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Battery Energy Storage Scenario Analyses Using the Lithium-Ion Battery Resource Assessment (LIBRA) Model

Meeting aggressive carbon emission goals will entail widespread deployment of renewable sources of electricity. Because these sources are variable, there is a need to develop scalable energy storage technologies. The U.S. Department of Energy is supporting efforts to increase U.S. manufacturing and recycling capabilities for LIBs and to decrease costs of stationary storage batteries. Many factors influence the domestic manufacturing and cost of stationary storage batteries, including availability of critical raw materials (lithium, cobalt, and nickel), competition from various demand sectors (consumer electronics, vehicles, and battery energy storage), resource recovery (recycling), government policies, and learning in the industry, among other factors. Understanding how these factors interact and identifying synergies and bottlenecks is important for developing effective strategies for the LIB stationary energy storage system. We developed the Lithium-Ion Battery Resource Analysis (LIBRA) model as a tool to help stakeholders better understand the following types of questions: What are the roles of R&D, industrial learning, and scaling of demand in lowering the cost of battery energy storage system production? How do the intersections between the EV and stationary storage sectors affect the battery supply chain? For various stationary storage and EV penetration scenarios, what volumes of critical materials might be required and what role can resource recovery play? What does expected demand for both EVs and stationary storage portend for mineral resources and overall mineral scarcity? The LIBRA model is developed using a System dynamics (SD) modeling approach to represent interactions across the segments of the battery materials supply chain. System dynamics models can capture the complex interactions and feedback between the various system components that influence supply and demand. The LIBRA model is comprised of several interacting modules that represent specific portions of the LIB supply chain. The model tracks the buildout of the domestic LIB industry over time (2020 - 2050) and in the context of competing demands for raw materials, recycling, and markets for LIBs. The LIBRA model represents major systemic feedback loops and delays across the supply chain. This report provides a complete documentation for the LIBRA model, including model assumptions, data, scenario analysis results, and sensitivity analysis of the model's input space.

25 ENERGY STORAGE↗

A visiting scientist program for the burst and transient source experiment

During this project, Universities Space Research Association provided program management and the administration for overseeing the performance of the total contractual effort. The program director and administrative staff provided the expertise and experience needed to efficiently manage the program.USRA provided a program coordinator and v visiting scientists to perform scientific research with Burst and Transient Source Experiment (BATSE) data. This research was associated with the primary scientific objectives of BATSE and with the various BATSE collaborations which were formed in response to the Compton Gamma Ray Observatory Guest Investigator Program. USRA provided administration for workshops, colloquia, the preparation of scientific documentation, etc. and also provided flexible program support in order to meet the on-going needs of MSFC's BATSE program. USRA performed tasks associated with the recovery, archiving, and processing of scientific data from BATSE. A bibliography of research in the astrophysics discipline is attached as Appendix 1. Visiting Scientists and Research Associates performed activities on this project, and their technical reports are attached as Appendix 2.

Kerr, Frank J.↗

Comparing extracting and recirculating residential kitchen range hoods for the use in high energy efficient housing

Residential cooking can be a significant indoor source of odour, pollutants and particulate matter. Conventionally, range hoods expel the air into the ambient. A number of studies have investigated their contaminant capture performance. However, for highly energy efficient houses the installation of extracting range hoods can pose certain challenges, e.g. high ventilation losses, additional thermal bridges and potential air leakage sites. Therefore, the use of recirculation range hoods has become standard for highly energy efficient housing with mechanical ventilation with heat recovery in Central Europe. Open questions remain regarding their capture and filtration efficiency as a function of filter age, especially for particles and odours. But also, the actual energy savings potential when using recirculating instead of extracting devices in a highly energy efficient housing had not been documented yet. This paper addresses these questions with a literature review and an energetic comparison. The review identified a good number of studies which have investigated the capture performance of extracting range hoods with a focus on pollutants resulting from gas combustion and/or the cooking generated particles. These studies show that capture efficiency, in particular for front burner use, can vary drastically for different designs and that particle capture does not necessarily match capture efficiency for gaseous contaminants. No scientific study investigating the performance of recirculating range hoods was found. Tests for consumer magazines as well as surveys indicate notably lower performance compared to extracting hoods. In summary one can say that performance tests are urgently needed to quantify the capture and filter efficiency for particles and (odorous) organic compounds as a function of filter age.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Impact Testing of Heat Source Exemplars

This report details the heat source impact testing performed at the Shock Thermodynamics Applied Research Facility (STAR). The purpose of these tests were to measure the impact behavior of a heated Ta-10W tantalum/tungsten alloy heat source exemplar. Each exemplar resembled a cylinder with a rectangular through-hole orthogonal to the cylinder axis-of-symmetry. In each test, the exemplar was impacted by a hardened steel impactor accelerated using the STAR air gun. The exemplars were impacted perpendicular to the through-hole and at an an angle to the cylindrical axis-of-symmetry. The exemplar bar stock source, impact angle, and impact velocity were varied throughout the testing series. High-speed video was used to measure dynamic impact behavior while photon doppler velocimetry (PDV) and shorting pins were used to measure the impact velocity. Foam support structures were used to thermally isolate the exemplar and provide a support structure which was non-perturbative to the impact event. Soft-catch techniques were used to minimize secondary impacts and enable recovery for detailed post-shot analysis. Results indicate positive correlation between exemplar fracture and the variables of impact velocity and impact angle. Exemplar fracture occurred consistently along a single corner of the through-hole.

36 MATERIALS SCIENCE↗

Helium mining on the Moon: Site selection and evaluation

The feasibility of recovering helium (He) from the Moon as a source of fusion energy on Earth is currently being studied at the University of Wisconsin. Part of this study is selection and evaluation of potential sites for lunar He mining. Selection and evaluation of potential mining sites are based on four salient findings by various investigators of lunar samples: (1) Regoliths from areas underlain by highland materials contain less than 20 wppm He; (2) Certain maria regoliths contain less than 20 wppm He, but other contain 25 to 49 wppm; (3) The He content of a mare regolith is a function of its composition; regoliths rich in Ti are relatively rich in He; and (4) He is concentrated in the less than 100-micron size fractions of regoliths. The first three findings suggest that maria are the most promising mining sites, specifically, those that have high-Ti regoliths. Information on the regional distribution and extent of high-Ti regoliths comes mainly from two sources: direct sampling by various Apollo and Luna missions, and remote sensing by gamma-ray spectroscopy and Earth-based measurements of lunar spectral reflectance. Sampling provides essential control on calibration and interpretation of data from remote sensing. These data indicate that Mare Tranquillitatis is the principal area of high-Ti regolith of the eastern nearside, but large areas of high-Ti regolith are indicated in the Imbrium and Procellarum regions. Recovery of significant amounts of He-3 will require mining billions of tonnes of regolith. Large individual areas suitable for mining must therefore be delineated. The concentration of He in the finer size fractions and considerations of ease of mining mean that mining areas must be as free as possible of sizable craters and blocks of rock. Pending additional lunar missions, information regarding these features must be obtained from lunar photographs, photogeologic maps, and radar surveys. The present study is decidedly preliminary; available information is much to limited to permit even a close approach to final evaluations. As a prelude to recovery of He from the Moon, systematic exploration and sampling of high-Ti regoliths should therefore have a high priority in future lunar missions.

Cameron, Eugene N.↗

Launch Complex 34, SWMU Cc054 2021 DNAPL Source Zone Operations, Maintenance, and Monitoring, and Hot Spot 6 Air Sparge System Annual Performance Monitoring Report Cape Canaveral Space Force Station, Florida

This Annual Performance Monitoring Report (PMR) for the Dense Non-Aqueous Phase Liquid (DNAPL) Source Zone (DSZ) and Hot Spot 6 (HS 6) Air Sparge (AS) System presents the results of Year 12 operation of the hydraulic containment (HC) Interim Measure (IM), the results of performance monitoring direct-push technology (DPT) sampling and monitoring well sampling conducted in the DSZ, and the results of operations and performance sampling of the HS 6 AS IM at Launch Complex 34 (LC34), located at Cape Canaveral Space Force Station (CCSFS), Florida. Site-wide biennial LTM sampling was not conducted during this reporting period and is scheduled to be conducted in December 2022. The timeframe for activities documented in this PMR extends from April 1, 2021 to March 31, 2022. LC34 has been designated Solid Waste Management Unit CC054 under the Kennedy Space Center (KSC) Resource Conservation and Recovery Act Corrective Action Program. The objective of the HC IM at LC34 is to contain the DSZ and deep dissolved-phase trichloroethene (TCE) high concentration plume via operation of a hydraulic containment system (HCS). The pre-IM design 300 micrograms per liter (μg/L) TCE groundwater contour was used to establish the deep zone capture area for deep recovery wells, and the shallow zone capture area was defined by the DSZ. The system began operating in 2010, and in 2015, the system was expanded to provide HC for areas within the 300 μg/L TCE groundwater isocontours of HS 3 and 4. In 2018 and 2019, an investigation was conducted to re-characterize the DSZ, which included investigating TCE mass in Layer 7. This data was subsequently used to optimize the pumping rates of the HCS to more adequately capture residual contaminant mass. The operational period for Year 12 of the HCS was from April 1, 2021 to March 31, 2022. Operational runtime for the system was 94 percent during Year 12, with downtime events attributed to planned maintenance, system repairs, and power outages. As of March 31, 2022, a total of 285,712,801 gallons of groundwater containing 84,933 pounds of VOCs have been removed by the HCS. Influent concentrations of TCE have decreased since startup from approximately 280,000 µg/L (January 2010) to 12,000 µg/L (March 2022). During the reporting period, all effluent concentrations from the HCS (aqueous and vapor) were below regulatory reporting limits, indicating the system continues to operate as intended. Performance monitoring was conducted in December 2021 within the DSZ to evaluate TCE contamination. Groundwater samples were collected via DPT at nine locations, consistent with previous events in 2017, 2018, 2019, and 2020. Full vertical profile sampling was completed at each DPT from 8 to 98 ft bls, at 5 foot intervals. The DPT performance monitoring results are summarized in this PMR. The results revealed TCE remains at concentrations greater than 11,000 µg/L in the DSZ (1-percent solubility, indicative of DNAPL) at eight of the nine DPT locations at depths ranging from 8 to 98 ft bls. An overall increasing trend of TCE concentrations was observed in DPT samples during this reporting period, which may be due to several recovery wells that were turned off during the AS Pilot Study in the DSZ that operated from July 2021 to February 2022 (documented separately from this report). The maximum TCE concentration in 2021 was 15,400,000 µg/L in the 58 ft bls depth interval at DPT597 (previous maximum result in 2020 was 1,690,000 at 48 ft bls at DPT596). During the 2021 DPT event, the overall majority of TCE contamination was identified in the 58 ft bls interval (below Layer 4), where in the previous year the majority of mass was observed in Layer 4. This trend appears to indicate continued mass discharge from Layer 4 (fine-grained unit). In addition to DPT sampling, monitoring well samples were collected from deep wells in the DSZ area (Layers 7 and 8) to verify vertical delineation. All monitoring well results were non-detect or below cleanup levels, with exception of one well (IW0162, screened 105 to 115 ft bls, which is below the existing recovery well capture zone) where TCE was identified above cleanup target levels. The HS 6 AS system remained operational during the reporting period covered under this report. The HS 6 AS IM was initiated in 2018 with 160 AS wells, and expanded in 2019 with an additional 140 AS wells. Quarterly performance monitoring was reduced to semi-annual prior to this operational period. The results of the HS 6 system operation and semi-annual performance monitoring are summarized in this report. Semi-annual monitoring results collected in April and October 2021 show concentrations of contaminants of concern (cis-1,2-dichloroethene, trans-1,2- dichloroethene, and vinyl chloride) are generally decreasing and not impacting the surface water drainage canal, indicating the HS 6 IM is meeting objectives. Overall, the tasks associated with Year 12 operation of the HC IM and operation of the HS 6 AS IM were performed in accordance with the recommendations of the 2020 LC34 (Year 11) Operations, Maintenance, and Monitoring Report for DNAPL Source Zone, Site Wide LongTerm Monitoring, and Hot Spot 6 Air Sparging System PMR (NASA, 2021c). Evaluation of results from the HC IM and HS 6 IM show that these systems are operating as designed and meeting performance objectives.

trichloroethene↗

2022 AI Testbed Expeditions Report

By exploiting the coherent properties of a light source, coherent diffraction imaging (CDI) is able to obtain the sample image at a nanoscale resolution using the measured diffraction pattern. Bragg Coherent Diffraction Imaging (BCDI) has become valuable for recovering the displacement and strain field of crystals, providing a valuable tool in material science and solid-state physics. X-ray ptychography is another emerging CDI technique that can produce a high-resolution image of the extended sample and has become popular in many research areas (e.g., materials science, biology, electronics, and optics characterization). CDI including BCDI and ptychography has become an established technique in Synchrotron Facilities including the Advanced Photon Source (APS) and will greatly benefit from the 100x coherent flux increase of the upcoming APS Upgrade (APSU). The current image formation process in CDI employs iterative phase retrieval algorithms, which is a time-consuming and computationally expensive process. Especially after APSU, the traditional iterative methods will not be able to match the experimental data acquisition speed. We employ deep learning (DL) approach to replace the iterative approaches, therefore allowing hundreds of times faster recovery of the object. We developed AutoPhaseNN, a DL-based approach which learns to solve the inverse problem without labeled data. Taking 3D BCDI as a representative technique, AutoPhaseNN has been demonstrated to be one hundred times faster than traditional iterative phase retrieval methods while providing comparable image quality. The current network is trained with 64 x 64 x 64 data size, to achieve higher resolution imaging, we will need to scale the network to input and train/infer 3D arrays of size 256 x 256 x 256 (today) and of size 2560x2560x2560 (APSU). However, the scalability of the network is restricted due to the memory-intensive training process. To perform the training for a 256 x 256 x 256 data size, the required memory exceeds the capacity of the current machine. In this project, we explore using Sambanova system to train the network for the direct data inversion for CDI.

36 MATERIALS SCIENCE↗

Shock recovery analogs and the origin of mesosiderites

The origin of mesosiderites, which consist of approximately equal-weight proportions of Fe-Ni metal and silicates (gabbros, basalts, orthopyroxenites, dunites), remains an interesting and complex problem in meteoritics. There is general agreement that multiple impact events were probably involved in the formation of these brecciated stony-iron meteorites, but given the heterogeneity of mesosiderites, additional processes have been invoked to explain the unique and intricate textural and compositional makeup of mesosiderites. We conducted a series of shock recovery experiments to test the impact event(s) scenario. The results indicated significant similarities between the shocked analogs and many mesosiderites. We have compared our analogs with a suite of thin sections of Barea mesosiderite. I have conducted a series of flash heating experiments in which equal-weight proportions of gabbro and stainless steel (SS304) powders were compressed into small charges and heated under reducing conditions for short times. These experiments were used to bracket localized, peak postshock temperatures in our analog shots and to compare the mixing relations between the silicate and metal. The shock recovery experiments used porous metal-silicate powder starting mixtures, therefore our experiments are most analogous to an impact scenario where the target is an asteroidal regolith surface composed of a loose mixture of Fe-Ni metal and heterogeneous silicates. Analog experiments may really describe a secondary impact process similar to the late-stage, localized impact melting event. This leaves one of the crucial questions about mesosiderite genesis unanswered, namely what is the source of the Fe-Ni metal that is so intimately distributed in these meteorites?

Rowan, L. R.↗

Secure and Resilient Operations Using Open-Source Distributed Systems Platform (OpenDSP)

The goal of this project is to identify and address cybersecurity gaps by developing a multi-layer multi-channel cyber-physical defense and survival mechanism for operating distribution networks with high penetration of solar / inverter-based resource (IBR) / distributed energy resource (DER). The proposed security enhancements are built upon the distributed framework and solution architecture for both information technology (IT) and operational technology (OT) systems. The technical solutions consist of two composite functionalities and six layers: proactive defense (vulnerability assessment, communication protection, and attack detection, as layers 1-3), and adaptive self-healing (attack-resilient control, adaptive recovery, and resilient survival, as layers 4-6). These layers, built on and extended from DHS CISA Cyber Framework, establish an integrated and robust cybersecurity framework for operating large-scale distribution networks.

14 SOLAR ENERGY↗

Numerical Analysis of the Source of Excessive Na + and Cl – Species in Flowback Water From Hydraulically Fractured Shale Formations

Fracture fluid comprises fresh water, proppant, and a small percentage of other additives, which support the hydraulic fracturing process. Excluding situations in which flowback water is recycled and reused, total dissolve solids in fracture fluid is limited to the fluid additives, such as potassium chloride (1-7 weight percent KCL), which is used as a clay stabilizer to minimize clay swelling, and clay particle migration. However, the composition of recovered fluid, especially as it relates to the total dissolve solids (TDS), is always substantially different than the injected fracture fluid. The ability to predict flowback water volume and composition is useful when planning for the management or reuse of this aqueous byproduct stream. In this work, an ion transport and halite dissolution model was coupled with a fully implicit, dual porosity, numerical simulator, to study the source of the excess solutes in flowback water, and to predict the concentration of both Na+ and Cl- species seen in recovered water. The results showed that mixing alone, between the injected fracture fluid and concentrated in situ formation brine, could not account for the substantial rise in TDS seen in flowback water. Instead, the results proved that halite dissolution is a major contributor to the change in TDS seen in fracture fluid during injection and recovery. Halite dissolution can account for as much as 81% of Cl- and 86.5% of Na+ species seen in 90-day flowback water; mixing, between the injected fracture fluid and in situ concentrated brine, accounts for approximately 19% Cl- and 13% Na+.

03 NATURAL GAS↗

Systems Biology of Lipid Body Formation in the Green Alga Chlamydomonas reinhardtii

The project aimed to deepen our understanding of alga triacylglycerol (TAG) production to undergird explorations of using algal TAG as a source of biodiesel fuel. Our published contributions included the following: 1) Development of a rapid assay for TAG in algal cultures which was widely distributed to the algal community. 2) A comprehensive transcriptome analysis of the development of the ultra-high-TAG “obese” phenotype In Chlamydomonas reinhardtii . 3) A comprehensive biochemical and ultrastructural analysis of the cell wall of Nannochloropsis gaditana, whose walls render it both growth-hardy and difficult to rupture for TAG recovery. A manuscript in preparation considers the autophagy response in C. reinhardtii and its entrance into stationary phase, both having an impact on TAG production.

09 BIOMASS FUELS↗

Joint Assimilation of the Aura Microwave Limb Sounder and Ozone Mapping and Profiler Suite Limb Profiler Data: Towards a Reanalysis of Stratospheric Ozone for Trend Studies

The future trajectory of the stratospheric ozone recovery will be sensitive to greenhouse gas concentrations through thermal control of chemical loss and via stratospheric circulation changes. The latter in particular is subject to considerable uncertainty meriting continuing monitoring of the evolution of ozone throughout the depth of the stratosphere. Atmospheric reanalyses utilize the data assimilation methodology to obtain comprehensive representations of the state of the atmosphere, including its composition, on multidecadal scales by combining diverse measurements from satellite-borne and conventional data sources. Systematic biases among these various data types pose a challenge for assimilation by introducing spurious discontinuities that affect the utility of reanalyses for studies of long-term variability and trends.In this presentation we will outline an approach, developed at NASA's Global Modeling and Assimilation Office (GMAO), that allows joint assimilation of stratospheric ozone profiles from the Microwave Limb Sounder (MLS) on EOS Aura and the Ozone Mapping and Profiler Suite Limb Profiler (OMPS-LP) currently flying on the Suomi-NPP satellite with future missions projected into the 2030s. We will demonstrate that a simple offline correction significantly reduces biases between MLS and OMPS-LP ozone data providing a strategy for generating a long-term vertically resolved homogenized representation of stratospheric ozone in future reanalyses. One novel element of our approach compared to previous GMAO reanalysis is the use of a version of the Goddard Earth Observing System model with full stratospheric chemistry. We will show selected comparisons of MLS and OMPS-LP assimilation experiments with independent ozonesonde and satellite data as well as two examples of process-based evaluation focused on the 2016 QBO disruption and Arctic winter ozone loss focusing on the relative performance of the MLS and OMPS-LP analyses.

Wargan, K.↗

Final Technical Report for DE-SC0013619

The Facility for Rare Isotope Beams (FRIB) is a new national user facility currently under construction on the campus of Michigan State University (MSU) in the United States. This facility will produce beams of radionuclides that have previously only existed in supernovae explosions and the crusts of neutron stars. As it creates and delivers beams of some of the most exotic nuclei in the universe, FRIB will simultaneously generate thousands of other radionuclides that could be synergistically harvested without impact to the primary experiment. Many of these co-produced isotopes are of significant interest for research in biomedicine, energy, environmental studies, plant sciences, and materials science. The primary beam dump, a spinning titanium container filled with cooling water, will contain the vast majority of co-produced isotopes at FRIB. There are several challenges associated with isotope harvesting from the primary beam dump loop. While a long-lived isotopes like 148Gd (70.9 y) can be harvested from the spent resin beds, methods will need to be developed to efficiently recover trace amounts of the isotope from the large volume resin. Conversely, while short-lived isotopes can be recovered in situ, the neutral pH environment, high flow rates, and large volume introduce unique challenges for efficiently harvesting ultra-trace amounts of an isotope from the circulating water loop. We have demonstrated in this work a way to harvest long-lived isotopes like 148Gd from the spent resin beds in way that minimizes the waste generated from processing nearly 200 L of the resin. We have also demonstrated that hollow fiber supported liquid membranes (HFSLM) can recover 70% of ultra-trace levels (less than 10 parts-per-trillion) of vanadium from a circulating water loop at pH 7. The work also demonstrated recovery from a solution containing the competing species at the concentrations anticipated for a one week run at FRIB with the primary ion beam 58Ni. To the best of our knowledge, this is the first demonstration of HFSLM for such ultra-trace concentrations.

07 ISOTOPE AND RADIATION SOURCES↗

Recovery and Recycle of Irradiated Low-Enriched Uranium from the Production of 99 Mo

Technetium-99m ( 99m Tc), the daughter (decay product) of molybdenum-99 ( 99 Mo), is the most commonly used medical radioisotope in the world. 99 Mo is produced primarily from the fissioning of 235 U. A potential future producer, Eden Radioisotopes, is planning to irradiate low-enriched-uranium metal-foil targets for production of 99 Mo. Their plan is to recover, purify, and recycle the irradiated LEU in a new set of targets inside their facility. This study assesses processes to (1) purify and recycle uranium following 99 Mo recovery and (2) convert the uranium to metal for subsequent foil production and target fabrication. A UREX (uranium recovery by extraction) liquid–liquid extraction flowsheet that utilizes centrifugal contactors was developed using the Argonne model for universal solvent extraction (AMUSE) to recover and purify the uranium. The calculated flowsheet predicted high decontamination from Pu and most fission products and >99.99% recovery of uranium. Suggestions for conversion of the UREX U-product (uranyl nitrate in dilute nitric acid) to U metal were provided based on literature studies and earlier laboratory studies performed at Argonne National Laboratory.

07 ISOTOPE AND RADIATION SOURCES↗

Data for Sustainable Co-Production of Plant Lipids and Cellulosic Sugars from Transgenic Energycane at an Industrially Relevant Scale: A Proof of Concept for Alternative Feedstocks

Development of sustainable and scalable technologies to convert lignocellulosic biomass to biofuels is critical to achieving carbon neutrality. The potential of transgenic bioenergy crops as a renewable source of sugars and lipids has been demonstrated at bench-scale. However, scaling up these processes is important for holistic analysis. Here proof-of-concept for chemical-free hydrothermal pretreatment of transgenic energycane-oilcane line L13 at an industrially relevant scale to recover vegetative lipids along with cellulosic sugars is presented. Pilot-scale processing of 97 kg of transgenic energycane-oilcane L13 stems and high solids pretreatment of bagasse enhanced the recovery of cellulosic glucose and xylose by 5-fold as compared to untreated bagasse and helped in the enrichment of vegetative lipids in the biomass residues which allowed its recovery at the end of the bioprocess. Palmitic and oleic acids were the predominant fatty acids (FAs) extracted from stems and leaves. The processing did not affect lipid composition. The efficiency of lipid recovery from untreated biomass was 75.9% which improved to 88.7% upon pretreatment. The vegetative tissues of transgenic energycane-oilcane L13 contained 0.42 metric tons/hectare of lipids. Processing vegetative tissues yielded 0.38 metric tons/hectare of lipids. This approaches an oil yield similar to soybean (global average 0.44 metric tons/hectare) and is almost twice as high as the oil yield from sugarcane engineered to hyperaccumulate lipids (0.20 metric tons/hectare). The study suggests that further optimization by state-of-the-art metabolic engineering and biomass processing can establish transgenic bioenergy crops for commercial drop-in fuel production.

Biomass Analytics↗

Ambiguity resolution for satellite Doppler positioning systems

The implementation of satellite-based Doppler positioning systems frequently requires the recovery of transmitter position from a single pass of Doppler data. The least-squares approach to the problem yields conjugate solutions on either side of the satellite subtrack. It is important to develop a procedure for choosing the proper solution which is correct in a high percentage of cases. A test for ambiguity resolution which is the most powerful in the sense that it maximizes the probability of a correct decision is derived. When systematic error sources are properly included in the least-squares reduction process to yield an optimal solution the test reduces to choosing the solution which provides the smaller valuation of the least-squares loss function. When systematic error sources are ignored in the least-squares reduction, the most powerful test is a quadratic form comparison with the weighting matrix of the quadratic form obtained by computing the pseudoinverse of a reduced-rank square matrix. A formula for computing the power of the most powerful test is provided. Numerical examples are included in which the power of the test is computed for situations that are relevant to the design of a satellite-aided search and rescue system.

Argentiero, P.↗

Design Solutions for the Treatment of DMSD in the ISS Water Recovery System

Dimethylsilanediol (DMSD) has been identified as a problematic organic on ISS. This contaminant was initially identified in the Water Processor Assembly (WPA) product water in 2010 by the Total Organic Carbon Analyzer (TOCA). DMSD is not a crew health hazard at the levels observed in the product water, but it may degrade the performance of the Oxygen Generation System (OGS) which uses the WPA product water for electrolysis and does impact the effective operation of the WPA catalytic reactor. To mitigate these impacts, early replacement of the Multifiltration Beds in the WPA is required. An investigation has determined that the decomposition of atmospheric polydimethylsiloxanes (PDMSs) is the primary source of DMSD in the condensate. PDMSs are prevalent on ISS from a variety of sources, including crew hygiene products, adhesives, caulks, lubricants, and various nonmetallics. These PDMSs also contribute to degradation of the CHX hydrophilic coating, rendering it hydrophobic and therefore affecting its ability to transmit water to the condensate bus. In addition, literature research has determined that PDMSs are likely oxidized to DMSD in the atmosphere when exposed to hydroxyl radicals in the ISS atmosphere. To address these mechanisms, filters have been developed for removal of PDMSs from the ISS atmosphere. However, ongoing analysis indicates a significant reduction in atmospheric PDMSs is required to achieve a measurable reduction of DMSD in the condensate. As a result, additional measures are being pursued to mitigate this issue. First, credible sources are being investigated to quantity to the extent possible the significant sources of PDMSs and identify sources that can be reasonably removed from ISS. Second, a Reverse Osmosis technology is being investigated as an alternate means for removing DMSD from the condensate. This paper summarizes the current status of the overall effort to mitigate DMSD in the US condensate.

Perry, Jay↗

Pollen and Bio-Soiling in the Southeast U.S.

Typical PV soiling models presume that soiling follows a sawtooth pattern: linear soiling during dry periods followed by abrupt recovery or cleaning during rainfall events. Due to frequency of rainfall in the in the eastern U.S. sawtooth soiling models report near zero soiling losses in this region. Alternatively, through work with system owner/operators per NREL's PVfleet project it has become clear that there are systems in the Southeast that have soiled as high as 10% which are not recovering with regular rainfall. The current hypothesis is that sticky soiling due to pollen or other biological sources is persistent to rainfall removal. Field data and the latest progress towards de-risking bio-soiling will be presented.

photovoltaic↗