Search NASA⌕ Search

SEARCH · Search NASA

Results for “ALTERNATE REDUCTANT”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 919 records · Page 51

A path to higher Q0 with large grain niobium cavities

The improvement of the quality factor Q{sub 0} of superconducting radio-frequency (SRF) cavities at medium accelerating gradients ({approx} 20 MV/m) is important in order to reduce the cryogenic losses in continuous wave accelerators for a variety of applications. In recent years, SRF cavities fabricated from ingot niobium have become a viable alternative to standard high-purity fine-grain Nb for the fabrication of high-performing SRF cavities with the possibility of significant cost reduction. Initial studies demonstrated the improvement of Q{sub 0} at medium field in cavities heat treated at 800-1000 C without subsequent chemical etching. To further explore this treatment procedure, a new induction furnace with an all-niobium hot-zone was commissioned. A single-cell 1.5 GHz cavity fabricated from ingot material from CBMM, Brazil, with RRR {approx} 200, was heat treated with the new furnace in the temperature range 600-1200 C for several hours. Residual resistance values 1-5 nano-ohm have been consistently achieved on this cavity as well as Q{sub 0} values above {approx} 2 x 10{sup 11} at 2 K and 100 mT peak surface magnetic field. Q{sub 0}-values of the order of 10{sup 11} have been measured at 1.5 K.

43 PARTICLE ACCELERATORS↗

Nuclear Liquid Wastes Calcination: The High-Level French Experience - 17184

Calcination is an efficient process for volume reduction and stabilization of nuclear liquid wastes. It is often the first step of waste containment processes such as vitrification or grouting. The CEA (French Alternative Energies and Atomic Energy Commission) and AREVA have acquired a high-level experience in the field of calcination through more than forty years of R and D and industrial operation. During this period, a broad range of liquid wastes have been studied and treated. R and D work and associated engineering studies allowed defining the design and sizing of the equipment and the process control parameters to be applied for the calcination of all kinds of solutions. The calcination process has been qualified for the following effluents amongst others: - Liquid waste from UOx fuel reprocessing; - Liquid waste from UMo fuel reprocessing (high molybdenum and phosphorus contents); - Hanford HLW; - Liquid waste from D and D operation (sodium bearing waste). This paper presents several studies led by the Joint Vitrification Laboratory (L.C.V), a common research laboratory between CEA and AREVA in charge of qualifying new processes and matrices for waste containment. These studies allowed defining the calcination rules, in particular for very hard to process solutions such as effluents with high boron, molybdenum and sodium contents. The feedback from industrial operation of the calcination process with fission products and effluents from D and D operations, highly loaded with sodium, is also presented. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Non-lethal heat treatment of cells results in reduction of tumor initiation and metastatic potential

Non-lethal hyperthermia is used clinically as adjuvant treatment to radiation, with mixed results. Denaturation of protein during hyperthermia treatment is expected to synergize with radiation damage to cause cell cycle arrest and apoptosis. Alternatively, hyperthermia is known to cause tissue level changes in blood flow, increasing the oxygenation and radiosensitivity of often hypoxic tumors. In this study, we elucidate a third possibility, that hyperthermia alters cellular adhesion and mechanotransduction, with particular impact on the cancer stem cell population. We demonstrate that cell heating results in a robust but temporary loss of cancer cell aggressiveness and metastatic potential in mouse models. In vitro, this heating results in a temporary loss in cell mobility, adhesion, and proliferation. Our hypothesis is that the loss of cellular adhesion results in suppression of cancer stem cells and loss of tumor virulence and metastatic potential. Our study suggests that the metastatic potential of cancer is particularly reduced by the effects of heat on cellular adhesion and mechanotransduction. If true, this could help explain both the successes and failures of clinical hyperthermia, and suggest ways to target treatments to those who would most benefit. - Highlights: • Non-lethal hyperthermia treatment of cancer cells is shown to cause a reduction in rates of tumor initiation and metastasis. • Dynamic imaging of cells during heat treatment shows temporary changes in cell shape, cell migration, and cell proliferation. • Loss of adhesion may lead to the observed effect, which may disproportionately impact the tumor initiating cell fraction. • Loss or suppression of the tumor initiating cell fraction results in the observed loss of metastatic potential in vivo. • This result may lead to new approaches to synergizing hyperthermia with surgery, radiation, and chemotherapy.

60 APPLIED LIFE SCIENCES↗

Formate dependent heterodisulfide reduction in a Methanomicrobiales archaeon

Hydrogenotrophic methanogens produce CH 4 using H 2 as an electron donor to reduce CO 2 . In the absence of H 2 , many are able to use formate or alcohols as alternate electron donors. Methanogens from the order Methanomicrobiales are capable of growth with H 2 , but many lack genes encoding hydrogenases that are typically found in other hydrogenotrophic methanogens. In an effort to better understand electron flow in methanogens from the Methanomicrobiales, we undertook a genetic and biochemical study of heterodisulfide reductase (Hdr) in Methanoculleus thermophilus. Hdr catalyzes an essential reaction by coupling the first and last steps of methanogenesis through flavin-based electron bifurcation. Hdr from M. thermophilus co-purified with formate dehydrogenase (Fdh) and only displayed activity when formate was supplied as an electron donor. We found no evidence of an Hdr associated hydrogenase, and H 2 could not function as an electron donor, even with Hdr purified from cells grown on H 2 . Here, we found that cells catalyze a formate hydrogenlyase activity that is likely essential for generating the formate needed for the Hdr reaction. Together, these results highlight the importance of formate as an electron donor for methanogenesis and suggest the ability to use formate is closely integrated into the methanogenic pathway in organisms from the order Methanomicrobiales.

59 BASIC BIOLOGICAL SCIENCES↗

Transmission and Alternatives Analysis and Strategic Stakeholder Engagement

Over the life of this 3-year agreement NREL has developed data, tools, and analyses for utilities to integrate high levels of solar, and demonstrated reliability results to produce a reduction in cost and lower overall risk for stakeholders. There were five projects that made up the Agreement 25805 portfolio, including: 1. Phase 3 of the Western Wind and Solar Integration Study which studied WECC large-scale stability and frequency response. 2. Transient Solar Model Development which developed a generic solar model for cycle-by-cycle analysis. 3. Utility Scale PV Plant Demo which demonstrated control capability on a demo plant. 4. Targeted Transmission Support which contributed to transmission planning with reinforcements 5. Strategic Stakeholder Engagement which communicated and disseminated latest research with utility and industry stakeholders so that discussions and decision-making can be informed by the most current and reliable information available.

14 SOLAR ENERGY↗

Evaluating alternative refrigerants for high ambient temperature environments

According to the Montreal Protocol, developing countries have started the phase out schedule of the ozone depleting substances, including HCFC refrigerants, in 2015 and expect them to reach 35% reduction in 2020. This commitment to the start the phase out of HCFC refrigerants, especially R-22, in developing countries is seen as an opportunity to introduce lower Global Warming Potential (GWP) refrigerants. Furthermore, this paper summarizes an investigation into the performance of lower GWP refrigerants in high ambient temperature environments, experienced in some of the developed countries, in mini-split air conditioning units.

54 ENVIRONMENTAL SCIENCES↗

Technical Note: On the use of nudging for aerosol–climate model intercomparison studies

Nudging as an assimilation technique has seen increased use in recent years in the development and evaluation of climate models. Constraining the simulated wind and temperature fields using global weather reanalysis facilitates more straightforward comparison between simulation and observation, and reduces uncertainties associated with natural variabilities of the large-scale circulation. On the other hand, the forcing introduced by nudging can be strong enough to change the basic characteristics of the model climate. In the paper we show that for the Community Atmosphere Model version 5 (CAM5), due to the systematic temperature bias in the standard model and the sensitivity of simulated ice formation to anthropogenic aerosol concentration, nudging towards reanalysis results in substantial reductions in the ice cloud amount and the impact of anthropogenic aerosols on long-wave cloud forcing. In order to reduce discrepancies between the nudged and unconstrained simulations, and meanwhile take the advantages of nudging, two alternative experimentation methods are evaluated. The first one constrains only the horizontal winds. The second method nudges both winds and temperature, but replaces the long-term climatology of the reanalysis by that of the model. Results show that both methods lead to substantially improved agreement with the free-running model in terms of the top-of-atmosphere radiation budget and cloud ice amount. The wind-only nudging is more convenient to apply, and provides higher correlations of the wind fields, geopotential height and specific humidity between simulation and reanalysis. Results from both CAM5 and a second aerosol–climate model ECHAM6-HAM2 also indicate that compared to the wind-and-temperature nudging, constraining only winds leads to better agreement with the free-running model in terms of the estimated shortwave cloud forcing and the simulated convective activities. This suggests nudging the horizontal winds but not temperature is a good strategy for the investigation of aerosol indirect effects since it provides well-constrained meteorology without strongly perturbing the model's mean climate.

Zhang, K.↗

Analysis of Historical International Space Station Logistical Mass Delivery

Crewed space exploration missions are extremely logistics dependent, as cargo requirements shape numerous program elements such as vehicle and habitat size. Logistics mass is the mass of items like food and clothing that are not a part of the vehicle or habitat, yet are required by the crew to complete the mission. Numerous studies, such as the Human Exploration Research Analog (HERA) and the Human Exploration Spacecraft Testbed for Integration and Advancement (HESTIA) 20-foot chamber analog, have been conceived to research the rates at which crews consume logistics mass. These analogs can simulate many aspects of life in space, including confinement, isolation, limited supplies, and, in certain experiments, the habitat pressure. However, some aspects of space exploration, such as the effects of low gravity and the use of space-based amenities, cannot currently be tested on the ground. In this paper, International Space Station (ISS) manifest data obtained through the National Aeronautics and Space Administration’s (NASA’s) Mission Integration Database Application System (MIDAS) portal is used as a precursor to space-based analogs. The objective of the analysis is determining the breakdown of logistics mass used in space exploration. This identifies potential areas of improvement and highlights the rates at which significant items are supplied, aiding in the weighing of alternative options such as utilizing in space manufacturing for supplies vs. manifesting spares, or cleaning clothing in flight vs. discarding it. Official flight manifests ranging a span of 878 days, just short of the three-year length of a potential human mission to Mars, were analyzed to find the rates at which astronauts consumed various logistics supplies. From this analysis we have found that contrary to our own hypothesis, ‘food’ was not the largest portion of the supplied mass. Instead, ‘Environmental Control and Life Support Systems’ (ECLSS) contributed 34% of the overall supplied mass, followed by ‘Science and Outfitting,’ which contributed 29%. Food totaled less than a quarter (21% of the resupplied mass, while other items of focus in mass reduction efforts such as ‘Hygiene’ (6%), ‘Clothing’ (3%), and ‘Operational Supplies’ (4%) each contributed less than a tenth of the supplied mass. This data suggests that by categorizing and analyzing the data based on an alternative taxonomy and analyzing the full supply manifests rather than handpicked items, we have revealed unexpectedly significant items which had not been previously tracked by exploration logistics efforts. For example, toilet hardware made up 4% of ECLSS mass, and laptop hardware and multi-tools each made up 10% of operational supplies mass. Additionally, the ‘Specialized Clothing’ subcategory containing fire protective equipment, coveralls, and penguin suits made up 15% of the overall clothing mass. By identifying these newly found significant items, we can create more realistic mass estimates for exploration missions and direct mass reduction efforts to new areas, potentially leading to lower future mission masses.

Logistics↗

Rare‐Earth Reduction in High‐Speed PM‐Assisted Synchronous Reluctance Motors Using Hybrid Magnet Strategies and Design Optimisation for 800 V EVs

The trend towards electrifying transportation systems has stimulated research endeavours aimed at developing electric machines that are not only high speed and efficient but also low‐cost and compact. To support this transition, the US Department of Energy (DOE) has established ambitious targets of $7/kW cost and 12 kW/L power density for the electric drivetrains. This paper attempts to meet these targets by proposing high‐speed permanent magnet assisted synchronous reluctance machine (PMASynRM) topologies enabled by hybrid magnet strategies, combining rare‐earth (RE) magnets with low‐cost, RE‐free alternatives. Modified 2‐layer and 3‐layer U‐shaped rotor configurations, featuring structural reinforcements to withstand high mechanical stress at elevated speeds, are developed. A multi‐objective design optimisation framework is employed to optimise the rotor design, targeting reductions in RE magnet volume, magnet demagnetisation risk and torque ripple while achieving the desired electromagnetic performance. A comprehensive analysis of the optimised rotor designs, compared against a 16,000 rpm, 800 V baseline IPM motor, shows over 70% RE reduction, demagnetisation risk below 3.5% and torque ripple under 10%. Detailed analyses of performance trends across various magnet combinations and rotor configurations highlight the viability of hybrid magnet PMASynRM designs as cost‐effective, robust and energy‐efficient solutions for next‐generation EVs.

33 ADVANCED PROPULSION SYSTEMS↗

Application of Machine Learning Techniques in Calibration and Data Reduction of Multi-Hole Probes

This work presents procedures for implementing machine learning methods into existing algorithms for multi-hole probe calibration and data reduction. It demonstrates that using artificial neural networks (ANNs) can decrease the amount of calibration data needed to achieve a specific calibration uncertainty by over 50%, while also significantly reducing data reduction times. Instead of surface fitting methods, ANNs are employed. Initially, directional calibration coefficients related to flow angles are computed based on pressure measurements, and then these flow angles serve as input parameters for subsequent ANNs to iteratively define Mach number, static pressure, and total pressure. In an alternative approach, new calibration coefficients directly relate pressure measurements from the five-hole probe to the quantities of interest, thereby eliminating the need for iterative algorithms used in conventional surface fitting methods. This method offers several advantages: an average increase of less than 1%in calibration uncertainty for flow angles and a significant reduction in data reduction times to a few seconds on average. Additionally, the methodology is confirmed to avoid both over- and under-fitting.

Machine Learning↗

Desalination of Impaired Water Using Geothermal Energy

Membrane distillation (MD) and nanofiltration (NF) are explored as a means to provide high quality water for on-site use at the Tuscarora geothermal power plant in northern Nevada. The plant uses a wet cooling tower, but decreasing flow from the wells providing makeup water necessitates exploration for alternative water or alternative cooling sources. Scenarios are explored to extend cooling water by (1) extracting fresh water from the geothermal brine, (2) upgrading the makeup-water quality to allow for increased cycles of concentration in the cooling tower, or (3) recovering water from the cooling tower blowdown. The preliminary cost analysis indicates that applying NF to extract water from the injection brine is the most attractive option of the scenarios examined. This approach may be useful for other plants as well. The estimated cost for the NF treatment of the injection brine ranges from $0.63/m3 to $0.45/m3 and provides a reduction in the current makeup well flows of 35% to 71%. Savings from the reduction in makeup well pumping and chemical treatment do not fully offset the estimated cost of the proposed treatment systems; the site will have to weigh the cost of these water treatment options versus alternatives in light of the diminishing flows from the existing cooling-water wells. Testing is planned to quantify the performance of the proposed NF and MD technologies and help refine the estimated system costs.

15 GEOTHERMAL ENERGY↗

Model Order Reduction Algorithm for Estimating the Absorption Spectrum

The ab initio description of the spectral interior of the absorption spectrum poses both a theoretical and computational challenge for modern electronic structure theory. Due to the often spectrally dense character of this domain in the quantum propagator’s eigenspectrum for medium-to-large sized systems, traditional approaches based on the partial diagonalization of the propagator often encounter oscillatory and stagnating convergence. Electronic structure methods which solve the molecular response problem through the solution of spectrally shifted linear systems, such as the complex polarization propagator, offer an alternative approach which is agnostic to the underlying spectral density or domain location. This generality comes at a seemingly high computational cost associated with solving a large linear system for each spectral shift in some discretization of the spectral domain of interest. In this work, we present a novel, adaptive solution to this high computational overhead based on model order reduction techniques via interpolation. Model order reduction reduces the computational complexity of mathematical models and is ubiquitous in the simulation of dynamical systems and control theory. The efficiency and effectiveness of the proposed algorithm in the ab initio prediction of X-ray absorption spectra is demonstrated using a test set of challenging water clusters which are spectrally dense in the neighborhood of the oxygen K-edge. On the basis of a single, user defined tolerance we automatically determine the order of the reduced models and approximate the absorption spectrum up to the given tolerance. We also illustrate that, for the systems studied, the automatically determined model order increases logarithmically with the problem dimension, compared to a linear increase of the number of eigenvalues within the energy window. Furthermore, we observed that the computational cost of the proposed algorithm only scales quadratically with respect to the problem dimension.

IDREAM, K-Edge, theoretical, computational, electr↗

Solid-State Transformer and Hybrid Transformer With Integrated Energy Storage in Active Distribution Grids: Technical and Economic Comparison, Dispatch, and Control

Solid-state transformer (SST) and hybrid transformer (HT) are promising alternatives to the line-frequency transformer (LFT) in smart grids. The SST features medium-frequency isolation, full controllability for voltage regulation, reactive power compensation, and the capability of battery energy storage system (BESS) integration with multiport configuration. The HT has a partially-rated converter for fractional controllability and can integrate a small BESS. Fast grid-edge voltage fluctuations from increased solar photovoltaic (PV) and electric vehicle (EV) penetration are difficult to manage for mechanical load tap changers. Hence, along with the trend towards more BESS in the grid, the controllability and the storage integration capability of the SST and HT are of strong interest. However, a review of literature shows existing SST and HT research is mostly at converter level, while system-level assessments are scarce. Assessing technical and economic impacts is critical to understanding the benefits and role of the SST and HT to guide future research, which is presented for the first time in this article. Experimental results from medium-voltage (MV) SST and MV HT prototypes are shown to confirm equipment-level feasibility, where the voltage controllability waveforms of a MV HT prototype are reported for the first time. Comparative simulations are performed on a modified IEEE 34-bus system. Here, a grid-model-less decentralized grid-edge voltage control method and a day-ahead BESS dispatch method are proposed for the SST and HT. The simulations show that the SST and HT with integrated storage can host more PV, achieve peak shaving, mitigate voltage fluctuation and reverse power flow, and support energy arbitrage for operational cost reduction, as compared to the LFT. Moreover, comprehensive analyses of net present value (NPV) and internal rate of return (IRR) are performed under different installed PV capacities, HT’s partial converter ratings, and BESS capacities. Sensitivities to future cost reductions of the PV and BESS are studied. Although the NPV and IRR are currently negative, 60% capital cost reduction or 150% revenue increase will make the SST and HT economically viable in the use case studied.

14 SOLAR ENERGY↗

The quest for improved air quality may push China to continue its CO 2 reduction beyond the Paris Commitment

China is challenged with the simultaneous goals of improving air quality and mitigating climate change. The “Beautiful China” strategy, launched by the Chinese government in 2020, requires that all cities in China attain 35 μg/m 3 or below for annual mean concentration of PM 2.5 (particulate matter with aerodynamic diameter less than 2.5 μm) by 2035. Meanwhile, China adopts a portfolio of low-carbon policies to meet its Nationally Determined Contribution (NDC) pledged in the Paris Agreement. Previous studies demonstrated the co-benefits to air pollution reduction from implementing low-carbon energy policies. Pathways for China to achieve dual targets of both air quality and CO 2 mitigation, however, have not been comprehensively explored. Here, we couple an integrated assessment model and an air quality model to evaluate air quality in China through 2035 under the NDC scenario and an alternative scenario (Co-Benefit Energy [CBE]) with enhanced low-carbon policies. Results indicate that some Chinese cities cannot meet the PM 2.5 target under the NDC scenario by 2035, even with the strictest end-of-pipe controls. Achieving the air quality target would require further reduction in emissions of multiple air pollutants by 6 to 32%, driving additional 22% reduction in CO 2 emissions relative to the NDC scenario. Results show that the incremental health benefit from improved air quality of CBE exceeds 8 times the additional costs of CO 2 mitigation, attributed particularly to the cost-effective reduction in household PM 2.5 exposure. The additional low-carbon energy polices required for China’s air quality targets would lay an important foundation for its deep decarbonization aligned with the 2 °C global temperature target.

54 ENVIRONMENTAL SCIENCES↗

Electro-optically responsive composites of gold nanospheres in 5CB liquid crystal under direct current and alternating current joint action

Direct current (DC) electro-optical (EO) control of transmitted laser beam intensity based on EO controlled coherent light scattering and diffraction by stationary longitudinal texture pattern (LTP) is achieved in planar-oriented cells with a composite mixture of polymer-coated gold spherical nanoparticles (Au-NPs) with a mean diameter of about 12 nm and the room-temperature nematic pentylcyanobiphenyl (5CB). At relatively low DC voltage of about 5 V, the effective scattering/diffraction by Au-NPs/5CB composites leads to a spatial spreading of transmitted coherent light from a low-power continuous wave laser beam, resulting in a drastic reduction of its local intensity. The effect is polarization dependent and is strongest when the polarization of the input laser beam is along the LTP. The EO response of Au-NPs/5CB mixtures is studied under DC and alternating current (AC) joint action with the aim of the potential use of these composite materials as EO controlled diffusers. The specific V-shaped sharp dip in the DC voltage-dependent coherent light transmittance of Au-NPs/5CB planar films, as well as the possibility for erasing the scattering/diffractive LTP in the films by joint low AC voltage, can be useful for EO applications in the field of process control and for detection of weak dynamic electric fields.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Persistent Sampling: Enhancing the Efficiency of Sequential Monte Carlo

Sequential Monte Carlo (SMC) samplers are powerful tools for Bayesian inference but suffer from high computational costs due to their reliance on large particle ensembles for accurate estimates. We introduce persistent sampling (PS), an extension of SMC that systematically retains and reuses particles from all prior iterations to construct a growing, weighted ensemble. By leveraging multiple importance sampling and resampling from a mixture of historical distributions, PS mitigates the need for excessively large particle counts, directly addressing key limitations of SMC such as particle impoverishment and mode collapse. Crucially, PS achieves this without additional likelihood evaluations-weights for persistent particles are computed using cached likelihood values. This framework not only yields more accurate posterior approximations but also produces marginal likelihood estimates with significantly lower variance, enhancing reliability in model comparison. Furthermore, the persistent ensemble enables efficient adaptation of transition kernels by leveraging a larger, decorrelated particle pool. Experiments on high-dimensional Gaussian mixtures, hierarchical models, and non-convex targets demonstrate that PS consistently outperforms standard SMC and related variants, including recycled and waste-free SMC, achieving substantial reductions in mean squared error for posterior expectations and evidence estimates, all at reduced computational cost. PS thus establishes itself as a robust, scalable, and efficient alternative for complex Bayesian inference tasks.

Karamanis, Minas↗