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At least 937 records · Page 52

DISSECTING THE POWER SOURCES OF LOW-LUMINOSITY EMISSION-LINE GALAXY NUCLEI VIA COMPARISON OF HST-STIS AND GROUND-BASED SPECTRA

Using a sample of ∼100 nearby line-emitting galaxy nuclei, we have built the currently definitive atlas of spectroscopic measurements of Hα and neighboring emission lines at subarcsecond scales. We employ these data in a quantitative comparison of the nebular emission in Hubble Space Telescope (HST) and ground-based apertures, which offer an order-of-magnitude difference in contrast, and provide new statistical constraints on the degree to which transition objects and low-ionization nuclear emission-line regions (LINERs) are powered by an accreting black hole at ≲10 pc. We show that while the small-aperture observations clearly resolve the nebular emission, the aperture dependence in the line ratios is generally weak, and this can be explained by gradients in the density of the line-emitting gas: the higher densities in the more nuclear regions potentially flatten the excitation gradients, suppressing the forbidden emission. The transition objects show a threefold increase in the incidence of broad Hα emission in the high-resolution data, as well as the strongest density gradients, supporting the composite model for these systems as accreting sources surrounded by star-forming activity. The narrow-line LINERs appear to be the weaker counterparts of the Type 1 LINERs, where the low accretion rates cause the disappearance of the broad-line component. The enhanced sensitivity of the HST observations reveals a 30% increase in the incidence of accretion-powered systems at z ≈ 0. A comparison of the strength of the broad-line emission detected at different epochs implies potential broad-line variability on a decade-long timescale, with at least a factor of three in amplitude.

79 ASTRONOMY AND ASTROPHYSICS↗

Multi-seasonal measurements of the ground-level atmospheric ice-nucleating particle abundance on the North Slope of Alaska

Atmospheric ice-nucleating particles (INPs) are an important subset of aerosol particles that are responsible for the heterogeneous formation of ice crystals. INPs modulate the arctic cloud phase (liquid vs. ice), resulting in implications for radiative feedbacks. The number of arctic INP studies investigating specific INP episodes or sources increased recently. However, existing studies are based on short-duration field data, and long-term datasets are lacking. Continuous, long-term measurements are key to determining the abundance and variability of ambient arctic INPs and constraining aerosol–cloud interactions, e.g., to verify and/or improve simulations of mixed-phase clouds. Here, we present a new long-duration INP dataset from the Arctic: 2 years of predominantly immersion-mode INP concentrations (n INP ) measured continuously at the National Oceanic and Atmospheric Administration's Barrow Atmospheric Baseline Observatory (BRW) on the North Slope of Alaska. A portable ice nucleation experiment chamber (PINE-03), which simulates adiabatic expansion cooling, was used to directly measure the ground-level INP abundance with an approximately 12 min time resolution from October 2021 to December 2023. We document PINE-03 n INP measurements as well as estimated ice nucleation active surface site density (n s ) over a wide range of heterogeneous freezing temperatures from −16 to −31 °C from which we introduce new season-specific parameterizations suitable for modeling mixed-phase clouds. Collocated aerosol and meteorological data were analyzed to assess the correlation between ambient n INP , air mass origin region, and meteorological variability. Our findings suggest (1) very high freezing efficiency of INPs across the measured temperatures (n s ≈ 2×10 8 –10 10 m −2 for −16 to −31 °C), which is a factor of 10–1000 times greater efficiency as compared to that found in the previous mid-latitude INP measurements in fall using the same instrument; (2) surprisingly high n INP (≥ 1 L −1 at −25 °C) for the examined temperatures throughout the year that were not measured by PINE-03 at other sites; and (3) high n INP in spring, possibly related to arctic haze episodes. Relatively low concentrations of aerosol surface area and contrasting high-INP concentrations at BRW relative to mid-latitude sites are the possible reasons for the observed high freezing efficiency.

54 ENVIRONMENTAL SCIENCES↗

Effective field theory of dissipative fluids

We develop an effctive fi eld theory for dissipative fluids which governs the dynamics of long-lived gapless modes associated with conserved quantities. The resulting theory gives a path integral formulation of fluctuating hydrodynamics which systematically incorporates nonlinear interactions of noises. The dynamical variables are mappings between a "fluid spacetime" and the physical spacetime and an essential aspect of our formulation is to identify the appropriate symmetries in the fluid spacetime. The theory applies to nonlinear disturbances around a general density matrix. For a thermal density matrix, we require an additional Z2 symmetry, to which we refer as the local KMS condition. This leads to the standard constraints of hydrodynamics, as well as a nonlinear generalization of the Onsager relations. It also leads to an emergent supersymmetry in the classical statistical regime, and a higher derivative deformation of supersymmetry in the full quantum regime.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Mechanical vulnerability and resistance to snapping and uprooting for Central Amazon tree species

We report high descending winds generated by convective storms are a frequent and a major source of tree mortality disturbance events in the Amazon, affecting forest structure and diversity across a variety of scales, and more frequently observed in western and central portions of the basin. Soil texture in the Central Amazon also varies significantly with elevation along a topographic gradient, with decreasing clay content on plateaus, slopes and valleys respectively. In this study we investigated the critical turning moments ( M crit - rotational force at the moment of tree failure, an indicator of tree stability or wind resistance) of 60 trees, ranging from 19.0 to 41.1 cm in diameter at breast height ( DBH ) and located in different topographic positions, and for different species, using a cable-winch load-cell system. Our approach used torque as a measure of tree failure to the point of snapping or uprooting. This approach provides a better understanding of the mechanical forces required to topple trees in tropical forests, and will inform models of wind throw disturbance. Across the topographic positions, size controlled variation in M crit was quantified for cardeiro ( Scleronema mincranthum (Ducke) Ducke), mata-matá ( Eschweilera spp.), and a random selection of trees from 19 other species. Our analysis of M crit revealed that tree resistance to failure increased with size (DBH and ABG) and differed among species. No effects of topography or failure mode were found for the species either separately or pooled. For the random species, total variance in M crit explained by tree size metrics increased from an R 2 of 0.49 for DBH alone, to 0.68 when both DBH and stem fresh wood density (SWD) were included in a multiple regression model. This mechanistic approach allows the comparison of tree vulnerability induced by wind damage across ecosystems, and facilitates the use of forest structural information in ecosystem models that include variable resistance of trees to mortality inducing factors. Furthermore, our results indicate that observed topographic differences in wind throw vulnerability are likely due to elevational differences in wind velocities, rather than by differences in soil-related factors that might effect M crit .

54 ENVIRONMENTAL SCIENCES↗

Cooperativity and Metal–Linker Dynamics in Spin Crossover Framework Fe(1,2,3-triazolate) 2

Cooperative interactions are responsible for the useful properties of spin crossover (SCO) materials–large hysteresis windows, critical temperatures near room temperature, and abrupt transitions–with hybrid framework materials exhibiting the greatest cooperativity and hysteresis of all SCO systems. However, little is known about the chemical origin of cooperativity in frameworks. Here, we present a combined experimental–computational approach for identifying the origin of cooperativity in the metal–organic framework (MOF) Fe(1,2,3-triazolate) 2 (Fe(TA) 2 ), which exhibits the largest known hysteresis window of all SCO materials and unusually high transition temperatures, as a roadmap for understanding the manipulation of SCO behavior in general. Variable-temperature vibrational spectroscopy provides evidence that “soft modes” associated with dynamic metal–linker bonding trigger the cooperative SCO transition. Thermodynamic analysis also confirms a cooperativity magnitude much larger than those of other SCO systems, while electron density calculations of Fe(TA) 2 support previous theoretical predictions that large cooperativity arises in materials where SCO produces considerable differences in metal–ligand bond polarities between different spin states. Taken together, this combined experimental–computational study provides a microscopic basis for understanding cooperative magnetism and highlights the important role of dynamic bonding in the functional behavior of framework materials.

36 MATERIALS SCIENCE↗

Correlating Mechanical Sensitivity with Spin Transition in the Explosive Spin Crossover Complex [Fe(Htrz) 3 ] n [ClO 4 ] 2 n

Spin crossover complexes are known to undergo bond length, volume, and enthalpy changes during spin transition. In an explosive spin crossover complex, these changes could affect the mechanical and initiation sensitivity of the explosive and lead to the development of a new class of sensitivity switchable materials. To explore this relationship, the well-known spin crossover compound [Fe(Htrz) 3 ] n [ClO 4 ] 2n (1) was re-evaluated for its explosive properties, and its mechanical impact sensitivity was correlated to spin transition. A variable temperature impact test was developed and used to evaluate the impact sensitivity of 1 in the low spin (LS, S = 0), thermally accessed high spin (HS, S = 2), and mixed LS and HS states. For comparison, the structurally similar Ni compound, [Ni(Htrz) 3 ] n [ClO 4 ] 2n (2), which does not undergo a spin transition at accessible temperatures, was synthesized and characterized, and its explosive properties and variable temperature impact sensitivity measured. These results reveal a correlation between impact sensitivity and spin transition, where 1 exhibits lower impact sensitivity in the LS state and increases in sensitivity upon transition to the HS state. Here, density functional theory was used to predict structural changes that occur upon spin transition that correlate to the change in sensitivity. This demonstrates, for the first time, an explosive spin crossover compound (ExSCO) that exhibits switchable impact sensitivity with a fully reversible internal switching mechanism.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Divertor turbulent transport in the single null and snowflake in the TCV tokamak

The relative importance of divertor radial turbulent particle fluxes is considered by comparing it against the fluxes in the main-chamber outer midplane (OMP) in a variety of conditions and divertor geometries in the tokamak à configuration variable. Within the first power falloff length, the radial turbulent fluxes in the leg of the outer divertor are consistently found to be small, and about 1/5th the magnitude measured at the OMP. In a low-density single null divertor, magnetic shear is found to play a strong role in isolating the main-chamber turbulence from the divertor. The snowflake divertor is purported to have turbulence-enhancing properties in the volume between the two X-points but was instead found to further reduce the divertor turbulent fluxes compared to the single null. Depending on the collisionality, the electric field fluctuations and radial turbulent fluxes were higher near the X-point than at the outer midplane, which is likely due to the binormal compression of the flux bundles consistent with analytical models of the resistive X-point mode. Density and potential fluctuation amplitudes decrease monotonically with distance from the OMP with a slope that depends on collisionality.

Physics↗

Geometric and Material Variability Influences Stress States Relevant to Coastal Permafrost Bluff Failure

Scientific knowledge and engineering tools for predicting coastal erosion are largely confined to temperate climate zones that are dominated by non-cohesive sediments. The pattern of erosion exhibited by the ice-bonded permafrost bluffs in Arctic Alaska, however, is not well-explained by these tools. Investigation of the oceanographic, thermal, and mechanical processes that are relevant to permafrost bluff failure along Arctic coastlines is needed. We conducted physics-based numerical simulations of mechanical response that focus on the impact of geometric and material variability on permafrost bluff stress states for a coastal setting in Arctic Alaska that is prone to toppling mode block failure. Our three-dimensional geomechanical boundary-value problems output static realizations of compressive and tensile stresses. We use these results to quantify variability in the loci of potential instability. We observe that niche dimension affects the location and magnitude of the simulated maximum tensile stress more strongly than the bluff height, ice wedge polygon size, ice wedge geometry, bulk density, Young's Modulus, and Poisson's Ratio. Our simulations indicate that variations in niche dimension can produce radically different potential failure areas and that even relatively shallow vertical cracks can concentrate displacement within ice-bonded permafrost bluffs. These findings suggest that stability assessment approaches, for which the geometry of the failure plane is delineated a priori, may not be ideal for coastlines similar to our study area and could hamper predictions of erosion rates and nearshore sediment/biogeochemical loading.

54 ENVIRONMENTAL SCIENCES↗

Uncertainty and Sensitivity Analysis of TREAT Transient Test #15

The U.S. Department of Energy (DOE) is preparing for the resumption of transient testing using the Transient Reactor Test Facility (TREAT) located at the Idaho National Laboratory (INL). In order to support the analysis of TREAT operation and experiment planning, the MAMMOTH reactor physics team has recently begun development of uncertainty and sensitivity analysis for the TREAT core simulated via MAMMOTH. MAMMOTH is a high-fidelity three-dimensional transient multi-physics code developed at INL under the DOE-NE Advanced Modeling and Simulation program (NEAMS) [1]. This research is part of the development presenting some initial uncertainty and sensitivity analysis of TREAT Transient Test #15 [2]. In this summary, we employ the Sobol sampling strategy implemented in RAVEN [3] to efficiently perform the sensitivity and uncertainty analysis. The idea is using Sobol functional decomposition with generalized polynomial chaos (gPC) expansions to estimate the responses of interest [4]. The gPC coefficients are then computed via the spectral projection method with sparse grid approach. In addition, this strategy includes evaluation of the second or higher order sensitivity indices, allowing the study of interactions between several input variables. The principal focus of this analysis is to quantify the uncertainties in the total power and maximum fuel temperatures with respect to uncertainties in the initial transient conditions, such as rated power, fuel temperature, graphite fuel density and control rod boron concentration. In addition, both the first order and second order time-dependent sensitivity indices are computed and analyzed. The results show that the interactions between initial control rod boron concentration and the rated power will contribute at most 1% to the total uncertainty of the power peak.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Uncertainty and Sensitivity Analysis of TREAT Transient Test no. 15

The U.S. Department of Energy (DOE) is preparing for the resumption of transient testing using the Transient Reactor Test Facility (TREAT) located at the Idaho National Laboratory (INL). In order to support the analysis of TREAT operation and experiment planning, the MAMMOTH reactor physics team has recently begun development of uncertainty and sensitivity analysis for the TREAT core simulated via MAMMOTH. MAMMOTH is a high-fidelity three-dimensional transient multi-physics code developed at INL under the DOE-NE Advanced Modeling and Simulation program (NEAMS). This research is part of the development presenting some initial uncertainty and sensitivity analysis of TREAT Transient Test no. 15. In this summary, we employ the Sobol sampling strategy implemented in RAVEN to efficiently perform the sensitivity and uncertainty analysis. The idea is using Sobol functional decomposition with generalized polynomial chaos (gPC) expansions to estimate the responses of interest. The gPC coefficients are then computed via the sparse grid spectral projection method. In addition, this strategy includes evaluation of the second or higher order sensitivity indices, allowing the study of interactions between several input variables. The principal focus of this analysis is to quantify the uncertainties in the total power and maximum fuel temperatures with respect to uncertainties in the initial transient conditions, such as rated power, fuel temperature, graphite fuel density and control rod boron concentration. In addition, both the first order and second order time-dependent sensitivity indices are computed and analyzed. The results show that the interactions between initial control rod boron concentration and the rated power will contribute at most 1% to the total uncertainty of the power peak.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Variable Grid Method

NETL’s Variable Grid Method (VGM) is a novel approach that leverages GIS capabilities to simultaneously visualize and quantify spatial data trends and underlying data uncertainty. The flexible VGM approach utilizes a range of spatial datasets and uncertainty quantifications, which can be calculated using data related to sample density, sample variance, interpolation error, multiple simulations, etc., to create an integrated visualization of data and uncertainty. The intuitive manner of the VGM helps communicate the relationship between uncertainty and spatial data to effectively guide research, support advanced computation analyses, and helps inform research, management and policy decisions. The VGM approach is being developed into a standalone tool designed to integrate into a variety of research workflows, providing users the capabilities to utilize the VGM for their datasets, analysis, and models in support of their decision making needs. The VGM approach was developed as part of NETL’s Offshore portfolio. It was further matured and utilized in projects associated with both NETL’s Unconventional Resources and Carbon Storage portfolios, and is now being further developed by Varigrid, LLC.

Carbon Storage↗

Extinction in the Star Cluster SAI 113 and Galactic Structure in Carina

Photometric CCD UB VI {sub C} photometry obtained for 4860 stars surrounding the embedded southern cluster SAI 113 (Skiff 8) is used to examine the reddening in the field and derive the distance to the cluster and nearby van Genderen 1. Spectroscopic color excesses for bright cluster stars, photometric reddenings for A3 dwarfs, and dereddening of cluster stars imply that the reddening and extinction laws match results derived for other young clusters in Carina: E{sub U-B}/E{sub B-V}≃0.64 and R{sub V}≃4. SAI 113 displays features that may be linked to a history of dynamical interactions among member stars: possible circumstellar reddening and rapid rotation of late B-type members, ringlike features in star density, and a compact core, with most stars distributed randomly across the field. The group van Genderen 1 resembles a stellar asterism, with potential members distributed randomly across the field. Distances of 3.90 ± 0.19 kpc and 2.49 ± 0.09 kpc are derived for SAI 113 and van Genderen 1, respectively, with variable reddenings E{sub B-V} ranging from 0.84 to 1.29 and 0.23 to 1.28. The SRC variables CK Car and EV Car may be outlying members of van Genderen 1, thereby of use for calibrating the period–luminosity relation for pulsating M supergiants. More importantly, the anomalous reddening and extinction evident in Carina and nearby regions of the Galactic plane in the fourth quadrant impact the mapping of spiral structure from young open clusters. The distribution of spiral arms in the fourth quadrant may be significantly different from how it is often portrayed.

79 ASTRONOMY AND ASTROPHYSICS↗

Assessment of the baseline scenario at q 95 ~ 3 for ITER

The International Tokamak Physics Activity topical group on integrated operational scenarios has compiled a database of stationary H-mode discharges at q 95 ~ 3 from AUG, C-Mod, DIII-D, JET and JT-60U, for both carbon wall and high-Z metal wall experiments with ~3300 entries. The analyses focus on discharges that are stationary for ≥5 thermal energy confinement times to evaluate the baseline scenario proposed for ITER at 15 MA for achieving its goals of Q = 10, fusion power of 500 MW at normalized pressure, β N = 1.8 and normalized confinement as predicted by the standard H-mode scaling, H 98y2 = 1. With the data restricted to stationary H-modes at q 95 ~ 3, the database shows significant variation of thermal energy confinement compared to the standard H-mode scaling (IPB98(y,2)) in dimensionless form. The data show similar scaling with normalized gyro-radius, but more favorable scaling towards lower collision frequency and more favorable scaling with plasma beta. Using all the engineering variables employed in IPB98(y,2), results in an overfit due to correlations among the data. Furthermore, there are significant residual trends in the confinement for plasma current, device size, loss power, and in particular for the plasma density. Significant differences between results obtained for devices with a carbon wall and high-Z metal wall are observed in the data, with data from carbon wall devices providing a larger operating space, encompassing ITER parameters or even exceeding them. H-modes in high-Z metal wall devices have, so-far, not accessed conditions at low collision frequencies, have lower normalized confinement (H 98y2 ~ 0.8–0.9) at low input power or beta, achieving H 98y2 ~ 1.0 only at input powers two times the L- to H-mode transition scaling predictions and at β N ~ 2.0. Hence, only the best H-modes with high-Z metal walls reach ITER baseline performance requirements.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

TCAD-Machine Learning Enabled TID Compact Model Development for Commercial SiC MOSFET

We propose a TCAD (Technology Computer Aided Design)-machine learning coupled approach that combines a TCAD tool (Charon), optimization/uncertainty quantification tool (Dakota), surrogate models, and Bayesian learning capabilities. The coupling approach is used for accurate modeling and calibration of total ionizing dose (TID) induced threshold voltage (V th ) shifts in Commercial-Off-The-Shelf (COTS) semiconductor devices and to develop physics-informed TID compact models. This versatile approach is applied to model the TID effect in an exemplar COTS 3.3 kV SiC power MOSFET (Metal-Oxide-Semiconductor Field-Effect Transistor). With the Charon-Dakota coupling, we can determine key device geometry and doping values based on device physics, which are difficult to obtain or not available for COTS devices but important for TCAD simulation; additionally, we can efficiently generate thousands of simulation results in a large parameter space, which makes it possible to develop data-driven surrogate models and perform Bayesian calibration. Utilizing the full tool-coupling approach, we achieve calibrated TCAD simulation models that accurately capture the average TID-induced V th shifts behavior with total doses and V th shifts saturation at high doses as observed in experimental data. More importantly, the calibrated TCAD simulations are obtained with determined TID model parameters (e.g., hole trap density and capture cross section) values that contain well quantified uncertainties. Furthermore, we can isolate and quantify the noises that are not captured by the TCAD models but exist in the measured data due to measurements and devices variabilities. Lastly, the calibrated surrogate models are used to develop physics-informed TID compact models. The method is generalizable to other devices and/or radiation conditions with few modifications and can provide well-determined uncertainties.

COTS↗

Opacity: A window into High Energy Density Plasma Physics

Opacity is a fundamental property of matter and knowledge of it is required to understand the transport of radiation through a material. Exact knowledge of opacity is crucial in many fields such as astrophysics, which recently produced a white paper on the current state of astrophysical opacities [1], plasma physics, including inertial confinement fusion (ICF) and magnetic confinement fusion, high energy density physics (HEDP), the semiconductor industry [2] and stockpile stewardship. In industry, the accurate knowledge of the opacity of tin is important for extreme ultraviolet (EUV) lithography and the development of processors with smaller components. In astrophysics, Cepheid variable stars are used as “standard candles” for determining the distance to objects. Opacities of these stars are required to understand the relationship between their periodicity, luminosity and distance. Our sun is the most studied star and provides the basis of our understanding for other stars. Yet in significant ways the sun is poorly understood. In recent years, there has been a debate over the abundances of heavy elements (Z > 2) in the solar interior. Current solar atmosphere models [3] find a significantly lower abundance for C, N, and O compared to models used roughly a decade ago. Although solar evolution models have matured, a discrepancy still exists between spectroscopic solar models (which require opacities) with updated abundances, and solar properties inferred from helioseismology and neutrinos [4]. Despite its necessity, opacity is not solved, and is an open and active area of research needed for improving our understanding of plasma physics.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Integrating Contaminant Source Indicators, Water Quality Measures, and Ecotoxicity to Characterize Contaminant Mixtures and Per- and Polyfluoroalkyl Substance (PFAS) Variability in an Urban Watershed

Thousands of chemical contaminants threaten watersheds but are time and cost prohibitive to monitor. Identifying their sources, transport, and ecological risk is limited in heterogeneous urban watersheds. We present an integrative watershed approach using source-specific indicator compounds, common water quality measures, and ecotoxicity assays to examine the distribution of contaminant mixtures in an urbanized watershed. Indicator compound concentrations were temporally and spatially distributed for treated/untreated sewage (sucralose, artificial sweetener), road runoff (diphenyl-guanidine [DPG] and 6PPD-quinone [6PPD-Q], automobile tire additives), and lawncare runoff (aminomethanephosphonic acid (AMPA), major degradant of the herbicide glyphosate). Sucralose was predominately sourced from treated wastewater; measurable concentrations in tributaries indicated raw sewage inputs. DPG and 6PPD-Q concentrations correlated to road density during base flow and were elevated during stormflow. AMPA was measurable spring through fall, especially where lawns were dense. When specific sources dominated flow, water quality measures correlated with wastewater (sulfate, potassium, chloride, and sodium) and road runoff (chromium and lead) indicators. The limited behavioral toxicity observed in exposed zebrafish (Danio rerio) (18%) was not well explained by source-indicators. PFAS concentrations were highly variable spatially but not well explained by our source-specific indicator compounds. Here, more costly compound-specific monitoring may be necessary when multiple sources exist or when unexpected toxicity trends occur.

computer simulations↗

Toward a Theory of the Evolution of Perturbations of the Dark Matter Density in the Very Early Universe

We investigate the influence of primordial baryonic matter in the form of cosmic plasma on the evolution of perturbations in dark matter considered as a gas of weakly interacting massive particles (WIMPs). Nonstationary equations of state of the WIMP gas for both its ideal model and its real model are proposed along with the state parameter of the gas in the form of a power-law dependence on time. A description of the appearance in the WIMP gas of seed perturbations is given which takes account of the influence of the primordial cosmic plasma and the variability of the state parameter of dark matter. Regimes of the evolution of perturbations of non-baryonic matter are found, describing their growth for various characteristics of the internal energy of the WIMP gas. The size and mass of the seed perturbations in the WIMP gas are estimated.

79 ASTRONOMY AND ASTROPHYSICS↗