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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 919 records · Page 51
All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Geology of Lunar Landing Sites and Origin of Basin Ejecta from a Clementine Perspective

The goals of this research were to examine Clementine multispectral data covering the Apollo landing sites in order to: (1) provide ground truth for the remotely sensed observations, (2) extend our understanding of the Apollo landing sites to the surrounding regions using the empirically calibrated Clementine data, and (3) investigate the composition and distribution of impact-basin ejecta using constraints based upon the remotely sensed data and the Apollo samples. Our initial efforts (in collaboration with P. Lucey and coworkers) to use the Apollo soil compositions to "calibrate" information derived from the remotely sensed data resulted in two extremely useful algorithms for computing estimates of the concentrations of FeO and TiO2 from the UV-VIS 5-band data. In this effort, we used the average surface soil compositions from 37 individual Apollo and 3 Luna sample stations that could be resolved using the Clementine data. We followed this work with a detailed investigation of the Apollo 17 landing site, where the sampling traverses were extensive and the spectral and compositional contrast between different soils covers a wide range. We have begun to investigate the nature and composition of basin ejecta by comparing the thick deposits on the rim of Imbrium in the vicinity of the Apollo 15 site and those occurring southeast of the Serenitatis basin, in the Apollo 17 region. We continue this work under NAG5-6784, "Composition, Lithology, and Heterogeneity of the lunar crust using remote sensing of impact-basin uplift structures and ejecta as probes. The main results of our work are given in the following brief summaries of major tasks. Detailed accounts of these results are given in the attached papers, manuscripts, and extended abstracts.

Jolliff, Bradley L.↗
DOE OSTI2021

Mapping of inhomogeneous quasi-3D electrostatic field in electro-optic materials

Abstract This paper describes a new method for direct measurement and evaluation of the inhomogeneous electrostatic vector field with translational symmetry in electro-optic materials exhibiting the Pockels effect. It is based on the evaluation of maximum transmittance of low intensity light passing through a sample under a voltage bias. Here, the sample is located between rotating crossed polarizers, and camera images are obtained at each point to determine the electric field. The evaluation procedure is demonstrated using data acquired on a CdZnTeSe quasi-hemispheric semiconductor gamma-ray detector. In addition to CdTe-related compounds, the method can be used for various other materials showing $$\overline{4}3m$$ 4 ¯ 3 m symmetry such as GaAs, CdTe, GaP, 3C-SiC, and ZnS. Furthermore, it can be generalized to other crystalline materials showing the Pockels effect. The method can be used to probe the space charge and the electric field in several kinds of electronic components and devices, as well as provide useful data on the role of defects, contact configurations and other surface and bulk inhomogeneities in the material that can affect the distribution of the internal electric field.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Synchrotron Characterization of the Oxidation of Advanced Steel Cladding Alloys

Advanced steel alloys are proposed as nuclear fuel claddings due to their high corrosion resistance under extreme conditions of pressure and temperature. APMT is an iron based alloy (Fe-22wt.%Cr-5.8wt.%Al) and Alloy 33 is a mixture of iron, chromium, and nickel (32wt.%Fe-33wt.%Cr-31wt.%Ni). This paper focuses on studying the corrosion mechanisms for these alloys under exposure to superheated steam at 800 deg. C and 1000 deg. C using the synchrotron based X-ray diffraction (XRD) and Hard X-ray photoelectron spectroscopy (HAXPES) techniques. HAXPES data was collected using 4 keV X-rays with a 1x1 mm spot size at X24A beamline. Specimens were mounted on the sample holder. The specimens were tilted 5 degrees relative to the beam and the estimated probe depth (for this fixed energy) is 63 A. The X-ray wavelength for XRD studies at X14A beamline is 0.7792 A with a beam size of of 2 x 0.2 mm{sup 2}. Specimens were exposed to steam environment at 800 and 1000 deg. C for 8, 24, and 48 hours. For Alloy 33; a layer of mixed Cr{sub 2}O{sub 3} and FeCr{sub 2}O{sub 4} oxides is formed after exposure to steam. Specimen tilting indicated that Cr{sub 2}O{sub 3} is formed near the metal/oxide interface and FeCr{sub 2}O{sub 4} was formed on the oxide surface. The oxide peak intensities increased with an increase in steam temperature. The specimen oxidized at 1000 deg. C had well-developed oxide peaks compared to the specimen oxidized at 800 deg. C. For APMT; a layer of mixed α-Al{sub 2}O{sub 3} and monoclinic θ-Al{sub 2}O{sub 3} oxides is formed on the outer surface. The peak intensities of the monoclinic θ-Al{sub 2}O{sub 3} phase, decreases relative to the peaks from the Al{sub 2}O{sub 3} phase with increasing tilt angle. This indicates that the surface is dominated by the θ-Al{sub 2}O{sub 3}. After exposure to steam at 800 deg. C, oxidation of Alloy 33 results in the formation of Cr{sub 2}O{sub 3} oxide with time and absence of both metallic and substoichiometric phases is observed. No nickel peaks are seen on the surface after oxidation at 800 deg. C, however Fe(II) peak is noticed after 8 and 24 hours of steam exposure, which then disappears after 48 hours. This presence of FeCr{sub 2}O{sub 4} oxide phase is observed after 8 and 24 hours. After exposure to steam at 1000 deg. C, the Cr{sub 2}p{sub 3/2} doublet persists at all exposure times, indicating the presence of the FeCr{sub 2}O{sub 4} oxide. Nickel peak is found on the surface at all exposure times and is attributed to the presence of Ni(OH){sub 2} phase. This may be due to increased diffusion of Ni through chromic oxide scale at higher temperature as compared to 800 deg. C. This nickel reacts with steam at 1000 deg. C to form Ni hydroxide at the surface. For APMT, after exposure to steam at 800 and 1000 deg. C, no Al and Cr metal peaks are seen. Growth of oxide layer is seen with increase in exposure time. The oxide structure contains mainly Al{sub 2}O{sub 3} oxide with the addition of mixed oxide (Al{sub x}Cr{sub 1-x}){sub 2}O{sub 3}. These results demonstrate that Cr diffuses into the alumina layer. (authors)

36 MATERIALS SCIENCE↗
DOE OSTI2015

Infrared Chemical Nano-Imaging: Accessing Structure, Coupling, and Dynamics on Molecular Length Scales

This Perspective highlights recent advances in infrared vibrational chemical nano-imaging. In its implementations of scattering scanning near-field optical microscopy (s-SNOM) and photothermal-induced resonance (PTIR), IR nanospectroscopy provides few-nanometer spatial resolution for the investigation of polymer, biomaterial, and related soft-matter surfaces and nanostructures. Broad-band IR s-SNOM with coherent laser and synchrotron sources allows for chemical recognition with small-ensemble sensitivity and the potential for sensitivity reaching the single-molecule limit. Probing selected vibrational marker resonances, it gives access to nanoscale chemical imaging of composition, domain morphologies, order/disorder, molecular orientation, or crystallographic phases. Local intra- and intermolecular coupling can be measured through frequency shifts of a vibrational marker in heterogeneous environments and associated inhomogeneities in vibrational dephasing. In combination with ultrafast spectroscopy, the vibrational coherent evolution of homogeneous sub-ensembles coupled to their environment can be observed. Outstanding challenges are discussed in terms of extensions to coherent and multidimensional spectroscopies, implementation in liquid and in situ environments, general sample limitations, and engineering s-SNOM scanning probes to better control the nano-localized optical excitation and to increase sensitivity.

Environmental Molecular Sciences Laboratory↗
DOE OSTI2024

DESI Massive Poststarburst Galaxies at z ~ 1.2 Have Compact Structures and Dense Cores

Poststarburst galaxies (PSBs) are young quiescent galaxies that have recently experienced a rapid decrease in star formation, allowing us to probe the fast-quenching period of galaxy evolution. In this work, we obtained Hubble Space Telescope (HST)/WFC3 F110W imaging to measure the sizes of 171 massive (log(M $\ast$ /M ⊙ ) ~ 11) spectroscopically identified PSBs at 1 < z 1.3 selected from the DESI Survey Validation luminous red galaxy sample. This statistical sample constitutes an order of magnitude increase from the ~20 PSBs with space-based imaging and deep spectroscopy. We perform structural fitting of the target galaxies with pysersic and compare them to quiescent and star-forming galaxies in the 3D-HST survey. We find that these PSBs are more compact than the general population of quiescent galaxies, lying systematically ~0.1 dex below the established size–mass relation. However, their central surface mass densities are similar to those of their quiescent counterparts (log(Σ 1kpc /(M ⊙ kpc -2 ))~10.1). These findings are easily reconciled by later ex situ growth via minor mergers or a slight progenitor bias. These PSBs are round in projection (b/a median ~ 0.8), suggesting that they are primarily spheroids, not disks, in 3D. We find no correlation between the time since quenching and light-weighted PSB sizes or central densities. This disfavors apparent structural growth due to the fading of centralized starbursts in this galaxy population. Instead, we posit that the fast quenching of massive galaxies at this epoch occurs preferentially in galaxies with preexisting compact structures.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Shape Dependence on the Electrochemistry of Uncoated Magnetite Motifs

Using a variety of synthetic protocols including hydrothermal and microwave-assisted methods, the morphology of as-prepared magnetite has been reliably altered as a means of probing the effect of facet variations upon the resulting electrochemical processes measured. In particular, motifs of magnetite, measuring ~100 to 200 nm in diameter, were variously prepared in the form of cubes, spheres, octahedra, and plates, thereby affording the opportunity to preferentially expose either (111), (220), or (100) planes, depending on the geometry in question. Here, we deliberately prepared these samples, characterized using XRD and SEM, in the absence of a carbonaceous surfactant to enhance their intrinsic electrochemical function. Herein, we present a direct electrochemical comparison of specifically modified shape morphologies possessing 3 different facets and their impact as electrode materials for Li-ion batteries. Our overall data suggest that the shapes exhibiting the largest deliverable capacities at various current densities incorporated the highest surface energy facets, such as exposed (220) planes in this study. The faceted nature of different morphologies highlighted a trend in electrochemistry of (220) > (111) > (100); moreover, the degree of aggregation and polydispersity in prepared samples were found to play key roles as well.

25 ENERGY STORAGE↗
DOE OSTI2022

3D isotope density measurements by energy-resolved neutron imaging

Abstract Tools for three-dimensional elemental characterization are available on length scales ranging from individual atoms, using electrons as a probe, to micrometers with X-rays. However, for larger volumes up to millimeters or centimeters, quantitative measurements of elemental or isotope densities were hitherto only possible on the surface. Here, a novel quantitative elemental characterization method based on energy-resolved neutron imaging, utilizing the known neutron absorption cross sections with their ‘finger-print’ absorption resonance signatures, is demonstrated. Enabled by a pixilated time-of-flight neutron transmission detector installed at an intense short-pulsed spallation neutron source, for this demonstration 3.25 million state-of-the-art nuclear physics neutron transmission analyses were conducted to derive isotopic densities for five isotopes in 3D in a volume of 0.25 cm 3 . The tomographic reconstruction of the isotope densities provides elemental maps similar to X-ray microprobe maps for any cross section in the probed volume. The bulk isotopic density of a U-20Pu-10Zr-3Np-2Am nuclear transmutation fuel sample was measured, agrees well with mass-spectrometry and is evidence of the accuracy of the method.

36 MATERIALS SCIENCE↗
NASA NTRS2003

Carbon Nanotube Nanoelectrode Array for Ultrasensitive DNA Detection

A reliable nanoelectrode array based on vertically aligned multi-walled carbon nanotubes (MWNTs) embedded in SiO2 is used for ultrasensitive DNA detection. Characteristic nanoelectrode behavior is observed using low-density MWNT arrays for measuring both bulk and surface immobilized redox species such as K4Fe(CN)6. The open-end of MWNTs present similar properties as graphite edge-plane electrodes with wide potential window, flexible chemical functionalities, and good biocompatibility. Oligonucleotide probes are selectively functionalized at the open ends cf the nanotube array and specifically hybridized with oligonucleotide targets. The guanine groups are employed as the signal moieties in the electrochemical measurements. Ru(bpy)3(2+) mediator is used to further amplify the guanine oxidation signal. The hybridization of subattomoles of PCR amplified DNA targets is detected electrochemically by combining the MWNT nanoelectrode array with the Ru(bpy)32' amplification mechanism. This system provides a general platform of molecular diagnostics for applications requiring ultrahigh sensitivity, high-degree of miniaturization, and simple sample preparations.

Li, Jun↗
DOE OSTI2022

Nb₃Sn Coating of a 2.6 GHz SRF Cavity by Sputter Deposition Technique

Nb₃Sn is of interest as a coating for SRF cavities due to its higher transition temperature Tc ~18.3 K and superheating field Hsh ~400 mT, both are twice that of Nb. Nb₃Sn coated cavities can achieve high-quality factors at 4 K and can replace the bulk Nb cavities operated at 2 K. A cylindrical magnetron sputtering system was built, commissioned, and used to deposit Nb₃Sn on the inner surface of a 2.6 GHz single-cell Nb cavity. With two identical cylindrical magnetrons, this system can coat a cavity with high symmetry and uniform thickness. Using Nb-Sn multilayer sequential sputtering followed by annealing at 950°C for 3 hours, polycrystalline Nb₃Sn films were first deposited at the equivalent positions of the cavity’s beam tubes and equator. The film’s composition, crystal structure, and morphology were characterized by energy dispersive spectroscopy, X-ray diffraction, and atomic force microscopy. The Tc of the films was measured by the four-point probe method and was 17.61 to 17.76 K. Based on these studies, ~1.2 micron thick Nb₃Sn was deposited inside a 2.6 GHz Nb cavity. We will discuss first results from samples and cavity coatings, and the status of the coating system.

43 PARTICLE ACCELERATORS↗
DOE OSTI2024

SAIL Storm Boards 2022-2023

“Storm Boards” are simple installations comprised of a horizontal white plastic board that is placed in situ on the surface of the snowpack with a 1 m vertical marker pole for identifying the board center and approximate new snow height. Storm boards allow newly fallen snow to accumulate on them while staying separated from moisture and energy exchange with the snowpack, thus creating a discrete sample of newly fallen snow depth & SWE (snow water equivalent) that can be measured to calculate the net moisture input of individual or multiple storm events to the seasonal snowpack. Samples are measured with a 2” diameter plastic tube that allows the observer to non destructively take a snow core of the newly deposited snow; this core is weighed with a small hand scale - then the mass of the sample is converted to SWE. Depth of the snow sample is obtained with a snow depth probe or from graduated marks on the plastic tube. 3 or more replicate samples are taken for each board measurement and averaged. Total snow height (HS) of the snowpack is measured with a snow depth probe for each site & timepoint to track snowpack accumulation/ablation.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2017

NIAC Swarm Flyby Gravimetry Phase II Report

This NASA Innovative Advanced Concept (NIAC) grant has enabled the research and development of a method for conducting small body gravimetry from a spacecraft, using relative measurements to a set of deployed test-masses. The test-masses are tracked from a host spacecraft, which dispenses them near to the small body's surface. Thanks to this close proximity, the probes' orbits can be highly perturbed, which yields useful gravimetric measurements. The most readily achievable approach for tracking the probes is to use an optical instrument on- board the spacecraft. The probes then need only be reflective to sunlight. This implementation, called optical gravimetry (OpGrav), has the fewest requirements for the host spacecraft and probes.The results of this study indicate that OpGrav is feasible and offers meaningful improvement over existing methods. Parametric studies suggest roughly an order of magnitude improvement in accuracy or asteroid accessibility (how small an asteroid one can measure) over Earth-based Doppler-only mass estimation. This exponentially expands the number of potential near-Earth objects that one could study, which has implications for planetary defense.As a sample mission, we evaluated OpGrav as an added instrument on a main- belt asteroid tour mission. In this case, simulations show that OpGrav would increase the number of asteroid mass estimates from 3 of 9 to 7 of 9. That is, OpGrav has sufficient sensitivity to offer utility in missions for which it is not explicitly designed for.We designed and fabricated a prototype hardware implementation for this concept called the Small-body In-situ Multi-probe Mass Estimation Experiment (SIMMEE). This hardware provides a basis for many inputs into the simulations and grounds the models with physical values. The primary design driver for the hardware is a long life, on the order of five years prior to operation, and a need for high pointing accuracy to enable flybys of the smallest objects.The next steps include further hardware testing and extension of the concept to rendezvous cases. We believe that this concept offers planetary scientists a new and relevant means of better understanding small-bodies.

Atchison, Justin A.↗
DOE OSTI2024

Dynamical Nonlinear Inversion of the Surface Photovoltage at Si(100)

A surface photovoltage (SPV) is observed whenever a doped semiconductor with non-negligible band bending is illuminated by light and charge carriers are excited across the band gap. The sign of the SPV depends on the nature of the doping, the amplitude of the SPV increases with the fluence of the light illumination up to a saturation value, which is determined by the doping concentration. We have investigated Si(100) samples with well-characterized doping levels over a wide range of illumination fluences. Surprisingly, the sign of the SPV upon illumination with 532 nm photons reverses for some p-doping concentrations at high fluences. This is a new effect associated with a crossover between electronic excitations in the bulk and at the surface of the semiconductor.

14 SOLAR ENERGY↗
DOE OSTI2025

A Perspective into Operando Methods for Probing Catalytic Interfaces

Rational design of electrocatalysts for (photo)electrochemical (PEC) processes like hydrogen and oxygen evolution and CO2 reduction reactions is aided by the recent improvements in capabilities of operando measurements, where morphology, composition, and/or function are probed during active catalysis. Through operando microscopy and spectroscopy, structure, catalytic microenvironment, oxidation state, adsorbates, and products can be measured to gain a better understanding of catalyst behavior and suggest possible improvements. Visualizing evolving catalyst morphologies, surface compositions, and electrochemical behavior also helps address many fundamental research questions for a better understanding of catalytic mechanisms. Correlating morphology with chemical identity or functional behavior using a variety of innovative microscopy methods is particularly promising for guiding development of next generation catalysts, and there are also many recent examples of using AI and robotics tools to innovate and speed development. In this Perspective, advances made over the past few years in operando imaging of catalysts relevant to solar fuels will be explored, followed by an outlook on technological developments in instrumentation, sample design, and computational power that may be applied to this field.

Catalysts↗
DOE OSTI2025

Molten Salt Synthesis of Increased (100)-Facet and Polycrystalline Nickel Oxide Nanoparticles for the Oxygen Evolution Reaction: Impact of Facet and Crystallinity on Electrocatalysis

Nickel oxide nanocubes with increased (100) surface facet presence (NiO(100)) were synthesized through a molten salt synthesis procedure to probe their oxygen evolution reaction (OER) activity in order to investigate the relationship between the surface facet and OER performance. While altering the synthesis parameters to decrease NiO(100) particle sizes and agglomeration, a polycrystalline NiO nanoparticle system formed from using Li2O as a Lux-Flood base (labelled Li2O-MSS NiO, where MSS stands for molten salt synthesis). This novel synthesis was further elaborated and the obtained materials were also tested for OER activity. After thorough structural characterization to determine crystallinity, lattice spacings, and elemental distribution, their OER activity was compared versus high surface area NiO(111) nanosheets in a three-electrode rotating disk electrode (RDE) system. The activity trend of (111) > Li2O-MSS > (100) was observed. This decrease in activity of the nanocube and polycrystalline samples was explained by differences between theoretical and experimental conditions, differences in ink rheology and resulting catalyst layer properties, and significant agglomeration seen in the imaging of the sample. Methods for improving the OER activity of these samples are discussed in the conclusion of this study.

08 HYDROGEN↗
DOE OSTI2017

CURRENT STATUS OF THE CHARACTERIZATION OF RPV MATERIALS HARVESTED FROM THE DECOMMISSIONED ZION UNIT 1 NUCLEAR POWER PLANT

The decommissioning of Units 1 and 2 of the Zion Nuclear Power Station in Zion, Illinois, after ~ 15 effective full-power years of service presents a unique opportunity to characterize the degradation of in-service reactor pressure vessel (RPV) materials and to assess currently available models for predicting radiation embrittlement of RPV steels [1-3]. Moreover, through-wall thickness attenuation and property distributions are being obtained and the results to be compared with surveillance specimen test data. It is anticipated that these efforts will provide a better understanding of materials degradation associated with extending the lifetime of existing nuclear power plants (NPPs) beyond 60 years of service and subsequent license renewal. In support of extended service and current operations of the US nuclear reactor fleet, the Oak Ridge National Laboratory (ORNL), through the U.S. Department of Energy, Light Water Reactor Sustainability (LWRS) Program, coordinated procurement of materials, components, and other items of interest from the decommissioned Zion NPPs. In this report, harvesting, cutting sample blocks, machining test specimens, test plans, and the current status of materials characterization of the RPV from the decommissioned Zion NPP Unit 1 will be discussed. The primary foci are the circumferential, Linde 80 flux, wire heat 72105 (WF-70) beltline weld and the A533B base metal from the intermediate shell harvested from a region of peak fluence (0.7 X 1019 n/cm2, E > 1.0 MeV) on the internal surface of the Zion Unit 1 vessel. Following the determination of the through-thickness chemical composition, Charpy impact, fracture toughness, tensile, and hardness testing are being performed to characterize the through-thickness mechanical properties of base metal and beltline-weld materials. In addition to mechanical properties, microstructural characterizations are being performed using various microstructural techniques, including Atom Probe Tomography, Small Angle Neutron Scattering, and Positron Annihilation Spectroscopy

Rosseel, T. M.↗
DOE OSTI2012

Ring Walking/Oxidative Addition Reactions for the Controlled Synthesis of Conjugated Polymers

Power conversion efficiencies of plastic solar cells depend strongly on the molecular weight characteristics of the semiconducting polymers used for their fabrication. The synthesis of these materials typically relies on transition metal mediated catalytic reactions. In many instances, the ideal structures cannot be attained because of deficiencies in these reactions, particularly when it comes to being able to achieve high number average molecular weights and narrow molecular weight distributions. Another important conjugated polymer structure of interest is one in which a single functional group is attached at the end group of the chain. Such systems would be ideal for modifying surface properties at interfaces and for labeling biomolecular probes used in fluorescent biosensors. To respond to the challenges above, our efforts have centered on the design of homogenous transition metal complexes that are easy to prepare and effective in carrying out living, or quasi-living, condensative chain polymerization reactions. The key mechanistic challenge for the success of this reaction is to force the insertion of one monomer unit at a time via a process that involves migration of the transition metal-containing fragment to one terminus of the polymer chain. Chain growth characteristics are therefore favored when the metal does not dissociate from the newly formed reductive elimination product. We have proposed that dissociation is disfavored by the formation of a -complex, in which the metal can sample various locations of the electronically delocalized framework, a process that we term ring-walking , and find the functionality where oxidative addition takes place. Success has been achieved in the nickel-mediated cross coupling reaction of Grignard reagents with aromatic halides by using bromo[1,2-bis(diphenylphosphino)ethane]phenylnickel. This reagent can yield poly(thiophene)s (one of the most widely used type of polymer in plastic solar cells) with excellent stereoregularity and molecular weight distributions with polydispersities that are consistent with a living polymerization sequence. Another important objective of this program concerned the use of these new catalysts and improved mechanistic insight for the synthesis of specific polymeric materials with prespecified properties.

14 SOLAR ENERGY↗
DOE OSTI2023

Soliton formation and topology manipulation of coupled spins via ultrafast re-magnetization

The major goal of the project was to explore the properties of magnetic order driven far out of equilibrium by optical excitations. These include fundamental questions related to the interplay of magnetic, structural and electronic degrees of freedom in materials that are optically excited. These problems break down in short term quenching of the magnetization as a results of the energy of the optical pulse studying how the energy of the optical pulse and the angular momentum of the magnetization flow between the different degrees of freedom. This is followed by the longer time re-emergence of the magnetism as the system cools. Within this goal we explored the formation of solitons, both with and without non-trivial topology, via rapid re-magnetization processes after optical-driven ultrafast demagnetization. Guided by theory, we predict that turbulence and modulational instabilities will drive the formation of solitons, including dispersive shock waves, magnon droplets, and skyrmions. In the case of topological defect formation, i.e. skyrmion generation, related processes have long been predicted based on general principles of symmetry-breaking phase transitions; the density of topological defects in a long-range-ordered phase can be controlled by varying the quench rate through the second-order phase transition, i.e. the Kibble-Zurek (KZ) mechanism. We, more broadly, had the goal to study a range of other emergent magnetic behaviors after optical excitation. While great attention has been given to ultrafast demagnetization, less is known of the subsequent spin dynamics and coupling to the lattice. What is increasingly appreciated is that ultrafast demagnetization leads to spin currents that can carry angular momentum from the rapidly demagnetized sample. These spin currents appear in many ways but fundamentally controls demagnetization, drives interactions between regions of the material, and control the spin resulting structure. They can be probed many ways including THz emission which, in turn, gives insight into the demagnetization processes. Simultaneously if there is magneto-elastic coupling ultrafast demagnetization can drive structural excitations that are not expected from thermal energy added to the lattice. We explored a range of complex phenomena that arise from photo-excitation of magnetic systems with the coupling of electronic, magnetic and structural degrees of freedom. We have made a number of fundamental discoveries that are reflected in our publications list with additional work still being prepared for publication. Highlights of this work include (i) ultra-efficient, nonlinear THz surface acoustics (ii) spin-current-mediated rapid magnon localization and coalescence, (iii) spin-wave soliton formation in ferromagnetic FePt nanoparticles, (iv) dynamic phonon coupling in elemental antiferromagnetic Cr, (v) THz emission from Co/Pt bilayers and FeRh/Pt bilayers, (vi) theoretical investigation of spin hydrodynamics, solitons and shock waves, and (vii) ultrafast perturbation of magnetic domains by optical pumping.

36 MATERIALS SCIENCE↗
NASA NTRS1990

Design of a scientific probe for obtaining Mars surface material

With the recent renewed interest in interplanetary and deep space exploratory missions, the Red Planet, Mars, which has captured people's imagination for centuries, has again become a center of attention. In the late 1960s and early 1970s, a series of Mariner missions performed fly-by investigations of the Mars surface and atmosphere. Later, in the mid 1970s, the data gathered by these earlier Mariner missions provided the basis of the much-publicized Viking missions, whose main objective was to determine the possibility of extraterrestrial life on Mars. More recently, with the dramatic changes in international politics, ambitious joint manned missions between the United States and the Soviet Union have been proposed to be launched in the early 21st century. In light of these exciting developments, the Spacecraft Design course, which was newly established at UCLA under NASA/USRA sponsorship, has developed its curriculum around a design project: the synthesis of an unmanned Martian landing probe. The students are required to conceive a preliminary design of a small spacecraft that is capable of landing at a designated site, collecting soil samples, and then returning the samples to orbit. The goal of the project is to demonstrate the feasibility of such a mission. This preliminary study of an interplanetary exploration mission has shown the feasibility of such a mission. The students have learned valuable lessons about the complexity of spacecraft design, even though the mission is relatively simple.

Source record↗