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At least 919 records · Page 51

Integrated Microreactor for Chemical and Biochemical Applications

A completely integrated microreactor was developed that allows for the processing of very small amounts of chemical solutions. The entire system comprises several pumps and valves arranged in different branches as well as a mixing unit and a reaction chamber. The streaming path of each branch contains two valves and one pump each. The pumps are driven by piezoelectric elements mounted on thin glass membranes. Each pump is about 3.5 mm x 3.5 mm x 0.7 mm. A pumping rate up to 25 microliters per hour can be achieved. The operational voltage ranges between 40 and 200 V. A volume stroke up to 1.5 millimeter is achievable from the membrane structures. The valves are designed as passive valves. Sealing is by thin metal films. The dimension of a valve unit is 0.8 x 0.8. 07 mm. The ends of the separate streaming branches are arranged to meet in one point. This point acts as the beginning of a mixer unit which contains several fork-shaped channels. The arrangement of these channels allows for the division of the whole liquid stream into partial streams and their reuniting. A homogeneous mixing of solutions and/or gases can be observed after having passed about 10 of the fork elements. A reaction chamber is arranged behind the mixing unit to support the chemical reaction of special fluids. This unit contains heating elements placed outside of the chamber. The complete system is arranged in a modular structure and is built up of silicon. It comprises three silicon wafers bonded together by applying the silicon direct bonding technology. The silicon structures are made only by wet chemical etching processes. The fluid connections to the outside are realized using standard injection needles glued into v-shaped structures on the silicon wafers. It is possible to integrate other components, like sensors or electronic circuits using silicon as the basic material.

Schwesinger, N.↗

Modular Biomass Gasification for Co-Production of Hydrogen and Power

The overall goal of this project was to demonstrate a novel process-intensified and modular Combined Hydrogen, Heat and Power (CH 2 P) production technology, targeting commercial scales of 5-to-10-megawatt electric (MWe) equivalent of hydrogen (H 2 ). The process technology integrates a novel adaptation of the steam-iron process to produce high purity H 2 from gasification of biomass and biomass blends with a compression-ready carbon dioxide (CO 2 ) stream, enabling significant progress towards achieving $1 per kilogram (kg) cost for clean H 2 .

08 HYDROGEN↗

Steepening of nonlinear waves in the solar wind.

Two shock-like structures (i.e., abrupt step-like increases in number density, bulk speed, and proton temperature) were found in the data from Mariner 5 at 0.98 AU on June 26 and at 0.85 AU on Aug. 29, 1967. The thickness of these 'structures' determined from the magnetic field data was more than 1000 proton Larmor radii. They were also observed by Explorer 33, 34, and 35 at 1 AU, where the thicknesses were much smaller than in the Mariner 5 data. It is suggested that these two structures were nonlinear magnetoacoustic waves that were in the processes of steepening. It is further suggested that shocks would be formed just beyond 1 AU. These structures were not associated with corotating streams, but they could be associated with impressive solar events in which a flare was followed by type 2 and type 4 radio emission and a rare chromospheric wave.

Chao, J. K.↗

Strongly turbulent stabilization of electron beam-plasma interactions

The stabilization of electron beam interactions due to strongly turbulent nonlinearities is studied analytically and numerically for a wide range of plasma parameters. A fluid mode coupling code is described in which the effects of electron and ion Landau damping and linear growth due to the energetic electron beam are included in a phenomenological manner. Stabilization of the instability is found to occur when the amplitudes of the unstable modes exceed the threshold of the oscillating two-stream instability. The coordinate space structure of the turbulent spectrum which results clearly shows that soliton-like structures are formed by this process. Phenomenological models of both the initial stabilization and the asymptotic states are developed. Scaling laws between the beam-plasma growth rate and the fluctuations in the fields and plasma density are found in both cases, and shown to be in good agreement with the results of the simulation.

Freund, H. P.↗

Survival probabilities for interstellar hydrogen flowing into the interplanetary system from far regions of the heliosphere

The expressions for 'survival' probabilities are presented for an atomic hydrogen particle moving on a trajectory from far regions of the heliosphere to the vicinity of the sun. Three 'destroying' processes have been considered; photoionization, charge transfer and electron ionization. The solar wind has been assumed to be a two-flux steady stream radially expanding with constant flow velocity. Recent profiles of solar-wind electron temperature have been used. The results can be useful for theoretical analyses as well as for analysis of spaceflight observations.

Kunc, J. A.↗

Apparatus and method to keep the walls of a free-space reactor free from deposits of solid materials

An apparatus and method is disclosed for keeping interior walls of a reaction vessel free of undesirable deposits of solid materials in gas-to-solid reactions. The apparatus includes a movable cleaning head which is configured to be substantially complementary to the interior contour of the walls of the reaction vessel. The head ejects a stream of gas with a relatively high velocity into a narrow space between the head and the walls. The head is moved substantially continuously to at least intermittently blow the stream of gas to substantially the entire surface of the walls wherein undesirable solid deposition is likely to occur. The disclosed apparatus and process is particularly useful for keeping the walls of a free-space silane-gas-to-solid-silicon reactor free of undesirable silicon deposits.

Yamakawa, K. A.↗

Development of a coded 16-ary CPFSK coherent demodulator

Theory and hardware are described for a proof-of-concept 16-ary continuous phase frequency shift keying (16-CPFSK) digital modem. The 16 frequencies are spaced every 1/16th baud rate for 2 bits/sec/Hz operation. Overall rate 3/4 convolutional coding is incorporated. The demodulator differs significantly from typical quadrature phase detector approaches in that phase is coherently measured by processing the baseband output of a frequency discriminator. Baud rate phase samples from the baseband processor are decoded to yield the original data stream. The method of encoding onto the 16-ary phase nodes, together with convolutional coding gain, results in near quad PSK (QPSK) performance. The modulated signal is of constant envelope; thus the power amplifier can be saturated for peak performance. The spectrum is inherently bandlimited and requires no RF filter.

Clarke, Ken↗

Underplating, anatexis and assimilation of metacarbonate: A possible source for large CO2 fluxes in the deep crust

Recent models for granulite petrogenesis have involved infiltrative streaming of CO2 derived from deep-seated sources, removal of H2O in locally generated silicate melts, or various combinations of these two processes. All these models require a heat source of some type to generate the high crustal temperatures associated with anatexis and granulite-grade metamorphism, and this most likely takes the form of mantle-derived basaltic magma that is either underplated or intruded into the lower continental crust. Huppert and Sparks have recently shown that such underplating is likely to cause rapid, very large-scale melting of the overlying crust (roof rock) over time scales of only a few hundred years. This model is readily applicable to the granulite terrane of Southern India where metacarbonates occur within the deeper parts of the section including the amphibolite-granulite transition zone. Furthermore, it obviates the need to remove low melt fractions from deep crustal rocks as a principal dehydration mechanism; compaction theory has shown this to be a very sluggish process that is unlikely to be important over typical geological time scales. It also avoids any mechanism involving the subduction of large volumes of sedimentary carbonate into the mantle to provide a CO2 source.

Wickham, S. M.↗

Frame synchronization methods based on channel symbol measurements

The current DSN frame synchronization procedure is based on monitoring the decoded bit stream for the appearance of a sync marker sequence that is transmitted once every data frame. The possibility of obtaining frame synchronization by processing the raw received channel symbols rather than the decoded bits is explored. Performance results are derived for three channel symbol sync methods, and these are compared with results for decoded bit sync methods reported elsewhere. It is shown that each class of methods has advantages or disadvantages under different assumptions on the frame length, the global acquisition strategy, and the desired measure of acquisition timeliness. It is shown that the sync statistics based on decoded bits are superior to the statistics based on channel symbols, if the desired operating region utilizes a probability of miss many orders of magnitude higher than the probability of false alarm. This operating point is applicable for very large frame lengths and minimal frame-to-frame verification strategy. On the other hand, the statistics based on channel symbols are superior if the desired operating point has a miss probability only a few orders of magnitude greater than the false alarm probability. This happens for small frames or when frame-to-frame verifications are required.

Dolinar, S.↗

The meteorological environment of the tropospheric ozone maximum over the tropical South Atlantic Ocean

Atmospheric flow patterns are examined over the South Atlantic Ocean where a maximum of tropospheric ozone has been observed just west of southern Africa. We investigate the flow climatology during October and perform a case study for six days during October 1989. Horizontal and vertical motions are examined and used to prepare 3D backward trajectories from the region of greatest ozone. An initially zonally symmetric distribution of ozone is treated as a passive tracer and advected by 3D flows forecast by the global model. Results from the passive tracer simulation indicate that 3D advection alone can produce a maximum of tropospheric ozone in the observed location. In addition, the trajectories suggest that by-products of biomass burning could be transported to the area of maximum ozone. Low-level flow from commonly observed regions of burning in Africa streams westward to the area of interest. Over Brazil, if the burning by-products are carried into the upper troposphere by convective process, they then could be transported eastward to the ozone feature in approximately five days. There is considerable subsidence over the tropical southern Atlantic, such that stratospheric influences also are a factor in producing the ozone maximum. Both planetary-scale and transient synoptic-scale circulation features play major roles in the various transport processes that influence the region. In summary, the observed tropospheric ozone maximum appears to be caused by a complex set of horizontal and vertical advections, transport from regions of biomass burning, and stratospheric influences.

Krishnamurti, T. N.↗

Total ozone and total NO2 latitudinal distribution derived from measurements in the Atlantic Ocean in May 1988

Total ozone and NO2 were measured aboard a ship in the 40S - 40N latitude band in the Atlantic Ocean in the second half of May 1988. The main features of the latitudinal distributions of total NO2 and ozone are similar. There is seen an increase of total ozone and NO2 from the tropical to subtropical latitudes, strongest in the region of the subtropical jet stream. The fine structure has been revealed in the total ozone and NO2 latitudinal distributions, connected most likely with stratosphere-troposphere exchange processes in the tropopause folding zone.

Elokhov, Alexander S.↗

Effects of End-Wall Vibration on Oscillatory Thermocapillary Flow

Our previous float zone experiments 1,2 with NaNO3 revealed that steady thermocapillary flow (TC flow) can be balanced/offset by the controlled surface streaming flow (CSS flow), induced by end-wall vibration. In the current experiments, we are examining the effects of surface streaming flow on steadying/stabilizing oscillatory thermocapillary flow. To this effect, we have set up a controlled NaNO3 half-zone experiment, where the processing parameters like zone dimensions and temperature gradients scan be easily varied to achieve oscillatory TC flow. In the present paper, we discuss the thermal signature of the TC flow, and how it is affected by imposition of CSS flow. The results will also include a comparison of the microstructure of a NaNO3- BaNO3 eutectic, processed under oscillatory TC conditions, with and without imposed CSS flow.

Bhowmick, J.↗

Carbon Dioxide Clouds at High Altitude in the Tropics and in an Early Dense Martian Atmosphere

We use a time dependent, microphysical cloud model to study the formation of carbon dioxide clouds in the Martian atmosphere. Laboratory studies by Glandor et al. show that high critical supersaturations are required for cloud particle nucleation and that surface kinetic growth is not limited. These conditions, which are similar to those for cirrus clouds on Earth, lead to the formation of carbon dioxide ice particles with radii greater than 500 micrometers and concentrations of less than 0.1 cm(exp -3) for typical atmospheric conditions. Within the current Martian atmosphere, CO2 cloud formation is possible at the poles during winter and at high altitudes in the tropics during periods of increased atmospheric dust loading. In both cases, temperature perturbations of several degrees below the CO2 saturation temperature are required to nucleate new cloud particles suggesting that dynamical processes are the most common initiators of carbon dioxide clouds rather than diabatic cooling. The microphysical cloud model, coupled to a two-stream radiative transfer model, is used to reexamine the impact of CO2 clouds on the surface temperature within a dense CO2 atmosphere. The formation of carbon dioxide clouds leads to a warmer surface than what would be expected for clear sky conditions. The amount of warming is sensitive to the presence of dust and water vapor in the atmosphere, both of which act to dampen cloud effects. The radiative warming associated with cloud formation, as well as latent heating, work to dissipate the clouds when present. Thus, clouds never last for periods much longer than several days, limiting their overall effectiveness for warming the surface. The time average cloud optical depth is approximately unity leading to a 5-10 K warming, depending on the surface pressure. However, the surface temperature does not rise about the freezing point of liquid water even for pressures as high as 5 bars, at a solar luminosity of 75% the current value.

Colaprete, Anthony↗

Satellite Observations of Atmospheric Gravity Waves

The Microwave Limb Sounder (MLS) on the Upper Atmosphere Research Satellite produced the first global maps of small-scale gravity wave variances in the middle atmosphere. Observations at 30-88 km altitudes show that the variances of 30-100 km horizontal scales are strongly correlated with surface topography and stratospheric jet streams. The several years of MLS data will provide a climatology of global gravity wave activity needed for modeling atmospheric circulations and mixing processes.

atmospheric gravity waves middle atmosphere Microw↗

MARIE: A Python-Based Framework for Comprehensive Fuel Recycling Modeling

One of the most pressing challenges to the continued deployment of nuclear energy systems is in the ultimate management and disposition of discharged fuel assemblies. While reprocessing and recovery of valuable materials from UNF assemblies has been considered as part of an overall strategy for minimization of the volume of reactor-based wastes to be managed, the deployment of commercial-scale reprocessing facilities presents an enormous economic challenge. The MARIE software package has been developed as a means of confronting this challenge. Representing components of a generic fuel reprocessing operation as individual physical processes, MARIE is designed as a modular framework intended to allow for analysis and cost-optimization for a hypothetical reprocessing facility while realistically accounting for the physical characteristics of the used fuel source term, such as decay heat, activity, and radiation dose (informing corresponding shielding requirements). Capabilities supported by MARIE include head-end operations such as fuel shearing, voloxidation, and dissolution; generic solvent extraction operations informed by available open-literature data; a suite of unit operations intended to represent electrochemical processing of used fuel assemblies (i.e., oxide reduction, electrorefining, and electrowinning); and finally, accounting for both costs and physical features of discharged waste streams, which can be used to inform follow-on analyses such as the feasibility of deep-borehole disposal of HLW. This paper presents an overview of the MARIE software capabilities, including how individual unit operations are implemented to enable a larger-scale optimization of a hypothetical reprocessing operation on aspects such as cost and recovery of valuable materials.

Skutnik, Steve [ORNL] (ORCID:000000016441135X)↗

Coal-Waste-Enhanced Filaments for Additive Manufacturing of High-Temperature Plastics and Ceramic Composites

In the United States, coal waste from over a century of mining and burning coal for heat and electricity has accumulated as mountains of coal fly ash and bottom ash and acre-size ponds, coal fines and gob. These materials can be a problem for local communities and water systems. A cost-effective process to utilize high volumes of these coal wastes in a high-value product would be beneficial to those communities by reducing the amount of waste and providing jobs, manufacturing components, and materials from the waste. Many coal-to-products technologies (e.g., carbon fibers, graphene, carbon foam) rely on carefully choosing the starting material and then altering it chemically or thermally to make the products work. Due to the wide variability of composition and coal content in typical coal waste streams, many high-volume coal waste streams are likely to be unsuitable for use in those technologies. Semplastics’ technology has been shown to utilize most types of coal waste successfully without any pre-selection or pre-processing requirements other than a nominal particle-size reduction for wastes like bottom ash. This characteristic of Semplastics’ solution may enable the use of much larger volumes of a wider range of coal wastes than other coal-to-products technologies. In this project, Semplastics leveraged its unique experience with both coal waste (fly ash or coal combustion residuals), resin materials, and 3D printing to develop 3D printer filaments using common coal wastes – bituminous coal fines and fly ash – and researched the feasibility of using other forms of coal waste as fillers. Simple 3D-printed parts were successfully produced from the coal waste enhanced filaments, which were found to have improved strength and stiffness.

01 COAL, LIGNITE, AND PEAT↗

The motion of bubbles inside drops in containerless processing

A theoretical model of thermocapillary bubble motion inside a drop, located in a space laboratory, due to an arbitrary axisymmetric temperature distribution on the drop surface was constructed. Typical results for the stream function and temperature fields as well as the migration velocity of the bubble were obtained in the quasistatic limit. The motion of bubbles in a rotating body of liquid was studied experimentally, and an approximate theoretical model was developed. Comparison of the experimental observations of the bubble trajectories and centering times with theoretical predictions lends qualified support to the theory.

Shankar, N.↗

Centrifugal Sieve for Gravity-Level-Independent Size Segregation of Granular Materials

Conventional size segregation or screening in batch mode, using stacked vibrated screens, is often a time-consuming process. Utilization of centrifugal force instead of gravity as the primary body force can significantly shorten the time to segregate feedstock into a set of different-sized fractions. Likewise, under reduced gravity or microgravity, a centrifugal sieve system would function as well as it does terrestrially. When vibratory and mechanical blade sieving screens designed for terrestrial conditions were tested under lunar gravity conditions, they did not function well. The centrifugal sieving design of this technology overcomes the issues that prevented sieves designed for terrestrial conditions from functioning under reduced gravity. These sieves feature a rotating outer (cylindrical or conical) screen wall, rotating fast enough for the centrifugal forces near the wall to hold granular material against the rotating screen. Conventional centrifugal sieves have a stationary screen and rapidly rotating blades that shear the granular solid near the stationary screen, and effect the sieving process assisted by the airflow inside the unit. The centrifugal sieves of this new design may (or may not) have an inner blade or blades, moving relative to the rotating wall screen. Some continuous flow embodiments would have no inner auger or blades, but achieve axial motion through vibration. In all cases, the shearing action is gentler than conventional centrifugal sieves, which have very high velocity differences between the stationary outer screen and the rapidly rotating blades. The new design does not depend on airflow in the sieving unit, so it will function just as well in vacuum as in air. One advantage of the innovation for batch sieving is that a batch-mode centrifugal sieve may accomplish the same sieving operation in much less time than a conventional stacked set of vibrated screens (which utilize gravity as the primary driving force for size separation). In continuous mode, the centrifugal sieves can provide steady streams of fine and coarse material separated from a mixed feedstock flow stream. The centrifugal sieves can be scaled to any desired size and/or mass flow rate. Thus, they could be made in sizes suitable for small robotic exploratory missions, or for semi-permanent processing of regolith for extraction of volatiles of minerals. An advantage of the continuous-mode system is that it can be made with absolutely no gravity flow components for feeding material into, or for extracting the separated size streams from, the centrifugal sieve. Thus, the system is capable of functioning in a true microgravity environment. Another advantage of the continuous-mode system is that some embodiments of the innovation have no internal blades or vanes, and thus, can be designed to handle a very wide range of feedstock sizes, including occasional very large oversized pieces, without jamming or seizing up.

Walton, Otis R.↗