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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 919 records · Page 51
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Optimized Carbon Fiber Composites in Wind Turbine Blade Design: Follow-On Studies

This project has identified opportunities to bring further reductions in the mass and cost of modern wind turbine blades through the use of alternative material systems and manufacturing processes. The fiber reinforced polymer material systems currently used by the wind industry have stagnated as the technology continues to mature and as a means to reduce risk while introducing new products with continually increasing blade lengths. However, as blade lengths continue to increase, the challenge of controlling blade mass becomes even more critical to enabling the associated levelized cost of energy reductions. Stiffer and stronger reinforcement fibers can help to resolve the challenges of meeting the loading demands while limiting the increase in weight, but these materials are substantially more expensive than the traditional E-glass fiber systems. One goal of this project and associated work is to identify pathways that improve the cost-effectiveness of carbon fiber such that it is the reinforcement of choice in the primary structural elements of wind blades. The use of heavy-tow textile carbon fiber material systems has been shown to reduce the blade mass by 30-31% when used in the spar cap and by up to 7% when used in edgewise reinforcement. A pultrusion cost model was developed to enable a material cost comparison that includes an accurate estimate of the intermediate manufacturing step of pultrusion for the carbon fiber composite. Material cost reductions were revealed in most cases for the heavy-tow textile carbon fiber compared to infused fiberglass. The use of carbon fiber in the edgewise reinforcement produced the most notable material cost reduction of 33% for the heavy-tow textile carbon fiber. The mass and cost savings observed when using carbon fiber in edgewise reinforcement demonstrate a clear opportunity of this design approach. A carbon fiber conversion cost model was expanded to include a characterization of manufacturing costs when using advanced conversion processes with atmospheric plasma oxidation. This manufacturing approach was estimated to reduce the cost of carbon fiber material systems by greater than 10% and can be used with textile carbon systems or traditional carbon fiber precursors. The pultrusion cost model was also used to assess the opportunity for using pultruded fiberglass in wind blades, studying conventional E-glass fiber reinforcement. When using pultruded fiberglass as the spar cap material for two design classifications, the blade weight was reduced by 6% and 9% compared to infused fiberglass. However, due to the relatively large share of the pultrusion manufacturing cost compared to fiber cost, the spar cap material cost increased by 12% and 7%. When considering the system benefits of reduced blade mass and potentially lower blade manufacturing costs for pultruded composites, there may be opportunity for pultruded E-glass in wind blade spar caps, but further studies are needed. There is a clearer outcome for using pultruded fiberglass in the edgewise reinforcement where it resulted in a blade mass reduction of 2% and associated reinforcement material cost reduction of 1% compared to infused E-glass. The use of higher performing glass fibers, such as S-glass and H-glass systems, will produce greater mass savings but a study is needed to assess the cost implications for these more expensive systems. The most likely opportunity for these high-performance glass fibers is in the edgewise reinforcement, where the increased strength will reduce the damage accumulation of this fatigue-driven component. The blade design assessments in this project characterize the controlling material properties for the primary structural components in the flapwise and edgewise directions for modern wind blades. The observed trends with low and high wind speed turbine classifications for carbon and glass fiber reinforced polymer systems help to identify where cost reductions are needed, and where improvements in mechanical properties would help to reduce the material demands.

17 WIND ENERGY↗
DOE OSTI2025

Direct solar self-catalyzing pyrolysis of natural gas to hydrogen and high-quality graphite (Final Technical Report)

This project, led by researchers at UCLA in partnership with Southwest Solar Technology (SST) and SolGrapH, successfully demonstrated a new method for producing clean hydrogen fuel and high-quality graphite using concentrated solar energy. The primary goal was to develop a technology that converts natural gas (primarily methane) into two valuable products—hydrogen gas and solid carbon—without releasing carbon dioxide (CO2) into the atmosphere. This process, known as solar thermal pyrolysis, uses heat from the sun to split the methane molecules directly.

03 NATURAL GAS↗
DOE OSTI2026

Spatial Heterogeneity in Cloud Condensation Nuclei (SHINE) Field Campaign Report

Multiple land-atmosphere coupling processes influence the spatial distribution of boundary-layer energy, moisture, aerosol, or cloud condensation nuclei (CCN) properties. Accurately quantifying the spatial and temporal distributions of CCN concentrations is essential for investigating aerosol-cloud interactions and reducing uncertainties in aerosol radiative forcing estimates of Earth's system.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Evaluation of PBL Parameterization Schemes in WRF Model Predictions during the Dry Season of the Central Amazon Basin

Planetary Boundary Layer (PBL) parameterization schemes are employed to handle subgrid-scale processes on atmospheric models, playing a key role in accurately representing the atmosphere. Recent studies have shown that PBL schemes are particularly fundamental to the depiction of PBL height (PBLH), especially over the Amazon. In the present study, we investigated the performance of PBL schemes on the representation of meteorological variables, turbulent fluxes, PBL vertical structures, and PBLH over the central Amazon basin under dry conditions, taking advantage of observations from the Observations and Modeling of the Green Ocean Amazon campaign (GoAmazon2014/5) for validation and evaluation. Numerical experiments were carried out within the WRF model using eight PBL schemes for two dry periods from 2014 (typical year) and 2015 (El-Niño year), and results from the 1-km resolution domain were directly compared to hourly in situ observations. In general, all PBL schemes present good performance to reproduce meteorological variables, with nonlocal (local) PBL schemes producing better performance in the 2014 (2015) study period. All PBL schemes in general overestimate (>100%) daytime turbulent fluxes. Thermodynamic (daytime) vertical structures are better predicted than mechanical (nocturnal) ones. The local MYNN2.5 scheme showed the overall best performance for PBLH prediction, mainly at night.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Atmospheric oxidation in the presence of clouds during the Deep Convective Clouds and Chemistry (DC3) study

Deep convective clouds are critically important to the distribution of atmospheric constituents throughout the troposphere but are difficult environments to study. The Deep Convective Clouds and Chemistry (DC3) study in 2012 provided the environment, platforms, and instrumentation to test oxidation chemistry around deep convective clouds and their impacts downwind. Measurements on the NASA DC-8 aircraft included those of the radicals hydroxyl (OH) and hydroperoxyl (HO 2 ), OH reactivity, and more than 100 other chemical species and atmospheric properties. OH, HO 2 , and OH reactivity were compared to photochemical models, some with and some without simplified heterogeneous chemistry, to test the understanding of atmospheric oxidation as encoded in the model. In general, the agreement between the observed and modeled OH, HO 2 , and OH reactivity was within the combined uncertainties for the model without heterogeneous chemistry and the model including heterogeneous chemistry with small OH and HO 2 uptake consistent with laboratory studies. This agreement is generally independent of the altitude, ozone photolysis rate, nitric oxide and ozone abundances, modeled OH reactivity, and aerosol and ice surface area. For a sunrise to midday flight downwind of a nighttime mesoscale convective system, the observed ozone increase is consistent with the calculated ozone production rate. Even with some observed-to-modeled discrepancies, these results provide evidence that a current measurement-constrained photochemical model can simulate observed atmospheric oxidation processes to within combined uncertainties, even around convective clouds. For this DC3 study, reduction in the combined uncertainties would be needed to confidently unmask errors or omissions in the model chemical mechanism.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber

Abstract. Atmospheric oxidation is an important phenomenon which produces large quantities of low-volatility compounds such as sulfuric acid and oxidized organic compounds. Such species may be involved in the nucleation of particles and enhance their subsequent growth to reach the size of cloud condensation nuclei (CCN). In this study, we investigate α -pinene, the most abundant monoterpene globally, and its oxidation products formed through ozonolysis in the Cosmic Leaving Outdoor Droplets (CLOUD) chamber at CERN(the European Organization for Nuclear Research). By scavenging hydroxyl radicals (OH) with hydrogen (H 2 ), we were able to investigate the formation of highly oxygenated molecules (HOMs) purely driven by ozonolysis and study the oxidation of sulfur dioxide (SO 2 ) driven by stabilized Criegee intermediates (sCIs). We measured the concentrations of HOM and sulfuric acid with a chemical ionization atmospheric-pressure interface time-of-flight (CI-APi-TOF) mass spectrometer and compared the measured concentrations with simulated concentrations calculated with a kinetic model.We found molar yields in the range of 3.5–6.5 % for HOM formation and 22–32 % for the formation of stabilized Criegee intermediates by fitting our model to the measured sulfuric acid concentrations. The simulated time evolution of the ozonolysis products was in good agreement with measured concentrations except that in some of the experiments sulfuric acid formation was faster than simulated. In those experiments the simulated and measured concentrations met when the concentration reached a plateau but the plateau was reached 20–50 min later in the simulations. The results shown here are consistent with the recently published yields for HOM formation from different laboratory experiments. Together with the sCI yields, these results help us to understand atmospheric oxidation processes better and make there action parameters more comprehensive for broader use.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics

Abstract. Adsorption and desorption of gases on liquid or solid substrates are involved in multiphase processes and heterogeneous chemical reactions. The desorption energy (Edes0), which depends on the intermolecular forces between adsorbate and substrate, determines the residence time of chemical species at interfaces. We show how Edes0 and temperature influence the net uptake or release of gas species, the rates of surface–bulk exchange and surface or bulk reactions, and the equilibration timescales of gas–particle partitioning. Using literature data, we derive a parameterization to estimate Edes0 for a wide range of chemical species based on the molecular mass, polarizability, and oxygen-to-carbon ratio of the desorbing species independent of substrate-specific properties, which is possible because of the dominant role of the desorbing species' properties. Correlations between Edes0 and the enthalpies of vaporization and solvation are rooted in molecular interactions. The relation between Edes0 and desorption kinetics reflects the key role of interfacial exchange in multiphase processes. For small molecules and semi-volatile organics (VOC, IVOC, SVOC), Edes0 values around 10–100 kJ mol−1 correspond to desorption lifetimes around nanoseconds to days at room temperature. Even higher values up to years are obtained at low temperatures and for low volatile organic compounds (LVOC, ELVOC/ULVOC) relevant for secondary organic aerosols (SOA). Implications are discussed for SOA formation, gas–particle partitioning, organic phase changes, and indoor surface chemistry. We expect these insights to advance the mechanistic and kinetic understanding of multiphase processes in atmospheric and environmental physical chemistry, aerosol science, materials science, and chemical engineering.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Organic Acid Aerosol Measurements from the Mount Airy Site for CoURAGE

This study investigates the prevalence and distribution of organic acid aerosols in a rural environment using filter-based measurements collected in Mount Airy, Maryland, during the CoURAGE campaign from March 19th through June 12th 2025. PM2.5 filters quantify a range of organic acids commonly associated with secondary organic aerosol formation and atmospheric oxidation processes. Each filter was collected using a 15 LPM sampler and was extracted in ultrapure Millipore water (>18 MΩ), allowing water-soluble organic acids to be extracted into solution for analysis. The extracts were then examined using a Waters Acquity I-Class PLUS liquid chromatography system coupled to a Bruker Maxis-II ultra-high-resolution Q-TOF mass spectrometer with electrospray ionization, providing high-sensitivity detection and separation of target compounds. Concentrations of several key organic acids were quantified, including acetic, propionic, pyruvic, butyric, oxalic, isovaleric, valeric, malonic, maleic, succinic, glutaric, malic, adipic, and citric acids. These findings contribute to ongoing efforts to understand regional aerosol composition and their impacts on aerosol-cloud interactions.

Acetic acid↗
DOE OSTI2017

Northern Arabian Sea Circulation-Autonomous Research (NASCar): A Research Initiative Based on Autonomous Sensors

The Arabian Sea circulation is forced by strong monsoonal winds and is characterized by vigorous seasonally reversing currents, extreme differences in sea surface salinity, localized substantial upwelling, and widespread submesoscale thermohaline structures. Its complicated sea surface temperature patterns are important for the onset and evolution of the Asian monsoon. This article describes a program that aims to elucidate the role of upper-ocean processes and atmospheric feedbacks in setting the sea surface temperature properties of the region. The wide range of spatial and temporal scales and the difficulty of accessing much of the region with ships due to piracy motivated a novel approach based on state-of-the-art autonomous ocean sensors and platforms. The extensive data set that is being collected, combined with numerical models and remote sensing data, confirms the role of planetary waves in the reversal of the Somali Current system. These data also document the fast response of the upper equatorial ocean to monsoon winds through changes in temperature and salinity and the connectivity of the surface currents across the northern Indian Ocean. New observations of thermohaline interleaving structures and mixing in setting the surface temperature properties of the northern Arabian Sea are also discussed.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1970

Spectra of faint optical meteors

Spectra of faint optical meteors for chemical abundance, discussing radiative processes during atmospheric entry, Leonid meteors and data acquisition

Harvey, G. A.↗
NASA NTRS1972

Mathematics of Profile Inversion

One-dimensional and multi-dimensional inversion techniques for processing remote atmospheric and ionospheric sounding data

Colin, L.↗
NASA NTRS1978

Nightglow emissions of OH/X 2 pi/ - Comparison of theory and measurements in the /9-3/ band

The visible airglow experiments on the Atmosphere Explorer C and E satellites have viewed the (9-3) band nightglow emission of the excited hydroxyl radical in the lower thermosphere at tropical latitudes. The surface brightnesses observed at similar local times vary by approximately a factor of 2. Comparison of the measurements with time-dependent photochemical calculations shows reasonable agreement and indicates that temporal changes in atmospheric transport processes are the most likely explanation of the nightglow variations.

Frederick, J. E.↗
NASA NTRS1978

Aeronomy of Saturn and Titan

The Saturn system presents exciting and unique objects for planetary aeronomy. The photochemistry of H2 and He leads to the formation of an ionosphere. Methane photolysis results in the formation of spectroscopically detectable amounts of C2H6 and C2H2 and in the case of Titan, C2H4. Density profiles of C2H6, C2H2, and PH3 should be indicative of the strength of atmospheric mixing processes.

Strobel, D. F.↗
NASA NTRS1980

The distribution of temperature maxima for micrometeorites decelerated in the earth's atmosphere without melting

A simple model for the statistics of heating of micrometeorites decelerated in the earth's atmosphere without melting predicts that for 10 micron particles with thermal emissivity near 1, roughly half of those with density 1 g/cc are heated above 550 C, while half of those with density 3 g/cc are heated above 800 C. In the study of stratosphere collected interplanetary dust, the model can be helpful in identifying petrographic thermometers of the atmospheric entry process, and in understanding the most recent history of this new class of extraterrestrial material available in the laboratory.

Fraundorf, P.↗