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Stellar occultation experiment with the CASSINI VIMS instrument

The VIMS instrument (Visible and Infrared Mapping Spectrometer) will be flown in the late 1990s on the CASSINI mission to Saturn and its moons. VIMS is designed to generate two-dimensional multispectral images of planetary surfaces and their features in the visible and infrared spectra. Compared to earth-based instruments, the stellar occultation experiment will provide unprecedented thickness resolution and chemical composition of planetary atmospheres. It will also gather high SNR optical depth profiles and particle size distribution of the Saturnian rings. The stellar occultation mode ideally requires continuous data acquisition for periods of up to several hours as the instrument stares at a star. This presents a sizeable challenge to the instrument's operational mode: processes that normally occur during mirror retrace must be shifted to data acquisition cycles, thereby creating timing difficulties in the sequencing of these cycles. The presentation focuses on the analysis of the stellar occultation mode and presents solutions to the challenge of an uninterrupted data stream. Several options will be presented that minimize any possible degradation of the experiment's science content.

Walch, Marc↗

Erosive burning of solid propellants

Presented here is a review of the experimental and modeling work concerning erosive burning of solid propellants (augmentation of burning rate by flow of product gases across a burning surface). A brief introduction describes the motor design problems caused by this phenomenon, particularly for low port/throat area ratio motors and nozzleless motors. Various experimental techniques for measuring crossflow sensitivity of solid propellant burning rates are described, with the conclusion that accurate simulation of the flow, including upstream flow development, in actual motors is important since the degree of erosive burning depends not only on local mean crossflow velocity and propellant nature, but also upon this upstream development. In the modeling area, a brief review of simplified models and correlating equations is presented, followed by a description of more complex numerical analysis models. Both composite and double-base propellant models are reviewed. A second generation composite model is shown to give good agreement with data obtained in a series of tests in which composite propellant composition and heterogeneity (particle size distribution) were systematically varied. Finally, the use of numerical models for the development of erosive burning correlations is described, and a brief discussion of scaling is presented.

King, Merrill K.↗

Design and performance/measurement simulation studies for a ER-2 sunphotometer

Work and results, including developed software, obtained under this grant (NAG 2-620) have been reported in various progress reports, an M.S. Thesis, and software programs. The purpose of this final report is simply to provide a documented listing of what has already been reported. This includes the following: (1) Conceptual Design and Simulation of a Spectral Sunphotometer for the ER-2 Aircraft; (2) Continued Simulation and Design Studies for an ER-2 Sunphotometer; and (3) Simulation and Performance Studies of a Spectra Sunphotometer for the ER-2 Aircraft. Also, software and computational results for modeling airmass and diffuse light effects due to aerosols were provided in support of NASA ARC research on the effects of aerosols resulting from the Pinatubo volcanic eruptions. The references for these articles are as follows: (1) Post Pinatubo Optical Depth Spectra vs. Latitude and Vortex Structure; and (2) Pinatubo and Pre-Pinatubo Optical-Depth Spectra -- Mauna Loa Measurements, Comparisons, Inferred Particle Size Distributions, Radiative Effects, and Relationships to Lidar Data.

Reagan, J. A.↗

Magnetite: What it reveals about the origin of the banded iron formations

Magnetite, Fe3O4 is produced abiotically and biotically. Abiotically, magnetite is a late magmatic mineral and forms as a consequence of the cooling of iron rich magma. Biotically, magnetite is produced by several organisms, including magnetotactic bacteria. Hematite, Fe2O3, is also produced abiotically and biotically. Abiotically, hematite rarely occurs as a primary mineral in igneous rocks, but is common as an alteration product, fumarole deposit, and in some metamorphosed Fe-rich rocks. Biotically, hematite is produced by several types of microorganisms. Biologically-produced magnetite and hematite are formed under the control of the host organism, and consequently, have characteristics not found in abiotically produced magnetite and hematite crystals. To determine if the magnetite and hematite in the Banded Iron Formation was biologically or abiotically produced, the characteristics of biologically-produced magnetite and hematite (concentrated from Aquaspirillum magnetotacticum) and abiotically-produced magnetite and hematite obtained from Wards Scientific Supply Company, were compared with characteristics of magnetite and hematite concentrated from the Gunflint Banded Iron Formation (Ontario, Canada) using thermal and crystallographic analytical techniques. Whole rock analysis of the Gunflint Banded Iron Formation by x-ray diffraction (XRD) and differential thermal analysis (DTA) revealed the presence of quartz, hematite, siderite and dolomite as the major minerals, and magnetite, greenalite, pyrite, pyrrhotite and apatite as the minor minerals. Analysis of a crude magnetic fraction of the Gunflint showed the minerals quartz, hematite, siderite, dolomite, and magnetite. Analysis of the crude magnetic fraction from Aquaspirillum magnetotacticum revealed organic compounds plus hematite and magnetite. The mineral identification and particle size distribution data obtained from the DTA along with XRD data indicate that the magnetite and hematite from the Gunflint BIF share some similarities with biologically formed magnetite and hematite.

Schwartz, D. E.↗

Satellite remote sensing of H2SO4 aerosol using the 8- to 12-microns window region: Application to Mount Pinatubo

Monitoring stratospheric aerosols containing H2SO4 using the brightness temperature (BT) difference between 11 and 8.3 microns (BT(sub 8)-BT(sub 11)) spectral channels is demonstrated using theoretical calculations and satellite observations. Assuming an aqueous solution of 50% and 75% sulfuric acid, radiative transfer calculations indicate that over oceans an increase in the optical depth of the stratospheric aerosol results in an increase in BT(sub 8)-BT(sub 11). Theoretical simulations suggest that the technique is sensitive to visible optical depths greater than approximately 0.15. The simulations also demonstrate a lack of sensitivity to the particle size distribution. Changes in pre- and post-Pinatubo observations by the High-resolution Infrared Radiation Sounder 2 (HIRS2) on board the NOAA 10 are consistent with observed optical depth measurements and confirm the sensitivity of these channels to the presence of the aerosol. The technique is also applied to cold tropical convective clouds and desert regions where the signal, though evident, is less conclusive. Time series analysis is applied to the NOAA 10 and NOAA 12 combined BT(sub 8-BT(sub 11) observations to detect the periodicity of the spread of the volcanic aerosol. Over a region of the southern Pacific a 18- to 26-day period is present. Model simulations were conducted to demonstrate a trispectral with observations near 8, 11, and 12 microns. The trispectral approach has high potential in that the spectral signature of cirrus, water vapor, and H2SO4 aerosols are different. Observations from NOAA 10 and NOAA 11 are combined to demonstrate the capabilities of these infrared wavelengths of detecting the aerosol. The signal is clearly evident when a region of the South Atlantic is compared for pre- and post-Pinatubo conditions.

Ackerman, Steven A.↗

Evolution of the Pinatubo volcanic aerosol column above Pasadena, California observed with a mid-infrared backscatter lidar

The evolution of the volcanic debris plume originating from the June 1991 eruption of Mt. Pinatubo has been monitored since its genesis using a ground-based backscatter lidar facility sited at the Jet Propulsion Laboratory (JPL). Both absolute and relative pre- and post-Pinatubo backscatter observations are in accord with Mie scattering projections based on measured aerosol particle size distributions reported in the literature. The post-Pinatubo column-integrated backscatter coefficient peaked approximately 400 days after the eruption, and the observed upper boundary of the aerosol column subsided at a rate of approximately 200 m/mon.

Tratt, David M.↗

Martian aerosols: Near-infrared spectral properties and effects on the observation of the surface

Imaging sprectroscopic measurements (ISM) of Mars acquired by the ISM instrument on Phobos-2 are used to investigate the NIR spectral properties of aerosols and the effects of atmospheric scattering on inferred mineralogy of the surface. Estimates of aerosols spectra between 0.77 and 2.6 micrometers are derived above Tharsis and Ophir Planum. The spectral continua are consistent with the particle size distribution derived using data from the solar occultation experiment on-board the spacecraft (effective radius approximately = 1.2 micrometers, with an effective variance approximately = 0.2). The aerosols spectra contain water-ice absorption features and possibly absorptions due to clay and/or sulfates. The largest effect of the aerosols on surface spectra is in dark regions, where the continuum spectral slope becomes more negative and the 1-micrometers absorption due to Fe in pyroxene is shifted toward longer wavelengths. The effects of aerosols on spectra of bright regions are insufficiently large to change mineralogic interpretations based on ISM data, i.e., that bright regions in Tharsis are dominated spectrally by hematite, but that additional ferric minerals are probably present in other areas including Arabia.

Erard, Stephane↗

Theoretical spectra of circumstellar dust shells around carbon-rich asymptotic giant branch stars

Realistic modeling of circumstellar dust shells around evolved stars has to include a physical treatment of the interaction among hydrodynamics, thermodynamics, radiative transfer, chemistry and dust formation and -growth. A self-consistent solution of this problem is presented in the case of stationary, spherical symmetric dust-driven winds. The resulting shell structure and the mass-loss rate are completely determined by the three fundamental stellar parameters stellar mass M(stellar), stellar luminosity L(stellar) and effective temperature T(sub eff) and by the element abundances epsilon(sub i). A detailed calculation of the transport coefficients of the dust component by means of the particle size distribution function and the solution of the non-grey radiative transfer problem provide realistic synthetic spectra of the dust shell models. We discuss the dependence of the resulting spectra on the stellar parameters in terms of infrared two color diagrams. Application of these model calculations to the prominent infrared object IRC +10216 yields best agreement with the observed spectrum and the visibility data at maximum light for the stellar parameters M(stellar) = 0.7 solar mass, L(stellar) = 2.4 x 10(exp 4) solar luminosity, T(stellar) = 2010K and a carbon to oxygen ratio of epsilon(sub c)/epsilon(sub o) = 1.40, which corresponds to a mass-loss rate of M-dot = 8 x 10(exp -5) solar mass/yr. In this model only amorphous carbon grains are considered as the main opacity source. From this model a distance to IRC +10216 of d = 170pc is deduced. The total mass contained in the circumstellar dust shell implies and initial main sequence mass of M(sub ZAMS) greater than or = 1.3 solar mass for IRC +10216.

Winters, J. M.↗

Application of Two-Phase CFD to the Design and Analysis of a Subscale Motor Experiment to Evaluate Propellant Slag Production

The redesigned solid rocket motor (RSRM) Pressure Perturbation Investigation Team concluded that the cause of recent pressure spikes during both static and flight motor burns was the expulsion of molten aluminum oxide slag from a pool which collects in the aft end of the motor around the submerged nozzle nose during the last half of motor operation. It is suspected that some motors produce more slag than others due to differences in aluminum oxide agglomerate particle sizes which may relate to subtle differences in propellant ingredient characteristics such as particle size distribution, contaminants, or processing variations. In order to determine the effect of suspect propellant ingredient characteristics on the propensity for slag production in a real motor environment, a subscale motor experiment was designed. An existing 5 inch ballistic test motor was selected as the basic test vehicle due to low cost and quick turn around times. The standard converging/diverging nozzle was replaced with a submerged nozzle nose design to provide a positive trap for the slag which would increase both the quantity and repeatability of measured slag weights. Computational fluid dynamics (CFD) was used to assess a variety of submerged nose configurations to identify the design which possessed the best capability to reliably collect slag. CFD also was used to assure that the final selected nozzle design would result in flow field characteristics such as dividing streamline location, nose attach point, and separated flow structure which would have similtude with the RSRM submerged nozzle nose flow field. It also was decided to spin the 5 inch motor about its longitudinal axis to further enhance slag collection quantities. Again, CFD was used to select an appropriate spin rate along with other considerations, including the avoidance of burn rate enhancement from radial acceleration effects.

Whitesides, R. Harold↗

Mission goals of a 1998/1999 Leonid storm Multi-instrument Aircraft Campaign (MAC)

In November of 1998 (or in 1999 with about equal probability) will be our one chance in a lifetime to anticipate with some certainty the occurrence of a meteor storm. For a period of up to 2 hours, rates are expected to increase above 1 meteor per second for a naked eye observer. At that time, Earth passes through the outer regimes of the dust trail of comet 55P/Tempel-Tuttle. The high meteor flux offers unprecedented precision in characterizing the dust trail in terms of spatial and particle size distributions of dust grains and allows the measurement of composition, morphology and orbits of individual cometary grains relatively soon after ejection from the comet. By using the Earth's atmosphere as a detector for the dust trains, grains are sampled over a wide mass range, from the typical grain size of zodiacal dust (40 - 200 micron) up until the rare boulders that can still be lifted off the comet nucleus.

Jenniskens, P.↗

Cloud Liquid Water, Mean Droplet Radius and Number Density Measurements Using a Raman Lidar

A new technique for measuring cloud liquid water, mean droplet radius and droplet number density is outlined. The technique is based on simultaneously measuring Raman and Mie scattering from cloud liquid droplets using a Raman lidar. Laboratory experiments on liquid micro-spheres have shown that the intensity of Raman scattering is proportional to the amount of liquid present in the spheres. This fact is used as a constraint on calculated Mie intensity assuming a gamma function particle size distribution. The resulting retrieval technique is shown to give stable solutions with no false minima. It is tested using Raman lidar data where the liquid water signal was seen as an enhancement to the water vapor signal. The general relationship of retrieved average radius and number density is consistent with traditional cloud physics models. Sensitivity to the assumed maximum cloud liquid water amount and the water vapor mixing ratio calibration are tested. Improvements to the technique are suggested.

Whiteman, David N.↗

Investigations of Clouds and Aerosols on Mars, Venus and Titan

This final report was included as part of a new proposal. This new proposal was selected for funding on 9 Nov. 1999. For Titan our interest during the past few years was to explain the observed asymmetry in the albedo. We suggested earlier, from one-dimensional modeling studies, that vertical transport rates were comparable to particle fall speeds. Since heating of the upper atmosphere, which drives dynamical motions, is largely due to the aerosols, a nonlinear interaction between dynamics, radiative heating and particle microphysics is possible. We pursued this interaction in a two-dimensional model. We showed that the observed variations in the albedo between the two hemispheres and over an orbital cycle, could be due to dynamical motions suspending particles so that particle sizes and optical depths vary across the planet. In the Cassini time frame, future studies of this interaction between dynamics, radiation and microphysics may be worthwhile using, the strong modeling base that others, and we have developed. In our recently approved proposal, however, we plan to extend our modeling to hydrocarbon clouds that lie at lower levels. We know very little about such clouds, and numerical models for their properties are non-existent. These clouds may be observed by the Huygen's Probe, and by the Cassini orbiter, so predictions of their properties should help in the analysis of Cassini data. We have also developed a sophisticated model for the lower, condensational, clouds on Venus. In this model we explored the water vapor budget on Venus, and the properties of the clouds such as particle size distribution. During the past few years we have applied our model of the water ice clouds on Mars to new data sets from Pathfinder, and Mars Global Surveyor. We have compared our predictions of cloud properties with those seen by Pathfinder, and found reasonable agreement.

Toon, Owen B.↗

Ultrasonic Velocity Variations with Soil Composition for Moisture Measurement

Soil moisture content may be measured by many methods, but the presently available techniques all have drawbacks when used in ground truth measurements for remote sensing. Ultrasonic velocity varies with soil moisture content, and may be used as the basis of a new measurement technique. In order to characterize a sensor capable of field use, soil particle size distribution data are compared to ultrasonic velocity in a variety of soils over a wide moisture range.

Metzl, R.↗

Influence of Humidity on the Aerosol Scattering Coefficient and Its Effect on the Upwelling Radiance During ACE-2

Aerosol scattering coefficients (sigma(sub sp)) have been measured over the ocean at different relative humidities (RH) as a function of attitude in the region surrounding the Canary Islands during the Second Aerosol Characterization Experiment (ACE-2) in June and July 1997. The data were collected by the University of Washington passive humidigraph (UWPH) mounted on the Pelican research aircraft. Concurrently, particle size distributions absorption coefficients and aerosol optical depth were measured throughout 17 flights. A parameterization of sigma(sub sp) as a function of RH was utilized to assess the impact of aerosol hydration on the upwelling radiance (normalized to the solar constant and cosine of zenith angle). The top of the atmosphere radiance signal was simulated at wavelengths corresponding to visible and near-infrared bands or the EOS-AM ("Terra") detectors, MODIS and MISR. The UWPH measured (sigma(sub sp)) at 2 RHs, one below and the other above ambient conditions. Ambient (sigma(sub sp)) was obtained by interpolation of these 2 measurements. The data were stratified in terms of 3 types of aerosols: Saharan dust, clean marine (marine boundary layer background) and polluted marine aerosols (i.e., 2- or 1-day old polluted aerosols advected from Europe). An empirical relation for the dependence of (sigma(sub sp)) on RH, defined by (sigma(sub sp))(RH) = k. ((1 - RH/100)(exp -gamma), was used with the hygroscopic exponent gamma derived from the data. The following gamma values were obtained for the 3 aerosol types: gamma(dust) = 0.23 +/- 0.05, gamma(clean marine) = 0.69 +/- 0.06 and gamma(polluted marine) = 0.57 + 0.06. Based on the measured (gamma)(s), the above equation was utilized to derive aerosol models with different hygroscopicities. The satellite simulation signal code 6S was used to compute the upwelling radiance corresponding to each of those aerosol models at several ambient humidities. For the pre-launch estimated precision of the sensors and the assumed viewing geometry of the instrument, the simulations suggest that the spectral and angular dependence of the reflectance measured by MISR is not sufficient to distinguish aerosol models with various different combinations of values ror dry composition. y and ambient RH. A similar behavior is observed for MODIS at visible wavelengths. However, the 2100 nm band of MODIS appears to be able to differentiate between at least some aerosol models with different aerosol hygroscopicity given the MODIS calibration error requirements. This result suggests the possibility of retrieval of aerosol hygroscopicity by MODIS.

Gasso, B. S.↗

GCSS Idealized Cirrus Model Comparison Project

The GCSS Working Group on Cirrus Cloud Systems (WG2) is conducting a systematic comparison and evaluation of cirrus cloud models. This fundamental activity seeks to support the improvement of models used for climate simulation and numerical weather prediction through assessment and improvement of the "process" models underlying parametric treatments of cirrus cloud processes in large-scale models. The WG2 Idealized Cirrus Model Comparison Project is an initial comparison of cirrus cloud simulations by a variety of cloud models for a series of idealized situations with relatively simple initial conditions and forcing. The models (16) represent the state-of-the-art and include 3-dimensional large eddy simulation (LES) models, two-dimensional cloud resolving models (CRMs), and single column model (SCM) versions of GCMs. The model microphysical components are similarly varied, ranging from single-moment bulk (relative humidity) schemes to fully size-resolved (bin) treatments where ice crystal growth is explicitly calculated. Radiative processes are included in the physics package of each model. The baseline simulations include "warm" and "cold" cirrus cases where cloud top initially occurs at about -47C and -66C, respectively. All simulations are for nighttime conditions (no solar radiation) where the cloud is generated in an ice supersaturated layer, about 1 km in depth, with an ice pseudoadiabatic thermal stratification (neutral). Continuing cloud formation is forced via an imposed diabatic cooling representing a 3 cm/s uplift over a 4-hour time span followed by a 2-hour dissipation stage with no cooling. Variations of these baseline cases include no-radiation and stable-thermal-stratification cases. Preliminary results indicated the great importance of ice crystal fallout in determining even the gross cloud characteristics, such as average vertically-integrated ice water path (IWP). Significant inter-model differences were found. Ice water fall speed is directly related to the shape of the particle size distribution and the habits of the ice crystal population, whether assumed or explicitly calculated. In order to isolate the fall speed effect from that of the associated ice crystal population, simulations were also performed where ice water fall speed was set to the same constant value everywhere in each model. Values of 20 and 60 cm/s were assumed. Current results of the project will be described and implications will be drawn. In particular, this exercise is found to strongly focus the definition of issues resulting in observed inter-model differences and to suggest possible strategies for observational validation of the models. The next step in this project is to perform similar comparisons for well observed case studies with sufficient high quality data to adequately define model initiation and forcing specifications and to support quantitative validation of the results.

Starr, David OC.↗

Measurements and Calculations of Microwave Radiance and Reflectivity for Storm-Associated Frozen Hydrometeors

During the TEFLUN-B (Texas-Florida under-flights for the Tropical Rainfall Measuring Mission (TRMM)) field experiment of August-September, 1998, a number of ER-2 aircraft flights with a host of microwave instruments were conducted over many convective storms, including some hurricanes, in the coastal region of Florida and Texas. These instruments include MIR (Millimeter-wave Imaging Radiometer), AMPR (Advanced Microwave Precipitation Radiometer), and EDOP (ER-2 Doppler Radar). EDOP is operated at the frequency of 9.7 GHz, while the AMPR and the MIR together give eleven channels of radiometric measurements in the frequency range of 10-340 GHz. The concurrent measurements from these instruments provide unique data sets for studying the details of the microphysics of hydrometeors. Preliminary examination of these data sets shows features that are generally well understood; i.e., radiometric measurements at frequencies <= 37 GHz mainly respond to rain, while those at frequencies >= 150 GHz, to snow and ice clouds above the freezing level. In this paper we present results of comparisons between these measurements and model calculations of brightness temperature and radar reflectivity. For simplicity the analysis is limited to the anvil region of the storms where only frozen hydrometeors are present. Various models of particle size distribution (e.g., Gunn-Marshall, Sekhon-Srivastava, and the Central Equatorial Pacific Experiment (CEPEX)) are examined in the calculations of brightness temperatures at the MIR frequencies and radar reflectivity at the EDOP frequency. Estimation of ice water path is made based on the best agreement between the measurements and calculations of brightness temperature and reflectivity. Problems associated with these analyses and measurement accuracy will be discussed.

Wang, James R.↗

BOREAS TE-1 SSA Soil Lab Data

This data set was collected by TE-1 to provide a set of soil properties for BOREAS investigators in the SSA. The soil samples were collected at sets of soil pits in 1993 and 1994. Each set of soil pits was in the vicinity of one of the five flux towers in the BOREAS SSA. The collected soil samples were sent to a lab, where the major soil properties were determined. These properties include, but are not limited to, soil horizon; dry soil color; pH; bulk density; total, organic, and inorganic carbon; electric conductivity; cation exchange capacity; exchangeable sodium, potassium, calcium, magnesium, and hydrogen; water content at 0.01, 0.033, and 1.5 MPascals; nitrogen; phosphorus; particle size distribution; texture; pH of the mineral soil and of the organic soil; extractable acid; and sulfur. The data are stored in tabular ASCII text files. The data files are available on a CD-ROM (see document number 20010000884), or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).

Hall, Forrest G.↗

BOREAS TE-2 NSA Soil Lab Data

This data set contains the major soil properties of soil samples collected in 1994 at the tower flux sites in the Northern Study Area (NSA). The soil samples were collected by Hugo Veldhuis and his staff from the University of Manitoba. The mineral soil samples were largely analyzed by Barry Goetz, under the supervision of Dr. Harold Rostad at the University of Saskatchewan. The organic soil samples were largely analyzed by Peter Haluschak, under the supervision of Hugo Veldhuis at the Centre for Land and Biological Resources Research in Winnipeg, Manitoba. During the course of field investigation and mapping, selected surface and subsurface soil samples were collected for laboratory analysis. These samples were used as benchmark references for specific soil attributes in general soil characterization. Detailed soil sampling, description, and laboratory analysis were performed on selected modal soils to provide examples of common soil physical and chemical characteristics in the study area. The soil properties that were determined include soil horizon; dry soil color; pH; bulk density; total, organic, and inorganic carbon; electric conductivity; cation exchange capacity; exchangeable sodium, potassium, calcium, magnesium, and hydrogen; water content at 0.01, 0.033, and 1.5 MPascals; nitrogen; phosphorus: particle size distribution; texture; pH of the mineral soil and of the organic soil; extractable acid; and sulfur. These data are stored in ASCII text files. The data files are available on a CD-ROM (see document number 20010000884), or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).

Veldhuis, Hugo↗