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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 919 records · Page 51
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Perturbation theory of structure in classical liquid mixtures: Application to metallic systems near phase separation

The partial structure factors of classical simple liquid mixtures near phase separation are dicussed. The theory is developed for particles interacting through pair potentials, and is thus appropriate both to insulating fluids, and also to metallic systems if these may be described by an effective ion-ion pair interaction. The motivation arose from consideration of metallic liquid mixtures, in which resistive anomalies have been observed near phase separation. A mean field theory correction appropriate to 3 pair potential for the effects of correlated motions in the reference fluid is studied. The work is cast in terms of functions which are closely related to the direct correlation functions of Ornstein and Zernike. The results are qualitatively in accord with physical expectations. Quantitative agreement with experiment seems to turn on the selection of the hard core reference potential in terms of the metallic effective pair potential. It is suggested that the present effective pair potentials are perhaps not properly used to calculate the metallic structure factors at long wavelength.

Henderson, R. L.↗
NASA NTRS1993

Ion acceleration and abundance enhancements by electron beam instabilities in impulsive solar flares

We show that a nonrelativistic electron beam in a hydrogen-helium solar flare plasma will excite H(+) electromagnetic ion cyclotron, shear Alfven, and R-X waves, in addition to waves resulting from the two-stream instability. The H(+) electromagnetic ion cyclotron and shear Alfven waves are able to selectively accelerate ambient He-3 and Fe, respectively, to MeV energies through first harmonic gyroresonance, and thereby account for the large (He-3)/(He-4) and Fe/C ratios seen in the energetic particles from impulsive solar flares. In this model, separate heating and acceleration mechanisms for either He-3 or Fe are not required, and Fe acceleration is quite efficient since it does not need to occur by second harmonic gyroresonance. The combination of the other two unstable modes is able to accelerate ions to hundreds of MeV if the particles become trapped in an electrostatic potential well of a two-stream wave.

Miller, James A.↗
DOE OSTI2023

The Production of Low Ash Coals Using the Hydrophobic-Hydrophilic Separation Process with Novel Developments

Froth flotation is a common mineral processing method in coal preparation. This process becomes less efficient, however, as particle size is reduced, and ultrafine particles are often discarded prior to froth flotation, contributing to a substantial amount of coal waste in impoundments. Because of the land-use and risk of an impoundment failure, these impoundments pose an environmental liability. To address ultrafine coal rejection, researchers at Virginia Tech developed the hydrophobic-hydrophilic separation (HHS) process. Unlike in froth flotation, HHS uses an organic solvent to separate and dewater hydrophobic particles from hydrophilic minerals. Past work on the HHS process yielded promising results. In particular, the HHS process has produced a low-ash (<2%) and low moisture (<8%) product, which is a viable feed stock for carbon products. In this work, an investigation of the effects of auxiliary processes on the HHS process was conducted. The auxiliary processes included grinding, pre-concentration, and reagent conditioning. This work also contains an investigation on the interaction between two primary unit operations in the HHS process: oil agglomeration and de-emulsification. Lastly, to make the HHS process more viable for commercial scale-up, a novel unit operation was developed and tested that performs comparably to the current HHS process.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS1978

An experiment to study energetic particle fluxes in and beyond the earth's outer magnetosphere

This experiment is designed to take advantage of the ISEE Mother/Daughter dual spacecraft system to study energetic particle phenomena in the earth's outer magnetosphere and beyond. Large geometric factor fixed voltage electrostatic analyzers and passively cooled semiconductor detector telescopes provide high time resolution coverage of the energy range from 1.5 to 300 keV for both ions and electrons. Essentially identical instrumentation is placed on the two spacecraft to separate temporal from spatial effects in the observed particle phenomena.

Anderson, K. A.↗
DOE OSTI2013

A gas-jet transport and catcher technique for on-line production of radioactive ion beams using an electron cyclotron resonance ion-source

Radioactive ion beams (RIB) have been produced on-line, using a gas-jet recoil transport coupled Electron Cyclotron Resonance (ECR) ion-source at the VECC-RIB facility. Radioactive atoms/molecules carried through the gas-jet were stopped in a catcher placed inside the ECR plasma chamber. A skimmer has been used to remove bulk of the carrier gas at the ECR entrance. The diffusion of atoms/molecules through the catcher has been verified off-line using stable isotopes and on-line through transmission of radioactive reaction products. Beams of {sup 14}O (71 s), {sup 42}K (12.4 h), {sup 43}K (22.2 h), and {sup 41}Ar (1.8 h) have been produced by bombarding nitrogen and argon gas targets with proton and alpha particle beams from the K130 cyclotron at VECC. Typical measured intensity of RIB at the separator focal plane is found to be a few times 10{sup 3} particles per second (pps). About 3.2 Multiplication-Sign 10{sup 3} pps of 1.4 MeV {sup 14}O RIB has been measured after acceleration through a radiofrequency quadrupole linac. The details of the gas-jet coupled ECR ion-source and RIB production experiments are presented along with the plans for the future.

43 PARTICLE ACCELERATORS↗
DOE OSTI2024

Phase Transitions in Organic and Organic/Inorganic Aerosol Particles

The phase state of aerosol particles can impact numerous atmospheric processes, including new particle growth, heterogeneous chemistry, cloud condensation nucleus formation, and ice nucleation. In this article, the phase transitions of inorganic, organic, and organic/inorganic aerosol particles are discussed, with particular focus on liquid-liquid phase separation (LLPS). The physical chemistry that determines whether LLPS occurs, at what relative humidity it occurs, and the resultant particle morphology is explained using both theoretical and experimental methods. The known impacts of LLPS on aerosol processes in the atmosphere are discussed. Finally, potential evidence for LLPS from field and chamber studies is presented. By understanding the physical chemistry of the phase transitions of aerosol particles, we will acquire a better understanding of aerosol processes, which in turn impact human health and climate.

Chemistry↗
DOE OSTI2012

Catalytic Conversion of Biomass to Fuels and Chemicals Using Ionic Liquids

This project provides critical innovations and fundamental understandings that enable development of an economically-viable process for catalytic conversion of biomass (sugar) to 5-hydroxymethylfurfural (HMF). A low-cost ionic liquid (Cyphos 106) is discovered for fast conversion of fructose into HMF under moderate reaction conditions without any catalyst. HMF yield from fructose is almost 100% on the carbon molar basis. Adsorbent materials and adsorption process are invented and demonstrated for separation of 99% pure HMF product and recovery of the ionic liquid from the reaction mixtures. The adsorbent material appears very stable in repeated adsorption/regeneration cycles. Novel membrane-coated adsorbent particles are made and demonstrated to achieve excellent adsorption separation performances at low pressure drops. This is very important for a practical adsorption process because ionic liquids are known of high viscosity. Nearly 100% conversion (or dissolution) of cellulose in the catalytic ionic liquid into small molecules was observed. It is promising to produce HMF, sugars and other fermentable species directly from cellulose feedstock. However, several gaps were identified and could not be resolved in this project. Reaction and separation tests at larger scales are needed to minimize impacts of incidental errors on the mass balance and to show 99.9% ionic liquid recovery. The cellulose reaction tests were troubled with poor reproducibility. Further studies on cellulose conversion in ionic liquids under better controlled conditions are necessary to delineate reaction products, dissolution kinetics, effects of mass and heat transfer in the reactor on conversion, and separation of final reaction mixtures.

09 BIOMASS FUELS↗
DOE OSTI2019

Lower Estimates for Distances from a Given Quantum Channel to Certain Classes of Quantum Channels

By using estimates for the variation of quantum mutual information and the relative entropy of entanglement, we obtain ε-exact lower estimates for distances from a given quantum channels to sets of degradable, antidegradable, and entanglement-breaking channels. As an auxiliary result, we obtain ε-exact lower estimates for the distance from a given two-particle state to the set of all separable states.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2021

Microbe-Encapsulated Silica Gel Biosorbents for Selective Extraction of Scandium from Coal Byproducts

Establishing an inexpensive and environmentally friendly scandium (Sc) supply is critical for the development of clean energy technologies. However, refining Sc from Sc-bearing sources using current technologies poses economic and environmental challenges due to its low concentration relative to base metals and chemically similar lanthanides. In this work, we developed a biosorption-based flow-through process for extraction of Sc from low-grade feedstocks. A novel biosorbent material was synthesized by encapsulating Arthrobacter nicotianae, a bacterium that selectively adsorbs Sc, within a porous silica matrix. Through the use of several complementary microscopy techniques, we demonstrated a highly porous biosorbent structure with a high cell-loading density and a homogenous cell distribution. Batch adsorption assays revealed selective Sc adsorption over lanthanides and common based metals, with the exception of Fe(III), as evidenced by separation factors greater than 50. The MESG particles were packed into fixed-bed columns to enable adsorption under flow-through conditions, which demonstrated effective Sc extraction at flow rates up to 0.08 cm/s and high stability for reuse; greater than 95% of the adsorption capacity was maintained after 10 consecutive adsorption/desorption cycles. When applied to a lignite coal leachate, whose Fe content was depleted through pH-mediated precipitation, the MESG particles yielded Sc breakthrough at 30 bed volumes, whereas all other metals broke through after only a few bed volumes. Following desorption, an eluate with a 124-fold increase in Sc purity was achieved relative to the lignite leachate with Sc constituting 96.4% of the total REEs. This study established a rapid, facile, and scalable cell immobilization approach that enables the use of microbial biomass for Sc recovery from low-grade sources.

Dong, Ziye↗
DOE OSTI2025

On Alfvénic turbulence of solar wind streams observed by Solar Orbiter during March 2022 perihelion and their source regions

It has been recently accepted that the standard classification of the solar wind solely according to flow speed is outdated, and particular interest has been devoted to the study of the origin and evolution of so-called Alfvénic slow solar wind streams and to what extent such streams resemble or differ from fast wind. In March 2022, Solar Orbiter completed its first nominal phase perihelion passage. During this interval, it observed several Alfvénic streams, allowing for characterization of fluctuations in three slow wind intervals (AS1-AS3) and comparison with a fast wind stream (F) at almost the same heliocentric distance. This work makes use of Solar Orbiter plasma parameters from the Solar Wind Analyzer (SWA) and magnetic field measurements from the magnetometer (MAG). The magnetic connectivity to the solar sources of selected solar wind intervals was reconstructed using a ballistic extrapolation based on measured solar wind speed down to the (spherical) source surface at 2.5 R s below which a potential field extrapolation was used to map back to the Sun. The source regions were identified using SDO/AIA observations. A spectral analysis of in situ measured magnetic field and velocity fluctuations was performed to characterize correlations, Alfvénicity, normalized cross-helicity, and residual energy in the frequency domain as well as intermittency of the fluctuations and spectral energy transfer rate estimated via mixed third-order moments. A machine learning technique was used to separate proton core, proton beam, and alpha particles and to study v − b correlations for the different ion populations in order to evaluate the role played by each population in determining the Alfvénic content of solar wind fluctuations. The comparison between fast wind and Alfvénic slow wind intervals highlights the differences between the two solar wind regimes: The fast wind is characterized by larger amplitude fluctuations, and magnetic and velocity fluctuations are closer to equipartition of energy. In fact the Alfvénic slow wind streams appear to be on a spectrum of wind types, with AS1, originating from open field lines neighboring active regions and displaying similarities with the fast wind in terms of fluctuation amplitude and turbulence characteristics, but not with respect to the alpha particles and proton beams. The other two slow streams differed both in their sources as well as plasma characteristics, with AS2 coming from the expansion of a narrow coronal hole corridor and AS3 from a region straddling a pseudostreamer. The latter displayed the coldest and highest density but the slowest stream with the smallest fluctuation amplitude and greatest magnetic energy excess. It also showed the largest scatter in proton beam speeds and the greatest difference in speed between proton beam and alpha particles. This study shows how the old fast–slow solar wind dichotomy, already called into question by the observations of slower Alfvénic solar wind streams, should further be refined, as the Alfvénic slow wind, originating in different solar wind regions, show significant differences in density, temperature, and proton and alpha-particle properties in the inner heliosphere. The observations presented here provide the starting point for a better understanding of the origin and evolution of different solar wind streams as well as the evolving turbulence contained within.

magnetohydrodynamics (MHD)↗
DOE OSTI2017

Parametric decay of plasma waves near the upper-hybrid resonance

An intense X wave propagating perpendicularly to dc magnetic field is unstable with respect to a parametric decay into an electron Bernstein wave and a lower-hybrid wave. A modified theory of this effect is proposed that extends to the high-intensity regime, where the instability rate γ ceases to be a linear function of the incident-wave amplitude. An explicit formula for γ is derived and expressed in terms of cold-plasma parameters. Here, theory predictions are in reasonable agreement with the results of the particle-in-cell simulations presented in a separate publication.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2014

Nuclear Archaeology for Gaseous Diffusion Enrichment Plants

Gaseous diffusion was historically the most widely used technology for military production of highly enriched uranium. Since June 2013, all gaseous diffusion enrichment plants worldwide are permanently shut down. The experience with decommissioning some of these plants has shown that they contain large amounts of uranium particles deposited in the cascade equipment. This article evaluates the potential of using uranium particle deposition to understand and reconstruct the operating histories of gaseous diffusion enrichment plants. First, a squared-off cascade enrichment model is derived to estimate the enrichment capacity of a reference plant. Then, using a cross-flow filtration model, the mass of solid uranium particles deposited over time in the tubular separation membranes of the stage diffusers is calculated. Lastly, potential techniques to characterize these uranium deposits and help reconstruct the operating history of the plant are assessed.

07 ISOTOPE AND RADIATION SOURCES↗
DOE OSTI2025

Minimal cyclic behavior in sheared amorphous solids

Although jammed packings of soft spheres exist in potential energy landscapes with a vast number of minima, when subjected to cyclic shear they may revisit the same configurations repeatedly. Simple hysteretic spin models, in which particle rearrangements are represented by interacting spin flips called hysterons, capture many features of this periodic behavior. Yet it has been unclear to what extent individual rearrangements can be described by such binary objects and how such objects interact with one another. Using a particularly sensitive algorithm, we identify rearrangements in simulated jammed packings and select pairs of rearrangements that undo one another to create periodic cyclic behavior. We find that the rearrangement pairs surprisingly persist down to the smallest increments in strain, even in the smallest systems we can study. We explore the statistics of these rearrangement pairs and find that there is a relation between the amount of hysteresis and the energy drop and mean-square displacement of the particles; these results are inconsistent with the scaling found in models that treat rearrangements as localized buckling events. Finally, our analysis shows that there is no clean distinction between the particle motions that represent the identity of a single, individual rearrangement and the particle motions that lead to interactions between separated rearrangements or hysterons. These results offer insight into how complex systems such as amorphous solids can reach a limit cycle.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Community Structure and Microbial Associations in Sediment-Free Methanotrophic Enrichment Cultures from a Marine Methane Seep

We report Syntrophic consortia of anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB) consume large amounts of methane and serve as the foundational microorganisms in marine methane seeps. Despite their importance in the carbon cycle, research on the physiology of ANME-SRB consortia has been hampered by the slow growth and complex physicochemical environment the consortia inhabit. Here, we report successful sediment-free enrichment of ANME-SRB consortia from deep-sea methane seep sediments in the Santa Monica Basin, California. Anoxic Percoll density gradients and size-selective filtration were used to separate ANME-SRB consortia from sediment particles and single cells to accelerate the cultivation process. Over a 3-year period, a subset of the sediment-associated ANME and SRB lineages, predominantly comprised of ANME-2a/2b (“Candidatus Methanocomedenaceae”) and their syntrophic bacterial partners, SEEP-SRB1/2, adapted and grew under defined laboratory conditions. Metagenome-assembled genomes from several enrichments revealed that ANME-2a, SEEP-SRB1, and Methanococcoides in different enrichments from the same inoculum represented distinct species, whereas other coenriched microorganisms were closely related at the species level. This suggests that ANME, SRB, and Methanococcoides are more genetically diverse than other members in methane seeps. Flow cytometry sorting and sequencing of cell aggregates revealed that Methanococcoides, Anaerolineales, and SEEP-SRB1 were overrepresented in multiple ANME-2a cell aggregates relative to the bulk metagenomes, suggesting they were physically associated and possibly interacting. Overall, this study represents a successful case of selective cultivation of anaerobic slow-growing microorganisms from sediments based on their physical characteristics, introducing new opportunities for detailed genomic, physiological, biochemical, and ecological analyses. Biological anaerobic oxidation of methane (AOM) coupled with sulfate reduction represents a large methane sink in global ocean sediments. Methane consumption is carried out by syntrophic archaeal-bacterial consortia and fuels a unique ecosystem, yet the interactions in these slow-growing syntrophic consortia and with other associated community members remain poorly understood. The significance of this study is the establishment of sediment-free enrichment cultures of anaerobic methanotrophic archaea and sulfate-reducing bacteria performing AOM with sulfate using selective cultivation approaches based on size, density, and metabolism. By reconstructing microbial genomes and analyzing community composition of the enrichment cultures and cell aggregates, we shed light on the diversity of microorganisms physically associated with AOM consortia beyond the core syntrophic partners. These enrichment cultures offer simplified model systems to extend our understanding of the diversity of microbial interactions within marine methane seeps.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2019

Measurement of kernel swelling and buffer densification in irradiated UCO and UO 2 TRISO fuel particles from AGR-2

The second Advanced Gas Reactor irradiation (AGR-2) featured UCO tristructural isotropic (TRISO)-coated particle fuel and, for comparison purposes, UO2 TRISO fuel. Particles from three UCO fuel compacts and one UO2 fuel compact were chosen for analysis of kernel swelling and buffer shrinkage. Both kernel swelling and buffer shrinkage are common elements of TRISO fuel performance models. More recently, the AGR program has determined that buffer shrinkage may impact the integrity of the inner pyrolytic carbon (IPyC) layer, which may impact SiC layer integrity (particularly during high-temperature heating tests). Therefore, measurements of buffer irradiation-induced shrinkage may be useful in improving existing models and developing new models that capture buffer-IPyC-SiC-fission product interactions observed in recent AGR post-irradiation examination (PIE). TRISO particles were mounted in epoxy, ground, polished, and imaged via optical microscopy in four separate iterations. Each of the four iterations revealed progressively deeper cross sections within the particles. Images collected from each iteration were analyzed for the circumferences/radii of the kernel, buffer, IPyC, and SiC. Spheres were fit to each set of measurements to generate spherical radii representative of the components of the fuel particle. From these radii, volumes were computed and compared to the as-fabricated volumes. UCO kernel swelling was similar among the three AGR-2 compacts ranging from approximately 28 to 32%. This is only slightly higher swelling than was measured in an earlier study of an AGR-1 compact. However, the burnup at which this swelling occurred in AGR-2 was lower than in AGR-1, indicating a faster swelling rate for the AGR-2 kernels for the irradiation conditions covered by these compacts. The AGR-2 UO2 kernel swelling was less, at 9.9%, comparable to other studies of UO2 kernel swelling. While AGR-2 UCO and UO2 kernels demonstrated different rates of swelling, the extent of buffer shrinkage was similar among the two fuel types, ranging from 24-28%. For comparison, a prior study showed that AGR-1 Compact 1-3-1 experienced 39% buffer shrinkage. A commonly-observed post-irradiation particle morphology is where the buffer pulls away from the IPyC (at least in some regions of the particle). Besides the possibility of the buffer degrading the IPyC when it pulls away from the IPyC, this gap is significant because it may also reduce heat transfer within the particle. Average AGR-2 buffer-IPyC gaps were similar for the UCO and UO2 particles, ranging from 22.2 to 26.0 µm. This is similar to what was measured for AGR-1 Compact 1-3-1.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Fabrication of New PCM Hydrogel Composites

Salt hydrates are low-cost phase-change materials (PCMs) with excellent thermal energy storage capacities. However, they are limited by low thermal cycling stability due to incongruent melting-induced phase separation. This project will solve the long-standing issue of phase separation of salt hydrates by stabilizing salt particles in a charged polymer hydrogel network. The proposed approach uses combined physical and chemical stabilization mechanisms achieved by selecting a proper chemistry and molecular weight of the polymer matrix. In summary, we have identified several important formulations that show good energy storage capacity performance and good cycling stability. The thermal storage capacity can be further improved through further sample optimization. The thermal conductivities of the samples were low, but there are ways to improve it by adding a highly thermally conductive material with a high aspect ratio. The method of preparation is suitable for scale-up.

25 ENERGY STORAGE↗
DOE OSTI2023

Verification and Performance Impact of the New Parallel MCNP6.3 Particle Track Output Capability for Subcritical Multiplication Simulations [Slides]

A separate MCNP6.3 V&V document reports on all the default calculations for all test suites. This report does not include the subcritical multiplication benchmark suite. After some additional clean-up and finalizing the post-processing and documentation steps, the subcritical multiplication benchmark suite will be released in the next version of our vnvstats repository. We tested the new HDF5 PTRAC feature in MCNP6.3 and found encouraging outcomes. Identical results coming out of the simulation with respect to the legacy PTRAC results. The overall runtime for all simulations is reduced by ~20% with the new HDF5 PTRAC capability. We consider giving the new HDF5 PTRAC features a try and using it for all subcritical multiplication and any other relevant (PTRAC) calculations.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2022

Polar Aerosol Vertical Structures and Characteristics Observed with a High Spectral Resolution Lidar at the ARM NSA Observatory

Aerosol vertical distributions impact both the direct and indirect radiative effects of aerosols. High Spectra Resolution Lidar (HSRL) separates between atmospheric molecular signals and aerosol particle signals and therefore can provide reliable measurements of aerosol properties. Six years of HSRL measurements between 2014 and 2019 from the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) North Slope of Alaska (NSA) atmospheric observatory at Utqiaqvik are used to statistically analyze Arctic aerosol vertical distributions. The annual cycle of aerosol vertical distributions in terms of aerosol particulate backscatter coefficient ($β_p$), lidar scattering ratio (SR), and aerosol particulate depolarization ratio ($δ_p$) profiles at the wavelength of 532 nm shows that Arctic Haze events are prevalent in later winter and spring at the NSA site. Mineral dust is frequently presented in strong aerosol layers in the spring, fall, and winter seasons. Over the summer season, the NSA site has large aerosol loadings that are dominated by small spherical aerosol particles.

54 ENVIRONMENTAL SCIENCES↗