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At least 937 records · Page 52

Improved properties of recycled polypropylene by introducing the long chain branched structure through reactive extrusion

Highlights: • A novel approach is applied to modify recycled PP. • Long chain branched structure is introduced onto recycled PP. • The structural change of recycled PP is determined by FTIR, DSC and rheology. • The impact strength of recycled PP is obviously improved. • Inorganic fillers have no effect on the modification of recycled PP. - Abstract: An approach originated from preparing long chain branched polypropylene (PP) was applied to modify the properties of recycled PP that involved reactive extrusion to introduce a branched chain structure onto recycled PP under the assistance of chemical reaction between maleic anhydride (MAH) monomer and glycidyl methacrylate (GMA) grafts. The results from Fourier transformed infrared spectroscopy (FTIR) indicated the reaction took place during melt mixing, and the intensity of ester increased with increasing amount of MAH. Several rheological plots including complex viscosity, storage modulus, loss modulus, loss tangent and Cole-Cole plot were used to investigate the rheological properties of recycled PP and modified PP with MAH, which indicated an additional longer relaxation time that was not shown in recycled PP. The effects of branched structure on melting and crystallization behaviors were also investigated, demonstrating the branched chains acted as nucleating agent. Moreover, the branched structure of modified samples gave rise to enhance mechanical properties, especially, the higher impact strength compared with recycled PP.

36 MATERIALS SCIENCE↗

Local Spatial Heterogeneity of Holocene Carbon Accumulation throughout the Peat Profile of an Ombrotrophic Northern Minnesota Bog

Here, we evaluated the spatial heterogeneity of historical carbon accumulation rates in a forested, ombrotrophic bog in Minnesota to aid understanding of responses to an ongoing decade-long warming manipulation. Eighteen peat cores indicated that the bog has been accumulating carbon for over 11,000 years, to yield 176±40 kg C m –2 to 225±58 cm of peat depth. Estimated peat basal ages ranged from 5100 to 11,100 cal BP. The long-term apparent rate of carbon accumulation over the entire peat profile was 22±2 kg C m –2 yr –1 . Plot location within the study area did not affect carbon accumulation rates, but estimated basal ages were younger in profiles from plots closer to the bog lagg and farther from the bog outlet. In addition, carbon accumulation varied considerably over time. Early Holocene net carbon accumulation rates were 30±6 g C m –2 yr –1 . Around 3300 calendar BP, net carbon accumulation rates dropped to 15±8 g C m –2 yr –1 until the last century when net accumulation rates increased again to 74±57 g C m –2 yr –1 . During this period of low accumulation, regional droughts may have lowered the water table, allowing for enhanced aerobic decomposition and making the bog more susceptible to fire. These results suggest that experimental warming treatments, as well as a future warmer climate may reduce net carbon accumulation in peat in this and other southern boreal peatlands. Furthermore, our we caution against historical interpretations extrapolated from one or a few peat cores.

54 ENVIRONMENTAL SCIENCES↗

Phase Behavior of Mixtures of Block Copolymers and a Lithium Salt

We present experimental results on the phase behavior of block copolymer/salt mixtures over a wide range of copolymer compositions, molecular weights, and salt concentrations. The experimental system comprises polystyrene-block-poly(ethylene oxide) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt. It is well established that LiTFSI interacts favorably with poly(ethylene oxide) relative to polystyrene. The relationship between chain length and copolymer composition at fixed temperature is U-shaped, as seen in experiments on conventional block copolymers and as anticipated from the standard self-consistent field theory (SCFT) of block copolymer melts. The phase behavior can be explained in terms of an effective Flory-Huggins interaction parameter between the polystyrene monomers and poly(ethylene oxide) monomers complexed with the salt, χ eff , which increases linearly with salt concentration. The phase behavior of salt-containing block copolymers, plotted on a segregation strength versus copolymer composition plot, is similar to that of conventional (uncharged) block copolymer melts, when the parameter χ eff replaces χ in segregation strength.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Carbon Dioxide Insertion into Rhenium Hydrides as a Probe for the Impact of Solvent on Linear Free Energy Relationships between Thermodynamic and Kinetic Hydricity

The kinetics of CO 2 insertion into electronically different Re( R bpy)(CO) 3 H ( R bpy = 4,4'-R-2,2'- bipyridine; R = OMe, t Bu, Me, H, Br, COOMe, CF 3 ) complexes to form Re( R bpy)(CO) 3 {OC(H)O} compounds were determined in acetone, dimethylacetamide (DMAc), dimethylformamide (DMF), dimethylsulfoxide (DMSO), and 3-methoxypropionitrile (3-MPN) and compared with previous data in acetonitrile (MeCN). The rates of CO 2 insertion for any one complex of the type Re(Rbpy)(CO) 3 H in different solvents correlates with the Dimroth-Reichardt (E T (30)) solvent parameter. Hammett plots in each solvent indicate that insertion reactions are faster for bpy ligands with electron-donating groups. There is, however, no correlation between the slope of the Hammett plot in different solvents and any common solvent parameter. Similarly, the enthalpies and entropies of activation and kinetic isotope effects associated with CO 2 insertion into Re(bpy)(CO) 3 H in different solvents do not correlate with any common solvent parameters. Theoretical calculations were used to determine the relative thermodynamic hydricities of Re( R bpy)(CO) 3 H type complexes in MeCN, acetone, DMF, and DMSO and in each solvent complexes with more electron-donating substituents on the bpy ligand are stronger hydride donors. Linear Free Energy Relationships (LFERs) between calculated thermodynamic and experimental kinetic hydricity, as measured through CO 2 insertion reactions, were observed in MeCN, acetone, DMF, and DMSO. Furthermore, the slopes of the LFERs correlate with the dielectric constant of the solvent. Overall, this work provides fundamental information about the thermodynamics and kinetics of hydride transfer reactions in different solvents, which is valuable for catalyst design.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effects of PLA/PHB Blend Ratio and Wood Flour Loading on the Melt Rheology and Thermomechanical Properties of Biobased Polymer Composites

The development of sustainable, biobased polymer composites is crucial for reducing supply chain dependence on fossil fuels. A major challenge lies in understanding and predicting the processability of these sustainable material alternatives, which directly impacts large-scale manufacturing. Here, this study systematically investigates the effect of poly(lactic acid) (PLA)/polyhydroxybutyrate (PHB) blend ratios and wood flour (WF) loadings on the thermal, rheological, and mechanical properties of the composites. Composites were prepared via melt compounding and characterized by using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), oscillatory shear melt rheology, tensile testing, and scanning electron microscopy. Results showed that increasing the PHB content lowered the glass transition temperature, while higher PHB and WF loadings decreased thermal stability. Complex viscosity decreased with increasing PHB in 0 and 10% WF, whereas it increased in 20% and 30% WF for PHB-rich blends (80/20 and 70/30 PLA/PHB) due to stronger filler interactions with flexible PHB chains. At 30% WF, PHB-containing composites also showed elastic dominance with G′ higher than G″. This behavior was confirmed by van Gurp–Palmen plots, where the phase angle decreased with increasing PHB and WF loadings. WF addition also shifted Cole–Cole plots away from semicircular terminal relaxation, while time–temperature superposition validity was maintained, confirming that polymer chain dynamics continue to dominate melt behavior. Young’s modulus increased with WF loading, while tensile strength and toughness decreased due to weaker interfacial adhesion between the matrix and the filler. Interestingly, 10% WF systems containing PHB exhibited the highest toughness among all of the filled systems, indicating synergistic reinforcement from WF fillers and PHB-induced ductility. Overall, melt rheology effectively captured the internal structure and stiffness of the composites as the formulation changed, reinforcing the concept that the PLA/PHB ratio and WF content can be tuned to adjust melt elasticity and balance mechanical property trade-offs for targeted applications.

melt rheology↗

ENPOLITE: Comparing Lithium-Ion Cells across Energy, Power, Lifetime, and Temperature

Due to their impressive energy density, power density, lifetime, and cost, lithium-ion batteries have become the most important electrochemical storage system, with applications including consumer electronics, electric vehicles, and stationary energy storage. However, each application has unique, often conflicting product specifications, requiring a balanced overall assessment. The Ragone plot is a commonly-used plot to compare energy and power of lithium-ion battery chemistries. Important parameters including cost, lifetime, and temperature sensitivity are not considered. Overall, a standardized and balanced reporting and visualization of specifications would greatly help an informed cell selection process.

25 ENERGY STORAGE↗

Toward Optimization of Polymer Electrolytes by Electrochemical Characterization: Poly(pentyl malonate) versus Poly(ethylene oxide)

Ion transport in two polymer electrolytes, poly­(ethylene oxide) (PEO) and poly­(pentyl malonate) (PPM), mixed with lithium bis­(trifluoromethanesulfonyl)­imide (LiTFSI) is studied in the vicinity of the limiting current. The experimental measurements are in quantitative agreement with theoretical predictions based on the concentrated solution theory. The properties of two electrolytes are compared using a new plot wherein the length-normalized limiting current, i lim L, is plotted as a function of the length-normalized potential drop, Φlim/L, in symmetric cells with electrolyte thickness, L. We propose that electrolyte design should aim to obtain the largest values of i lim L and the smallest values of Φlim/L. Using this criterion, PPM/LiTFSI is a better polymer electrolyte than PEO/LiTFSI. We hope that PPM/LiTFSI will serve as a benchmark for developing next-generation polymer electrolytes.

Lee, Jaeyong↗

Comparative Technoeconomic Analysis of Pathways for Electrochemical Reduction of CO 2 with Methanol to Produce Methyl Formate

Electrochemical CO 2 reduction has promise as a technology that could help society reach carbon neutrality while producing valuable fuels and chemicals. Herein, the electrochemical synthesis of methyl formate, a product not observed in aqueous CO 2 electrolysis, has been analyzed by a rigorous technoeconomic model to evaluate its commercial viability. Methyl formate synthesis has been demonstrated with high faradaic efficiency through the electroreduction of CO 2 in methanol. Four competing approaches were analyzed: (1) Electroreduction of captured CO 2 in a dual CH 3 OH/H 2 O electrolyzer, (2) Direct electroreduction of flue gas CO 2 in a dual CH 3 OH/H 2 O electrolyzer, (3) Electroreduction of captured CO 2 in a CH 3 OH/CH 3 OH electrolyzer, and (4) Electroreduction of captured CO 2 in a H 2 O/H 2 O electrolyzer with a downstream CH 3 OH reactor. Sensitivity analyses, cost contour plots, and comparison plots were generated. The dual methanol/water electrolysis approach was the most cost-competitive, with a levelized cost of methyl formate below the present market price. Here, the all-methanol electrolysis route was more expensive due to increased methanol consumption and greater distillation costs. Methyl formate production through aqueous CO 2 electrolysis to formic acid with a secondary esterification reaction was by far the most expensive approach, primarily due to the energy-intensive nature of distilling formic acid from water.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Valence Band Modification and High Thermoelectric Performance in SnTe Heavily Alloyed with MnTe

Herein we demonstrate a high solubility limit of >9 mol% for MnTe alloying in SnTe. The electrical conductivity of SnTe decreases gradually while the Seebeck coefficient increases remarkably with increasing MnTe content, leading to enhanced power factors. The room-temperature Seebeck coefficients of Mn-doped SnTe are significantly higher than those predicted by theoretical Pisarenko plots for pure SnTe, indicating a modified band structure. The high-temperature Hall data of Sn 1– x Mn x Te show strong temperature dependence, suggestive of a two-valence-band conduction behavior. Moreover, the peak temperature of the Hall plot of Sn 1– x Mn x Te shifts toward lower temperature as MnTe content is increased, which is clear evidence of decreased energy separation (band convergence) between the two valence bands. The first-principles electronic structure calculations based on density functional theory also support this point. The higher doping fraction (>9%) of Mn in comparison with ~3% for Cd and Hg in SnTe gives rise to a much better valence band convergence that is responsible for the observed highest Seebeck coefficient of ~230 μV/K at 900 K. The high doping fraction of Mn in SnTe also creates stronger point defect scattering, which when combined with ubiquitous endotaxial MnTe nanostructures when the solubility of Mn is exceeded scatters a wide spectrum of phonons for a low lattice thermal conductivity of 0.9 W m –1 K –1 at 800 K. The synergistic role that Mn plays in regulating the electron and phonon transport of SnTe yields a high thermoelectric figure of merit of 1.3 at 900 K.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Mesopore-Confined and Graphene Oxide-Localized Ruthenium Catalyst Increases Rates of Mid-Chain Polyolefin Hydrogenolysis

A catalyst architecture with mesoporous silica coating Ru nanoparticles on reduced graphene oxide (mSiO 2 /Ru/rGO) localizes the 2 nm Ru solely at the closed bottoms of 2.9 nm diameter mesopores. mSiO 2 /Ru/rGO catalyzes the rapid, selective hydrogenolysis of polyolefins at wax formation rates (ν wax ) up to 1700 g wax ·g Ru –1 ·h –1 and a turnover frequency (TOF) for C–C bond cleavage of 130 ± 8 min –1 . The ν wax and TOF for mSiO 2 /Ru/rGO are 23× and 16× those of nonporous Ru/rGO, respectively, indicating that faster chain cleavage is also more selective inside mesopores. The methane yield from mSiO 2 /Ru/rGO is ca. 30% of the value obtained from Ru/rGO. Methane decreases, and wax selectivity improves with narrow-pore (2.3 nm) mSiO 2 /Ru/rGO. The reaction rate decreases at lower and higher H 2 pressures from its maximum at 37 bar. Log(TOF)-log(P H2 ) plots reveal rates ∝ [P H2 ] 2.8 or [P H2 ] −2.0 in the lower or higher pressure ranges, respectively. Corresponding plots for Ru/C give rates ∝ [P H2 ] 1 or [P H2 ] −2.4 . Ru is hydrocarbon-covered at low pressure; thus, the higher H 2 order for mSiO 2 /Ru/rGO indicates that mesopores increase the density of cleavable unsaturated moieties on the Ru surface. The lower H 2 order on Ru/C implies a lower density of cleavable groups because saturated segments occupy a larger fraction of the Ru surface. Higher surface occupancy by the hydrocarbon reactant correlates with more methane formation. Therefore, pore confinement, narrower pore diameter in mSiO 2 /Ru/rGO, or higher H 2 pressure leads to lower methane yields. Ru nanoparticles in mSiO 2 /Ru/rGO maintain equivalent activity and selectivity over five recycling tests.

Catalysts↗

Analytical Model to Detect Fault Permeability Alteration Induced by Fault Reactivation in Compartmentalized Reservoirs

Underground fluid injection induces changes in in situ stress condition of the target formation and local faults that can potentially lead to fault reactivation, which may result in the leakage of injected and/or native fluids into neighboring formations. In this paper, we introduce an analytical method to detect fault reactivation caused by fluid injection into deep faulted aquifers considering across-fault leakage. The fundamental assumption made in our model is that fault permeability will be altered upon fault slip. Therefore, we model fault reactivation as a sudden change in fault permeability at the onset of fault slip. The fault is modeled as a linear interface between two permeable formations with equal rock and fluid properties. The governing equations are coupled through the fault interface and are solved using the Laplace-Fourier integral transform technique. Based on the analytical solution, we find the characteristic bottomhole pressure and pressure derivative responses that enable detecting fault reactivation using diagnostic plots. We observe that pressure derivative undergoes a rapid change at the onset of fault slip followed by a late-time trend to attain a new equilibrium governed by the altered fault permeability. Furthermore, we discuss the evolution of the across-fault leakage rate upon and after fault slippage. Here, the results from this study are presented in the form diagnostic plots and type curves that may be used for reservoir and fault characterization purposes.

54 ENVIRONMENTAL SCIENCES↗

Getting to the Root of Plant–Mediated Methane Emissions and Oxidation in a Thermokarst Bog

Vascular plants are important in the wetland methane cycle, but their effect on production, oxidation, and transport has high uncertainty, limiting our ability to predict emissions. In a permafrost–thaw bog in Interior Alaska, we used plant manipulation treatments, field–deployed planar optical oxygen sensors, direct measurements of methane oxidation, and microbial DNA analyses to disentangle mechanisms by which vascular vegetation affect methane emissions. Vegetation operated on top of baseline methane emissions, which varied with proximity to the thawing permafrost margin. Emissions from vegetated plots increased over the season, resulting in cumulative seasonal methane emissions that were 4.1–5.2 g m –2 season –1 greater than unvegetated plots. Mass balance calculations signify these greater emissions were due to increased methane production (3.0–3.5 g m –2 season –1 ) and decreased methane oxidation (1.1–1.6 g m –2 season –1 ). Minimal oxidation occurred along the plant–transport pathway, and oxidation was suppressed outside the plant pathway. Our data indicate suppression of methane oxidation was stimulated by root exudates fueling competition among microbes for electron acceptors. This contention is supported by the fact that methane oxidation and relative abundance of methanotrophs decreased over the season in the presence of vegetation, but methane oxidation remained steady in unvegetated treatments; oxygen was not detected around plant roots but was detected around silicone tubes mimicking aerenchyma; and oxygen injection experiments suggested that oxygen consumption was faster in the presence of vascular vegetation. In conclusion, root exudates are known to fuel methane production, and our work provides evidence they also decrease methane oxidation.

58 GEOSCIENCES↗

Design and Assessment of a Novel Approach for Ecosystem Warming Experiments in High‐Energy Tidal Wetlands

Abstract Coastal salt marshes have an important role in climate change adaptation and mitigation. Direct and indirect responses to warming are expected to vary along the marsh elevation gradient, making ecosystem responses to warming at this marine‐terrestrial ecotone uncertain. The Marsh Ecosystem Response to Increased Temperatures (MERIT) experiment was established in 2018 on the North Sea coast of Germany. Experimental plots are evenly distributed over three elevational marsh zones (pioneer, low marsh, and high marsh) and include three temperature treatments (ambient, +1.5°C, +3.0°C). MERIT's novel design combines active warming (horizontal surface warming cables and vertical soil warming pins) with passive, partially covered domes. For performance assessment, temperature deltas between ambient and warmed plots were calculated and evaluated at seasonal, daily, and diurnal timescales. We used Linear Mixed Models with Residual Maximum Likelihood for evaluating warming treatment effects and constraining environmental factors. MERIT was effective at ecosystem warming in this high‐energy environment both above‐ and belowground. Mixed models show that warming treatment dominates temperature differences belowground and at the soil surface, along with factors such as wind speed, flooding duration, and solar radiation. Aboveground warming was lower than belowground warming, but the dome design minimized issues seen in other open‐top chamber experiments. The combination of passive aboveground warming with feedback‐controlled active surface and belowground heating provides a setup for understanding warming effects on tidal ecosystems without altering the natural impacts of wind, radiation, and tidal inundations at high‐energy coastlines. Our design creates opportunities to expand future warming experiments to remote locations and technically challenging environments.

Environmental Sciences & Ecology↗

Tundra soil carbon is vulnerable to rapid microbial decomposition under climate warming

Microbial decomposition of soil carbon in high-latitude tundra underlain with permafrost is one of the most important, but poorly understood, potential positive feedbacks of greenhouse gas emissions from terrestrial ecosystems into the atmosphere in a warmer world. Using integrated metagenomic technologies, we showed that the microbial functional community structure in the active layer of tundra soil was significantly altered after only 1.5 years of warming, a rapid response demonstrating the high sensitivity of this ecosystem to warming. The abundances of microbial functional genes involved in both aerobic and anaerobic carbon decomposition were also markedly increased by this short-term warming. Consistent with this, ecosystem respiration (R eco ) increased up to 38%. In addition, warming enhanced genes involved in nutrient cycling, which very likely contributed to an observed increase (30%) in gross primary productivity (GPP). However, the GPP increase did not offset the extra R eco , resulting in significantly more net carbon loss in warmed plots compared with control plots. Altogether, our results demonstrate the vulnerability of active-layer soil carbon in this permafrost-based tundra ecosystem to climate warming and the importance of microbial communities in mediating such vulnerability.

54 ENVIRONMENTAL SCIENCES↗

Reply to: Low-frequency quantum oscillations in LaRhIn 5 : Dirac point or nodal line?

We thank G.P. Mikitik and Yu.V. Sharlai for contributing this note and the cordial exchange about it. First and foremost, we note that the aim of our paper is to report a methodology to diagnose topological (semi)metals using magnetic quantum oscillations. Thus far, such diagnosis has been based on the phase offset of quantum oscillations, which is extracted from a “Landau fan plot”. A thorough analysis of the Onsager–Lifshitz–Roth quantization rules has shown that the famous π-phase shift can equally well arise from orbital or spin magnetic moments in topologically trivial systems with strong spin-orbit coupling or small effective masses. Therefore, the “Landau fan plot” does not by itself constitute a proof of a topologically nontrivial Fermi surface. In the paper at hand, we report an improved analysis method that exploits the strong energy dependence of the effective mass in linearly dispersing bands. This leads to a characteristic temperature dependence of the oscillation frequency which is a strong indicator of nontrivial topology, even for multi-band metals with complex Fermi surfaces. Three materials, Cd 3 As 2 , Bi 2 O 2 Se and LaRhIn5 served as test cases for this method. Linear band dispersions were detected for Cd 3 As 2 , as well as the F ≈ 7 T pocket in LaRhIn 5 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Large emissions of CO 2 and CH 4 due to active-layer warming in Arctic tundra

Climate warming may accelerate decomposition of Arctic soil carbon, but few controlled experiments have manipulated the entire active layer. To determine surface-atmosphere fluxes of carbon dioxide and methane under anticipated end-of-century warming, here we used heating rods to warm (by 3.8 °C) to the depth of permafrost in polygonal tundra in $Utqia\dot{g}vik$ (formerly Barrow), Alaska and measured fluxes over two growing seasons. We show that ecosystem respiration is ~30% higher in warmed plots than in control plots (0.99 μmol m -2 s -1 versus 0.67 μmol m -2 s -1 , p < 0.0001, n = 79). Additionally, the observed temperature sensitivity (Q 10 of 2.8) is higher than that imposed for soil in Earth system models or reported by arctic experiments warming only the surface. A shoulder-season warming experiment revealed that rapid snow melt, which is becoming a more common event, can result in large methane emissions that may have otherwise been oxidized to carbon dioxide. Thus, warming promotes greenhouse gas emissions from the whole, deepening active layer and may contribute to climate change amplification.

54 ENVIRONMENTAL SCIENCES↗

Warming induces unexpectedly high soil respiration in a wet tropical forest

Abstract Tropical forests are a dominant regulator of the global carbon cycle, exchanging more carbon dioxide with the atmosphere than any other terrestrial biome. Climate models predict unprecedented climatic warming in tropical regions in the coming decades; however, in situ field warming studies are severely lacking in tropical forests. Here we present results from an in situ warming experiment in Puerto Rico, where soil respiration responses to + 4 o C warming were assessed half-hourly for a year. Soil respiration rates were 42-204% higher in warmed relative to ambient plots, representing some of the highest soil respiration rates reported for any terrestrial ecosystem. While respiration rates were significantly higher in the warmed plots, the temperature sensitivity (Q 10 ) was 71.7% lower, pointing to a mechanistic shift. Even with reduced Q 10 , if observed soil respiration rates persist in a warmer world, the feedback to future climate could be considerably greater than previously predicted or observed.

Science & Technology - Other Topics↗

The Arctic Plant Aboveground Biomass Synthesis Dataset

Plant biomass is a fundamental ecosystem attribute that is sensitive to rapid climatic changes occurring in the Arctic. Nevertheless, measuring plant biomass in the Arctic is logistically challenging and resource intensive. Lack of accessible field data hinders efforts to understand the amount, composition, distribution, and changes in plant biomass in these northern ecosystems. Here, we present The Arctic plant aboveground biomass synthesis dataset, which includes field measurements of lichen, bryophyte, herb, shrub, and/or tree aboveground biomass (g m -2 ) on 2,327 sample plots from 636 field sites in seven countries. We created the synthesis dataset by assembling and harmonizing 32 individual datasets. Aboveground biomass was primarily quantified by harvesting sample plots during mid- to late-summer, though tree and often tall shrub biomass were quantified using surveys and allometric models. Each biomass measurement is associated with metadata including sample date, location, method, data source, and other information. This unique dataset can be leveraged to monitor, map, and model plant biomass across the rapidly warming Arctic.

54 ENVIRONMENTAL SCIENCES↗