer from an efficiency-noise trade-off that limits scalability. This trade-off arises because increasing power conversion efficiency entails reducing optical power, which makes the converted signal susceptible to shot noise. We analyze this trade-off and find that the laser-driven qubit gate infidelity scales inversely with the number of photons used. While methods such as nonlinear detection or squeezed light could mitigate this effect, we consider generating higher-frequency electrical signals, such as millimeter waves (100 GHz), using laser light. At these higher frequencies, circuits have higher operating temperatures and cooling power budgets and alleviate constraints posed by the trade-off. Therefore, we demonstrate an optically driven cryogenic millimeter-wave source with a maximum power efficiency of 8 ×10 −5 that can generate a maximum of 0.7 μW of 80 GHz power, with a 1200-thermal-photon equivalent of added noise at 4K. Using this source, we perform frequency-domain spectroscopy of superconducting NbTiN resonators at 80–90 GHz. Our results show a promising approach to lessen the efficiency-noise constraints on superconducting-photonic links, while leveraging the benefits of photonic signal delivery. Further optimization of power efficiency and noise at high frequencies could make scalable photonic control of superconducting qubits viable at temperatures exceeding 1K.
Optoelectronics↗
Low Power Ground-Based Laser Illumination for Electric Propulsion Applications
A preliminary evaluation of low power, ground-based laser powered electric propulsion systems is presented. A review of available and near-term laser, photovoltaic, and adaptive optic systems indicates that approximately 5-kW of ground-based laser power can be delivered at an equivalent one-sun intensity to an orbit of approximately 2000 km. Laser illumination at the proper wavelength can double photovoltaic array conversion efficiencies compared to efficiencies obtained with solar illumination at the same intensity, allowing a reduction in array mass. The reduced array mass allows extra propellant to be carried with no penalty in total spacecraft mass. The extra propellant mass can extend the satellite life in orbit, allowing additional revenue to be generated. A trade study using realistic cost estimates and conservative ground station viewing capability was performed to estimate the number of communication satellites which must be illuminated to make a proliferated system of laser ground stations economically attractive. The required number of satellites is typically below that of proposed communication satellite constellations, indicating that low power ground-based laser beaming may be commercially viable. However, near-term advances in low specific mass solar arrays and high energy density batteries for LEO applications would render the ground-based laser system impracticable.
Lapointe, Michael R.↗
Waveguide Harmonic Generator for the SIM
A second-harmonic generator (SHG) serves as the source of the visible laser beam in an onboard calibration scheme for NASA's planned Space Interferometry Mission (SIM), which requires an infrared laser beam and a visible laser beam coherent with the infrared laser beam. The SHG includes quasi-phase-matched waveguides made of MgO-doped, periodically poled lithium niobate, pigtailed with polarization- maintaining optical fibers. Frequency doubling by use of such waveguides affords the required combination of coherence and sufficient conversion efficiency for the intended application. The spatial period of the poling is designed to obtain quasi-phase- matching at a nominal middle excitation wavelength of 1,319.28 nm. The SHG is designed to operate at a warm bias (ambient temperature between 20 and 25 C) that would be maintained in its cooler environment by use of electric heaters; the heater power would be adjusted to regulate the temperature precisely and thereby maintain the required precision of the spatial period. At the state of development at the time of this reporting, the SHG had been packaged and subjected to most of its planned space-qualification tests.
Chang, Daniel↗
Biogas Biocatalysis
Biogas derived from anaerobic digestion of waste streams such as biorefinery wastewater, animal, agricultural, and municipal solid waste, offers a versatile renewable energy source. Total domestic methane potential from landfill material, animal manure, wastewater, and organic waste, combined with biogas generated from AD of lignocellulosic biomass, is estimated to offer >4 quadrillion Btu potential energy. This energy could displace nearly half of current domestic natural gas consumption in the electric power sector and all consumption in the transportation sector. However, despite this promise of this feedstock, its gaseous state prevents facile integration with extant transportation and industrial infrastructure. Microbial conversion of biogas to liquid fuel and chemical intermediates offers valorization potential. However, biogas biocatalysis is currently limited by poor substrate gas-to-liquid mass transfer, low conversion efficiencies, and incomplete biogas utilization. To this end, the Biogas Biocatalysis AOP aims to develop a carbon- and energy-efficient biogas bioconversion process via techno-economic-informed strain and fermentation engineering strategies. Efforts here will improve both process economics and sustainability via process-intensified, carbon-efficient biogas bioconversion to value-added platform molecules, enabling bolt-on deployment for valorization of biogas derived from standalone AD infrastructure.
BASIC BIOLOGICAL SCIENCES,BIOMASS FUELS↗
Fission Surface Power Technology Demonstration Unit Test Results
The Fission Surface Power (FSP) Technology Demonstration Unit (TDU) is a system-level demonstration of fission power technology intended for use on manned missions to Mars. The Baseline FSP systems consists of a 190 kWt UO2 fast-spectrum reactor cooled by a primary pumped liquid metal loop. This liquid metal loop transfers heat to two intermediate liquid metal loops designed to isolate fission products in the primary loop from the balance of plant. The intermediate liquid metal loops transfer heat to four Stirling Power Conversion Units (PCU), each of which produce 12 kWe (48 kW total) and reject waste heat to two pumped water loops, which transfer the waste heat to titanium-water heat pipe radiators. The FSP TDU simulates a single leg of the baseline FSP system using an electrically heater core simulator, a single liquid metal loop, a single PCU, and a pumped water loop which rejects the waste heat to a Facility Cooling System (FCS). When operated at the nominal operating conditions (modified for low liquid metal flow) during TDU testing the PCU produced 8.9 kW of power at an efficiency of 21.7% resulting in a net system power of 8.1 kW and a system level efficiency of 17.2%. The reduction in PCU power from levels seen during electrically heated testing is the result of insufficient heat transfer from the NaK heater head to the Stirling acceptor, which could not be tested at Sunpower prior to delivery to GRC. The maximum PCU power of 10.4 kW was achieved at the maximum liquid metal temperature of 875 K, minimum water temperature of 350 K, 1.1 kg/s liquid metal flow, 0.39 kg/s water flow, and 15.0 mm amplitude at an efficiency of 23.3%. This resulted in a system net power of 9.7 kW and a system efficiency of 18.7 %.
fission power technology↗
The Power Reclamation of Utilizing Micro-Hydro Turbines in the Aeration Basins of Wastewater Treatment Plants
Upgrading the aeration basin technology can improve the oxygen transfer efficiency (OTE), while keeping the energy consumption at its minimum level. Therefore, this paper introduces a new idea of installing micro-propeller turbines in the aeration basin of a wastewater treatment plant (WWTP) to extract power from the high-velocity location in the water column. This extracted power can be used to operate a mixer at the top of the membrane to induce the mixing in that region, which will drive the less oxygenated wastewater into the water column. The rest of the extracted power will rotate microturbine rotors for electric power generation. By applying the proposed microturbines to the 13 audited facilities, it was demonstrated to achieve a gross annual energy-savings of 3,836.9 MWh, a gross annual cost-saving of $260,497, and total CO 2 emissions that would be reduced by 2,714 metric tons/year. Generally, the addition of the proposed microturbines can save up to 15.7% of the annual plant electricity consumption (1.3–12.8% of the plant annual electricity bills).
13 HYDRO ENERGY↗
One joule output from a diode-array-pumped Nd:YAG laser with side-pumped rod geometry
Output of 1.25 J per pulse (1.064 micron) with an absolute optical efficiency of 28 percent and corresponding electrical efficiency of 10 percent was demonstrated in a diode-array-pumped Nd:YAG laser using a side-pumped rod geometry in a master-oscillator/power-amplifier configuration. In Q-switched operation, an output of 0.75 J in a 17-ns pulse was obtained. The fundamental laser output was frequency doubled in KTP with 60 percent conversion efficiency to obtain 0.45 J in a 16-ns pulse at 532 nm. The output beam had high spatial quality with pointing stability better than 40 microrad and a shot-to-shot pulse energy fluctuation of less than +/-3 percent.
Kasinski, Jeffrey J.↗
Electrified Automotive Powertrain Architecture Using Composite DC–DC Converters
In a hybrid or electric vehicle powertrain, a boost dc-dc converter enables reduction of the size of the electric machine and optimization of the battery system. Design of the powertrain boost converter is challenging because the converter must be rated at high peak power, while efficiency at medium-to-light load is critical for the vehicle system performance. By addressing only some of the loss mechanisms, previously proposed efficiency improvement approaches offer limited improvements in size, cost, and efficiency tradeoffs. This article shows how all dominant loss mechanisms in automotive powertrain applications can be mitigated using a new boost composite converter approach. In the composite dc-dc architecture, the loss mechanisms associated with indirect power conversion are addressed explicitly, resulting in fundamental efficiency improvements over wide ranges of operating conditions. Several composite converter topologies are presented and compared to state-of-the-art boost converter technologies. It is found that the selected boost composite converter results in a decrease in the total loss by a factor of 2-4 for typical drive cycles. Furthermore, the total system capacitor power rating and energy rating are substantially reduced, which implies potentials for significant reductions in system size and cost.
25 ENERGY STORAGE↗
Sustainable Federal Fleets: Deploying Electric Vehicles and Electric Vehicle Supply Equipment
The U.S. Department of Energy (DOE) Federal Energy Management Program (FEMP) helps federal agencies reduce petroleum consumption and increase alternative fuel use through its resources for Sustainable Federal Fleets. To assist agencies with the transition to plug-in electric vehicles (PEVs), including battery electric vehicles (BEVs) and plug-in hybrid electric vehicles (PHEVs), FEMP offers technical guidance on electric vehicle supply equipment (EVSE) installations and site-specific planning through partnerships with the National Renewable Energy Laboratory's (NREL's) EVSE Tiger Teams.
30 DIRECT ENERGY CONVERSION↗
Fission Surface Power Technology Demonstration Unit Test Results
The Fission Surface Power (FSP) Technology Demonstration Unit (TDU) is a system-level demonstration of fission power technology intended for use on manned missions to Mars. The Baseline FSP systems consists of a 190 kWt UO2 fast-spectrum reactor cooled by a primary pumped liquid metal loop. This liquid metal loop transfers heat to two intermediate liquid metal loops designed to isolate fission products in the primary loop from the balance of plant. The intermediate liquid metal loops transfer heat to four Stirling Power Conversion Units (PCU), each of which produce 12 kWe (48 kW total) and reject waste heat to two pumped water loops, which transfer the waste heat to titanium-water heat pipe radiators. The FSP TDU simulates a single leg of the baseline FSP system using an electrically heater core simulator, a single liquid metal loop, a single PCU, and a pumped water loop which rejects the waste heat to a Facility Cooling System (FCS). When operated at the nominal operating conditions (modified for low liquid metal flow) during TDU testing the PCU produced 8.9 kW of power at an efficiency of 21.7 percent resulting in a net system power of 8.1 kW and a system level efficiency of 17.2 percent. The reduction in PCU power from levels seen during electrically heated testing is the result of insufficient heat transfer from the NaK heater head to the Stirling acceptor, which could not be tested at Sunpower prior to delivery to the NASA Glenn Research Center (GRC). The maximum PCU power of 10.4 kW was achieved at the maximum liquid metal temperature of 875 K, minimum water temperature of 350 K, 1.1 kg/s liquid metal flow, 0.39 kg/s water flow, and 15.0 mm amplitude at an efficiency of 23.3 percent. This resulted in a system net power of 9.7 kW and a system efficiency of 18.7 percent.
Facility Cooling System↗
Reformer Fuel Injector
Today's form of jet engine power comes from what is called a gas turbine engine. This engine is on average 14% efficient and emits great quantities of green house gas carbon dioxide and air pollutants, Le. nitrogen oxides and sulfur oxides. The alternate method being researched involves a reformer and a solid oxide fuel cell (SOFC). Reformers are becoming a popular area of research within the industry scale. NASA Glenn Research Center's approach is based on modifying the large aspects of industry reforming processes into a smaller jet fuel reformer. This process must not only be scaled down in size, but also decrease in weight and increase in efficiency. In comparison to today's method, the Jet A fuel reformer will be more efficient as well as reduce the amount of air pollutants discharged. The intent is to develop a 10kW process that can be used to satisfy the needs of commercial jet engines. Presently, commercial jets use Jet-A fuel, which is a kerosene based hydrocarbon fuel. Hydrocarbon fuels cannot be directly fed into a SOFC for the reason that the high temperature causes it to decompose into solid carbon and Hz. A reforming process converts fuel into hydrogen and supplies it to a fuel cell for power, as well as eliminating sulfur compounds. The SOFC produces electricity by converting H2 and CO2. The reformer contains a catalyst which is used to speed up the reaction rate and overall conversion. An outside company will perform a catalyst screening with our baseline Jet-A fuel to determine the most durable catalyst for this application. Our project team is focusing on the overall research of the reforming process. Eventually we will do a component evaluation on the different reformer designs and catalysts. The current status of the project is the completion of buildup in the test rig and check outs on all equipment and electronic signals to our data system. The objective is to test various reformer designs and catalysts in our test rig to determine the most efficient configuration to incorporate into the specific compact jet he1 reformer test rig. Additional information is included in the original extended abstract.
Suder, Jennifer L.↗
Futures for electrochromic windows on high performance houses in arid, cold climates
This study investigates high performance electrochromic windows used on a passive house and residential dwelling to IECC 2021 (i.e., IECC dwelling). In the lab, the electrochromic film switches transmitted solar heat gain coefficient (SHGC) from 0.09 to 0.7 and visible transmittance from 0.15 to 0.82 with power consumption of 1.23 W/m 2 during switching times less than 3 minutes. We extrapolate these results to a window assembly. Building energy models of the houses were evaluated in Santa Fe, New Mexico. A Monte Carlo analysis for 2020, 2040, 2060, and 2080 was conducted for Shared Socioeconomic Pathways 2-4.5, 3-7.0, and 5-8.5. Cases with and without the electrochromic windows and with and without electricity were used to determine energy use intensity and hours beyond thermal safety thresholds. The passive house showed 1.3-3.1% mean energy savings and the IECC dwelling 4.4-5.1% with electrochromic efficiency benefits growing into the future for both cases. Even so, overall savings decrease into the future for the passive house, due to growth in cooling load being dominant, conversely overall energy savings increase into the future for the IECC dwelling due to heating loads being dominant. For thermal resilience, the passive house exhibited a mean percent decrease of 0.02-0.31% hours in the extreme caution (i.e., > 32.2 °C, ≤ 39.4 °C) range while the IECC dwelling exhibited 0.38-4.38%. The study therefore shows that electrochromic windows will have smaller benefits for the passive house in comparison to the IECC dwelling. The relationship between electrochromic windows is shown to have a complex relationship between house efficiency and climate change by these results.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Dynamic Characteristics and Test Results of a Wave Power Take-off System with Mechanical Motion Rectification and Transmission
An innovative ocean wave power takeoff (PTO) system is presented here to enhance electrical energy generation from oscillating wave motions. This PTO system, mainly consisting of dual ball screws, gearbox with mechanical motion rectification (MMR) and a permanent magnet synchronous generator (PMSG), can convert bidirectional irregular motions from a floating wave buoy into unidirectional regular generator rotations. Systematical operating principles, design and prototyping details of the PTO system are presented and analyzed. A hydrodynamics-mechanical-electrical model of the system is established by reasonably representing power switches attached to the PMSG as an equivalent external resistance. The overall dynamics of the system are then analyzed in the frequency-domain. Three power control strategies are proposed to maximize the wave power absorption by changing the equivalent external resistance. The effectiveness and relatively high energy conversion efficiency of the PTO system have been demonstrated based on lab bench test results. The levelized cost of energy of a full scale wave energy converter system is also calculated based on the proposed PTO system.
16 TIDAL AND WAVE POWER↗
Conceptual design of an advanced Stirling conversion system for terrestrial power generation
A free piston Stirling engine coupled to an electric generator or alternator with a nominal kWe power output absorbing thermal energy from a nominal 100 square meter parabolic solar collector and supplying electric power to a utility grid was identified. The results of the conceptual design study of an Advanced Stirling Conversion System (ASCS) were documented. The objectives are as follows: define the ASCS configuration; provide a manufacturability and cost evaluation; predict ASCS performance over the range of solar input required to produce power; estimate system and major component weights; define engine and electrical power condidtioning control requirements; and define key technology needs not ready by the late 1980s in meeting efficiency, life, cost, and with goalds for the ASCS.
Source record↗
Low to high temperature energy conversion system
A method for converting heat energy from low temperature heat sources to higher temperature was developed. It consists of a decomposition chamber in which ammonia is decomposed into hydrogen and nitrogen by absorbing heat of decomposition from a low temperature energy source. A recombination reaction then takes place which increases the temperature of a fluid significantly. The system is of use for the efficient operation of compact or low capital investment turbine driven electrical generators, or in other applications, to enable chemical reactions that have a critical lower temperature to be used. The system also recovers heat energy from low temperature heat sources, such as solar collectors or geothermal sources, and converts it to high temperatures.
Miller, C. G.↗
Thermal modeling and efficiency of a dual-stage sodium heat engine
In this paper, a thermal design of an axisymmetric dual-stage sodium thermal electrochemical converter (Na-TEC) is presented, where a reduced-order finite-element model is used in conjunction with a Na-TEC thermodynamic model to determine the total parasitic heat loss of this dual-stage design. A number of simplifications are applied in the reduced-order model to decrease the computational time while maintaining acceptable accuracy. These include the use of effective thermal conductivities to account for complex corrugated geometries and apparent surface emissivities to accommodate the effect of radiation shields. Furthermore, a simplified analytical model is developed to account for conduction bypass through the Na-TEC liquid-return path. An iterative procedure between the finite-element and thermodynamic models is described in detail, and the thermal performance of the design proposed herein is analyzed. According to this analysis, a maximum efficiency of 29% and a maximum power output of 125 W can be achieved.
14 SOLAR ENERGY↗