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At least 901 records · Page 50

Inducement of nanoscale Cu–BTC on nanocomposite of PPy–rGO and its performance in ammonia sensing

Highlights: • Formation of nanoscale Cu–BTC was induced on the PPy–rGO composite. • Cu–BTC/PPy–rGO nanocomposite exhibited high surface area and good stability. • Synergistic effect between PPy–rGO and Cu–BTC enhanced gas capture and detection. • Cu–BTC/PPy–rGO-based sensor exhibited excellent sensing performance for NH{sub 3}. - Abstract: In this study, polypyrrole-nanofiber-coated reduced graphene oxide (PPy–rGO) was decorated with nanoparticles of Cu–BTC [Cu{sub 3}(BTC){sub 2}(H{sub 2}O){sub 3}, where BTC is short for benzene-1,3,5-tricarboxylate], a typical metal–organic framework, via a hydrothermal process combined with in situ chemical polymerization. The Cu–BTC nanoparticles enabled gas capture because of their large surface area and high affinity for gases. PPy–rGO induced the formation of nanometer-sized Cu–BTC particles and provided a good platform for gas sensing because of the resulting decorated composite’s good electrical properties. The Cu–BTC/PPy–rGO nanocomposite exhibited good electrical-resistance response to NH{sub 3} at room temperature. Compared to the PPy–rGO thin film, the Cu–BTC/PPy–rGO thin film showed enhanced NH{sub 3}-sensing properties in the form of higher sensitivity and much faster response under the same conditions. The selectivity and stability of the NH{sub 3} sensor based on the Cu–BTC/PPy–rGO nanocomposite were also investigated.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

A Study of the Adequacy of Quasi-geostrophic Dynamics for Modeling the Effect of Frontal Cyclones on the Larger Scale Flow

The major objectives of this study are to test the validity of quasi-geostrophic (QG) dynamics, compared to primitive equation (PE) dynamics for modeling the effect of cyclone waves on the larger scale flow, and to study the formation of frontal cyclones and the dynamics of occluded frontogenesis. In order to extend the realism of the initial conditions over those used in earlier work of this nature and in order to include strong surface frontal zones in the initial conditions, a horizontal resolution on the order of 100 km between gridpoints is needed. In order to allow for integrations of up to two weeks simulated time and to keep the logistics and cost of the runs feasible, the horizontal domain of the models must be reduced. Based on work concerning polar lows, the tropospheric static stability was reduced and was also allowed to vary in different tropospheric layers. Previous work used a 'standard atmosphere' temperature lapse rate. Stratospheric stability remains unchanged. The use of one of these 'reduced stability' cases, with no surface frontal zone present resulted in the discovery of normal mode perturbations.

Mudrick, S.↗

Concept for Hydrogen-Impregnated Nanofiber/Photovoltaic Cargo Stowage System

A stowage system was conceived that consists of collapsible, reconfigurable stowage bags, rigid polyethylene or metal inserts, stainless-steel hooks, flexible photovoltaic materials, and webbing curtains that provide power generation, thermal stabilization, impact resistance, work/sleeping surfaces, and radiation protection to spaceflight hardware and crew members. Providing materials to the Lunar surface is costly from both a mass and a volume standpoint. Most of the materials that will be transferred to other planets or celestial bodies will not be returned to the Earth. In developing a plan to reconfigure pressurized logistics modules, it was determined that there was a requirement to be able to utilize the interior volume of these modules and transform them from Logistics Modules to Storage/Living Quarters. Logistics-to-living must re-utilize stowage bags and the structures that support them to construct living spaces, partitions, furniture, protective shelters from solar particle events, galactic cosmic radiation, and workspaces. In addition to reusing these logistics items for development of the interior living spaces, these items could also be reused outside the habitable volumes to build berms that protect assets from secondary blast ejecta, to define pathways, to stabilize high traffic areas, to protect against dust contamination, to secure assets to mobility elements, to provide thermal protection, and to create other types of protective shelters for surface experiments. Unique features of this innovation include hydrogen-impregnated nano fibers encapsulated in a polyethelyne coating that act as radiation shielding, flexible solar collection cells that can be connected together with cells from other bags via the webbing walls to create a solar array, and the ability to reconfigure each bag to satisfy multiple needs.

Kennedy, Kriss J.↗

A study of a collision avoidance system mounted on a curved ground plane

Research conducted on a traffic advisory and collision avoidance system (TCAS 2) mounted on a curved ground plane is described. It is found that a curved finite ground plane can be used as a good simulation model for the fuselage of an aircraft but may not be good enough to model a whole aircraft due to the shadowing of the vertical stabilizer, wings, etc. The surface curvature of this curved disc significantly affects the monopulse characteristics in the azimuth plane but not as much in the elevation plane. These variations of the monopulse characteristics verify the need of a lookup table for the 64 azimuth beam positions. The best location of a TCAS 2 array on a Boeing 737 is to move it as far from the vertical stabilizer as possible.

Law, P. H.↗

On-Demand Designing of Cathode Internal Surface Architecture for Dramatic Enhancement of SOFC Performance and Durability

This project is aimed to design and modify the internal surfaces of porous composite cathode from currently commercially viable Solid Oxide Fuel Cells (SOFCs), using additive manufacturing process of Atomic Layer Deposition (ALD). The material systems being investigated are commercial composite electrodes complex three-dimensional topographies. In term of the chemistry of the ALD layer applied on the internal surface of the porous cathode, this project has employed commercially relevant electrolyte, electrocatalyst and noble metal materials set. Such materials are fully compatible with the commercial fuel cells, and this project has developed special nanostructure on the surface of the commercial composite cathodes. The formation of the designed nanoarchitecture on the surface of SOFC cathode has been achieved through precise control of ALD parameters and their effect on overall cell performance and resultant electrochemical reaction mechanism of cathodes has been investigated through full cell electrochemical performance testing and nanostructure characterization by transmission electron microscopy (TEM). Under the support of this award, following has been achieved: (1). For cathode materials in solid oxide fuel cells (SOFCs), such as perovskite mixed conductor La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-x (LSCF), cation surface segregation and consequently losing conductivity and active sites for the oxygen reduction reaction (ORR) are problematic. To mitigate the cation segregation and enhance SOFC durability, further decorating the internal backbone surface using the desired electrocatalysts could be a promoting approach. Commonly, the cation segregation such as Sr is very volatile, so the effective surface decoration is ideally conformal. Nevertheless, the conformal surface coating would inevitably alter the ORR pathways that initially take place on the surface of the backbone. To reveal the impact of the conformal coating on both the catalytic activity and the conductivity of the cathode, the unary electrocatalyst of Pt or CoO x , was applied to the LSCF/SDC composite electrode of inherently functional SOFCs, respectively. Both ALD coating layers evolve strong interaction with the LSCF composite cathode. Upon operations, the Pt coating layer remains conformal on LSCF grain surfaces but turns into discrete particles on SDC grain surfaces. Meanwhile, CoO x conformal coating grows to be the discrete nanograins on both the LSCF and SDC grains. ALD coating of the cathode alone reduces the ohmic resistance up to 28 % for the entire cells. The increased conductivity induced by the ALD coating of Pt or CoO x is ascribed to different mechanisms. For the inherent functional SOFCs, the present study presents a novel and feasible approach to apply a conformal, dense coating layer on the surface of a mixed conductor, simultaneously increasing the conductivity and durability of the SOFC cathode. (2). High resistance of the oxygen electrode still significantly hinders the state-of-the-art Solid Oxide Fuel Cells (SOFCs). In particular, for an oxygen electrode consisting of mixed electronic and ionic conductors, such as perovskite lanthanum strontium cobalt ferrite (LSCF), it deteriorates due to its low chemical stability of the grain surface. Such degradation is often associated with the segregation of cations. To prevent the cation surface segregation and its resultant perovskite phase decomposition, we demonstrate a conformal ultra-thin (7-10 nm) surface heterogeneous coating layer consisting of subjacent discrete Pt nanoparticles capped with a superjacent fully dense conformal CoO x layer. The performance studies indicate the ALD coating reduces the cell series resistance by up to 40 %. The conformal CoO x layer consists of randomly orientated but single-layered nanograins, with high-density intergranular and surface grain boundaries serving as the electrochemical reaction sites and facilitating mass transport. The conformal coating layer appears to have successfully suppressed the Sr outward diffusion and confined the Sr enriched layer to a ~ 2 nm interface perovskite phase between the coating layer and the LSCF grain surface. Moreover, this ultra-thin Sr enriched perovskite layer presumably possesses high oxygen vacancy and high ionic conductivity and further imposes tensile strain to the LSCF grain surfaces. With the combination of a conformal CoO x nanoionics, Sr enriched layer, and its strained interface, the ALD coating induced surface layer is estimated to have a conductivity of ~ 1.27x10 4 S/cm, which is over two orders magnitude of that from LSCF at 750 ºC.

30 DIRECT ENERGY CONVERSION↗

Influence of ocean surface conditions on atmospheric vertical thermodynamic structure and deep convection

The authors analyze the influence of Sea Surface Temperature (SST) and surface wind divergence on atmospheric thermodynamic structure and the resulting effects on the occurrence of deep convection using National Meteorological Center radiosonde data and International Satellite Cloud Climatology Program data for July 1983-July 1985. The onset of deep convection requires not only the existence of positive convective available potential energy (CAPE), but also an unstable planetary boundary layer (PBL). A stable PBL is observed to suppress deep convection even when CAPE is positive. Variations of SST have a major effect on CAPE, but surface wind divergence can also affect deep convection by changing the lapse rate in the lower troposphere and humidity in the PBL. Specifically, when SST is greater than or equal to 28 C, CAPE is always positive, and surface wind divergence does not qualitatively change the buoyancy profile above the PBL. Strong surface wind divergence, however, stabilizes the PBL so as to suppress the initiation of deep convection. In warm SST regions, CAPE is greater than 0 regardless of assumptions about condensate loading, although the pseudoadiabatic limit is more consistent with the observed deep convection than the reversible moist-adiabatic limit under these circumstances. When SST is less than 27 C, CAPE is usually negative and inhibits convection, but strong surface wind convergence can destabilize the inversion layer and moisten the PBL enough to make the atmosphere neutrally stable in the mean. As a result, deep convection is generally enhanced either when SST is greater than or equal to 28 C in the absence of strong surface wind divergence or when strong surface wind convergence occurs even if SST is less than 27 C. The anomalous suppression of deep convection in the warm area of the equatorial west Pacific lying between the intertropical convergence zone (ITCZ) and south Pacific convergence zone (SPCZ) is probably caused by dryness in the PBL and an inversion in that area. The seasonal cycles of deep convection and surface wind divergence are in phase with the maximum solar radiation and lead SST for one to three months in the central Pacific. The change of PBL relative humidity plays a critical role in the changeover to convective instability in this case. The seasonal change of deep convection and associated clouds seems not to have important effects on the seasonal change of local SST in the central Pacific.

Fu, Rong↗

Hybrid Mesoporous Carbon/Copper Ferrite Electrode for Asymmetric Supercapacitors

Asymmetric supercapacitors (ASCs) with two dissimilar electrodes are known to exhibit relatively moderate energy and power densities. If electrodes derived from earth-abundant materials or renewable resources such as lignocellulosic biomass (LCB) are used for fabrication, energy storage systems are expected to become less expensive and more sustainable. Hybrid electrode materials have advantages such as higher surface area, better chemical stability, and superior energy density. This study reports on the synthesis of a novel hybrid electrode material containing porous carbon (POC) and copper ferrite, which is designated as POC@Cu-ferrite, and its electrochemical performance in ASC configuration. Corn stover derived hydrochar is utilized for the sol–gel synthesis of POC@Cu-ferrite hybrid material using earth-abundant Cu and Fe-based precursors. This material is characterized using X-ray diffraction (XRD), Raman spectroscopy, Brunauer–Emmett–Teller (BET) surface area analyzer, and scanning and transmission electron microscopy (SEM/TEM). As-synthesized Cu-ferrite is found to contain 89.2% CuFe 2 O 4 and 10.8% Fe 2 O 3 , whereas other phases such as Fe 3 O 4 , CuFeO 2 , and CuO are observed for the POC@Cu-ferrite. BET-specific surface area (SSA) and pore volume of POC@Cu-ferrite are observed as 1068 m 2 /g and 0.72 cm 3 /g, respectively. POC@Cu-ferrite hybrid electrode is used with POC opposite electrode to fabricate ASC, which is tested using Gamry G-300 potentiostat/galvanostat/ZRA to obtain cyclic voltammetry (CV) profiles and galvanostatic charge–discharge (GCD) plots. ASC is also prepared using Cu-ferrite and POC materials and its specific capacitance and stability are compared with ASCs prepared with POC@Cu-ferrite and POC or graphene nanoplatelets (GNPs) electrodes. POC@Cu-ferrite hybrid electrode is found to be superior with a 2-fold higher capacitance and significant electrochemical stability over 100 GCD cycles as compared to the Cu-ferrite electrode.

36 MATERIALS SCIENCE↗

Machine‐Learning‐Driven Exploration of Surface Reconstructions of Reduced Rutile TiO 2

Abstract Titanium dioxide (TiO 2 ) is widely used as a catalyst support due to its stability, tunable electronic properties, and surface oxygen vacancies, which are crucial for catalytic processes such as the reverse water‐gas shift (RWGS) reaction. Reduced TiO 2 surfaces undergo complex surface reconstructions that endow unique properties but are computationally challenging to describe. In this study, we utilize machine‐learning interatomic potentials (MLIPs) integrated with an active‐learning workflow to efficiently explore reduced rutile TiO 2 surfaces. This approach enabled the prediction of a phase diagram as a function of oxygen chemical potential, revealing a variety of reconstructed phases, including a previously unreported subsurface shear plane structure. We further investigate the electronic properties of these surfaces and validate our results by comparing experimental and theoretical high‐resolution transmission electron microscopy (HRTEM). Our findings provide new insights into how extreme surface reductions influence the structural and electronic properties of TiO 2 , with potential implications for catalyst design.

Lee, Yonghyuk [Chemistry and Biochemistry Universi↗

Photometric evidence on long-term stability of albedo and colour markings on Io

Photometric measurements of the color and albedo of Io during the last 50 years are examined in order to determine the stability of the Ionian surface. Brightness measurements of Io relative to Ganymede show a slight, however inconclusive, increase with time, while light curve amplitudes and shapes are found to agree well during this period. The extent of volcanic activity observed by Voyager 1, however, is shown to be undetectable with the precision attainable by earth-based albedo determinations, and just barely detectable as color changes, which explains the observed photometric stability. Possible mechanisms for the preservation of the observed longitudinal distribution of color on Io are also discussed.

Morrison, D.↗

Estimation of the average exchanges in momentum and latent heat between the atmosphere and the oceans with Seasat observations

Ocean-surface momentum flux and latent heat flux are determined from Seasat-A data from 1978 and compared with ship observations. Momentum flux was measured using the Seasat-A scatterometer system (SASS) heat flux, with the scanning multichannel MW radiometer (SMMR). Ship measurements were quality selected and averaged to increase their reliability. The fluxes were computed using a bulk parameterization technique. It is found that although SASS effectively measures momentum flux, variations in atmospheric stability and sea-surface temperature cause deviations which are not accounted for by the present data-processing algorithm. The SMMR-latent-heat-flux algorithm, while needing refinement, is shown to given estimations to within 35 W/sq m in its present form, which removes systematic error and uses an empirically determined transfer coefficient.

Liu, W. T.↗

Experimental Investigation of the Effect of Vertical-tail Size and Length and of Fuselage Shape and Length on the Static Lateral Stability Characteristics of a Model with 45 Degree Sweptback Wing and Tail Surfaces

An investigation was made to determine the effects of vertical-tail size and length and of fuselage shape and length on the static lateral stability characteristics of a model with wing and vertical tails having the quarter-chord lines swept back 45 degrees. The results indicate that the directional instability of the various isolated fuselages was about two-thirds as large as that predicted by classical theory.

Queijo, M J↗

Enhanced Performance of Silicon Anodes through Hybrid Surface Engineering

Silicon (Si) is a promising anode material for nextgeneration lithium-ion batteries (LIBs) due to its high theoretical capacity. However, Si-containing anodes typically suffer from unacceptably short lives because of the unrestricted growth of the solid electrolyte interphase (SEI). Here, in this study, hybrid surface coatings are developed to stabilize the SEI in high loading pure Si anodes using atomic and molecular layer deposition. The coatings, consisting of LiF paired with lithicone, create an ionically conductive surface that enhances the capacity retention, rate performance, and longevity. Careful binder selection helps demonstrate the full utility of the coatings by enabling high loading electrodes to cycle continuously at current densities of 1200 mA/g Si . Uncoated controls, in comparison, fail within just 10 cycles at lower loadings. X-ray photoelectron spectroscopy and electrochemical impedance spectroscopy are used to provide supporting evidence of the coating composition and efficacy. The data indicate that our lithicone coating is converted to Li 2 CO 3 upon cycling contributing to favorable LiF/Li 2 CO 3 interfaces that enhance the space-charge effect at the active material’s surface. When applied to electrodes made with thermally stable binders and increasingly higher loadings (approaching 5 mAh/cm 2 ), ion transport through the bulk electrode, rather than SEI growth, is shown to be the limiting factor. Furthermore, data suggests a favorable interaction between lithicone precursors and poly(acrylic acid) binders mitigates thermal decomposition at higher temperatures. The work presented here represents the successful realization of composite coatings containing LiF/Li 2 CO 3 components to stabilize high-loading Si anodes. This work helps inform advanced surface engineering strategies to achieve highly reversible, high-capacity Si anodes capable of fast charging for high-performance LIBs.

atomic layer deposition↗

Morphology, Modification and Characterisation of Electrospun Polymer Nanofiber Adsorbent Material Used in Metal Ion Removal

Among a wide range of technologies available to separate metal ions, adsorption is a major treatment technique for removing or recovering metals from aqueous solutions. Electrospun nanofiber adsorbents have attracted research consideration due to the distinctive properties such as their high surface area, high porosity and high adsorption capacity which makes nanofibers a good choice for selective metal recovery applications. Thus, the modification of electrospun nanofiber adsorbents by functionalisation with suitable ligands for selective metal extraction is a growing area of scientific research aiming to improve the selectivity of the adsorption process. This study reviews and summarises available information related to the different nanofiber modification processes for increasing adsorption efficiency, functionality and selectivity of modified nanofiber adsorbents as well as improving their durability and stability during use. The surface properties of an adsorbent is an essential control factor for its metal ion adsorption efficiency. The various techniques available for characterisation of specific properties of nanofiber adsorbents are also considered. Lastly, the recovery of the metal ions after adsorption by regenerating adsorbent materials and understanding the kinetics of nanofiber adsorption processes is summarised and recommendations made for further studies in order to address existing weaknesses of these materials.

36 MATERIALS SCIENCE↗

Casein from Bovine Milk as a Binder for Silicon Based Electrodes

Silicon is a promising anode material for lithium ion batteries due to the high theoretical capacity (∼3600mAh/g). However, silicon-based electrodes face rapid degradation due to the extensive volume variation (∼300%) during the lithiation/delithiation process. Binders used in the electrode fabrication play a crucial role for silicon electrodes since it can reduce the mechanical fracture during the cycling process. Recent investigations suggest that in addition to the importance of the mechanical properties of the binder, the chemical reactions between the binder and the surface of the silicon particles also contribute to stabilization. Further investigations suggest that functionalized small molecules can also modify the surface of silicon particles and stabilize cycling. An inexpensive, environmentally friendly alternative has been investigated as a binder for silicon electrodes. Casein is a milk protein found in bovine milk rich in amine groups and carboxylic acid groups which can form bonds with the silanol groups in silicon. A comparative study conducted between PVDF and Casein as binders have shown that when casein was used as binder, it shows better performance compared to PVDF. Surface morphology and solid electrolyte interphase (SEI) was analyzed using electron microscopy techniques and spectroscopic methods and the results will be discussed.

36 MATERIALS SCIENCE↗

Phase Separation, Capillarity, and Odd-Surface Flows in Chiral Active Matter

Active phase separations evade canonical thermodynamic descriptions and have thus challenged our understanding of coexistence and interfacial phenomena. Considerable progress has been made towards a nonequilibrium theoretical description of these traditionally thermodynamic concepts. Spatial parity symmetry is conspicuously assumed in much of this progress, despite the ubiquity of chirality in experimentally realized systems. Here, in this Letter, we derive a theory for the phase coexistence and interfacial fluctuations of a system that microscopically violates spatial parity. We find suppression of the phase separation as chirality is increased as well as the development of steady-state currents tangential to the interface dividing the phases. These odd flows are irrelevant to stationary interfacial properties, with stability, capillary fluctuations, and surface area minimization determined entirely by the capillary surface tension. Using large-scale Brownian dynamics simulations, we find excellent agreement with our theoretical scaling predictions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Current Methods for Modeling and Simulating Icing Effects on Aircraft Performance, Stability and Control

Icing alters the shape and surface characteristics of aircraft components, which results in altered aerodynamic forces and moments caused by air flow over those iced components. The typical effects of icing are increased drag, reduced stall angle of attack, and reduced maximum lift. In addition to the performance changes, icing can also affect control surface effectiveness, hinge moments, and damping. These effects result in altered aircraft stability and control and flying qualities. Over the past 80 years, methods have been developed to understand how icing affects performance, stability and control. Emphasis has been on wind tunnel testing of two-dimensional subscale airfoils with various ice shapes to understand their effect on the flow field and ultimately the aerodynamics. This research has led to wind tunnel testing of subscale complete aircraft models to identify the integrated effects of icing on the aircraft system in terms of performance, stability, and control. Data sets of this nature enable pilot in the loop simulations to be performed for pilot training, or engineering evaluation of system failure impacts or control system design.

Ralvasky, Thomas P.↗

Upgrading the Performance and Stability of Lithium, Manganese-Rich Layered Oxide Cathodes with Combined-Formic Acid and Spinel Coating Treatment

We report improving sluggish rate performance and cycling stability of Li, Mn-rich cathode materials (LMR) is of great importance for practical implementation. Here, dual surface modification on LMR particles with formic acid washing and spinel coating improves the electrochemical performance. Dilute formic acid can remove the Li2CO3 surface impurities and selectively reduce Ni while significantly increasing specific surface area by ~32 %, unlocking more electrochemically active surfaces. Spinel coating enhances cycle stability by suppressing detrimental side reactions at electrode-electrolyte interfaces at high voltage. Post-annealing temperature was found to significantly affect the cathode performance. Higher temperature favors diffusion of transition metal (TM)/Li ions of the spinel coating from surface to the bulk, removing the coating by possible reconstruction into the layered structure and thus degrading the performance. The spinel coating also appears to increase Co 3+ segregation on the particle surface. Compared to the original material, the optimized sample demonstrates 47 % higher capacity retention at 3C and retains 89 % of initial capacity after 150 cycles at 0.5C. Besides, the specific energy density of 523 Wh kg -1 can be attained after 150 cycles at 0.5C. Moreover, the post-cycling analysis of modified sample verifies a better structural integrity with less particle cracking. Altogether, this study portrays an alternative strategy to overcome the shortcomings of LMR cathode materials.

25 ENERGY STORAGE↗

Performance of textured carbon on copper electrode multistage depressed collectors with medium-power traveling wave tubes

Performance of multistage depressed collectors (MDCs) using textured carbon on copper substrate electrode surfaces was evaluated in conjunction with medium-power traveling wave tubes (TWTs). The MDC and TWT overall efficiencies for these electrodes were measured and compared with those obtained with the same TWT and a copper electrode MDC of identical design. Long-term stability of the carbon-coated copper electrode surfaces was investigated by periodic evaluation of TWT-MDC performance over an extended period of continuous wave (CW) operation. Application of textured carbon coating on copper MDC electrode surfaces produced a 13% improvement in both MDC and TWT overall efficiencies for the TWT-MDC tests. During 1600 hr of CW operation with a medium power TWT, no significant changes in MDC performance were noted. This indicated good stability of the textured carbon electrode surfaces. This stability was confirmed by scanning electron microscope examinations of the electrode surfaces before assembly of the MDC and after completion of the test program.

Ramins, Peter↗