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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 901 records · Page 50

Better Radiation Response and Accident Tolerance of Nanostructured Ceramic Fuel Materials?

The objective of this research is to study structural stability and fission product behavior in nanostructured ZrO 2 and CeO 2 at temperatures and irradiation conditions relevant to operation and accidental scenarios. The fundamental understanding will support the development of innovative fuel forms. Specifically, the proposed work employs novel ion irradiation approaches, complementary characterization techniques, and advanced simulation methods to perform separate and integrated effect studies that expand the fundamental understanding of: Task (1) damage evolution in ceramic fuel materials in a controlled irradiation environment with focus in the transition energy regime where simultaneous energy deposition to both atomic and electronic structures is significant; Task (2) phase and structural stability in nanostructured fuel materials to high-temperature high-dose irradiation; and Task (3) role of the grain boundaries, surface/interface properties on migration and segregation of fission products.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Computational Modeling and Experimental Characterization of Martensitic Transformations in Nicoal for Self-Sensing Materials

Fundamental changes to aero-vehicle management require the utilization of automated health monitoring of vehicle structural components. A novel method is the use of self-sensing materials, which contain embedded sensory particles (SP). SPs are micron-sized pieces of shape-memory alloy that undergo transformation when the local strain reaches a prescribed threshold. The transformation is a result of a spontaneous rearrangement of the atoms in the crystal lattice under intensified stress near damaged locations, generating acoustic waves of a specific spectrum that can be detected by a suitably placed sensor. The sensitivity of the method depends on the strength of the emitted signal and its propagation through the material. To study the transition behavior of the sensory particle inside a metal matrix under load, a simulation approach based on a coupled atomistic-continuum model is used. The simulation results indicate a strong dependence of the particle's pseudoelastic response on its crystallographic orientation with respect to the loading direction and suggest possible ways of optimizing particle sensitivity. The technology of embedded sensory particles will serve as the key element in an autonomous structural health monitoring system that will constantly monitor for damage initiation in service, which will enable quick detection of unforeseen damage initiation in real-time and during onground inspections.

Wallace, T. A.↗

Development of Multi-Physics Dynamics Models for High-Frequency Large-Amplitude Structural Response Simulation

An analytic approach is demonstrated to reveal potential pyroshock-driven dynamic effects causing power losses in the Thermo-Electric (TE) module bars of the Mars Science Laboratory (MSL) Multi-Mission Radioisotope Thermoelectric Generator (MMRTG). This study utilizes high-fidelity finite element analysis with SIERRA/PRESTO codes to estimate wave propagation effects due to large-amplitude suddenly-applied pyro shock loads in the MMRTG. A high fidelity model of the TE module bar was created with approximately 30 million degrees-of-freedom (DOF). First, a quasi-static preload was applied on top of the TE module bar, then transient tri-axial acceleration inputs were simultaneously applied on the preloaded module. The applied input acceleration signals were measured during MMRTG shock qualification tests performed at the Jet Propulsion Laboratory. An explicit finite element solver in the SIERRA/PRESTO computational environment, along with a 3000 processor parallel super -computing framework at NASA AMES, was used for the simulation. The simulation results were investigated both qualitatively and quantitatively. The predicted shock wave propagation results provide detailed structural responses throughout the TE module bar, and key insights into the dynamic response (i.e., loads, displacements, accelerations) of critical internal spring/piston compression systems, TE materials, and internal component interfaces in the MMRTG TE module bar. They also provide confidence on the viability of this high-fidelity modeling scheme to accurately predict shock wave propagation patterns within complex structures. This analytic approach is envisioned for modeling shock sensitive hardware susceptible to intense shock environments positioned near shock separation devices in modern space vehicles and systems.

Shock Waves↗

Finite Element Simulation of Three Full-Scale Crash Tests for Cessna 172 Aircraft

The NASA Emergency Locator Transmitter Survivability and Reliability project was initiated in 2013 to assess the crash performance standards for the next generation of emergency locator transmitter (ELT) systems. Three Cessna 172 aircraft were acquired to perform crash testing at the NASA Langley Research Center Landing and Impact Research Facility. Full-scale crash tests were conducted in the summer of 2015, and each test article was subjected to severe, but survivable, impact conditions including a flare-to-stall during emergency landing and two controlled-flight-into-terrain scenarios. Finite element analyses were performed to numerically simulate the aircraft response to the crash tests. The first test simulated impacting a concrete surface represented analytically by a rigid plane. Tests 2 and 3 simulated impacting a dirt surface represented analytically by an Eulerian grid of brick elements using a Mohr–Coulomb material model. The objective of this paper is to summarize the test and analysis results for the three full-scale crash tests. Simulation models of the airframe that correlate well with the tests are needed for future studies of alternate ELT mounting configurations.

Finite Element Analysis↗

Evaluation of Composite Airframe Dynamic Impact Modeling Using Hawker 4000 Fuselage Drop Test Data

Two drop tests of partial Hawker 4000 fuselage sections were conducted at the National Aeronautics and Space Administration (NASA) Langley Research Center (LaRC) to characterize the response of representative composite aerospace structure to dynamic impact loads. Test conditions were selected to induce damage into the composite structure in order to study material failure within a composite fuselage and evaluate the capability of finite element (FE) model analysis to predict that failure. The tests were simulated using FE models which were generated to isolate the effect of developmental data availability on predictive capability. FE Models of the tested fuselage sections were generated using two limited data sets. The first model configuration was reverse engineered from the test article with no information related to design or fabrication details which would be known only by the manufacturer. The second model was generated from data provided by the manufacturer but without additional material characterization test data. Models were developed using these methodologies for both fuselage sections tested. Correlation of each model to the tests conducted was evaluated in terms of damage, deformation, and cabin acceleration measurements. Correlation between the developed models and the tested fuselage sections showed that the reverse engineered model predicted the composite damage and cabin acceleration measured during test though it was limited due to lack of detail in the composite layup changes through the structure. The model developed using manufacturer specifications did not predict damage, due to limited material and component model characterization data, but it did predict acceleration on par with the reverse engineered model. Model capability and limitation sources identified were verified through correlation of a final model which was developed by combining the individual data sets. The combined model demonstrated that the addition of calibrated composite material models to accurate composite layup definitions and detailed geometry led to improved correlation of damage and acceleration response within the composite fuselage structures.

Crashworthiness↗

Evaluation of Composite Airframe Dynamic Impact Modeling Using Hawker 4000 Fuselage Drop Test Data

Two drop tests of partial Hawker 4000 fuselage sections were conducted at the National Aeronautics and Space Administration (NASA) Langley Research Center (LaRC) to characterize the response of representative composite aerospace structure to dynamic impact loads. Test conditions were selected to induce damage into the composite structure in order to study material failure within a composite fuselage and evaluate the capability of finite element (FE) model analysis to predict that failure. The tests were simulated using FE models which were generated to isolate the effect of developmental data availability on predictive capability. FE Models of the tested fuselage sections were generated using two limited data sets. The first model configuration was reverse engineered from the test article with no information related to design or fabrication details which would be known only by the manufacturer. The second model was generated from data provided by the manufacturer but without additional material characterization test data. Models were developed using these methodologies for both fuselage sections tested. Correlation of each model to the tests conducted was evaluated in terms of damage, deformation, and cabin acceleration measurements. Correlation between the developed models and the tested fuselage sections showed that the reverse engineered model predicted the composite damage and cabin acceleration measured during test though it was limited due to lack of detail in the composite layup changes through the structure. The model developed using manufacturer specifications did not predict damage, due to limited material and component model characterization data, but it did predict acceleration on par with the reverse engineered model. Model capability and limitation sources identified were verified through correlation of a final model which was developed by combining the individual data sets. The combined model demonstrated that the addition of calibrated composite material models to accurate composite layup definitions and detailed geometry led to improved correlation of damage and acceleration response within the composite fuselage structures.

Crashworthiness↗

The Contributions of Polar Nanoregions to the Dielectric and Piezoelectric Responses in Domain-Engineered Relaxor-PbTiO 3 Crystals

The existence of polar nanoregions is the most important characteristic of relaxor-based ferroelectric materials. Recently, the contributions of polar nanoregions to the shear piezoelectric property of relaxor-PbTiO 3 (PT) crystals are confirmed in a single domain state, accounting for 50%–80% of room temperature values. For electromechanical applications, however, the outstanding longitudinal piezoelectricity in domain-engineered relaxor-PT crystals is of the most significance. In this paper, the contributions of polar nanoregions to the longitudinal properties in [001]-poled Pb(Mg 1/3 Nb 2/3 )O 3 -0.30PbTiO 3 and [110]-poled Pb(Zn 1/3 Nb 2/3 )O3-0.15PbTiO 3 (PZN-0.15PT) domain-engineered crystals are studied. Taking the [110]-poled tetragonal PZN-0.15PT crystal as an example, phase-field simulations of the domain structures and the longitudinal dielectric/piezoelectric responses are performed. According to the experimental results and phase-field simulations, the contributions of polar nanoregions (PNRs) to the longitudinal properties of relaxor-PT crystals are successfully explained on the mesoscale, where the PNRs behave as “seeds” to facilitate macroscopic polarization rotation and enhance electric-field-induced strain. The results reveal the importance of local structures to the macroscopic properties, where a modest structural variation on the nanoscale greatly impacts the macroscopic properties.

36 MATERIALS SCIENCE↗

A Common Probe Design for Multiple Planetary Destinations

Atmospheric probes have been successfully flown to planets and moons in the solar system to conduct in situ measurements. They include the Pioneer Venus multi-probes, the Galileo Jupiter probe, and Huygens probe. Probe mission concepts to five destinations, including Venus, Jupiter, Saturn, Uranus, and Neptune, have all utilized similar-shaped aeroshells and concept of operations, namely a 45-degree sphere cone shape with high density heatshield material and parachute system for extracting the descent vehicle from the aeroshell. Each concept designed its probe to meet specific mission requirements and to optimize mass, volume, and cost. At the 2017 International Planetary Probe Workshop (IPPW), NASA Headquarters postulated that a common aeroshell design could be used successfully for multiple destinations and missions. This "common probe" design could even be assembled with multiple copies, properly stored, and made available for future NASA missions, potentially realizing savings in cost and schedule and reducing the risk of losing technologies and skills difficult to sustain over decades. Thus the NASA Planetary Science Division funded a study to investigate whether a common probe design could meet most, if not all, mission needs to the five planetary destinations with extreme entry environments. The Common Probe study involved four NASA Centers and addressed these issues, including constraints and inefficiencies that occur in specifying a common design. Study methodology: First, a notional payload of instruments for each destination was defined based on priority measurements from the Planetary Science Decadal Survey. Steep and shallow entry flight path angles (EFPA) were defined for each planet based on qualification and operational g-load limits for current, state-of-the-art instruments. Interplanetary trajectories were then identified for a bounding range of EFPA. Next, 3-degrees-of-freedom simulations for entry trajectories were run using the entry state vectors from the interplanetary trajectories. Aeroheating correlations were used to generate stagnation point convective and radiative heat flux profiles for several aeroshell shapes and entry masses. High fidelity thermal response models for various Thermal Protection System (TPS) materials were used to size stagnation-point thicknesses, with margins based on previous studies. Backshell TPS masses were assumed based on scaled heat fluxes from the heatshield and also from previous mission concepts. Presentation: We will present an overview of the study scope, highlights of the trade studies and design driver analyses, and the final recommendations of a common probe design and assembly. We will also indicate limitations that the common probe design may have for the different destinations. Finally, recommended qualification approaches for missions will be presented.

Hwang, H. H.↗

Attenuation of empennage buffet response through active control of damping using piezoelectric material

Dynamic response and damping data obtained from buffet studies conducted in a low-speed wind tunnel by using a simple, rigid model attached to spring supports are presented. The two parallel leaf spring supports provided a means for the model to respond in a vertical translation mode, thus simulating response in an elastic first bending mode. Wake-induced buffeting flow was created by placing an airfoil upstream of the model of that the wake of the airfoil impinged on the model. Model response was sensed by a strain gage mounted on one of the springs. The output signal from the strain gage was fed back through a control law implemented on a desktop computer. The processed signals were used to 'actuate' a piezoelectric bending actuator bonded to the other spring in such a way as to add damping as the model responded. The results of this 'proof-of-concept' study show that the piezoelectric actuator was effective in attenuating the wake-induced buffet response over the range of parameters investigated.

Heeg, Jennifer↗

Stability Evaluation for a Damped, Constrained-Motion Cutting Force Dynamometer

This paper describes the dynamic stability evaluation of a constrained-motion dynamometer (CMD) with passive damping. The CMD’s flexure-based design offers an alternative to traditional piezoelectric cutting force dynamometers, which can exhibit adverse effects of the complex structural dynamics on the measurement accuracy. In contrast, the CMD system’s structural dynamics are nominally single degree of freedom and are conveniently altered by material selection, flexure element geometry, and element arrangement. In this research, a passive damping approach is applied to increase the viscous damping ratio and, subsequently, the stability limit. Cutting tests were completed and the in situ CMD displacement and velocity signals were sampled at the spindle rotating frequency. The periodic sampling approach was used to determine if the milling response was synchronous with the spindle rotation (stable) or not (chatter) by constructing Poincaré maps for both experiment and prediction (time-domain simulation). It was found that the viscous damping coefficient was increased by 130% and the critical stability limit was increased from 4.3 mm (no damping) to 15.4 mm (with damping).

36 MATERIALS SCIENCE↗

Time-resolved in situ visualization of the structural response of zeolites during catalysis

Zeolites form an important class of materials that are widely used in various fields. Their unique properties come primarily from their size, shape, and connectivity of their sub-nm crystalline voids, the Si/Al ratio of the anionic framework, and the number and the nature of charge-balancing cations.The inhomogeneous distribution of the Si/Al ratio within crystals, and hence the cation density, the presence of organic residues, and their inhomogeneous distribution within crystals sensitively affect their performances because these factors influencethe intra-crystalline diffusion rates of the reactants and products. However, the information regarding these inhomogeneities in zeolite crystals cannot be obtained by conventional analytical tools because they only provide information regardingthe average properties of zeolite crystals. Here we employin situX-ray free electron laser-based time-resolved coherent X-ray diffraction imaging to investigate the internal deformations originating from the inhomogeneous Cu ion distributions in Cu-exchanged ZSM-5 zeolite crystals during the deoxygenation of nitrogen oxides with propene. We show that the interactions between the reactants and the active sites lead to an unusual strain distribution,which is confirmed by density functional theory simulations. Moreover, this elucidates the factors responsible for distinct active regions,which are essential to maximizing some applications with enhanced performances. These observations provide insights into the role of structural inhomogeneity in zeolites during a catalytic processand will assist the future design of zeolites for their applications.

36 MATERIALS SCIENCE↗

High Temperature Solid Particle Erosion in a Melt-Infiltrated SiC/SiC Ceramic Matrix Composite

Ceramic matrix composites (CMCs) are an enabling propulsion material system that offer weight benefits over current Ni-based superalloys, and have higher temperature capabilities that can reduce cooling requirements. Incorporating CMCs into the hot section of gas-turbine engines therefore leads to an increase in engine efficiency. While significant advancements have been made, challenges still remain for current and next-generation gas-turbines; particularly when operating in dust-laden or erosive environments. Solid particles entrained in the gas flow can impact engine hardware resulting in localized damage and material removal due to repeated, cumulative impacts. In this study, the erosion behavior of a melt-infiltrated (MI) silicon carbide fiber-reinforced silicon carbide (SiC/SiC) CMC is investigated at high temperature (1,200 °C) in a simulated combustion environment using 150 µm alumina particles as erodent. Particle impact velocities ranged from 100 to 200 m/s and the angle of impingement varied from 30° to 90°. Erosion testing was also performed on α-SiC to elucidate similarities and differences in the erosion response of the composite compared to that of a monolithic ceramic. Scanning electron microscopy (SEM) was used to study the post-erosion damage morphology and the governing mechanisms of material removal.

Ceramic matrix composites (CMCs), solid particle e↗

Characterization of ion beam modified ceramic wear surfaces using Auger electron spectroscopy

An investigation of the surface chemistry and morphology of the wear surfaces of ceramic material surfaces modified by ion beam mixing has been conducted using Auger electron spectroscopy and secondary electron microscopy. Studies have been conducted on ceramic/ceramic friction and wear couples made up of TiC and NiMo-bonded TiC cermet pins run against Si3N4 and partially stabilized zirconia disc surfaces modified by the ion beam mixing of titanium and nickel, as well as ummodified ceramic/ceramic couples in order to determine the types of surface changes leading to the improved friction and wear behavior of the surface modified ceramics in simulated diesel environments. The results of the surface analyses indicate that the formation of a lubricating oxide layer of titanium and nickel, is responsible for the improvement in ceramic friction and wear behavior. The beneficial effect of this oxide layer depends on several factors, including the adherence of the surface modified layer or subsequently formed oxide layer to the disc substrate, the substrate materials, the conditions of ion beam mixing, and the environmental conditions.

Wei, W.↗

Surface characteristics of spacecraft components affect the aggregation of microorganisms and may lead to different survival rates of bacteria on Mars landers

Layers of dormant endospores of Bacillus subtilis HA101 were applied to eight different spacecraft materials and exposed to martian conditions of low pressure (8.5 mbar), low temperature (-10 degrees C), and high CO(2) gas composition and irradiated with a Mars-normal ultraviolet (UV-visible- near-infrared spectrum. Bacterial layers were exposed to either 1 min or 1 h of Mars-normal UV irradiation, which simulated clear-sky conditions on equatorial Mars (0.1 tau). When exposed to 1 min of Mars UV irradiation, the numbers of viable endospores of B. subtilis were reduced three to four orders of magnitude for two brands of aluminum (Al), stainless steel, chemfilm-treated Al, clear-anodized Al, and black-anodized Al coupons. In contrast, bacterial survival was reduced only one to two orders of magnitude for endospores on the non-metal materials astroquartz and graphite composite when bacterial endospores were exposed to 1 min of Mars UV irradiation. When bacterial monolayers were exposed to 1 h of Mars UV irradiation, no viable bacteria were recovered from the six metal coupons listed above. In contrast, bacterial survival was reduced only two to three orders of magnitude for spore layers on astroquartz and graphite composite exposed to 1 h of Mars UV irradiation. Scanning electron microscopy images of the bacterial monolayers on all eight spacecraft materials revealed that endospores of B. subtilis formed large aggregates of multilayered spores on astroquartz and graphite composite, but not on the other six spacecraft materials. It is likely that the formation of multilayered aggregates of endospores on astroquartz and graphite composite is responsible for the enhanced survival of bacterial cells on these materials.

Mars↗

Investigation of the decolorization efficiency of two pin-to-plate corona discharge plasma system for industrial wastewater treatment

In this article, a dual pin-to-plate high-voltage corona discharge system is introduced to study experimentally the gap distance, the contact time, the effect of pin and plate materials, the thickness of ground plate and the conductivity on the amount of Acid Blue 25 dye color removal efficiency from polluted water. A study for the optimum air gap distance between dual pin and surface of Acid Blue 25 dye solution is carried out using 3D-EM simulator to find maximum electric field intensity at the tip of both pins. The outcomes display that the best gap for corona discharge is approximately 5 mm for 15-kV source. This separation is constant during the study of other factors. In addition, an investigation of the essential reactive species responsible for oxidation of the dye organic compounds (O{sub 3} in air discharge, O{sub 3} in water, and H{sub 2}O{sub 2}) during the experimental time is conducted. Three various materials such as: stainless steel, copper and aluminum are used for pins and plate. The maximum color removal efficiencies of Acid Blue 25 dyes are 99.03, 82.04, and 90.78% after treatment time 15 min for stainless steel, copper, and aluminum, respectively. Measurement results for the impact of thickness of an aluminum ground plate on color removal competence show color removal efficiencies of 86.3, 90.78, and 98.06% after treatment time 15 min for thicknesses of 2, 0.5, and 0.1 mm, respectively. The increasing of the solution conductivity leads to the reduction of decolorization efficiency. A kinetic model is used to define the performance of corona discharge system. The models of pseudo-zero-order, pseudo-first-order, and pseudo-second-order reaction kinetics are utilized to investigate the decolorization of Acid Blue 25 dye. The rate of degradation of Acid Blue 25 dye follows the pseudo-first-order kinetics in the dye concentration.

36 MATERIALS SCIENCE↗

3D Source Reconstruction Using Coded Aperture Gamma-Ray Imaging

Recent measurements with coded-aperture imagers demonstrate material mass determination in a holdup setting to an accuracy within a few percent. This capability is of particular interest to the Surplus Plutonium Disposition (SPD) project, which aims to dilute and dispose of surplus plutonium oxide. Gamma-ray imagers can be used to determine holdup without interrupting normal operations. In this work, we examine techniques for 3D source localization and mass determination using gamma-ray imagers. Coded-aperture imagers provide excellent source localization within the 2D image plane; however, multiple imagers operating in tandem are necessary to identify source location in 3D space. A Maximum Likelihood Expectation-Maximization (MLEM) method for fitting detector mappings is a powerful tool for accomplishing this task. MLEM allows 3D source localization to be simultaneously constrained using multiple gamma-ray imagers by constructing the basis for the MLEM fit using detector mappings from different detector locations stitched together. Each of these basis points represents a singular response from a source in 3D space and is generated using Monte Carlo simulations of sources placed individually at different locations throughout the imager’s field of view. Additionally, implementing knowledge of the physical equipment in the simulations of the glovebox used for the SPD project incorporates attenuation effects that are needed to calculate material holdup.

Laminack, Alex↗

Phase-field simulations of fission gas bubbles in high burnup UO2 during steady-state and LOCA transient conditions

To improve the economics of commercial nuclear energy generation, U.S. utilities are currently seeking licensing approval to operate UO2 fuel to higher burnups. One significant safety issue that must be addressed to obtain approval is the potential for fine fragmentation/pulverization of the fuel during a loss-of-coolant accident (LOCA). It has been hypothesized this is caused by the rapid increase of pressure in fission gas bubbles in the high burnup region of the fuel. To better understand this phenomenon, a novel phase-field model of the fission gas bubble microstructure in UO2 has been developed and implemented in Idaho National Laboratory's Marmot application for phase-field simulation of nuclear materials. Simulations of bubble growth in the high burnup region during steady-state conditions showed that initially overpressurized bubbles decreased in pressure during growth, but still remained above equilibrium pressure. During a LOCA transient, simulations of bubbles in the high burnup region showed that bubble size did not change significantly, and the pressure increase due to the transient was calculated and passed to a phase-field model of fracture.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Graphite and ablative material response to CO2 laser, carbon-arc, and xenon-arc radiation

The behavior was investigated of graphite and several charring ablators in a variety of high-radiative heat-flux environments. A commercial-grade graphite and nine state-of-the-art charring ablators were subjected to various radiative environments produced by a CO2 laser and a carbon arc. Graphite was also tested in xenon-arc radiation. Heat-flux levels ranged from 10 to 47 MW/sq m. Tests were conducted in air, nitrogen, helium, and a CO2-N2 mixture which simulated the Venus atmosphere. The experimental results were compared with theoretical results obtained with a one-dimensional charring-ablator analysis and a two-dimensional subliming-ablator analysis. Neither the graphite nor the charring ablators showed significant differences in appearance or microstructure after testing in the different radiative environments. The performance of phenolic nylon and graphite was predicted satisfactorily with existing analyses and published material property data. Good agreement between experimental and analytical results was obtained by using sublimation parameters from a chemical nonequilibrium analysis of graphite sublimation. Some charring ablators performed reasonably well and could withstand radiative fluxes of the level encountered in certain planetary entries. Other materials showed excessive surface recession and/or large amounts of cracking and spalling, and appear to be unsuitable for severe radiative environments.

Brewer, W. D.↗