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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 919 records · Page 51
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Molecular-Level Structure and Packing in Phase-Separated Arachidic Acid–Perfluorotetradecanoic Acid Monolayer Films

Synchrotron-based X-ray scattering measurements of phase-separated surfactant monolayers at the air–water interface provide molecular-level structural information about the packing and ordering of film components. In this work, grazing incidence X-ray diffraction (GIXD) and X-ray reflectivity (XR) measurements were used to collect crystallographic structural information for binary mixed monolayers of arachidic acid (AA, C 19 H 39 COOH) with perfluorotetradecanoic acid (PA, C 13 F 27 COOH), a system that has previously been investigated using a variety of thermodynamic and micron-scale structural characterization methods. GIXD measurements at surface pressures of π = 5, 15, and 30 mN/m indicated that AA in pure and mixed films forms a rectangular lattice at π = 5 and 15 mN/m but a hexagonal lattice at π = 30 mN/m. PA formed hexagonal lattices under all conditions, with films being highly ordered and crystalline (as determined by Bragg peak width) at even the lowest surface pressures investigated. Phase separation occurred for all mixed monolayer film compositions and surface pressures, manifesting as diffraction peaks characteristic of the individual components appearing at different in-plane scattering vector q xy . For both pure and mixed films, the molecular tilt angle of the AA hydrocarbon chain toward the nearest-neighbor was substantial at low pressures but decreased with increasing pressure. The PA fluorocarbon chain showed negligible molecular tilt under all conditions, and was oriented normal to the subphase surface regardless of surface pressure or the presence of AA in the films. In all cases, the two components in the mixed film behaved entirely independently of film composition, which is exactly the expected result for a fully phase-separated, immiscible system. XR measurements of film thickness at the air–water interface supported these results; overall film thickness approached the calculated ideal surfactant tail lengths with increasing surface pressure, indicating nearly normal oriented surfactants. Furthermore, the overall surfactant packing and crystallographic features of the mixed monolayers are discussed in terms of the lipophobic nature of the perfluorinated surfactant as well as in context of thermodynamic miscibility and domain structure formation reported elsewhere in the literature for these mixed monolayer systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Photocatalytic degradation of cooking fume on a TiO2-coated carbon nanotubes composite filter

Highlights: • The TiO{sub 2}-coated carbon nanotube composite filter was fabricated for treating cooking fume particles. • MWCNTs formed a network-like structure surface layer of composite filter. • The composite filter showed high surface area. • The composite filter was tested in oleic acid decomposition reaction. • Parallel reaction mechanism was attempted to describe oleic acid degradation. A TiO{sub 2}/MWCNTs/Al{sub 2}O{sub 3}/NF (TiO{sub 2} nanoparticles/multi-walled carbon nanotubes /Al{sub 2}O{sub 3}-modified nickel foams) composite filter was prepared through grown of MWCNTs upon Al{sub 2}O{sub 3}-modified nickel foams using chemical vapor deposition (CVD) method and then coated TiO{sub 2} nanoparticles onto MWCNTs using dip-coating method. The MWCNTs forms a network-like structure on the surface layer of composite filter. The BET surface area of TiO{sub 2}/MWCNTs/Al{sub 2}O{sub 3}/NF composite filter is more than 375 times higher than that of the pristine nickel foam. The degradation performance of oil particles was evaluated. Under optimized reaction conditions, 90% of the oleic acid on the filter was decomposed after 25 h. In addition, the effect of reaction temperature and light intensity were studied. Increased reaction temperature and light intensity were found to significantly improve the degradation rate and restrain the formation of refractory product. Furthermore, a parallel reaction kinetic model was adopted for degradation of oleic acid on the composite filter. The composite filter can reduces the accumulation of oil particles on the filter and the energy consumption of the filter. This approach proposes a new way to treat the cooking fume emission at residential building roofs.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1996

Studies of the Surface Treatment and Sizing of Carbon Fiber Surfaces on the Mechanical Properties of Composites Containing Carbon Fibers

Carbon fiber reinforced composites are materials where carbon fibers are used to reinforce a matrix to produce a light and strong material with important applications in the aerospace industry. There are many aspects of the preparation of these materials that would benefit from a study which combines the research of groups involved in the production, testing and analysis of these materials, and studies of the basic surface chemistry involved. This final reports presents the results of a project that has developed a collaboration between groups in all three of the major research universities in the State of Kansas, and promises to lead to a collaborative program that covers the major aspects of composite development and application. Sherwood has provided initial fiber surface treatment and sizing together with fiber and composite surface analysis; Lease, Tomblin and Wang have worked together toward the goal of preparing pre-preg and fabrication of laminated panels; Locke has developed computational models to evaluate the effect of surface treatment (and chemistry) on mechanical properties; Lease, Tomblin and Wang have worked together to perform all necessary mechanical testing. The research has been focused on materials that would benefit the High Speed Civil Transport (HSCT) program. The group has visited Dr. Howard Maars and his colleagues at NASA Langley, and has focused their studies on the NASA requirements discussed in this meeting. An important development, requested by NASA scientists, has been the acquisition and study of K3B as a matrix material for the composites. The project has led to the successful acquisition and surface analysis of K3B, together with the successful deposition of this material onto surface oxidized carbon fibers. Mechanical testing, modelling and the construction of composite preparation equipment has been achieved during the grant period.

Sherwood, Peter M. A.↗
NASA NTRSDate not supplied

Preliminary XANES Analysis of Laboratory Analogs of Titan Tholins

Titan, the largest moon of Saturn, is a fascinating object. It is the only other object in the Solar System, besides Earth, with a dense (1.5 bar at the surface) atmosphere whose composition is dominated by N2, with CH4 as the second most abundant gas. A complex organic chemistry between N2 and CH4, induced by solar UV photons and energetic particles, results in the formation of a large variety of organic compounds, including hydrocarbons (e.g., C2H2, C2H4, C2H6, C3H4, C6H6), nitriles (e.g., HCN, HNC, HC3N, CH3CN, C2N2), as well as larger molecules that include aromatic and heteroaromatic compounds [1]. This complex organic chemistry also leads to the formation of aerosols that play an important role in Titan’s atmospheric dynamics, climate, as well as surface composition and processes. Because of its N2-based dense atmosphere, and its CH4 cycle that resembles the hydrological cycle on Earth, Titan is often considered to be an analog of early Earth. In recent years, Titan’s atmosphere and surface were monitored in detail by the NASA Cassini mission, which orbited the Saturnian system from 2004 to 2017, as well as the ESA Huygens probe, which plunged into Titan’s atmosphere and landed on its surface in 2005.

Titan↗
NASA NTRS1990

Low-Thermal-Stress Structural Joints For Dissimilar Materials

Structural joint developed for attachment of hypersonic control surface to aircraft wing structure. Transmits large torque loads from composite control surface and torque tube to wing structure through metallic attachment lug and collar. Torque load transmitted from tube to collar by series of radially oriented cleats. Bearing surfaces of cleats plane passing through center-line of torque tube. Such joints accommodate differential thermal growth between parts of dissimilar materials. Potential for application to high-temperature structural joints associated with hypervelocity vehicles.

Matza, Edward C.↗
NASA NTRS1991

Space environmental effects on silvered Teflon thermal control surfaces

Cumulative space environment effects on Ag/fluorinated ethylene propylene (FEP) were a function of exposure orientation. Samples from nineteen silvered Teflon (Ag/FEP) thermal control surfaces recovered from the Long Duration Exposure Facility (LDEF) were analyzed to determine changes in this material as a function of position on the spacecraft. Although solar absorptance and infrared emittance of measured thermal blanket specimens are relatively unchanged from control specimen values, significant changes in surface morphology, composition and chemistry were observed. Researchers hypothesize that the FEP surfaces on LDEF were degraded by ultraviolet radiation exposure at all orientations, but that the damaged material had been removed by erosion from the blankets exposed to atomic oxygen flux and that contamination is masking the damage on trays flanking the trailing edge.

Hemminger, C. S.↗
NASA NTRS1992

Space environmental effects on silvered Teflon thermal control surfaces

Cumulative space environmental effects on silver/fluorinated ethylene propylene (Ag/FEP) were a function of exposure orientation. Samples from nineteen silvered Teflon (Ag/FEP) thermal control surfaces recovered from the Long Duration Exposure Facility (LDEF) were analyzed to determine changes in this material as a function of position on the spacecraft. Although solar absorptance and infrared emittance of measured thermal blanket specimens are relatively unchanged from control specimen values, significant changes in surface morphology, composition, and chemistry were observed. We hypothesize that the FEP surfaces on the LDEF are degraded by UV radiation at all orientations, but that the damaged material has been removed by erosion from the blankets exposed to atomic oxygen flux and that contamination is masking the damage in some areas on the trays flanking the trailing edge.

Hemminger, C. S.↗
DOE OSTI2019

Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode

A method of making a supercapacitor from waste tires, includes the steps of providing rubber pieces and contacting the rubber pieces with a sulfonation bath to produce sulfonated rubber; pyrolyzing the sulfonated rubber to produce a tire-derived carbon composite comprising carbon black embedded in rubber-derived carbon matrix comprising graphitized interface portions; activating the tire-derived carbon composite by contacting the tire-derived carbon composite with a specific surface area-increasing composition to increase the specific surface area of the carbon composite to provide an activated tire-derived carbon composite; and, mixing the activated tire-derived carbon composite with a monomer and polymerizing the monomer to produce a redox-active polymer coated, activated tire-derived carbon composite. The redox-active polymer coated, activated tire-derived carbon composite can be formed into a film. An electrode and a supercapacitor are also disclosed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Investigations of Polymethacrylate Tribochemical Films Using X-Ray Spectroscopy and Optical Profilometry

This study investigates the elemental composition and surface morphology of solid tribochemical films formed on steel surfaces. The reversible addition-fragmentation chain transfer (RAFT) method was used to synthesize nine different metal-free polymers, which were blended into commercial base oils. The polymers were either homopolymers of dodecyl methacrylate and ethylhexyl methacrylate or were co-polymers of these monomers with six polar monomers. After tribological testing at 100 degrees C using the ball-on-flat geometry, the resulting tribochemical films were imaged using scanning electron microscopy (SEM) and optical microscopy. The resulting tribochemical films have thicknesses around 50-100 nm. Two of the films corresponding to small (P1-imidazole-containing copolymer) and large (P3-less polar homopolymer) wear were cross-sectioned using focused ion beam (FIB) and analyzed for elemental composition using energy-dispersive X-Ray (EDX) mapping. Oxygen and nitrogen enrichment was observed, consistent with the relative chemical composition of the precursor polymers. Transmission electron microscopy (TEM) evidence suggests that at the worn surface, some organic elements penetrate or are mixed into the steel substrate giving an interlocking appearance. The two samples examined with TEM showed that P1 tribofilm is diffused or mixed with the steel substrate more so than P3, suggesting a stronger affinity and contact during tribofilm formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1992

The effects of crushing surface roughness on the crushing characteristics of composite tubes

The effects of crushing-surface roughness on the energy-absorption capability of graphite and glass-epoxy composite tubes were investigated. Fifty different combinations of fiber, matrix, and specimen ply orientation were evaluated. Two different crushing surface roughnesses were used in this investigation. Crushing surface significantly influences the energy-absorption capability only of tubes that crush in the lamina bending crushing mode; tubes that crush in other modes are not influenced because their lamina bundles do not slide against the crushing surface. Those tubes that crush in the lamina bending mode can achieve higher, lower, or no change in energy-absorption capability as crushing surface roughness increases. If the fiber failure strain of tubes that crush in the lamina bending crushing mode exceeds the matrix failure strain then the energy-absorption capability increases as crushing surface roughness increases. However, if the matrix failure strain exceeds the fiber failure strain then the energy-absorption capability increases as crushing surface roughness decreases. Energy-absorption capability is uninfluenced by crushing surface roughness for tubes that have equal fiber and matrix failure strains.

Farley, Gary L.↗
NASA NTRS2004

X-ray Probes of Magnetospheric Interactions with Jupiter's Auroral zones, the Galilean Satellites, and the Io Plasma Torus

Remote observations with the Chandra X-ray Observatory and the XMM-Newton Observatory have shown that the Jovian system is a source of x-rays with a rich and complicated structure. The planet's polar auroral zones and its disk are powerful sources of x-ray emission. Chandra observations revealed x-ray emission from the Io Plasma Torus and from the Galilean moons Io, Europa, and possibly Ganymede. The emission from these moons is certainly due to bombardment of their surfaces of highly energetic protons, oxygen and sulfur ions from the region near the Torus exciting atoms in their surfaces and leading to fluorescent x-ray emission lines. Although the x-ray emission from the Galilean moons is faint when observed fiom Earth orbit, an imaging x-ray spectrometer in orbit around these moons, operating at 200 eV and above with 150 eV energy resolution, would provide a detailed mapping (down to 40 m spatial resolution) of the elemental composition in their surfaces. Here we describe the physical processes leading to x-ray emission fiom the surfaces of Jupiter's moons and the instrumental properties, as well as energetic ion flux models or measurements, required to map the elemental composition of their surfaces. We discuss the proposed scenarios leading to possible surface compositions. For Europa, the two most extreme are (1) a patina produced by exogenic processes such as meteoroid bombardment and ion implantation, and (2) upwelling of material fiom the subsurface ocean. We also describe the characteristics of X - m , an imaging x-ray spectrometer under going a feasibility study for the JIM0 mission, with the ultimate goal of providing unprecedented x-ray studies of the elemental composition of the surfaces of Jupiter's icy moons and Io, as well as of Jupiter's auroral x-ray emission.

Elsner, R. F.↗
DOE OSTI2019

Formation of the Francisella tularensis Biofilm is Affected by Cell Surface Glycosylation, Growth Medium, and a Glucan Exopolysaccharide

Abstract Biofilms are matrix-associated communities that enable bacteria to colonise environments unsuitable for free-living bacteria. The facultative intracellular pathogen Francisella tularensis can persist in water, amoebae, and arthropods, as well as within mammalian macrophages. F . tularensis Types A and B form poor biofilms, but F . tularensis mutants lacking lipopolysaccharide O-antigen, O-antigen capsule, and capsule-like complex formed up to 15-fold more biofilm than fully glycosylated cells. The Type B live vaccine strain was also 50% less capable of initiating surface attachment than mutants deficient in O-antigen and capsule-like complex. However, the growth medium of all strains tested also influenced the formation of biofilm, which contained a novel exopolysaccharide consisting of an amylose-like glucan. In addition, the surface polysaccharide composition of the bacterium affected the protein:DNA:polysaccharide composition of the biofilm matrix. In contrast, F . novicida attached to surfaces more efficiently and made a more robust biofilm than Type A or B strains, but loss of O-antigen or capsule-like complex did not significantly affect F . novicida biofilm formation. These results indicated that suppression of surface polysaccharides may promote biofilm formation by F . tularensis Types A and B. Whether biofilm formation enhances survival of F . tularensis in aquatic or other environmental niches has yet to be determined.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1997

The Nature of Comet Materials and Attachment to Them

Because cometary surfaces are likely to be far colder and of a different composition and surface topography than other planetary surfaces with which we have experience, there are some new considerations that must be examined in regards to placing and attaching instrumented packages or sample return devices in or on their surfaces. The qualitative analysis of the problem of embedding hardware in a comet icy core is limited to only one of several means for the purposes of this discussion. This means can be characterized as a kinetic impact piercing device. Such kinetic impact piercing device may be used to attach the feet of an instrumented package on the surface or it may be the means for implanting the package in the icy core below the mantle. The functional requirement is to implant a device in the icy core and by mechanical means, prevent the device from being ejected back into space.

Stephens, James↗
NASA NTRS1992

The Apollo 17 region: A compositional overview

Apollo 17 is located at a mare/highland boundary where the surface shows significant compositional heterogeneities. The composition of surface materials is estimated by analyzing their spectral/chemical correlations. Based on this spectral/chemical analysis, the chemical and normative mineralogical composition of two highland units and three mare units has been estimated.

Jaumann, R.↗
DOE OSTI2019

Solidifiable composition for preparaton of liquid-infused slippery surfaces and methods of applying

A body having a lubricant reservoir is described, comprising: a porous polymeric body; and a lubricating liquid, said lubricating liquid occupying the pores to provide a lubricated porous surface having a lubricant reservoir and a lubricant overlayer over the polymer surface. Also described herein is a system for use in the formation of a low-adhesion and low-friction surface includes a flowable precursor composition comprising a prepolymer and a curing agent, said composition capable of application as a coating over a large surface area; a lubricating liquid that is capable of forming a coating with the hardened precursor composition, wherein the lubricating liquid and hardened polymer together form a coating of lubricating liquid stabilized on and in the hardened polymer; and instructions for applying the precursor composition onto a surface for the purpose of obtaining a low-adhesion and low-friction surface.

Aizenberg, Joanna↗
DOE OSTI2025

Depth-dependent links between microbial taxa and nitrous oxide emissions in a long-term cotton cropping system employing soil health practices

Long-term management practices can shape soil microbial communities in ways that influence nitrogen (N) dynamics and nitrous oxide (N 2 O) emissions. We leverage a 41-year continuous cotton cropping experiment with contrasting tillage, cover cropping, and N fertilization regimes to investigate how these long-term strategies influence soil microbial communities and their associations with N 2 O fluxes during the cotton growing season. Using 16S rRNA gene metabarcoding, we assessed microbial composition in surface and subsurface soils and evaluated its relationship with temporal N 2 O emissions. Among the management practices, N fertilization – a known driver of N 2 O emissions – had the strongest effect on microbial community composition and was linked to a greater number of taxa correlated to N 2 O emissions, particularly in surface soils. Soil pH emerged as a key variable influencing microbial structure across depth and was negatively associated with both N 2 O emissions and microbial composition in the surface layers of fertilized soils. In total, 57 archaeal/bacterial taxa were correlated with N 2 O fluxes, but only seven were shared across depths, suggesting distinct microbial contributors in surface and subsurface soils. Several of these taxa have been previously reported to be associated with N and C cycling processes such as nitrate respiration or carbon turnover, indicating functional context to their correlation with N 2 O fluxes. Temporal shifts in the abundance of key taxa aligned with seasonal peaks in N 2 O emissions, notably in early and late August, and were most pronounced under conventional tillage, hairy vetch cover cropping, and N fertilization. While 16S-based associations cannot confirm functional gene presence or activity, these findings demonstrate that long-term fertilization and associated soil acidification are dominant drivers of microbial shifts linked to N 2 O emissions and highlight the importance of accounting for depth-specific and seasonal microbial dynamics when evaluating management impacts on greenhouse gas emissions.

16S rRNA gene sequencing↗
NASA NTRS1988

Effects of bleeder cloth impressions on the use of polar backscatter to detect porosity

The influence of the nature of the composite's surface on ultrasonic polar backscatter measurements for detecting and characterizing porosity in composite laminates is studied, focusing on the effects of bleeder cloth impressions noted by Bar-Cohen (1987). The results indicate that the presence of the bleeder cloth impressions substantially influences the degree of anisotropy. It is found that, for relatively thin samples in which selective time gating is not feasible, the state of the insonified surface and the state of the back surface both influence the received signal.

Handley, S. M.↗
DOE OSTI2021

Deep reinforcement learning for predicting kinetic pathways to surface reconstruction in a ternary alloy

Abstract The majority of computational catalyst design focuses on the screening of material components and alloy composition to optimize selectivity and activity for a given reaction. However, predicting the metastability of the alloy catalyst surface at realistic operating conditions requires an extensive sampling of possible surface reconstructions and their associated kinetic pathways. We present CatGym, a deep reinforcement learning (DRL) environment for predicting the thermal surface reconstruction pathways and their associated kinetic barriers in crystalline solids under reaction conditions. The DRL agent iteratively changes the positions of atoms in the near-surface region to generate kinetic pathways to accessible local minima involving changes in the surface compositions. We showcase our agent by predicting the surface reconstruction pathways of a ternary Ni 3 Pd 3 Au 2 (111) alloy catalyst. Our results show that the DRL agent can not only explore more diverse surface compositions than the conventional minima hopping method, but also generate the kinetic surface reconstruction pathways. We further demonstrate that the kinetic pathway to a global minimum energy surface composition and its associated transition state predicted by our agent is in good agreement with the minimum energy path predicted by nudged elastic band calculations.

36 MATERIALS SCIENCE↗