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At least 919 records · Page 51

Summary of FY2024 Experimental Results to Support Development of New Inelastic Material Models and Validation of Section III, Division 5, Class A Design Rules

To address the data gap crucial for updating existing viscoplastic constitutive material models for the Class A materials in the American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel Code, Section III, Division 5, High Temperature Reactors (ASME, 2023) for inelastic design analysis, Oak Ridge National Laboratory (ORNL) conducted experimental studies on Alloy 800H and Alloy 617 across a range of temperatures up to their maximum temperature limits in Section III, Division 5. The studies aim to characterize the materials' deformation behavior under both strain-controlled mechanical cyclic loading and thermal cycling conditions. This report summarizes ORNL's FY 2024 experimental findings on Alloy 800H and Alloy 617, focusing on pure fatigue tests, cyclic stress-strain curves, thermomechanical fatigue experiments, and verification of the high temperature cyclic damage summation design rules.

36 MATERIALS SCIENCE↗

ASME Section III, Division 5, Class A 100,000-hour design data for Alloy 709

This report documents the 100,000 hour, Class A ASME design material data for Alloy 709 based on the extensive Department of Energy, Office of Nuclear Energy, Advanced Reactor Technologies qualification test campaign. This report includes design tensile properties, creep rupture data, allowable stresses, isochronous stress-strain curves, buckling charts, and a few additional miscellaneous pieces of design data. Companion work at Oak Ridge National Laboratory and Argonne National Laboratory provide design cyclic data --- fatigue charts and creep-fatigue diagrams --- and an inelastic constitutive model. This work substantially completes the ASME data package for the Alloy 709 Code Case, though the design data will continue to updated as the final tests finish. This report also compares the design performance of Alloy 709 against that of 316H stainless steel to provide a reference for the improved high temperature strength of 709 compared to a reference material for sodium fast reactor construction.

36 MATERIALS SCIENCE↗

Megawatt-Class, High-Voltage SiC Power Electronics Converters for Advanced Manufacturing with Grid Support Services

DE-EE0009135 aimed to push the 10kV SiC MOSFET based power electronics to 3-phase 13.8kV 10MW to be used as a Megawatt Class Medium-Voltage Power Conditioning Systems – PCS – to enable “Resilient Distribution through Grid-dispatching and Uninterrupted Quality Power to Manufacturing Facilities” during transitory grid disturbances. As a stretch to those goals, Eaton added the load power peak shaving opportunity.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Alloy 625 Qualification Pathway for ASME Section III Division 5 Class A construction

The American Society of Mechanical Engineers Boiler and Pressure Vessel Code Section III Division 5 provides construction and inspection rules to ensure the safety of nuclear components operating at elevated temperatures, defined as those operating above 700°F (370°C) or 800°F (425°C), depending on the material type. At present, there are six materials approved for Class A (high safety significance) component construction under ASME BPVC Section III Division 5. Out of these six materials, five materials are steels or iron-based alloys and one material, Alloy 617, is a nickel alloy. Nickel alloys are stronger than steels; however, Alloy 617 consists of 10-15% cobalt, and activation is a concern under irradiation. Therefore, there is a need to qualify new nickel alloy with lower cobalt content. Alloy 625 is one candidate which has similar mechanical properties at elevated temperature compared to Alloy 617 and has a maximum of 1% cobalt. Although Alloy 625 material properties have been developed in the past to support allowable stress development under ASME Section II, new test results would be needed to qualify this material for elevated temperature component construction under ASME Section III Division 5. The purpose of this report is to describe a path towards developing a Nuclear Code Case to qualify Alloy 625 (UNS N06625; Grade 1 and Grade 2) for elevated temperature nuclear use in accordance with the ASME BPVC rules. This report reviews the existing database on Alloy 625, presents proposed test campaign, and discusses potential paths for accelerating the accelerated material qualification process.

36 - MATERIALS SCIENCE↗

PFLOTRAN: Reactive Flow & Transport Code for Use on Laptops to Leadership-Class Supercomputers. In: Groundwater Reactive Transport Models

PFLOTRAN, a next-generation reactive flow and transport code for modeling subsurface processes, has been designed from the ground up to run efficiently on machines ranging from leadership-class supercomputers to laptops. Based on an object-oriented design, the code is easily extensible to incorporate additional processes. It can interface seamlessly with Fortran 9X, C and C++ codes. Domain decomposition parallelism is employed, with the PETSc parallel framework used to manage parallel solvers, data structures and communication. Features of the code include a modular input file, implementation of high-performance I/O using parallel HDF5, ability to perform multiple realization simulations with multiple processors per realization in a seamless manner, and multiple modes for multiphase flow and multicomponent geochemical transport. Chemical reactions currently implemented in the code include homogeneous aqueous complexing reactions and heterogeneous mineral precipitation/dissolution, ion exchange, surface complexation and a multirate kinetic sorption model. PFLOTRAN has demonstrated petascale performance using 217 processor cores on problems composed of over 2 billion degrees of freedom. The code is currently being applied to simulate uranium transport at the Hanford 300 Area and CO2 sequestration in deep geologic formations.

carbon sequestration↗

Single crystalline thin films as a novel class of electrocatalysts

The ubiquitous use of single crystal metal electrodes has garnered invaluable insight into the relationship between surface atomic structure and functional electrochemical properties. But, the sensitivity of their electrochemical response to surface orientation and the amount of precious metal required can limit their use. We present here a generally applicable procedure for producing thin metal films with a large proportion of atomically flat (111) terraces without the use of an epitaxial template. Thermal annealing in a controlled atmosphere induces long-range ordering of magnetron sputtered thin metal films deposited on an amorphous substrate. The ordering transition in these thin metal films yields characteristic (111) electrochemical signatures with minimal amount of material and provides an adequate replacement for oriented bulk single crystals. Our procedure can be generalized towards a novel class of practical multimetallic thin film based electrocatalysts with tunable near-surface compositional profile and morphology. Annealing of atomically corrugated sputtered thin film Pt-alloy catalysts yields an atomically smooth structure with highly crystalline, (111)-like ordered and Pt segregated surface that displays superior functional properties, bridging the gap between extended/bulk surfaces and nanoscale systems.

36 MATERIALS SCIENCE↗

Leveraging gradient weighted class activation mapping to improve classification effectiveness: Case study in transportation infrastructure characterization

Roadway “corners†are common for pedestrian use, whether designated with markings or not. Different types of markings have been deployed, ranging from simple parallel lines to more complex designs. Understanding the impact of different types of crosswalks is important for public safety. In this work we explore methods to improve the logging of marked crosswalk types. We used the Roadway Information Database from the Second Strategic Highway Research Project and used active learning methods with transfer learning to identify the crosswalk types (marked or unmarked). Upon completion we found our classifiers were unable to perform above roughly 94% correct classifications. To improve their efficacy, we separated the crosswalks into their “fine grained†types and used Gradient-Weighted Class Activation Mapping to isolate and study the features that classified the crosswalks. We compared this with sampled manually marked crosswalks and present findings. We believe this use case can represent a process to improve the active learning method for some visual machine learning applications.

Karnowski, Thomas↗

Hydrophobic, Thermal Shock-and-Corrosion-Resistant XSBR Latex-Modified Lightweight Class G Cement Composites in Geothermal Well Energy Storage Systems

Energy losses can be significantly reduced if thermally insulating cement is used for energy storage and recovery. The thermal conductivity (TC) of the currently used cement is between 1 and 1.2 W/mK. In this study we assessed the ability of polystyrene (PS)–polybutadiene (PB)–polyacrylic acid (PAA) terpolymer (cross-linked styrene–butadiene rubber, XSBR) latex to improve thermal insulating properties and thermal shock (TS) resistance of class G ordinary Portland cement (OPC) and fly ash cenosphere (FCSs) composites in the temperature range of 100–175 °C. The composites autoclaved at 100 °C were subjected to three cycles, one cycle: 175 °C heat → 25 °C water quenching). In hydrothermal and thermal (TS) environments at elevated temperatures in cement slurries the XSBR latex formed acrylic calcium complexes through acid–base reactions, and the number of such complexes increased at higher temperatures due to the XSBR degradation with formation of additional acrylic groups. As a result, these complexes offered the following five advanced properties to the OPC-based composites: (1) enhanced hydrophobicity; (2) decreased water-fillable porosity; (3) reduced TC for water-saturated composites; (4) minimized loss of compressive strength, Young’s modulus, and compressive fracture toughness after TS; and (5) abated pozzolanic activity of FCSs, which allowed FCSs to persist as thermal insulators under strongly alkaline conditions of cement slurries. Additionally, XSBR-modified slurries possessed improved workability and decreased slurry density due to the air-entraining effect of latex, which resulted in further improvement of thermal insulation performance of the modified composites.

15 GEOTHERMAL ENERGY↗

SIMULTANEOUS IRIS AND HINODE/EIS OBSERVATIONS AND MODELING OF THE 2014 OCTOBER 27 X2.0 CLASS FLARE

We present a study of the X2-class flare which occurred on 2014 October 27 and was observed with the Interface Region Imaging Spectrograph (IRIS) and the EUV Imaging Spectrometer (EIS) on board the Hinode satellite. Thanks to the high cadence and spatial resolution of the IRIS and EIS instruments, we are able to compare simultaneous observations of the Fe xxi 1354.08 Å and Fe xxiii 263.77 Å high-temperature emission (≳10 MK) in the flare ribbon during the chromospheric evaporation phase. We find that IRIS observes completely blueshifted Fe xxi line profiles, up to 200 km s{sup −1} during the rise phase of the flare, indicating that the site of the plasma upflows is resolved by IRIS. In contrast, the Fe xxiii line is often asymmetric, which we interpret as being due to the lower spatial resolution of EIS. Temperature estimates from SDO/AIA and Hinode/XRT show that hot emission (log(T[K]) > 7.2) is first concentrated at the footpoints before filling the loops. Density-sensitive lines from IRIS and EIS give estimates of electron number density of ≳10{sup 12} cm{sup −3} in the transition region lines and 10{sup 10} cm{sup −3} in the coronal lines during the impulsive phase. In order to compare the observational results against theoretical predictions, we have run a simulation of a flare loop undergoing heating using the HYDRAD 1D hydro code. We find that the simulated plasma parameters are close to the observed values that are obtained with IRIS, Hinode, and AIA. These results support an electron beam heating model rather than a purely thermal conduction model as the driving mechanism for this flare.

79 ASTRONOMY AND ASTROPHYSICS↗

Detection of linearly polarized 6.9 mm continuum emission from the class 0 young stellar object NGC 1333 IRAS4A

We report new Karl G. Jansky Very Large Array (JVLA), 0--AMP--farcs;5 angular resolution observations of linearly polarized continuum emission at 6.9 mm, toward the class 0 young stellar object NGC 1333 IRAS4A. This target source is a collapsing dense molecular core that was resolved at short wavelengths to have an hourglass shaped B-field configuration. We compare these 6.9 mm observations with previous polarization Submillimeter Array observations at 0.88 mm, which have a comparable angular resolution (∼0--AMP--farcs;7). We find that at the same resolution, the observed polarization position angles at 6.9 mm are slightly deviated from those observed at 0.88 mm. Due to the lower optical depth of the emission at 6.9 mm, and the potential effect of dust grain growth, the new JVLA observations are likely probing B-field alignments in regions interior to those sampled by the previous polarization observations at higher frequencies. Our understanding can be improved with more sensitive observations, and with observations for the more extended spatial scales.

79 ASTRONOMY AND ASTROPHYSICS↗

IGRINS spectroscopy of class I sources: IRAS 03445+3242 and IRAS 04239+2436

We have detected molecular and atomic line emission from the hot and warm disks of two Class I sources, IRAS 03445+3242 and IRAS 04239+2436, using the high-resolution Immersion GRating INfrared Spectrograph (IGRINS). CO overtone band transitions and near-IR lines of Na i and Ca i, all in emission, trace the hot inner disk, while CO rovibrational absorption spectra of the first overtone transition trace the warm gas within the inner few AU of the disk. The emission-line profiles for both sources show evidence for Keplerian disks. A thin Keplerian disk with power-law temperature and column density profiles with a projected rotational velocity of ∼60–75 km s{sup −1} and a gas temperature of ∼3500 K at the innermost annulus can reproduce the CO overtone band emission. Na i and Ca i emission lines also arise from this disk, but they show complicated line features possibly affected by photospheric absorption lines. Multi-epoch observations show asymmetric variations of the line profiles on one-year (CO overtone bandhead and atomic lines for IRAS 03445+3242) or on one-day (atomic lines for IRAS 04239+2436) timescales, implying non-axisymmetric features in disks. The narrow CO rovibrational absorption spectra (v = 0 → 2) indicate that both warm (>150 K) and cold (∼20–30 K) CO gas are present along the line of sight to the inner disk. This study demonstrates the power of IGRINS as a tool for studies of the sub-AU-scale hot and AU-scale warm protoplanetary disks with its simultaneous coverage of the full H and K bands with high spectral resolution (R = 45,000) allowing many aspects of the sources to be investigated at once.

79 ASTRONOMY AND ASTROPHYSICS↗

RELATIONSHIP BETWEEN CHROMOSPHERIC EVAPORATION AND MAGNETIC FIELD TOPOLOGY IN AN M-CLASS SOLAR FLARE

Chromospheric evaporation is observed as Doppler blueshift during solar flares. It plays a key role in the dynamics and energetics of solar flares; however, its mechanism is still unknown. In this paper, we present a detailed analysis of spatially resolved multi-wavelength observations of chromospheric evaporation during an M 1.0-class solar flare (SOL2014-06-12T21:12) using data from NASA’s Interface Region Imaging Spectrograph and HMI/ SDO (the Helioseismic and Magnetic Imager on board the Solar Dynamics Observatory), and high-resolution observations from VIS/NST (the Visible Imaging Spectrometer at the New Solar Telescope). The results show that the averaged over the flare region Fe xxi blueshift of the hot (10{sup 7} K) evaporating plasma is delayed relative to the C ii redshift of the relatively cold (10{sup 4} K) chromospheric plasma by about one minute. The spatial distribution of the delays is not uniform across the region and can be as long as two minutes in several zones. Using vector magnetograms from HMI, we reconstruct the magnetic field topology and the quasi-separatrix layer, and find that the blueshift delay regions as well as the H α flare ribbons are connected to the region of the magnetic polarity inversion line (PIL) and an expanding flux rope via a system of low-lying loop arcades with a height of ≲4.5 Mm. As a result, the chromospheric evaporation may be driven by the energy release in the vicinity of PIL, and has the observed properties due to a local magnetic field topology.

79 ASTRONOMY AND ASTROPHYSICS↗

SLIPPING MAGNETIC RECONNECTION OF FLUX-ROPE STRUCTURES AS A PRECURSOR TO AN ERUPTIVE X-CLASS SOLAR FLARE

We present the quasi-periodic slipping motion of flux-rope structures prior to the onset of an eruptive X-class flare on 2015 March 11, obtained by the Interface Region Imaging Spectrograph and the Solar Dynamics Observatory . The slipping motion occurred at the north part of the flux rope and seemed to successively peel off the flux rope. The speed of the slippage was 30−40 km s{sup −1}, with an average period of 130 ± 30 s. The Si iv λ 1402.77 line showed a redshift of 10−30 km s{sup −1} and a line width of 50−120 km s{sup −1} at the west legs of slipping structures, indicative of reconnection downflow. The slipping motion lasted about 40 minutes, and the flux rope started to rise up slowly at the late stage of the slippage. Then an X2.1 flare was initiated, and the flux rope was impulsively accelerated. One of the flare ribbons swept across a negative-polarity sunspot, and the penumbral segments of the sunspot decayed rapidly after the flare. We studied the magnetic topology at the flaring region, and the results showed the existence of a twisted flux rope, together with quasi-separatrix layer (QSL) structures binding the flux rope. Our observations imply that quasi-periodic slipping magnetic reconnection occurs along the flux-rope-related QSLs in the preflare stage, which drives the later eruption of the flux rope and the associated flare.

79 ASTRONOMY AND ASTROPHYSICS↗

ON THE RELATIONSHIP OF UC H ii REGIONS AND CLASS II METHANOL MASERS. I. SOURCE CATALOGS

We conducted Very Large Array C-configuration observations to measure positions and luminosities of Galactic Class II 6.7 GHz methanol masers and their associated ultra-compact H ii regions. The spectral resolution was 3.90625 kHz and the continuum sensitivity reached 45 μ Jy beam{sup −1}. We mapped 372 methanol masers with peak flux densities of more than 2 Jy selected from the literature. Absolute positions have nominal uncertainties of 0.″3. In this first paper on the data analysis, we present three catalogs; the first gives information on the strongest feature of 367 methanol maser sources, and the second provides information on all detected maser spots. The third catalog presents derived data of the 127 radio continuum counterparts associated with maser sources. Our detection rate of radio continuum counterparts toward methanol masers is approximately one-third. Our catalogs list properties including distance, flux density, luminosity, and the distribution in the Galactic plane. We found no significant relationship between luminosities of masers and their associated radio continuum counterparts, however, the detection rate of radio continuum emission toward maser sources increases statistically with the maser luminosities.

79 ASTRONOMY AND ASTROPHYSICS↗