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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 937 records · Page 52

Project Title: Development of a Pipe Crawler Inspection Tool for Fossil Energy Power Plants (Final Report)

This research effort focuses on the development of a pipe crawler inspection tool for fossil energy power plants. The pipe crawler is tethered and can navigate through 2 inch pipes that are often found in various systems within a power plant. The crawler can navigate through straight pipes and 180 degree elbows and includes instrumentation that can assess the integrity of the pipes. The sensors include a UT sensor for measuring the thickness of the pipe, a range finder and a camera. An additional module is used to prep the surface of the pipe prior to taking thickness measurements. Both bench scale and engineering scale testing was conducted to demonstrate the concept. Multiple crawlers were created and tethered together to distribute the load of the tether so that the crawler can navigate longer pipe distances.

01 COAL, LIGNITE, AND PEAT↗

Report on the Integration of Experimental and Modeling Data for Initial Equivalence Study of Mechanical Performance in Irradiated LPBF 316 Stainless Steel

To ensure the rapid development, deployment, and use of advanced nuclear technologies, faster qualification approaches are needed. Typically, the primary pathway uses traditional data packages consistent with the American Society of Mechanical Engineers Boiler and Pressure Vessel Code, which does not consider the environmental effects the material will experience such as corrosion and radiation damage. Examining radiation effects requires a significant amount of space in US facilities at the Advanced Test Reactor and the High Flux Isotope Reactor (HFIR) and suffers from natural gradients in temperature and neutron flux profiles. Ion irradiation may enable rapid assessment of radiation-induced damage to a material and is proposed as part of an accelerated materials qualification framework through the Advanced Materials and Manufacturing Technologies program. To enhance the utility of ion irradiation as an examination tool, this report provides the initial assessment of engineering-relevant properties of microstructures produced from ion irradiation in the near-surface volume. Nanoindentation, Vickers hardness, and known tensile properties were brought together with simple mathematical models and experimental data for an initial equivalence study of the mechanical performance of irradiated laser powder bed fusion (LPBF) 316 stainless steels across length scales. Direct observation of the calculated ion irradiation yield stress and measured neutron irradiation yield stress at 2 dpa showed that both datasets exhibit the same trend with irradiation temperature and overlap within an acceptable band of stress values. Ion irradiations at 10 dpa serve as a prediction of properties to compare to postirradiation examination of HFIR-irradiated LPBF 316H further in the program. This work is a significant demonstration of the Licensing Approach with Ions and Neutrons, which uses ion irradiations to generate mechanical property information more rapidly than through neutron irradiations.

36 MATERIALS SCIENCE↗

Evaporation-driven engines

Evaporation-driven engines are disclosed herein. An example engine can include a water source having a high humidity zone proximate the surface of the water source, a supporting structure, and a hygroscopic material disposed on the supporting structure and configured to generate mechanical force in response to a changing relative humidity. The hygroscopic material can be repeatedly exposed to the high humidity zone and removed from the high humidity zone thereby causing the hygroscopic material to generate mechanical force.

Chen, Xi↗

Dynamic Monitoring of the Ion-Plasma Treatment of Complex Components

Low-temperature ion-plasma treatment of metal workpieces may be monitored in terms of the electrical signals recorded in the circuit consisting of the plasma, the workpiece, the clamp, and ground. The electrical signals are analyzed by means of the Hurst statistic H, which provides a basic quantitative picture of the formation and modification of the signal structure in the course of machining. Experiments show that the best results (a surface layer of maximum hardness) are obtained when machining is accompanied by the generation of signals for which the Hurst statistic indicates antipersistent behavior.

42 ENGINEERING↗

Investigating the Impact of Absorbed Surface Impurities (CO, CO 2 , CH 4 , and H 2 O) on Getter Rate Performance

This report provides an overview of engineering and experimental efforts to establish a new capability for measuring H2 uptake rates for Tritium Producing Abosrber Rod (TPBAR) getter materials. This new system was used to gain a better understanding of the impact of contaminant species (CO 2 , CO, CH 4 , and H 2 O) on getter performance under relevant hydrogen uptake conditions (350 °C, 20 torr). Herein, we successfully established a high-resolution gravimetric sorption (HRGS) system in a flow through configuration that can measure sample mass changes with high resolution (1 µg or 10 µg) over long experiment times (days), high temperature, and varying pressures. We coupled this capability with an in-line universal gas analyzer (UGA) system to characterize potential surface chemistry side reactions occurring after contaminant gas exposure. The major findings of this study suggest that methane and CO have the most detrimental effects on getter H 2 uptake performance showing large changes in rate after exposure compared to CO 2 and water. The effect of these contaminant species did not influence getter sample capacity (~ 1.8 wt% H 2 ). After CO and methane exposure, changes in getter rate were accompanied by observable Ni-surface defects and pinholes via SEM imaging suggesting possible Ni- layer corrosion. Additionally, the increase in C and O signal in the zircaloy layer, observed via EDX, point to C and O species transport through the getter sample resulting in the formation of carbides and oxide species. Thus, co-exposure studies where mixed gases or water vapor are introduced together will be important to further understand what mechanisms are contributing to Ni-layer corrosion and changes in getter performance.

36 MATERIALS SCIENCE↗

Alpha Shape Analysis (ASA) Framework for Post- Clustering Property Determination in Atom Probe Tomographic Data

While application of clustering algorithms to atom probe tomography data have enabled quantification of solute clusters in terms of number density, size, and subcomposition there exist other properties (e.g., volume, surface area, and composition) that are better determined by defining an interface between the cluster and the surrounding matrix. The limitation in composition results from an ion selection step where the expected matrix ion types are omitted from the cluster search algorithm to enhance the contrast between the matrix and cluster and to reduce the complexity of the search. Previously, composition determination within solute clusters has utilized a secondary envelopment and erosion step on top of conventional methods such as maximum separation. In this work, we present a novel stochastic method that combines the particle identification fidelity of a conventional clustering algorithm with the analytical flexibility of mesh-based approaches through the generation of alpha shapes for each identified cluster. Furthermore, the corresponding mesh accounts for concave components of the clusters and determines the volume and surface area of the clusters; additionally, the mesh boundary is utilized to update the total composition according to the internal ions.

42 ENGINEERING↗

Dynamics of a Cylinder with a Displaced Center of Gravity on a Vibrating Base with Dry Friction

Forced vibrations of a cylinder with a displaced center of gravity on a rigid base vibrating horizontally (perpendicular to the generatrix of the cylindrical surface) are investigated. At the contact point between the cylindrical surface and the base, dry friction is assumed. The problem is solved by the Bubnov–Galerkin method. The results are expressed as amplitude–frequency characteristics.

42 ENGINEERING↗

Influence of Ultrasonic Finishing on the Surface Roughness of Ship Components

The influence of plastic deformation by ultrasonic smoothing on the surface roughness of 17Kh18N9 and 20Kh1M1F1TR steel billet in finishing is studied. In the experiments, a D-optimal Hartley–Kono design for four factors is employed. The four factors are the speed of billet rotation, the supply, the clamping force, and the ultrasonic power.

42 ENGINEERING↗

Superacid-Treated Silicon Surfaces: Extending the Limit of Carrier Lifetime for Photovoltaic Applications

Minimizing carrier recombination at interfaces is of extreme importance in the development of high-efficiency photovoltaic devices and for bulk material characterization. Here, we investigate a temporary room temperature superacid-based passivation scheme, which provides surface recombination velocities below 1 cm/s, thus placing our passivation scheme amongst state-of-the-art dielectric films. Application of the technique to high-quality float-zone silicon allows the currently accepted intrinsic carrier lifetime limit to be reached and calls its current parameterization into doubt for 1 Ω·cm n-type wafers. The passivation also enables lifetimes up to 65 ms to be measured in high-resistivity Czochralski silicon, which, to our knowledge, is the highest ever measured in Czochralski-grown material. The passivation strategies developed in this work will help diagnose bulk lifetime degradation under solar cell processing conditions and also help quantify the electronic quality of new passivation schemes.

42 ENGINEERING↗

Radon Considerations at Environmental Remediation Sites - 19469

Radon and how it is regulated poses many challenges to the U.S. Army Corps of Engineers (USACE) in executing the Formerly Utilized Sites Remedial Action Program (FUSRAP). These challenges include:, terminology; radon measurement methods and limitations; state certification and testing requirements; limited and potentially conflicting federal guidance; background considerations; and limited experience regarding application of guidance; among others. These challenges and others are discussed in detail. The FUSRAP Maywood Superfund Site (FMSS) is presented as a case study demonstrating these challenges and considerations to mitigate or address the challenges. The USACE, U.S. Environmental Protection Agency (USEPA), and the New Jersey Department of Environmental Protection (NJDEP) (NJDEP) have spent several years working on and continue to work through the radon issues at FMSS. The FMSS experience, information, and solutions presented in this paper will be helpful to other environmental sites with radium and thorium contamination. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Droplet Evaporation on Hot Micro-Structured Superhydrophobic Surfaces: Analysis of Evaporation from Droplet Cap and Base Surfaces

In this study, evaporation of sessile water droplets on hot micro-structured superhydrophobic surfaces is experimentally and theoretically investigated. Water droplets of 4 µL are placed on micro-pillared silicon substrates with the substrate temperature heated up to 120°C. A comprehensive thermal circuit model is developed to analyze the effects of substrate roughness and substrate temperature on the sessile droplet evaporation. For the first time, two components of heat and mass transfer, i.e., one from the droplet cap surface and the other from the droplet base surface, during droplet evaporation are distinguished and systematically studied. As such, the evaporation heat transfer rates from both the droplet cap surface and the interstitial liquid-vapor interface between micropillars at the droplet base are calculated in various conditions. For droplet evaporation on the heated substrates in the range of 40°C – 80°C, the predicted droplet cap temperature matches well with the experimental results. Furthermore, during the constant contact radius mode of droplet evaporation, the decrease of evaporation rate from the droplet base contributes most to the continuously decreasing overall evaporation heat transfer rate, whereas the decrease of evaporation rate from the droplet cap surface is dominant in the constant contact angle mode. The influence of internal fluid flow is considered for droplet evaporation on substrates heated above 100°C, and an effective thermal conductivity is adopted as a correction factor to account for the effect of convection heat transfer inside the droplet. Temperature differences between the droplet base and the substrate base are estimated to be about 2°C, 5°C, 8°C, 13°C and 18°C for droplet evaporation on substrates heated at 40°C, 60°C, 80°C, 100°C, and 120°C, respectively, elucidating the delayed or depressed boiling of water droplets on a heated rough surface due to evaporative cooling.

42 ENGINEERING↗

Bioinspired nonwetting surfaces for corrosion inhibition over a range of temperature and corrosivity

Applications of superhydrophobic (SHS) and lubricant infused surfaces (LIS) involve exposure to corrosive environments from the acidic to the basic, at a range of temperatures, that are not fully characterized. Here, we present for the first time a multifactorial study of the effects of surface fabrication method, surface modification, surface functionalization time, temperature and pH of the immersion medium on the corrosion performance of nonwetting copper surfaces. Bioinspired SHS and LIS fabricated using facile methods of etching and electrodeposition are systematically assessed using potentiodynamic polarization measurements for their corrosion resistance in saline solution (pH ≈7) over a temperature range 23–85°C. SHS and LIS are shown to exhibit diminished corrosion rate, by up to two orders of magnitude, compared to bare copper surface. An Arrhenius model is developed for the first time, describing the temperature- dependent corrosion rate of SHS and LIS. Electrochemical impedance spectroscopy is used to show that corrosion resistance of LIS is larger by three orders of magnitude in extremely acidic (pH = 1) and by an order magnitude in extremely alkaline (pH = 14) media compared to bare copper surface. Etched LIS are generally more resistant to corrosion compared to SHS at all temperatures with excellent microstructural durability.

42 ENGINEERING↗

Bidirectional reflection of semitransparent polytetrafluoroethylene (PTFE) sheets on a silver film

In our recent work, record-high solar reflectance (exceeding 99%) has been demonstrated by placing a layer of highly scattering, semitransparent polytetrafluoroethylene (PTFE) sheet on top of a silver film. This can significantly improve the performance of daytime radiative cooling system. Although a PTFE slab of 10-mm thick acts as an excellent diffuse reflector, it is unclear how this dual-layer structure made of a thin PTFE on a mirror-like reflector will alter the bidirectional reflection. Here, we report measurements of the bidirectional reflectance distribution function (BRDF) of the dual-layer structure using a laser scatterometer at the wavelength of 635 nm. Measurements of the BRDF and the bidirectional transmittance distribution function (BTDF) of free-standing PTFE sheets are also performed. The measured BRDF for a PTFE sheet as thin as 236 μm on Ag is essentially diffuse except at large incidence angles. A Monte Carlo ray-tracing method incorporating both surface scattering and volumetric scattering is developed to theoretically model the BRDF in order to elucidate the underlying mechanisms. Finally, the numerical model captures the main features and can be used to study the bidirectional properties for PTFE sheets thinner than what is experimentally available.

42 ENGINEERING↗

On estimating the curvature attributes and strain invariants of deformed surface through radial basis functions

Numerical methods in approximation of derivatives on regular or irregular gridded and scattered data points are of significance in the study of numerous problems in engineering and geoscience. A mathematically accurate and stable method is assessed to compute the differential quantities, while being flexible and easy to implement. Strain-invariant parameters in deformation analysis and curvature attributes in geometrical analysis of approximated surfaces are independent quantities which could be derived numerically through radial basis functions (RBFs) for scattered data points. Approximation of a function or its derivatives through RBFs is highly correlated to its shape parameter which depends on the number and distribution of the particles on the support domain. A procedure to find the optimal shape parameter for RBFs in the influence domain of each nodal point together with the presentation of a manner of calculating the curvature attributes and strain parameters through Gaussian RBFs is proposed here. Results indicate a significant improvement in the approximation accuracy of strain parameters and curvature attributes, while this approximation is more stable when RBFs with optimal shape parameter are implemented rather than the traditional moving least squares.

97 MATHEMATICS AND COMPUTING↗