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Hygroscopic chemicals and the formation of advection warm fog: A numerical simulation

The formation of advection fog is closely associated with the characteristics of the aerosol particles, including the chemical composition, mass of the nuclei, particle size, and concentration. Both macrophysical and microphysical processes are considered. In the macrophysical model, the evolution of wind components, water vapor content, liquid water content and potential temperature under the influences of vertical turbulent diffusion, turbulent momentum, and turbulent energy transfers are taken into account. In the microphysical model, the supersaturation effect is incorporated with the surface tension and hygroscopic material solution.

Hung, R. J.↗

An evaluation of computer codes for simulating the Galileo Probe aerothermal entry environment

The approaches of three computer flow field codes (HYVIS, COLTS, and RASLE), used to determine the Galileo Probe aerothermal environment and its effect on the design of the thermal protection system, are analyzed in order to resolve differences in their predicted results. All three codes account for the hypersonic, massively blown, radiation shock layers, characteristic of Jupiter entry. Significant differences, however, are evident in their solution procedures: the governing conservation equations, the numerical differencing methods, the governing physics (chemical, radiation, diffusion, and turbulence models), and the basic physical data (thermodynamic, transport, chemical, and spectral properties for atomic and molecular species). Solutions are compared for two near peak heating entry conditions for a Galileo Probe baseline configuration, having an initial mass of 242 kg and simulating entry into the Orton nominal atmosphere. The modern numerical methodology of COLTS and RASLE appear to provide an improved capability for coupled flow-field solutions.

Menees, G. P.↗

Supernova remnant revolution in an inhomogeneous medium. I - Numerical models

The first numerical simulations of supernova remnant evolution in an inhomogeneous gas are presented. Evolution in the lowest density substrate (the intercloud) is assumed to be spherically symmetric with a large intercloud filling factor and many dense regions (clouds) within the remnant; however, mass momentum and energy transfer between cloud and intercloud are included and the position and morphology of individual clouds tracked. Evolution is considered in several different models of the interstellar medium, both those in which the intercloud gas is diffuse (0.001 to 0.01/cu cm) and those in which it is relatively dense (n approximately 0.3/cu cm) under a variety of assumptions about the efficiency of thermal evaporation from the clouds into the intercloud medium.

Cowie, L. L.↗

Numerical modeling of flame-balls in fuel-air mixtures

At low gravity, when buoyancy effects are small, flame-balls can be generated. These are stationary spherical structures whose existence appears to require a near-limit mixture, a small Lewis number and heat losses from radiation. It is our goal to combine computational modeling with existing experimental and theoretical studies (NASA) of these structures so that an improved understanding of flammability limits and near-limit phenomena will occur. The question of flammability limits is of fundamental importance and has long been examined. It is of great practical importance to predict, from first principles, a limit mixture strength that agrees with experimental values for the configuration at hand. Flame-balls provide an excellent configuration in which convective losses can be eliminated and the resulting stable solutions are produced from a diffusive, reactive and radiative balance. Although analytical modeling provides convincing evidence that the key physical ingredients of flame-balls have been identified, quantitative confirmation can only come from detailed numerical simulations. Our goal is to predict theoretically the mass fractions of the species and the temperature as functions of the independent coordinate r.

Smooke, Mitchell D.↗

Influence of Transport on Two-Dimensional Model Simulation: 2. Stratospheric Aircraft Perturbations: Stratospheric Aircraft Perturbations - 2

We have adopted the transport scenarios used in Part 1 to examine the sensitivity of stratospheric aircraft perturbations to transport changes in our 2-D model. Changes to the strength of the residual circulation in the upper troposphere and stratosphere and changes to the lower stratospheric K(sub zz) had similar effects in that increasing the transport rates decreased the overall stratospheric residence time and reduced the magnitude of the negative perturbation response in total ozone. Increasing the stratospheric K(sub yy) increased the residence time and enhanced the global scale negative total ozone response. However, increasing K(sub yy) along with self-consistent increases in the corresponding planetary wave drive, which leads to a stronger residual circulation, more than compensates for the K(sub yy)-effect, and results in a significantly weaker perturbation response, relative to the base case, throughout the stratosphere. We found a relatively minor model perturbation response sensitivity to the magnitude of K(sub yy) in the tropical stratosphere, and only a very small sensitivity to the magnitude of the horizontal mixing across the tropopause and to the strength of the mesospheric gravity wave drag and diffusion. These transport simulations also revealed a generally strong correlation between passive NO(sub y) accumulation and age of air throughout the stratosphere, such that faster transport rates resulted in a younger mean age and a smaller NO(y) mass accumulation. However, specific variations in K(sub yy) and mesospheric gravity wave strength exhibited very little NO(sub y)-age correlation in the lower stratosphere, similar to 3-D model simulations performed in the recent NASA "Models and Measurements" II analysis. The base model transport, which gives the most favorable overall comparison with inert tracer observations, simulated a global/annual mean total ozone response of -0.59%, with only a slightly larger response in the northern compared to the southern hemisphere. For transport scenarios which gave tracer simulations within some agreement with measurements, the annual/globally averaged total ozone response ranged from -0.45% to -0.70%. Our previous 1995 model exhibited overly fast transport rates, resulting in a global/annually averaged perturbation total ozone response of -0.25%, which is significantly weaker compared to the 1999 model. This illustrates how transport deficiencies can bias model simulations of stratospheric aircraft.

Fleming, Eric L.↗

The structure of mass-loading shocks. 1: Comets

A new multifluid model to describe the solar wind-cometary ion plasma in the outer cometary coma is derived. This model is distinguished from previous multifluid models in that wave-particle effects are included explicitly. By considering hydrodynamic timescales, self-consistent dissipative terms (which correspond to the spatial diffusion of cometary ions) are derived, thereby allowing the structure of a cometary bow shock to be resolved. In the hypersonic limit, our diffusive multifluid model reveals an attractive connection to the one-fluid model formulated by Biermann et al. (1967), a connection which serves as an important guide when investigating our more complicated nonhypersonic diffusive model. The detailed model consists of cometary ions diffusing in a warm solar wind which is heated by the dissipation of Alfvenic turbulence (in situ and generated by the initial ring beam distribution). The quasi-parallel cometary shock is found to be at least an order of magnitude thicker than a quasi-perpendicular cometary shock. It is furthermore found that for undisturbed solar wind (sonic) Mach numbers in excess of approximately 6, the cometary bow shock (for both perpendicular and parallel cases) is smoothed completely by the cometary ions and no 'proton' or thermal subshock is necessary. Finally, a detailed comparison of the model with the plasma observations made at Halley by Giotto is undertaken. It is found that the observed shock structure, thickness, location, and plasma parameters compare well with the predictions of the theoretical model, particularly in the case of the quasi-parallel shock.

Zank, G. P.↗

Radiant Extinction of Gaseous Diffusion Flames

The absence of buoyancy-induced flows in microgravity (mu-g) and the resulting increase in the reactant residence time significantly alters the fundamentals of many combustion processes. Substantial differences between normal gravity (ng) and mu-g flames have been reported in experiments on candle flames, flame spread over solids, droplet combustion, and others. These differences are more basic than just in the visible flame shape. Longer residence times and higher concentration of combustion products in the flame zone create a thermochemical environment that changes the flame chemistry and the heat and mass transfer processes. Processes such as flame radiation, that are often ignored in ng, become very important and sometimes even controlling. Furthermore, microgravity conditions considerably enhance flame radiation by: (1) the build-up of combustion products in the high-temperature reaction zone which increases the gas radiation; and (2) longer residence times make conditions appropriate for substantial amounts of soot to form which is also responsible for radiative heat loss. Thus, it is anticipated that radiative heat loss may eventually extinguish the "weak" (low burning rate per unit flame area) mu-g diffusion flame. Yet, space shuttle experiments on candle flames show that in an infinite ambient atmosphere, the hemispherical candle flame in mu-g will burn indefinitely. This may be because of the coupling between the fuel production rate and the flame via the heat-feedback mechanism for candle flames, flames over solids and fuel droplet flames. Thus, to focus only on the gas-phase phenomena leading to radiative extinction, aerodynamically stabilized gaseous diffusion flames are examined. This enables independent control of the fuel flow rate to help identify conditions under which radiative extinction occurs. Also, spherical geometry is chosen for the mu-g experiments and modeling because: (1) It reduces the complexity by making the problem one-dimensional; (2) The spherical diffusion flame completely encloses the soot which is formed on the fuel rich side of the reaction zone. This increases the importance of flame radiation because now both soot and gaseous combustion products co-exist inside the high temperature spherical diffusion flame; (3) For small fuel injection velocities, as is usually the case for a pyrolyzing solid, the diffusion flame in mu-g around the solid naturally develops spherical symmetry. Thus, spherical diffusion flames are of interest to fires in mu-g and identifying conditions that lead to radiation-induced extinction is important for spacecraft fire safety.

Berhan, Sean↗

Large-scale characteristics of interstellar dust from COBE DIRBE observations

Observations from the COBE Diffuse Infrared Background Experiment of the 140 and 240 micrometer emissions from the Galatic plane region (absolute value of b less than 10 deg) are combined with radio surveys that trace the molecular (H2), neutral atomic (H I), and extended low-density (n(sub e) approximately 10 to 100/cm(exp 3)) ionized (H II) gas phases of the interstellar medium to derive physical conditions such as the dust temperature, dust-to-gas mass ratio, and far-infrared emissivity (1) averaged over these gas phases along each line of sight and (2) within each of these three gas phases. This analysis shows large-scale longitudinal and latitudinal gradients in the dust temperature and a decrease in dust temperature with increasing Galactocentric distance. The derived dust temperatures are significantly different from those derived in similar analyses using the Infrared Astronomical Satellite (IRAS) 60 and 100 micrometer data, suggesting that small (5 A approximately less than radius approximately less than 200 A) transiently heated dust particles contribute significantly o the Galactic 60 micrometer emission. It is found that 60% to 75% of the far-infrared luminosity arises from cold (approximately 17 to 22 K) dust associated with diffuse H I clouds, 15% to 30% from cold (approximately 19 K) dust associated with molecular gas, and less than 10% from warm (approximately 29 K) dust in extended low-density H II regions, consistent with the results of the IRAS analyses of the Galactic 60 and 100 micrometer emission. Within 2 deg of longitude of the Galactic center, the derived gas-to-dust mass ratio along the line of sight, G(sub d), reverses its general trend of decreasing G(sub d) toward the inner Galaxy and increases by a factor of approximately 2 to 3 toward the Galactic center. One possible explanation for this result is that the ratio of H2 column density to (12)CO intensity is lower in the Galactic center region than in the Galactic disk.

Sodroski, T. J.↗

Radiant Extinction Of Gaseous Diffusion Flames

The absence of buoyancy-induced flows in microgravity (mu:g) and the resulting increase in the reactant residence time significantly alters the fundamentals of many combustion processes. Substantial differences between normal gravity (ng) and :g flames have been reported in experiments on candle flames [1, 2], flame spread over solids [3, 4], droplet combustion [5,6], and others. These differences are more basic than just in the visible flame shape. Longer residence times and higher concentration of combustion products in the flame zone create a thermochemical environment that changes the flame chemistry and the heat and mass transfer processes. Processes such as flame radiation, that are often ignored in ng, become very important and sometimes even controlling. Furthermore, microgravity conditions considerably enhance flame radiation by: (i) the build-up of combustion products in the high-temperature reaction zone which increases the gas radiation, and (ii) longer residence times make conditions appropriate for substantial amounts of soot to form which is also responsible for radiative heat loss. Thus, it is anticipated that radiative heat loss may eventually extinguish the Aweak@ (low burning rate per unit flame area) :g diffusion flame. Yet, space shuttle experiments on candle flames show that in an infinite ambient atmosphere, the hemispherical candle flame in :g will burn indefinitely [1]. This may be because of the coupling between the fuel production rate and the flame via the heat-feedback mechanism for candle flames, flames over solids and fuel droplet flames. Thus, to focus only on the gas-phase phenomena leading to radiative extinction, aerodynamically stabilized gaseous diffusion flames are examined. This enables independent control of the fuel flow rate to help identify conditions under which radiative extinction occurs. Also, spherical geometry is chosen for the :g experiments and modeling because: (i) It reduces the complexity by making the problem one-dimensional. (ii) The spherical diffusion flame completely encloses the soot which is formed on the fuel rich side of the reaction zone. This increases the importance of flame radiation because now both soot and gaseous combustion products co-exist inside the high temperature spherical diffusion flame. (iii) For small fuel injection velocities, as is usually the case for a pyrolyzing solid, the diffusion flame in :g around the solid naturally develops spherical symmetry. Thus, spherical diffusion flames are of interest to fires in :g and identifying conditions that lead to radiation-induced extinction is important for spacecraft fire safety.

Berhan, S.↗

Unsteady Spherical Diffusion Flames in Microgravity

The absence of buoyancy-induced flows in microgravity (mu-g) and the resulting increase in the reactant residence time significantly alters the fundamentals of many combustion processes. Substantial differences between normal gravity (ng) and (mu-g) flames have been reported in experiments on candle flames, flame spread over solids, droplet combustion, and others. These differences are more basic than just in the visible flame shape. Longer residence times and higher concentration of combustion products in the flame zone create a thermochemical environment that changes the flame chemistry and the heat and mass transfer processes. Processes such as flame radiation, that are often ignored in ng, become very important and sometimes even controlling. Furthermore, microgravity conditions considerably enhance flame radiation by: (i) the build-up of combustion products in the high-temperature reaction zone which increases the gas radiation, and (ii) longer residence times make conditions appropriate for substantial amounts of soot to form which is also responsible for radiative heat loss. Thus, it is anticipated that radiative heat loss may eventually extinguish the "weak" (low burning rate per unit flame area) mu-g diffusion flame. Yet, space shuttle experiments on candle flames show that in an infinite ambient atmosphere, the hemispherical candle flame in mu-g will burn indefinitely. This may be because of the coupling between the fuel production rate and the flame via the heat-feedback mechanism for candle flames, flames over solids and fuel droplet flames. Thus, to focus only on the gas-phase phenomena leading to radiative extinction, aerodynamically stabilized gaseous diffusion flames are examined. This enables independent control of the fuel flow rate to help identify conditions under which radiative extinction occurs. Also, spherical geometry is chosen for the mu-g experiments and modeling because: (i) It reduces the complexity by making the problem one-dimensional; (ii) The spherical diffusion flame completely encloses the soot which is formed on the fuel rich side of the reaction zone. This increases the importance of flame radiation because now both soot and gaseous combustion products co-exist inside the high temperature spherical diffusion flame. (iii) For small fuel injection velocities, as is usually the case for a pyrolyzing solid, the diffusion flame in mu-g around the solid naturally develops spherical symmetry. Thus, spherical diffusion flames are of interest to fires in mu-g and identifying conditions that lead to radiation-induced extinction is important for spacecraft fire safety.

Atreya, Arvind↗

Convection and mass-transport in laser-induced chemical vapor deposition

Gas flow and energy and species transport in laser-induced chemical vapor deposition (LICVD) of amorphous silicon films by silane pyrolysis are analyzed by finite element analysis of a two-dimensional model for the process. Spatial nonuniformity of the deposited film is shown to result from diffusion controlled transport of products between the beam and substrate. Deposition profiles are affected by buoyancy-driven convection only at increased gas pressures. Horizontal orientation of the reactor with respect to gravity is optimal because the stagnation-like flow, that results adjacent to the substrate, enhances mixing, and smoothes the film profile.

Patnaik, S.↗

In situ measurements of neon in the thermosphere

The open source neutral mass spectrometer on the Atmosphere Explorer-C satellite has measured neon in the thermosphere. The absolute density of Ne is close to that predicted by using the ground level fraction by volume of Ne along with the assumption of diffusive equilibrium above 100 km. Data is presented for both geomagnetically quiet and disturbed circular orbits. At 290 km, a typical low latitude value of Ne is 3.0 x 10 to the 4th/cu cm. At this altitude Ne appears to be predominantly controlled by temperature except during magnetic disturbances, when offsetting forces due to wind systems may be present.

Potter, W. E.↗

Composition and structure of the Martian upper atmosphere - Analysis of results from Viking

Densities for carbon dioxide measured by the upper-atmospheric mass spectrometers on Viking 1 and Viking 2 are analyzed to yield height profiles for the temperature of the Martian atmosphere between 120 and 200 kilometers. Densities for nitrogen and argon are used to derive vertical profiles for the eddy diffusion coefficient over the same height range. The upper atmosphere of Mars is surprisingly cold, with average temperatures for both Viking 1 and Viking 2 of less than 200 K, and there is significant vertical structure. Model calculations are presented and shown to be in good agreement with measured concentrations of carbon monoxide, oxygen, and nitric oxide.

Mcelroy, M. B.↗

Confining hot spots in 3C 196 - Implications for QSO-companion galaxies

VLBI observations of the extremely compact hot spot in the northern radio lobe of the QSO 3C 196 reveal the angular size of its smallest substructure to be 0.065 arcsec x 0.045 arcsec or about 300 pc at the redshift distance. The morphology of the hot spot and its orientation relative to the more diffuse radio emission suggest that it is formed by an oblique interaction between the nuclear QSO jet and circum-QSO cloud. The inferred density in this cloud, together with its apparent size, imply that the cloud contains a galactic mass, greater than a billion solar masses of gas. The effect of the jet will be to hasten gravitational collapse of the cloud. If many QSOs such as 3C 196 are formed or found in gas-rich environments, the QSO radio phase may commonly stimulate the metamorphosis of circum-QSO gas to QSO-companion galaxies or it may play a significant part in catalyzing star formation in existing companions.

Brown, R. L.↗

Intrusions into the lower stratospheric Arctic vortex during the winter of 1991-1992

Investigations of the kinematics of the lower stratospheric Arctic vortex during the winter of 1991-1992 using the contour advection with surgery technique reveal three distinct events in which there was substantial intrusion of midlatitude air into the vortex, in apparent contradiction of the view that the polar vortex constitutes an isolated air mass. Two of these events, in late January and mid-February, were well documented. They were predicted in high-resolution forecasts by the European Centre for Medium-Range Weather Forecasts, most clearly in experimental forecasts with reduced diffusion. Direct confirmation of the presence of the intrusions and of their calculated locations was provided by aerosol observations from the airborne differential absorption laser lidar aboard the NASA DC-8, taken as part of the second Airborne Arctic Stratospheric Expedition campaign; aerosol-rich air of midlatitude origin was seen in the expected position of the intrusions. The reality of the February event was also confirmed by in situ measurements from the NASA ER-2. Such events may be significant for the chemical processes taking place within the winter vortex. The intrusions were evidently related to the meteorology of the northern stratosphere during this winter and in particular to persistent tropospheric blocking over the northeastern Atlantic Ocean and western Europe and concomitant ridging into the lower stratospheric vortex in this region. Nevertheless, preliminary investigations have indicated that such events are not uncommon in other northern hemisphere winters, although no such events were found in the southern hemisphere during the Antarctic winter of 1987.

Plumb, R. A.↗

Combustion Processes in Hybrid Rocket Engines

In recent years, there has been a resurgence of interest in the development of hybrid rocket engines for advanced launch vehicle applications. Hybrid propulsion systems use a solid fuel such as hydroxyl-terminated polybutadiene (HTPB) along with a gaseous/liquid oxidizer. The performance of hybrid combustors depends on the convective and radiative heat fluxes to the fuel surface, the rate of pyrolysis in the solid phase, and the turbulent combustion processes in the gaseous phases. These processes in combination specify the regression rates of the fuel surface and thereby the utilization efficiency of the fuel. In this paper, we employ computational fluid dynamics (CFD) techniques in order to gain a quantitative understanding of the physical trends in hybrid rocket combustors. The computational modeling is tailored to ongoing experiments at Penn State that employ a two dimensional slab burner configuration. The coordinated computational/experimental effort enables model validation while providing an understanding of the experimental observations. Computations to date have included the full length geometry with and with the aft nozzle section as well as shorter length domains for extensive parametric characterization. HTPB is sed as the fuel with 1,3 butadiene being taken as the gaseous product of the pyrolysis. Pure gaseous oxygen is taken as the oxidizer. The fuel regression rate is specified using an Arrhenius rate reaction, which the fuel surface temperature is given by an energy balance involving gas-phase convection and radiation as well as thermal conduction in the solid-phase. For the gas-phase combustion, a two step global reaction is used. The standard kappa - epsilon model is used for turbulence closure. Radiation is presently treated using a simple diffusion approximation which is valid for large optical path lengths, representative of radiation from soot particles. Computational results are obtained to determine the trends in the fuel burning or regression rates as a function of the head-end oxidizer mass flux, G=rho(e)U(e), and the chamber pressure. Furthermore, computation of the full slab burner configuration has also been obtained for various stages of the burn. Comparisons with available experimental data from small scale tests conducted by General Dynamics-Thiokol-Rocketdyne suggest reasonable agreement in the predicted regression rates. Future work will include: (1) a model for soot generation in the flame for more quantitative radiative transfer modelling, (2) a parametric study of combustion efficiency, and (3) transient calculations to help determine the possible mechanisms responsible for combustion instability in hybrid rocket motors.

Venkateswaran,S.↗

Reproducible Crystal Growth Experiments in Microgravity Science Glovebox at the International Space Station (SUBSA Investigation)

Solidification Using a Baffle in Sealed Ampoules (SUBSA) is the first investigation conducted in the Microgravity Science Glovebox (MSG) Facility at the International Space Station (ISS) Alpha. 8 single crystals of InSb, doped with Te and Zn, were directionally solidified in microgravity. The experiments were conducted in a furnace with a transparent gradient section, and a video camera, sending images to the earth. The real time images (i) helped seeding, (ii) allowed a direct measurement of the solidification rate. The post-flight characterization of the crystals includes: computed x-ray tomography, Secondary Ion Mass Spectroscopy (SIMS), Hall measurements, Atomic Absorption (AA), and 4 point probe analysis. For the first time in microgravity, several crystals having nearly identical initial transients were grown. Reproducible initial transients were obtained with Te-doped InSb. Furthermore, the diffusion controlled end-transient was demonstrated experimentally (SUBSA 02). From the initial transients, the diffusivity of Te and Zn in InSb was determined.

Ostrogorsky, A.↗

Volatile Analysis by Pyrolysis of Regolith (Vapor) on the Moon using Mass Spectrometry

The identification of lunar resources such as water is a fundamental component of the the NASA Vision for Space Exploration. The Lunar Prospector mission detected high concentrations of hydrogen at the lunar poles that may indicate the presence of water or other volatiles in the lunar regolith [1]. One explanation for the presence of enhanced hydrogen in permanently shadowed crater regions is long term trapping of water-ice delivered by comets, asteroids, and other meteoritic material that have bombarded the Moon over the last 4 billion years [2]. It is also possible that the hydrogen signal at the lunar poles is due to hydrogen implanted by the solar wind which is delayed from diffusing out of the regolith by the cold temperatures [3]. Previous measurements of the lunar atmosphere by the LACE experiment on Apollo 17, suggested the presence of cold trapped vola'tiles that were expelled by solar heating [4]. In situ composition and isotopic analyses of the lunar regolith will be required to establish the abundance, origin, and distribution of water-ice and other volatiles at the lunar poles. Volatile Analysis by Pyrolysis of Regolith (VAPoR) on the Moon using mass spectrometry is one technique that should be considered. The VAPoR pyrolysis-mass spectrometer (pyr-MS) instrument concept study was selected for funding in 2007 by the NASA Lunar Sortie Science Opportunities (LSSO) Program. VAPoR is a miniature version of the Sample Analysis at Mars (SAM) instrument suite currently being developed at NASA Goddard for the 2009 Mars Science Laboratory mission (Fig. 1).

Glavin, D. P.↗